基本介紹
- 中文名：葉保輝
- 出生地：海南文昌
- 畢業院校：中山大學
- 學位/學歷：博士
- 專業方向：功能配合物和超分子化學
- 任職院校：中山大學
人物經歷,講授課程,科研方向,學術成果,科研項目,論著一覽,相關成果,獲獎情況,
人物經歷
1994年畢業於中山大學，獲博士學位；
1994年10月至1997年10月在香港科技大學作博士後；
講授課程
曾講授《無機化學》、《套用無機化學》、《無機化學實驗》、《配位化學》等本科生、研究生課程
科研方向
研究方向：功能配合物和超分子化學。 主要研究興趣：(1) 結構新穎的框架、籠狀配合物設計和合成及在催化和分離方面的套用；(2) 釕、稀土配合物在感測器和光學材料方面的套用
學術成果
科研項目
1. 仿生水解酶的模研究（廣東省自然科學基金，編號021423398）
2. 手性配合物的識別及組裝（教育部，編號31240415001）
3. 金屬卟啉分子篩類雜化材料的合成及性質研究 （廣東省自然科學基金資助，編號031581）
4. 新型金屬卟啉多孔聚合物的合成及性質研究 (國家自然科學資助，編號20371052)
論著一覽
1. Template Trapping and Crystal Structure of the Magic Number (H2O)21Cluster in the Tetrahedral Hole of a Nanoscale Global Ion Packed in a Face-Centered Cubic PatternMan-LiCao, Jin-JiWu, Hao-JunMo,Bao-HuiYe*,J. Am. Chem. Soc.2009,131, 3458-3459.
2. Characterization of a Dinuclear MnV=O Complex and Its Efficient Evolution of O2in the Presence of Water Y. Shimazaki, T. Nagano, H. Takesue,Bao-Hui Ye, F. Tani, Y. Naruta,Angew. Chem. Int. Ed.2004,43, 98-100.
3. Metal-organic Molecular Architectures with 2,2’-Bipyridyl-like and Carboxylate LigandsBao-Hui Ye, Ming-Liang Tong, Xiao-Ming Chen*,Coord. Chem. Rev.2005,249, 545-565.
4. Spontaneous Chiral Resolution ofmer-[CoII(N,N,O-L3)2] Enantiomers Mediated byp-pInteractionsJin-Ji Wu, Man-Li Cao,Bao-Hui Ye*,Chem. Commun., 2010,46, 3687-3689.
5.Interlocking of Molecular Rhombi into a 2D Polyrotaxane Network via p-p Interactions. Crystal Structure of [Cu2(bpa)2(phen)2(H2O)2].2H2O (bpa2- = biphenyl-4,4’-dicarboxylate, phen = 1,10-phenanthroline)Gao-Feng Liu,Bao-Hui Ye, Y.-H. Liu, Xiao-Ming Chen*,Chem. Commun.2002, 1442-1443.
6. Novel Dimanganese(II) Complexes with (m-H2O)(m-OAc)2Bridges. Model for Dimanganese EnzymesBao-HuiYe, T. Mak, I. D. Williams and Xiao-Yuan Li*,Chem. Commun.1997, 1813-1814.
7. Formation of a Novel Tetranuclear Iron(III) Complex with a m4-PO4Bridge from 4-Nitrophenyl PhosphateBao-Hui Ye, Xiao-Yuan Li*, Feng Xue and T. C. W. Mak,Chem. Commun.1997, 2407-2408.
8. Ruthenium(II) 2,2′-Bibenzimidazole Complex as a Second-SphereReceptor for Anions Interaction and Colorimeter Ying Cui, Yan-Li Niu, Man-Li Cao, Ke Wang, Hao-Jun Mo, Yong-Rui Zhong, andBao-Hui Ye*,Inorg. Chem.2008,47, 5616-5624
9. Assembly of a Cubic Nanocage Co8L12and a Hydrogen-Bonded 3D NbONet Based on the [(HCO3)2]2-Synthon and Water Man-Li Cao, Hong-Guo Hao, Wei-Xiong Zhang, andBao-Hui Ye*,Inorg. Chem,2008,47, 8126-8133
10. A Copper(II) Ion-Selective ON-OFF Type Fluoroionophore Based on Zinc Porphyrin-DipyridylaminoYan-Qin Weng, Fan Yue, Yong-Rui Zhong andBao-Hui Ye*,Inorg. Chem.2007,46,7749-7755.
11. Anion Selective Interaction and Colorimeter by An Optical Metalloreceptor Based on Ruthenium(II) 2,2’-Biimidazole. Hydrogen Bonding and Proton Transfer.Ying Cui, Hao-Jun Mo, Jin-Can Chen, Yan-Li Niu, Yong-Rui Zhong, Kang-Cheng Zheng, andBao-Hui Ye*,Inorg. Chem,2007,46,6427-6436
12. In Situ Solvothermal Generation of 1,2,4-Triazolates and Related Compounds from Organonitriles and Hydrazine Hydrate: A Mechanism Study LinCheng, Wei-Xiong Zhang,Bao-Hui Ye*,Jian-Bin Lin,Xiao-Ming Chen*,Inorg. Chem.2007,46, 1135-1143.
13. Pillared-layer Microporous Metal-organic Frameworks Constructed by Robust Hydrogen Bonds. Synthesis, Characterization, Magnetic and Adsorption Properties of 2,2’-Biimidazole and Carboxylate Complexes.Bing-Bing Ding, Yan-Qin Weng, Zong-Wan Mao, C.-K. Lam, Xiao-Ming Chen,Bao-Hui Ye*,Inorg. Chem.2005,44, 8836-8845.
14. Formation of One-dimensional Metal-water Chain Containing Cyclic Water Hexamers,Bao-Hui Ye*, Bing-Bing Ding, Yan-Qin Weng, Xiao-Ming Chen,Inorg. Chem.2004,43, 6866-6868.
15. Synthesis and Structural Characterization of Di- and Tetranuclear Zinc Complexes with Phenolate and Carboxylate Bridges. Correlations between13C NMR Chemical Shifts and Carboxylate Binding ModesBao-Hui Ye*, Xiao-Yuan Li, I. D. Williams, Xiao-Ming Chen,Inorg. Chem.2002,41, 6426-6431.
16. The First Two Aqua-bridged Dimagnesium(II) complexes: Structural Models for Active Sites in Dimetallic HydrolasesBao-Hui Ye, T. Mak, I. D. Willams and Xiao-Yuan Li*,J. Chem. Soc. Dalton Trans.1998, 1935-1936.
17. Mononuclear Nickel Complexes Assembled into Two-dimensional Networks via Hydrogen Bonds andp-pStacking interactionsBao-Hui Ye*, Xiao-Ming Chen, Gen-Qiang Xue and Liang-Nian Ji,J. Chem. Soc. Dalton Trans.1998, 2827-2827.
18. Mono- and Binuclear Ruthenium(II) Complexes Containing a New Asymmetric Ligand 3-Pyrazyl-as-triazino[5,6-f]1,10-phenanthroline: Synthesis, Characterization and DNA-binding PropertiesXiao-Hua Zou,Bao-Hui Ye*, Hong Li, Jing-Gang Liu, Ya Xiong and Liang-Nian Ji,J. Chem. Soc. Dalton Trans.1999, 1423-1428.
19. A Novel Method for the Synthesis of Regiospcicically Sulfonated Porphyrin Monomers and Dimmers,Bao-Hui Ye*, Y. Naruta,Tetrahedron2003,59, 3593-3601.
20. Synthesesand Characterization of Aqua-bridged Dimetallic Complexes, M2(m-H2O)(m-OAc)2(Im)4(OAc)2( M = Mg2+, Mn2+and Ni2+). Structural Models for the Active Sites of Dimetallic HydrolasesBao-Hui Ye*, I. D. Williams, X.-Y. Li,J. Inorg.Biochem.2002,92, 128-136.
相關成果
1994年“黑曲酶發酵生產葡萄糖酸鋅” 獲中國專利局發明專利，1996年3月27日公開，公開號：CN119213A。
獲獎情況
1. 1996年“混配配合物的生物功能、作用機制及其套用探索”1996年獲廣東省自然科學一等獎。（第三完成人）
2. 1998年“金屬酶體系的結構、機制和模擬研究”獲國家教育部科技進步二等獎（基礎類）。（第三完成人）
3. 200年“金屬酶模型化合物的結構、生物功能、作用機制之間規律性” 獲中國高校自然科學二等獎。（第四完成人）
