趙俊偉,中國科學院福建物質結構研究所博士(2008);河南大學特聘教授,河南省優秀碩士論文指導教師,河南省高等學校青年骨幹教師,河南省教育廳學術技術帶頭人。
基本介紹
- 中文名:趙俊偉
- 國籍:中華人民共和國
- 民族:漢族
- 職業:教師
- 畢業院校:河南大學(本、碩)福建物構所(博)
- 主要成就:首屆中國青少年科技創新獎、寶鋼教育獎
- 職稱:河南大學特聘教授
人物經歷,研究方向,主要貢獻,獲獎記錄,
人物經歷
主要教育經歷:
2005.9-2008.7 中國科學院福建物質結構研究所 無機化學博士;
2010.1-2012.6 河南大學化學博士後流動站 無機化學博士後;
2008.7-2010.10河南大學化學化工學院講師;
2010.10-2014.11 河南大學化學化工學院 副教授。
2014.11-至今 河南大學化學化工學院 教授。
2016.3-至今 河南大學化學化工學院 河南大學特聘教授。
2012.7 河南省高等學校青年骨幹教師。
2015.6河南省教育廳學術技術帶頭人。
2015.11 河南省高校科技創新人才獲得者。
2016.1 河南省科技創新人才傑出青年基金獲得者。
趙俊偉,中國科學院福建物質結構研究所博士(2008);河南大學特聘教授,河南省優秀碩士論文指導教師,河南省高等學校青年骨幹教師,河南省教育廳學術技術帶頭人,河南省高校科技創新人才支持計畫獲得者,河南省科技創新人才傑出青年基金獲得者,雜誌《American Journal of Chemistry and Application》的編輯部成員,《Jacobs Journal of Inorganic Chemistry》的編輯部成員,教育部學位中心抽檢學位論文通訊評議專家,J. Am. Chem. Soc., Chem. Commun., Inorg. Chem.等20多個國際著名學術雜誌的審稿人。
研究方向
主要貢獻
主要在高核過渡金屬簇取代多金屬氧酸鹽合成及相關性能研究、不含孤對電子雜原子多金屬氧酸鹽體系的3d-4f異金屬反應性能的研究、鎢氧簇基材料鐵電性能研究和孤對電子雜原子空間效應調控的多鎢氧簇異金屬材料研究等方面開展工作,相關研究成果在J. Am. Chem. Soc. Chem. Commun., Sci. Rep., Chem. Eur. J., Chem. Asian J., Inorg. Chem., Cryst. Growth Des., Dalton Trans.等國外知名雜誌上發表學術論文100餘篇,被引次數達1400餘次,H因子為20,授權發明專利3項,在審專利3項。參編《無機化學實驗》(化學工業出版社)、《無機及分析化學》(浙江大學出版社)和《實用儀器分析教程》(浙江大學出版社)教材3部。主持國家自然科學面上基金、國家自然科學青年基金、中國博士後特別資助、中國博士後面上基金、河南省科技創新人才傑出青年基金、河南省高校科技創新人才支持計畫、河南省科技廳基礎前沿研究、河南省教育廳自然科學基金、結構化學國家重點實驗室開放基金、河南大學交叉學科培育項目等總計15項。曾榮獲首屆中國青少年科技創新獎、寶鋼教育獎。榮獲河南省自然科學優秀論文獎一等獎2項(第1完成人)、二等獎3項(第1完成人)。榮獲河南省教育廳優秀科技論文一等獎1項(第1完成人)。榮獲河南省教育廳科技成果一等獎(第4完成人)。
承擔項目
1.多核稀土取代含As, Sb, Bi, Se, Te雜原子多鎢氧酸鹽納米簇的設計合成及抗癌活性研究(21571048);
2.有機-無機雜化鎢氧簇基材料的製備、鐵電及磁性研究(21101055);
3.有機功能配體調控的多核稀土離子嵌入的雜多鎢氧簇材料的合成、結構、發光性能及發光機理研究;
4.高核稀土取代多鎢氧酸鹽納米簇合物的設計、製備及抗癌活性研究(16HASTIT001);
5.含孤對電子雜原子的多鎢氧酸鹽3d-4f異金屬磁性材料的設計合成和性能研究(142300410451);
6.雜多鎢氧酸鹽基有機-無機雜化壓電材料的製備及相關性能研究(XXJC20140001);
7.多核稀土取代多鎢氧酸鹽納米簇的設計合成及抗癌活性研究(20160016);
8.多核稀土取代含孤對電子雜原子多鎢氧酸鹽納米簇的設計合成、發光及磁性性能研究;
9.稀土簇與缺位多金屬氧酸鹽簇的組裝化學及相關性能研究(92300410119);
10.雜化鎢氧簇基材料的製備和鐵電磁性研究(2012GGJS-027);
11.有機-無機雜化的過渡金屬取代多鎢氧酸鹽的製備和磁性質研究(2010B150006);
12.有機-無機雜化多鎢氧酸鹽基3d-4f異金屬衍生材料的製備、鐵電及磁性研究(201104392);
13.多金屬氧酸鹽基3d-4f金屬衍生物的合成及螢光磁性研究(20100470996);
14.無機-有機雜化鎢-氧簇基鐵電和磁性材料的製備與性能研究(20120013)。
科研成果
首次提出了金屬-氧簇的缺位位點可以作為結構導向劑誘導第二金屬在缺位位點處聚集成簇的思想,構築了多系列新型高核稀土或過渡金屬-氧簇、簇聚物及空曠骨架材料,並研究了它們的光學、熱學和磁學性質,探討了部分化合物的催化性能,相關研究成果在J. Am. Chem. Soc. Chem. Commun., Chem. Eur. J., Chem. Asian J.; Inorg. Chem. , Cryst. Growth Des., Dalton Trans., CrystEngComm, Eur. J. Inorg. Chem., J. Solid State Chem.等國外知名雜誌上發表學術論文90餘篇。
代表性SCI論文
1. Han Xue,Jun-Wei Zhao*, Rui Pan, Bai-Feng Yang, Guo-Yu Yang*, Hong-Sheng Liu*, Diverse ligand-functionalized mixed-valent hexamanganese sandwiched silicotungstates with single-molecule magnet behavior,Chem. Eur. J.,2016, 22, 12322-12331;
2.Jun-Wei Zhao*, Yan-Zhou Li, Li-Juan Chen, Guo-Yu Yang*, Research progress on polyoxometalate-based transition-metal-rare-earth heterometallic derived materials: synthetic strategies, structural overview and functional applications,Chem. Commun., 2016, 52, 4418-4445;
3.Jun-Wei Zhao*,Hai-Lou Li, Xing Ma, Zhigang Xie*, Li-Juan Chen, Yongsheng Zhu*, Lanthanide-connecting and lone-electron-pair active trigonal-pyramidal-AsO3inductive nanosized poly(polyoxotungstate) aggregates and their anticancer activity,Sci. Rep.,2016,6, 26406;
4. Hailou Li, Yajie Liu, Rui Zheng, Lijuan Chen*,Jun-Wei Zhao*, Guo-Yu Yang*, Trigonal pyramidal {AsO2(OH)} bridging tetra-nuclear rare-earth encapsulated polyoxotungstate aggregates,Inorg. Chem., 2016, 55, 3881-3893;
5. Lei-Lei Li, Gao-Juan Cao,Jun-Wei Zhao*,Huan He, Bai-Feng Yang, Guo-Yu Yang*, Lanthanide germanate cluster organic frameworks based on {Ln8Ge12} clusters: from one-dimensional chains to two-dimensional layers and three-dimensional frameworks,Inorg. Chem.,2016,55,5671-5683;
6. Hailou Li, Wen Yang, Xiuhua Wang, Jianru Ma, Lijuan Chen*,Junwei Zhao*, Self-assembly of a family of isopolytungstates induced by the synergistic action of lanthanoids and pH variation in the process of reaction: syntheses, structures and properties,Cryst. Growth Des., 2016, 16, 108-120;
7. Xing Ma, Hailou Li, Lijuan Chen*,Junwei Zhao*, The main progress over the past decade and future outlook on high-nuclear transition-metal substituted polyoxotungstates: from synthetic strategies, structural features to functional properties,Dalton Trans., 2016, 45, 4935-4960;
8. Jiancai Liu, Jing Yu, Qing Han, Yue Wen, Lijuan Chen*,Junwei Zhao*, First quadruple-glycine bridging mono-lanthanide-substituted borotungstate hybrids,Dalton Trans.,2016, 45, 16471-16484;
9. Jiancai Liu, Qing Han, Lijuan Chen,*Junwei Zhao,*A brief review of the crucial progress on heterometallic polyoxotungstates in the past decade,CrystEngComm,2016, 18, 842-862;
10. Xin-Xiong Li, Wei-Hui Fang,Jun-Wei Zhao*, Guo-Yu Yang*, The first 3-connected SrSi2-type 3D chiral framework constructed from {Ni6PW9} building units,Chem. Eur. J.,2015, 21, 2315-2318;
11. Xiaoqiang Du, Jinli Zhao, Jiaqi Mi, Yong Ding*, Panpan Zhou, Baochun Ma,Junwei Zhao*, Jie Song*, Efficient photocatalytic H2evolution catalyzed by an unprecedented robust molecular semiconductor {Fe11} nanocluster without cocatalysts at neutral conditions,Nano Energy, 2015, 16, 247-255;
12. Xing Ma, Wen Yang, Lijuan Chen*,Junwei Zhao*, Significant developments on rare-earth-containing polyoxometalate chemistry: synthetic strategies, structural diversities and correlative properties, CrystEngComm, 2015, 17, 8175-8197;
13. Ling Huang, Sa-Sa Wang,Jun-Wei Zhao*, Lin Cheng, Guo-Yu Yang*, Synergistic combination of multi-Zrcations and lacunary Keggin germanotungstates leading to a gigantic Zr24-cluster-substitutedpolyoxometalate,J. Am. Chem. Soc.,2014, 136, 7637-7642;
14. Jian Zhou,Jun-Wei Zhao, Qi Wei, Jie Zhang, Guo-Yu Yang*, Two tetra-Cd-substituted vanadogermanate frameworks,J. Am. Chem. Soc., 2014, 136, 5065-5071;
15. Xin-Xiong Li, Wei-Hui Fang,Jun-Wei Zhao*,Guo-Yu Yang*, Hydrothermal combination of trilacunary Dawson phosphotungstates and hexanickel clusters: from an isolated cluster to a 3D framework,Chem.Eur. J.,2014, 20, 17324-17332;
16.Junwei Zhao*, Jing Cao, Yanzhou Li, Jing Zhang, Lijuan Chen*, First tungstoantimonate -based transition-metal-lanthanide heterometallic hybrids functionalized by aminoacid ligands,Cryst. Growth Des.,2014, 14, 6217-6229;
17.Jun-Wei Zhao*, Jing-Li Zhang, Yan-Zhou Li, Jing Cao, Li-Juan Chen*, Novel one-dimensional organic-inorganic polyoxometalate hybrids constructed from heteropolymolybdate units and copper-aminoacid complexes,Cryst. Growth Des.,2014, 14, 1467-1475;
18.Junwei Zhao*,Hailou Li, Yanzhou Li, Chunyang Li, Zhenling Wang, Lijuan Chen*, Rectangle versus square oxalate-connective tetra-lanthanide cluster anchored in lacunary Lindqvist isopolytungstates: syntheses, structures and properties,Cryst. Growth Des., 2014, 14, 5495-5505;
19.Junwei Zhao*,Yanzhou Li, Fan Ji, Jing Yuan, Lijuan Chen, Guoyu Yang*, Syntheses, structures and electrochemical properties of a class of 1-D double chain polyoxotungstate hybrids [H2dap][Cu(dap)2]0.5[Cu(dap)2(H2O)][Ln(H2O)3(α-GeW11O39)]·3H2O,Dalton Trans., 2014, 43, 5694-5706;
20. Yan-Ying Li,Jun-Wei Zhao*, Qi Wei, Bai-Feng Yang,Huan He, Guo-Yu Yang*, Two organic-inorganic Hybrid 3D {P5W30}-based heteropolyoxotungstates with transition-metal/ Ln-carboxylate-Ln connectors,Chem. Asian J.,2014, 9, 858-867。
代表性專利
2.趙俊偉,李明雪,陳利娟,李彥克,張麗枝,二(2-乙醯吡嗪基)硫代縮二氨基脲及其鉍(III)配合物的製備方法及套用,中國授權發明專利,ZL 201210493229.4,2014年9月。
獲獎記錄
1. Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster,河南省第十屆自然科學優秀學術論文一等獎;
2. Two-dimensional extended (4,4)-topological network constructed from tetra-Ni-substituted sandwich-type Keggin polyoxometalate building blocks and Ni-organic cation bridges,河南省第十屆自然科學優秀學術論文一等獎;
3. Hydrothermal syntheses, crystal structures and properties of 0-D, 1-D and 2-D organic–inorganic hybrid borotungstates constructed from Keggin-type heteropolyanion [α-BW12O40],河南省首屆自然科學學術獎—河南省自然科學優秀學術論文二等獎;
4.A combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. Part II: From double cluster, dimer, and tetramer to three-dimensional frameworks,河南省教育廳優秀科技論文一等獎;
5. Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: first 6·8 CdSO4-type 3-D framework built by hexa-Cusandwiched polyoxotungstates,河南省教育廳優秀科技論文一等獎;
6. Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of [{FeFe12(μ3-OH)12(μ4-PO4)4} (B-α-PW9O34)4], 河南省教育廳優秀科技論文一等獎;
7. 雜多陰離子稀土衍生物的合成、結構分析及性質,河南省教育廳科技成果一等獎;
8. Novel polyoxometalate hybrids containing copper-lanthanide heterometallic germanotungstate / lanthanide-germanotungstate fragments,河南省第二屆自然科學學術獎—河南省自然科學優秀學術論文二等獎;
9. Two 1-D multi-nickel substituted arsenotungstate aggregates,河南省第二屆自然科學學術獎—河南省自然科學優秀學術論文二等獎;
10. Two organic–inorganic hybrid 1-D and 3-D polyoxotungstates constructed from hexa-CuII substituted sandwich-type arsenotungstate units,河南省第二屆自然科學學術獎—河南省自然科學優秀學術論文三等獎;
11. 趙俊偉, 史東英, 陳利娟,馬鵬濤,王敬平, Tetrahedral Polyoxometalate Nanoclusters withTetrameric Rare-Earth Cores and Germanotungstate Vertexes, 河南省第三屆自然科學學術獎—河南省自然科學優秀學術論文二等獎;
12. 趙俊偉,李海樓,李彥舟,李春陽,王珍玲,Rectangle versus SquareOxalate-Connective Tetralanthanide Cluster Anchored in Lacunary LindqvistIsopolytungstates: Syntheses, Structures, and Properties,河南省第三屆自然科學學術獎—河南省自然科學優秀學術論文三等獎。