《金屬卡賓的反應以及合成研究》是王劍波為項目負責人，北京大學為依託單位的重點項目。
基本介紹
- 中文名：金屬卡賓的反應以及合成研究
- 外文名：Reaction and Synthesis of Metal Valery Karpin
- 項目類別 ：重點項目
- 項目負責人：王劍波
- 依託單位 ：北京大學
科研成果,項目摘要,
科研成果
序號 | 標題 | 類型 | 作者 |
|---|---|---|---|
1 | 碳龍化學研究 | 科研獎勵 | 夏海平(#) |
2 | Palladium(0)-Catalyzed C(sp3)-Si Bond Formation via Formal Carbene Insertion into Si-H Bond | 期刊論文 | Zhenxing Liu; Jingfeng Huo; Tianren Fu; Haocheng Tan; Fei Ye; Mohammad Lokman Hossain; Jianbo Wang(*) |
3 | RhI-Catalyzed Stille-Type Coupling of Diazoesters with Aryl Trimethylstannanes | 期刊論文 | Liu, Zhen(#); Xia, Ying; Feng, Sheng; Wang, Shuai; Qiu, Di; Zhang, Yan; Wang, Jianbo(*) |
4 | Rhodium(I)-Catalyzed Sequential C(sp)-C(sp3) and C(sp3)-C(sp3) Bond Formation through Migratory Carbene Insertion | 期刊論文 | Ying Xia(#); Sheng Feng; Zhen Liu; Yan Zhang; Jianbo Wang(*) |
5 | Conversion of Aromatic Amino into Trifluoromethyl Groups through a Sandmeyer-Type Transformation | 期刊論文 | Wang, Xi(#); Xu, Yan; Zhou, Yujing; Zhang, Yan; Wang, Jianbo(*) |
6 | Cu(I)-catalyzed coupling of diaryldiazomethanes with terminal alkynes: an efficient synthesis of tri-aryl-substituted allenes | 期刊論文 | Chenggui Wu(#); Fangdong Hu; Zhenxing Liu; Guisheng Deng(*); Fei Ye; Yan Zhang; Jianbo Wang(*) |
7 | Metallapentalenofurans and Lactone-Fused Metallapentalynes | 期刊論文 | Zhengyu Lu(#); Congqing Zhu(#); Yuanting Cai; Jun Zhu; Yuhui Hua; Zhixin Chen; Jiangxi Chen(*); Haiping Xia(*) |
8 | Palladium-catalyzed cross-coupling of aryl fluorides with N-tosylhydrazones via C-F bond activation | 期刊論文 | Haiqing Luo(#); Guojiao Wu; Shuai Xu; Kang Wang; Chaoqiang Wu; Yan Zhang; Jianbo Wang(*) |
9 | Synthesis of alpha-Aryl Esters and Nitriles: Deaminative Coupling of alpha-Aminoesters and alpha-Aminoacetonitriles with Arylboronic Acids | 期刊論文 | Guojiao Wu(#); Yifan Deng; Chaoqiang Wu; Yan Zhang; Jianbo Wang(*) |
10 | Ir(III)-Catalyzed Aromatic C−H Bond Functionalization via Metal Carbene Migratory Insertion | 期刊論文 | Ying Xia(#); Zhen Liu; Sheng Feng; Yan Zhang,; Jianbo Wang(*) |
11 | Catalyst-free cross-coupling of N-tosylhydrazones with chromium(0) Fischer carbene complexes: A new approach to diarylethanone | 期刊論文 | Fangdong Hu(#); Jinghui Yang; Ying Xia; Chen Ma; Haiping Xia; Yan Zhang; Jianbo Wang(*) |
12 | Rh(I)-Catalyzed Reaction of Trifluoromethylketone N-Tosylhydrazones and Arylboronates | 期刊論文 | Zhang, Zhikun(#); Yu, Weizhi; Zhou, Qi; Li, Tianjiao; Zhang, Yan; Wang, Jianbo(*) |
13 | Palladium-Catalyzed Oxygenative Cross-Coupling of Ynamides and Benzyl Bromides via Carbene Migratory Insertion | 期刊論文 | Yunpeng Gao(#); Guojiao Wu; Qi Zhou; Jianbo Wang(*) |
14 | Palladium-Catalyzed Carbene Migratory Insertion Using Conjugated Ene-Yne-Ketones as Carbene Precursors | 期刊論文 | Xia, Ying(#); Qu, Shuanglin(#); Xiao, Qing(#); Wang, Zhi-Xiang(*); Qu, Peiyuan; Chen, Li; Liu, Zhen; Tian, Leiming; Huang, Zhongxing; Zhang, Yan; Wang, Jianbo(*) |
15 | Copper(I)-Catalyzed Stereoselective Synthesis of (E)-alpha-Alkynyl-alpha,beta-unsaturated Esters from a Terminal Alkyne, Diazoesters and Aldehydes | 期刊論文 | Wu, Chenggui(#); Liu, Zhenxing; Zhang, Zhikun; Ye, Fei; Deng, Guisheng; Zhang, Yan; Wang, Jianbo(*) |
16 | 金屬橋位稠環化合物及其製備方法和用途 | 專利 | 夏海平(#); 卓慶德; 林劍鋒; 周小茜; 卓凱玥; 何旭敏; 張弘 |
17 | Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes | 期刊論文 | Wen-Dao Chu(#); Lei Zhang; Zhikun Zhang; Qi Zhou; Fanyang Mo; Yan Zhang; Jianbo Wang(*) |
18 | CCCCC Pentadentate Chelates with Planar Möbius Aromaticity and Unique Properties | 期刊論文 | Congqing Zhu(#); Caixia Yang(#); Yongheng Wang; Gan Lin; Yuhui Yang; Xiaoyong Wang; Jun Zhu; Xiaoyuan Chen; Xin Lu(*); Gang Liu(*); Haiping Xia(*) |
19 | Catalytic asymmetric trifluoromethylthiolation via enantioselective [2,3]-sigmatropic rearrangement of sulfonium ylides | 期刊論文 | Zhikun Zhang(#); Zhe Sheng; Weizhi Yu; Guojiao Wu; Rui Zhang; Wen-Dao Chu; Yan Zhang; Jianbo Wang(*) |
20 | Synthesis, Characterization and Electrochemical Properties of 4, 5-Diazafluoren-9-yl or Fluoren-9-yl Terminated Homobimetallic Ruthenium and Osmium Allenylidene, Alkynyl-Allenylidene Complexes | 期刊論文 | Jinbo Huang(#); Xiaoxi Zhou; Qianyi Zhao; Shunhua Li; Haiping Xia(*) |
21 | Regioselective Copper-catalyzed Aminoborylation of Styrenes with Bis(pinacolato)diboron and Diazo Compounds | 期刊論文 | Jingfeng Huo(#); Yazhen Xue; Jianbo Wang(*) |
22 | 1,2-Migration in the reactions of ruthenium vinylcarbene with propargyl alcohols | 期刊論文 | Xiaoxi Zhou(#); Chunhong Zhang; Yumei Lin; Xumin He; Yan Zhang; Jianbo Wang; Haiping Xia(*) |
23 | Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metals | 期刊論文 | Congqing Zhu(#); Haiping Xia(*) |
24 | Cu(I)-Catalyzed Cross-Coupling of Conjugated Ene-yne-ketones and Terminal Alkynes: Synthesis of Furan-Substituted Allenes | 期刊論文 | Hu, Fangdong(#); Xia, Ying; Ma, Chen(*); Zhang, Yan; Wang, Jianbo(*) |
25 | Rh(II)-Catalyzed [2,3]-Sigmatropic Rearrangement of Sulfur Ylides Derived from Cyclopropenes and Sulfides | 期刊論文 | Hang Zhang(#); Bo Wang; Heng Yi; Yan Zhang; Jianbo Wang(*) |
26 | Palladium-Catalyzed [3+3] Annulation of Vinyl Chromium(0) Carbene Complexes via Carbene Migratory Insertion/Tsuji-Trost Reaction | 期刊論文 | Kang Wang(#); Yifan Ping; Taiwei Chang; Jianbo Wang(*) |
27 | 重氮化合物參與的連續流動反應 | 期刊論文 | 郜雲鵬(#); 王劍波(*) |
28 | Zn(II)- or Rh(I)-Catalyzed Rearrangement of Silylated [1,1 '-Bi(cyclopropan)]-2 '-en-1-ols | 期刊論文 | Zhang, Hang(#); Li, Changkun; Xie, Guojun; Wang, Bo; Zhang, Yan; Wang, Jianbo(*) |
29 | Cu(I)-Catalyzed Synthesis of Furan-Substituted Allenes by Use of Conjugated Ene-yne Ketones as Carbene Precursors | 期刊論文 | Hu, Fangdong(#); Xia, Ying; Ma, Chen; Zhang, Yan; Wang, Jianbo(*) |
30 | Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion | 期刊論文 | Wang, Xi(#); Zhou, Yujing; Ji, Guojing; Wu, Guojiao; Li, Ming; Zhang, Yan; Wang, Jianbo(*) |
31 | Alternation of Metal-Bridged Metallacycle Skeletons: From Ruthenapentalyne to Ruthenapentalene and Ruthenaindene Derivative | 期刊論文 | Jinhua Li(#); Huijun Kang; Kaiyue Zhuo; Qingde Zhuo; Hong Zhang; Yu-Mei Lin(*); Haiping Xia(*) |
32 | Rh(I)-catalyzed cross-coupling of α-diazoesters with arylsiloxanes | 期刊論文 | Ying Xia(#); Zhen Liu; Sheng Feng; Fei Ye; Yan Zhang; Jianbo Wang(*) |
33 | A Missing Member of Conjugated N-Heterocycles: Realizing Pyrido[1, 2-α]azepine by Reacting Ruthenium Alkenylcarbene Complex with Alkyne | 期刊論文 | Xiaoxi Zhou(#); Fanping Huang; Chun Tang; Qingde Zhuo; Zhixin Chen; Hong Zhang(*); Haiping Xia(*) |
34 | Synthesis of Trimethylstannyl Arylboronate Compounds by Sandmeyer-Type Transformations and Their Applications in Chemoselective Cross-Coupling Reactions | 期刊論文 | Qiu, Di(#); Wang, Shuai; Tang, Shengbo; Meng, He; Jin, Liang; Mo, Fanyang; Zhang, Yan; Wang, Jianbo(*) |
35 | Palladium-Catalyzed C-H Functionalization of Acyldiazomethane and Tandem Cross-Coupling Reactions | 期刊論文 | Fei Ye(#); Shuanglin Qu; Lei Zhou; Cheng Peng; Chengpeng Wang; Jiajia Cheng; Mohammad Lokman Hossain; Yizhou Liu; Yan Zhang; Zhi-Xiang Wang(*); Jianbo Wang(*) |
36 | Cross-Coupling Reactions Involving Metal Carbene: From C=C/C-C Bond Formation to C-H Bond Functionalization | 期刊論文 | Liu, Zhenxing(#); Wang, Jianbo(*) |
37 | Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla-aromatics. | 期刊論文 | Zhu, Congqing(#); Yang, Yuhui; Luo, Ming; Yang, Caixia; Wu, Jingjing; Chen, Lina; Liu, Gang; Wen, Tingbin; Zhu, Jun(*); Xia, Haiping(*) |
38 | Synthesis of Fused Metallaaromatics via Intramolecular C-H Activation of Thiophenes | 期刊論文 | Zhuo, Qingde(#); Zhou, Xiaoxi; Kang, Huijun; Chen, Zhiyong; Yang, Yuhui; Han, Feifei; Zhang, Hong(*); Xia, Haiping(*) |
39 | Rhodium(III)-Catalyzed ortho Alkenylation of N-Phenoxyacetamides with N-Tosylhydrazones or Diazoesters through C-H Activation | 期刊論文 | Fangdong Hu(#); Ying Xia; Fei Ye; Zhenxing Liu; Chen Ma; Yan Zhang; Jianbo Wang(*) |
40 | Synthesis of Aryldiazoacetates through Palladium(0)-Catalyzed Deacylative Cross-Coupling of Aryl Iodides with Acyldiazoacetates | 期刊論文 | Fei Ye(#); Chengpeng Wang; Yan Zhang; Jianbo Wang(*) |
41 | Synthesis of terminal allenes through copper-mediated cross-coupling of ethyne with N-tosylhydrazones or α-diazoesters | 期刊論文 | Ye, Fei(#); Wang, Chengpeng; Ma, Xiaoshen; Hossain, Mohammad Lokman; Xia, Ying; Zhang, Yan; Wang, Jianbo(*) |
42 | Rhodium(III)-Catalyzed Transannulation of Cyclopropenes with N-Phenoxyacetamides through C-H Activation | 期刊論文 | Hang Zhang(#); Kang Wang; Bo Wang; Heng Yi; Fangdong Hu; Changkun Li; Yan Zhang; Jianbo Wang(*) |
43 | Cu(I)-Catalyzed Asymmetric Cross-Coupling of N-Tosylhydrazones and Trialkylsilylethynes: Enantioselective Construction of C(sp)-C(sp3) Bonds | 期刊論文 | Wen-Dao Chu(#); Fangfang Guo; Lefei Yu; Junting Hong; Qianyi Liu; Fanyang Mo; Yan Zhang; Jianbo Wang(*) |
44 | Transition-metal-free intramolecular carbene aromatic substitution/Büchner reaction: Synthesis of fluorenes and [6,5,7]benzo-fused rings | 期刊論文 | Zhenxing Liu(#); Haocheng Tan; Long Wang; Tianren Fu; Ying Xia; Yan Zhang; Jianbo Wang(*) |
45 | Palladium-catalyzed coupling of N-tosylhydrazones and beta-bromostyrene derivatives: new approach to 2H-chromenes | 期刊論文 | Xia, Yamu(#); Xia, Ying; Zhang, Yan; Wang, Jianbo(*) |
46 | Directing group-assisted transition-metal-catalyzed vinylic C-H bond functionalization | 期刊論文 | Wang, Kang(#); Hu, Fangdong; Zhang, Yan; Wang, Jianbo(*) |
47 | m-Metallaphenol: Synthesis and Reactivity Studies | 期刊論文 | Feifei Han(#); Tongdao Wang; Jinhua Li; Hong Zhang(*); Haiping Xia(*) |
48 | Pd-Catalyzed Cross-Coupling of Terminal Alkynes with Chromium(0) Fischer Carbene Complexes | 期刊論文 | Kang Wang(#); Fengjin Wu; Yan Zhang; Jianbo Wang(*) |
49 | Copper(I)-Catalyzed Alkylation of Polyfluoroarenes through Direct C - H Bond Functionalization | 期刊論文 | Shuai Xu(#); Guojiao Wu; Fei Ye; Xi Wang; Huan Li; Xia Zhao; Yan Zhang; Jianbo Wang(*) |
50 | Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five-Membered Rings | 期刊論文 | Congqing Zhu(#); Jingjing Wu; Shenyan Li; Yuhui Yang; Jun Zhu; Xin Lu; Haiping Xia(*) |
51 | Renaissance of Sandmeyer-Type Reactions: Conversion of Aromatic C-N Bonds into C-X Bonds (X = B, Sn, P, CF3) | 期刊論文 | Fanyang Mo(#)(*); Di Qiu; Yan Zhang; Jianbo Wang(*) |
52 | Five-Membered Cyclic Metal Carbyne: Synthesis of Osmapentalynes by the Reactions of Osmapentalene with Allene, Alkyne, and Alkene | 期刊論文 | Zhu, Congqing(#); Yang, Yuhui; Wu, Jingjing; Luo, Ming; Fan, Jinglan; Zhu, Jun(*); Xia, Haiping(*) |
53 | Switchable 2,2,2-Trifluoroethylation and gem-Difluorovinylation of Organoboronic Acids with 2,2,2-Trifluorodiazoethane | 期刊論文 | Wu, Guojiao(#); Deng, Yifan; Wu, Chaoqiang; Wang, Xi; Zhang, Yan; Wang, Jianbo(*) |
54 | Rh(II)- or Cu(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp2)-H Bond: An Access toward Substituted 1H Indenes | 期刊論文 | Qi Zhou(#); Shichao Li; Yan Zhang; Jianbo Wang(*) |
55 | 一種烯基磷酯化合物的製備方法 | 專利 | 王劍波; 周鈺靜; 葉飛; 王兮; 徐帥; 張艷 |
56 | Formal Carbon Insertion of N-Tosylhydrazone into B-B and B-Si Bonds: gem-Diborylation and gem-Silylborylation of sp(3) Carbon | 期刊論文 | Li, Huan(#); Shangguan, Xianghang; Zhang, Zhikun; Huang, Shan; Zhang, Yan; Wang, Jianbo(*) |
57 | Reactions of Cyclic Osmacarbyne with Coinage Metal Complexes | 期刊論文 | Xiaoxi Zhou(#); Yunlong Li; Yifan Shao; Yuhui Hua; Hong Zhang; Yu-Mei Lin(*); Haiping Xia(*) |
58 | sigma-Aromaticity in an unsaturated ring: osmapentalene derivatives containing a metallacyclopropene unit. | 期刊論文 | Zhu, Congqing(#); Zhou, Xiaoxi; Xing, Hongjie; An, Ke; Zhu, Jun(*); Xia, Haiping(*) |
59 | Pd(0)-catalyzed carbene insertion into Si-Si and Sn-Sn bonds | 期刊論文 | Zhenxing Liu(#); Haochen Tan; Tianren Fu; Ying Xia; Di Qiu; Yan Zhang; Jianbo Wang(*) |
60 | 一種金屬橋位稠環化合物及其中間體和製備方法及套用 | 專利 | 夏海平(#); 卓慶德; 林劍鋒; 周小茜; 陳志昕; 邵一凡; 張弘; 何旭敏 |
61 | Cu(I)-Catalyzed Tandem Reaction of Carbene Coupling and Horner-Wadsworth-Emmons Type Olefination: Access toward Enynes | 期刊論文 | Zhou, Yujing(#); Ye, Fei; Zhou, Qi; Zhang, Yan; Wang, Jianbo(*) |
62 | Pd-catalyzed oxidative cross-coupling of alkyl chromium(0) Fischer carbene complexes with organoboronic acids | 期刊論文 | Kang Wang(#); Jinghui Yang; Xingqi Yao; Jianbo Wang(*) |
63 | Multiyne Chains Chelating Osmium via Three Metalcarbon σ Bonds | 期刊論文 | Qingde Zhuo(#); Jianfeng Lin; Yuhui Hua; Xiaoxi Zhou; Yifan Shao; Shiyan Chen; Zhixin Chen; Jun Zhu; Hong Zhang; Haiping Xia(*) |
64 | Conversion of Aromatic Amino into Trifluoromethyl Groups through a Sandmeyer-Type Transformation | 期刊論文 | Wang, Xi(#); Xu, Yan; Zhou, Yujing; Zhang, Yan; Wang, Jianbo(*) |
65 | Planar Mobius aromatic pentalenes incorporating 16 and 18 valence electron osmiums | 期刊論文 | Zhu, Congqing(#); Luo, Ming; Zhu, Qin; Zhu, Jun(*); Schleyer, Paul V. R.; Wu, Judy I-Chia; Lu, Xin; Xia, Haiping(*) |
66 | Construction of All-Carbon Quaternary Centers through Cu-Catalyzed Sequential Carbene Migratory Insertion and Nucleophilic Substitution/Michael Addition | 期刊論文 | Chengpeng Wang(#); Fei Ye; Chenggui Wu; Yan Zhang; Jianbo Wang(*) |
67 | Transition-metal-free three-component reaction of cyclopropenes, aldehydes and amines | 期刊論文 | Hang Zhang(#); Bo Wang; Heng Yi; Tong Sun; Yan Zhang; Jianbo Wang(*) |
68 | Cu(I)-catalyzed reaction of diazo compounds with terminal alkynes: a direct synthesis of trisubstituted furans | 期刊論文 | Hossain, Mohammad Lokman(#); Ye, Fei; Zhang, Yan; Wang, Jianbo(*) |
69 | Oxidative Cross-Coupling of Allenyl Ketones and Organoboronic Acids: Expeditious Synthesis of Highly Substituted Furans | 期刊論文 | Ying Xia(#); Yamu Xia; Rui Ge; Zhen Liu; Qing Xiao; Yan Zhang; Jianbo Wang(*) |
70 | Transition-Metal-Catalyzed Cross-Couplings through Carbene Migratory Insertion | 期刊論文 | Ying Xia(#); Di Qiu; Jianbo Wang(*) |
71 | Palladium-Catalyzed Formal [4+1] Annulation via Metal Carbene Migratory Insertion and C(sp2)-H Bond Functionalization | 期刊論文 | Shuai Xu(#); Ri Chen; Zihao Fu; Qi Zhou; Yan Zhang; Jianbo Wang(*) |
72 | Chain multiyne compound, preparation method and application thereof | 專利 | Haiping Xia(#); Qingde Zhuo; Jianfeng Lin; Xiaoxi Zhou; Zhixin Chen; Yifan Shao; Hong Zhang; Xumin He |
73 | 一種1,3-二取代聯烯化合物的製備方法 | 專利 | 葉飛; 侯塞恩; 馬曉申; 張艷; 王劍波 |
74 | Synthesis of Allenylphosphonates through Cu(I)-Catalyzed Coupling of Terminal Alkynes with Diazophosphonates | 期刊論文 | Wu, Chenggui(#); Ye, Fei; Wu, Guojiao; Xu, Shuai; Deng, Guisheng; Zhang, Yan; Wang, Jianbo(*) |
75 | Recent Advances in Transition-Metal-Catalyzed Cross-Coupling Reactions with N-Tosylhydrazones | 期刊論文 | Di Qiu(#); Fanyang Mo; Yan Zhang; Jianbo Wang(*) |
76 | A Metal-Bridged Tricyclic Aromatic System: Synthesis of Osmium Polycyclic Aromatic Complexes | 期刊論文 | Zhu, Congqing(#); Zhu, Qin; Fan, Jinglan; Zhu, Jun; He, Xumin; Cao, Xiao-Yu(*); Xia, Haiping(*) |
77 | Reactions of OsmiumHydrido Alkenylcarbyne with Allenoates: Insertion and [3 + 2] Annulation. | 期刊論文 | Xiaoxi Zhou(#); Xiehua He; Jianfeng Lin; Qingde Zhuo; Zhixin Chen; Hong Zhang(*); Jianbo Wang; Haiping Xia(*) |
78 | Metallaaromatics Containing Main-Group Heteroatoms | 期刊論文 | Hongjian Wang(#); Xiaoxi Zhou(#); Haiping Xia(*) |
79 | Synthesis of Olefinic Carbolong Complexes | 期刊論文 | Zhengyu Lu(#); Jiangxi Chen; Haiping Xia(*) |
80 | Synthesis, Structure, and Reactivity of an Osmacyclopentene Complex | 期刊論文 | Han, Feifei(#); Wang, Tongdao; Li, Jinhua; Zhang, Hong; Zhang, Laiying; He, Xumin(*); Xia, Haiping(*) |
81 | Pd(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with 2,2′-Dibromobiphenyls: Synthesis of 9H-Fluorenes | 期刊論文 | Xu, Shuai(#); Shangguan, Xianghang; Li, Huan(*); Zhang, Yan; Wang, Jianbo(*) |
82 | C-H bond functionalization based on metal carbene migratory insertion | 期刊論文 | Fangdong Hu(#); Ying Xia; Chen Ma; Yan Zhang; Jianbo Wang(*) |
83 | Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation | 期刊論文 | Wang, Tongdao(#); Han, Feifei; Huang, Haiping; Li, Jinhua; Zhang, Hong(*); Zhu, Jun; Lin, Zhenyang(*); Xia, Haiping(*) |
84 | Palladium(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with Vinyl Bromides and 1,1-Dibromoalkenes | 期刊論文 | Huan Li(#); Zhikun Zhang; Xianghang Shangguan; Shan Huang; Jun Chen; Yan Zhang; Jianbo Wang(*) |
85 | Pd-Catalyzed Cyclization and Carbene Migratory Insertion: New Approach to 3-Vinylindoles and 3-Vinylbenzofurans | 期刊論文 | Liu, Zhenxing(#); Xia, Ying; Zhou, Shiyi; Wang, Long; Zhang, Yan(*); Wang, Jianbo(*) |
86 | Cu(I)-Catalyzed Chemoselective Coupling of Cyclopropanols with Diazo Esters: Ring-Opening C-C Bond Formations | 期刊論文 | Hang Zhang(#); Guojiao Wu(#); Heng Yi; Tong Sun; Bo Wang; Yan Zhang; Guangbin Dong; Jianbo Wang(*) |
87 | Synthesis of Trifluoromethylated Cycloheptatrienes from N-Tosylhydrazones:Transition-Metal-Free Büchner Ring Expansion | 期刊論文 | Zhikun Zhang(#); Jiajie Feng; Yan Xu,; Songnan Zhang; Yuxuan Ye,; Tianjiao Li,; Xi Wang(*); Jun Chen; Yan Zhang; Jianbo Wang(*) |
88 | Constraint of a Ruthenium-Carbon Triple Bond to a Five-Membered Ring | 期刊論文 | Qingde Zhuo(#); Hong Zhang(#); Yuhui Hua; Huijun Kang; Xiaoxi Zhou; Xinlei Lin; Zhixin Chen; Jianfeng Lin; Kaiyue Zhuo; Haiping Xia(*) |
89 | 鏈狀多炔化合物及其製備方法和套用 | 專利 | 夏海平(#); 卓慶德; 林劍鋒; 周小茜; 陳志昕; 邵一凡; 張弘; 何旭敏 |
90 | Synthesis of Cyclic Vinylidene Complexes and Azavinylidene Complexes by Formal [4+2] Cyclization Reactions | 期刊論文 | Chen, Jinxiang(#); Huang, Zi-Ao; Lu, Zhengyu; Zhang, Hong(*); Xia, Haiping(*) |
91 | Rational Design and Synthesis of Unsaturated Se-Containing Osmacycles with σ-Aromaticity | 期刊論文 | Xiaoxi Zhou(#); Jingjing Wu(#); Yulei Hao; Congqing Zhu; Qingde Zhuo; Haiping Xia(*); Jun Zhu(*) |
92 | Synthesis and Characterization of Photothermal Osmium Carbolong Complexes | 期刊論文 | Qin Lin(#); Shenyan Li(#); Jianfeng Lin(#); Meijin Chen; Zhengyu Lu; Chun Tang; Zhixin Chen; Xumin He; Jiangxi Chen(*); Haiping Xia(*) |
93 | Isolation of an Eleven-Atom Polydentate Carbon‐Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne | 期刊論文 | Congqing Zhu(#); Jun Zhu; Xiaoxi Zhou; Qin Zhu; Yuhui Yang; Ting Bin Wen; Haiping Xia(*) |
94 | Synthesis of alpha-Aryl Esters and Nitriles: Deaminative Coupling of alpha-Aminoesters and alpha-Aminoacetonitriles with Arylboronic Acids | 期刊論文 | Wu, Guojiao(#); Deng, Yifan; Wu, Chaoqiang; Zhang, Yan; Wang, Jianbo(*) |
95 | Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion | 期刊論文 | Luo, Ming(#); Zhu, Congqing; Chen, Lina; Zhang, Hong(*); Xia, Haiping(*) |
96 | Palladium-Catalyzed Reductive Cross-Coupling Reaction of Aryl Chromium(0) Fischer Carbene Complexes with Aryl Io-dides | 期刊論文 | Kang Wang; Yu Lu; Yan Zhang; Fangdong Hu; Jinghui Yang; Zhi-Xiang Wang; Jianbo Wang(*) |
97 | Formal Carbene Insertion into C-C Bond: Rh(I)-Catalyzed Reaction of Benzocyclobutenols with Diazoesters | 期刊論文 | Ying Xia(#); Zhenxing Liu; Zhen Liu; Rui Ge; Fei Ye; Mohammad Hossain; Yan Zhang; Jianbo Wang(*) |
98 | 基於卡賓及自由基過程的有機合成新方法 | 科研獎勵 | 王劍波(#); 張艷; 莫凡洋; 王兮; 周磊; 肖卿; 趙霞; 夏瑩; 葉飛; 邱頔 |
99 | Cu(I)-Catalyzed Cross-coupling of Diazo Compounds with Terminal Alkynes: An Efficient Access to Allenes | 期刊論文 | Mohammad Lokman Hossain(#); Jianbo Wang(*) |
100 | Synthesis of Phenanthrenes through Copper-Catalyzed Cross-Coupling of N-Tosylhydrazones with Terminal Alkynes | 期刊論文 | Hossain, Mohammad Lokman(#); Ye, Fei; Liu, Zhenxing; Xia, Ying; Shi, Yi; Zhou, Lei; Zhang, Yan; Wang, Jianbo(*) |
項目摘要
金屬卡賓在金屬有機化學中占有重要的地位，有關金屬卡賓的合成、結構以及反應性的研究一直是金屬有機化學的重要內容。另一方面，經由金屬卡賓的催化反應是一類重要的反應，在有機合成中得到了廣泛的套用。金屬卡賓中間體可以發生烯烴複分解反應，環丙烷化反應，X-H鍵插入反應，形成葉立德以及1，2－遷移反應等。這些多樣的反應性可以通過反應條件，包括金屬催化劑，配體，底物，反應介質等來進行有效的控制。除了這些經典的反應之外，鈀、銅等過渡金屬催化的經由金屬卡賓的交叉偶聯反應也在近年引起關注。這類反應為交叉偶聯以及金屬卡賓拓展了新的方向。基於以上的背景以及我們的研究積累，本項研究將圍繞金屬卡賓展開，主要包括三個方面的內容：（1）基於金屬卡賓以及金屬氮賓插入反應的惰性sp3碳氫鍵的活化；（2）過渡金屬催化的金屬卡賓參與的交叉偶聯反應；（3）鉑族金屬卡賓絡合物的合成、分離、表征及反應性研究。
