樊保敏

樊保敏

樊保敏 ,男,二級教授,雲南民族大學化學與環境學院院長,雲南省中青年學術和技術帶頭人、雲南省“萬人計畫”青年拔尖人才,雲南省高校天然源抗癌藥物靶向遞送研發重點實驗室、雲南省高校氘代胺基酸合成與套用工程研究中心負責人,雲南民族大學學術特區建設負責人。

基本介紹

  • 中文名:樊保敏
  • 外文名:BaoMin Fan
  • 國籍中國
  • 民族:漢
  • 出生地:河南滎陽
  • 出生日期:1979年12月
  • 畢業院校:蘭州大學
  • 代表作品:鈀催化芳基乙炔對氧/氮雜苯並降冰片烯開環反應研究.
  • 職稱:雲南民族大學化學與環境學院
  • 職務:院長
人物生平,主要成就,個人成就,

人物生平

樊保敏,博士,二級教授,雲南省中青年學術技術帶頭人、雲南省“萬人計畫”青年拔尖人才。2001年6月本科畢業於蘭州大學,獲理學學士學位;2001年9月至2006年6月,在南開大學周其林院士和蘭州大學塗永強院士指導下從事手性合成方面的學習和研究,獲理學博士學位。2006年8月作為博士後加入香港理工大學陳新滋院士團隊從事不對稱催化方面的研究。2009年7月,加入雲南民族大學從事教學和科研工作,研究領域為不對稱催化、光化學反應、藥物活性分子合成等。 迄今,國家自然科學基金項目已主持完成4項、主持在研1項;主持完成省部級重點項目1項、面上項目1項;主持橫向項目多項.目前,已發表論文近120篇,第一作者、通訊或共同通訊作者論文96篇,其中SCI中科院一區論文26篇、二區論文29篇,包括Angew. Chem. Int. Ed. 2篇,Green Chem. 2篇、Chem. Eur. J.1篇、Org. Lett.14篇、Chem.Comm. 5篇、Org. Chem. Front. 7篇、J. Med. Chem.1篇及Adv. Syn. Catal. 13篇。獲雲南省自然科學獎三等獎一項,排名第一。獲授權中國發明專利19項、美國專利3項;轉讓發明專利3項。

主要成就

2015.02 特聘教授
2016.01 雲南省中青年學術和技術帶頭人
2019.02 雲南省萬人計畫青年拔尖人才
2019.05 雲南省自然科學三等獎

個人成就

一、主持和參加的主要科研項目
[1] 21572198,無水碘化氫的製備及其與α,β-不飽和羰基化合物的不對稱共軛加成反應研究,項目負責人,國家自然科學基金,65萬,2016.01-2019.12。
[2] 21362043,端基炔烴對氧/氮雜苯並降冰片烯的不對稱催化開環反應研究,項目負責人,國家自然科學基金,50萬,2014.01-2017.12。
[3] 21162040,端基炔烴C-H鍵和冰片烯類化合物中C=C雙鍵的不對稱加成反應及其產物的抗癌活性,項目負責人,國家自然科學基金,55萬,2012.01-2015.12。
[4] 20902080,不對稱催化的[2+2]環化反應及其在斑蝥素類抗癌活性分子合成中的套用研究,項目負責人,國家自然科學基金,19萬,2010.01-2012.12。
[5] 2017FA004,氮雜苯並降冰片烯與醇的不對稱開環反應及其在神經活性藥物中的套用研究,項目負責人,雲南省套用基礎研究計畫重點項目,50萬,2017.06-2020.05。
[6] 2012FB170,氧雜苯並冰片烯的不對稱矽氫化反應及其在新型除草劑合成中的套用研究,項目負責人,雲南省套用基礎研究計畫面上項目, 10萬,2012.01-2015.12。
[7] ZD2015012,無水碘化氫溶液的製備及其在碘代有機化合物合成中的套用研究,項目負責人,雲南省教育廳科學研究基金重大專項, 10萬,2015.09-2017.08。
[8] 201505,路易斯酸共催化劑在過渡金屬催化的氧/氮雜苯並冰片烯中的不對稱開環反應研究,項目負責人,元素有機化學國家重點實驗室開放基金項目,3萬, 2015.12-2016.12。
[9] 201302,氧雜苯並降冰片烯與端基炔烴間的新型反應研究,項目負責人,元素有機化學國家重點實驗室開放基金項目,3萬,2013.12-2014.12。
[10] 201206 ,冰片烯類化合物不對稱氫化炔基化反應中手性銠催化劑的開發研究,項目負責人,項目負責人,元素有機化學國家重點實驗室開放基金項目,3萬,2012.12-2013.12。
二、主要發表的學術論文
[1] Ruhima Khan, Jingchao Chen, Baomin Fan*.Versatile Catalytic Reactions of Norbornadiene Derivatives with Alkynes . Adv.Synth.Catal. 2020, DOI:10.1002/adsc.201901494 .
[2] Guangrui Shi, Ruhima Khan, Xuexin Zhang, Yong Yang*, Yong Zhan, Juan Li, Yang Luo, Baomin Fan*. Rhodium-Catalyzed Direct ortho C-H Thiolation of Cyclic N-Sulfonyl Ketimines. Asian J. Org. Chem. 2020, DOI: 10.1002/ajoc.202000017.
[3] Keyang Zhang, Ruhima Khan, Jingchao Chen, Xuexin Zhang, Yang Gao, Yongyun Zhou*, Kangkui Li, Youxian Tian, Baomin Fan*. Directing- Group-Controlled Ring-Opening Addition and Hydroarylation of Oxa/azabenzonorbornadienes with Arenes via C–H Activation. Org. Lett. 2020, 22, 3339-3344.
[4] Jiayan Li,Ronibala Devi Laishram, Jingchao Chen*, Dandan Xu, Guangrui Shi, Haiping Lv, Ruifeng Fan, Baomin Fan*. Regioselective Hydroiodination of Alkynes by the in situ Generated HI. Asian J. Org. Chem. 2020, 9, 73 – 76.
[5] Kangkui Li, Xuexin Zhang, Jingchao Chen*, Yang Gao, Chunhui Yang, Keyang Zhang, Yongyun Zhou, Baomin Fan*. Blue Light Induced Difluoroalkylation of Alkynes and Alkenes . Org. Lett., 2019, 21, 9914-9918 .
[6] Xia Zhang, Jingchao Chen*, Ruhima Khan, Guoli Shen, Zhenxiu He, Yongyun Zhou, Baomin Fan*, Rhodium-Catalyzed Transfer Hydrogenation of Quinoxalines with Water as Hydrogen Source. Org. Biomol. Chem., 2019, 17, 10142–10147 .
[7] Yongyun Zhou, Ruhima Khana, Baomin Fan*, Lijin Xu*, Ruthenium-Catalyzed Selective Reduction of Carboxylic Esters and Carboxamides. Synthesis. 2019, 51, 2491-2505.
[8] Jianxiao Ni, Jingchao Chen, Yongyun Zhou*, Gaowei Wang, Sida Li, Zhenxiu He, Weiqing Sun, Baomin Fan*. Rhodium-Catalyzed Asymmetric [2+2+2] Cycloaddition Reactions of 1,6-Enynes and Oxabenzonorbornadienes. Adv.Synth. Catal., 2019. 361. 3543-3547.
[9] Yang Gao, Xuexin Zhang, Ronibala Devi Laishram,Jingchao Chen*, Kangkui Li, Keyang Zhang, Guangzhi Zeng, Baomin Fan *. Cobalt-Catalyzed Transfer Hydrogenation of α-Ketoesters and N-Cyclicsulfonylimides Using H2O as Hydrogen Source. Adv.Synth. Catal., 2019. 361. 3991-3997.
[10] Xuexin Zhang, Yang Gao, Jingchao Chen*, Ruifeng Fan, Guangrui Shi, Zhenxiu He, Baomin Fan*. Rh(III)-Catalyzed Ring-Opening Addition of Azabenzonorbornadienes with Cyclic N-Sulfony Ketimines via C-H Bond Activation. Adv.Synth. Catal., 2019. 361,4495-4499 .
[11] Sida Li, Ruhima Khan, Xia Zhang, Yong Yang*, Zheting Wang, Yong Zhan, Yuze Dai, Yue-e Liu, Baomin Fan* . One Stone Two Birds: Cobalt Catalyzed in situ Generation of Isocyanate and Benzyl alcohol for the Synthesis of N-aryl Carbamates. Org. Biomol. Chem., 2019, 17, 5891-5896 .
[12] Xuexin Zhang, Jingchao Chen,* Yang Gao, Kangkui Li, Yongyun Zhou, Weiqing Sun, Baomin Fan* .Photocatalyzed Transfer Hydrogenation and Deuteriation of Cyclic N-Sulfonylimines. Org. Chem. Front., 2019, 6, 2410-2414.
[13] Haiping Lv, Ronibala Devi Laishram, Jiayan Li, Yongyun Zhou*, Dandan Xu, Sagar More,Yuze Dai, Baomin Fan*. Photocatalyzed Oxidative Dehydrogenation of Hydrazobenzenes to Azobenzenes. Green Chem., 2019, 21, 4055-4061.
[14] Kangkui Li, Ruhima Khan, Xuexin Zhang, Yang Gao, Yongyun Zhou*, Heng Tan, Jingchao Chen, Baomin Fan *. Cobalt catalyzed stereodivergent semi- Q2 hydrogenation of alkynes using H2O as the hydrogen source. Chem. Commun., 2019, 55, 5663—5666.
[15] Guoli Shen, Ruhima Khan*, Haiping Lv, Yong Yang, Xia Zhang, Yong Zhan,Yongyun Zhou and Baomin Fan*. Palladium/silver co-catalyzed syn-stereoselective asymmetric ring-opening reactions of azabenzonorbornadienes with amides. Org. Chem. Front.,2019, 6, 1423–1427.
[16] Haiping Lv, Ronibala Devi Laishram, Jiayan Li, Guangrui Shi, Weiqing Sun*, Jianbin Xu, Yong Yang,Yang Luo, Baomin Fan*. Nickel(0) catalyzed oxidation of organosilanes to disiloxanes by air as an oxidant. Tetrahedron Letters.2019,60, 971–974.
[17] He Zhenxiu,Zhou Yongyun*,Sun,Weiqing,Fan Ruifeng,Shen,Guoli,Fan Baomin*. Asymmetric Ring Opening Reaction of Oxabenzonorbornadienes With Phenols Promoted By Rhodium/Zinc Complexes. Chin. J. Org. Chem., 2019, 39, 754-760.
[18] Guoli Shen, Jingchao Chen,* Dandan Xu, Xia Zhang, Yongyun Zhou,and Baomin Fan*. Asymmetric Transfer Hydrogenation of Heterobicyclic Alkenes with Water as Hydrogen Source. Org. Lett.,2019, 21, 1364−1367.
[19] Xuexin Zhang, Yang Gao, Ronibala Devi Laishram, Kangkui Li,Yong Yang*, Yong Zhan, Yang Luo,
Baomin Fan *. Pd(II)/Zn co-catalyzed chemo-selectivehydrogenation ofα-methylene-γ-ketocarboxylic acids. Org. Biomol. Chem., 2019, 17, 2174–2181.
[20] Lingling Zou, Weiqing Sun*, Ruhima Khan, Haiping Lv, Heng Tan, Jianbin Xu, Junlin Yin, Baomin Fan*, Palladium Catalyzed Tandem Reaction of Oxabenzonorbornadienes with Anhydrides, Eur. J. Org. Chem., 2019, 746–752.
[21] GuoliShen, Ruhima Khan, Fan Yang, Yong Yang,* DongdongPu, Yang Gao, Yong Zhan, Yang Luo Baomin Fan*. Pd/Zn Co-catalyzed Asymmetric Ring-opening Reactions of Aza/Oxabicyclic alkenes with Oximes.Asian J. Org. Chem. 2019, 8, 97 -102.
[22] Chaoyuan Zeng, Guoli Shen, Fan Yang, Jingchao Chen,* Xuexin Zhang, Cuiping Gu, Yongyun Zhou, Baomin Fan*. Rhodium-Catalyzed Generation of Anhydrous Hydrogen Iodide: An Effective Method for the Preparation of Iodoalkanes. Org. Lett., 2018, 20, 6859-6862.
[23] Yang Gao, Yang Fan, Dongdong Pu, Ronibala Devi Laishram*, Ruifeng Fan, Guoli Shen, Xuexin Zhang, Jingchao Chen, Baomin Fan*. Pd/Zn(OTf)2 Co‐catalyzed Asymmetric Hydrogenation of Imines under Normal Pressure of Hydrogen. Eur.J. Org.Chem., 2018, 45, 6274-6279.
[24] Dongdong Pu, Yongyun Zhou,* Fan Yang,Guoli Shen,Yang Gao, Weiqing Sun,Ruhima Khan and Baomin Fan*.Asymmetric ring-opening reactions ofazabenzonorbornadienes through transfer
hydrogenation using secondary amines ashydrogen sources: tuning of absoluteconfiguration by acids.Org. Chem. Front., 2018, 5, 3077-3082.
[25] Dapeng Zhang, Ruhima Khan,* Fan Yang, Xuexin Zhang, Guoli Shen, Yang Gao, Ruifeng Fan, Weiqing Sun, and Baomin Fan*.Palladium and Lewis acid Co-catalyzed Reductive Asymmetric Ring-Opening Reaction of Azabenzonorbornadienes with TertiaryAmines as Hydrogen Source. Eur. J. Org. Chem. 2018, 26, 3464–3470.
[26] Hongyu Qin, Jingchao Chen,* Kangkui Li, Zhenxiu He, Yongyun Zhou, Baomin Fan*. Nickel-Catalyzed Asymmetric [2+2] Cycloaddition Reaction ofHetero-Bicyclic Alkenes with Internal Alkynes.Chem. Asian J. 2018, 13, 2431-2434.
[27] Jirong Hu,JianbinXu*,LinglingaZou,HaipingLv,Ruifeng Fan, Na Liu, Yongyun Zhou, Baomin Fan*.Rhodium Catalyzed Asymmetric Ring-Opening Reaction of OxabenzonorbornadieneswithAnhydride. Chin. J. Org. Chem., 2018, 38, 1687-1694.
[28] Zhenxiu He, Yongyun Zhou*, Baiqiu Han, XinXu, Yun Li, HongyuQin,Ruifeng Fan, Ronibala Devi Laishram, Baomin Fan*. Asymmetric ring-opening reaction of azabenzonorbornadienes with phenols promoted by palladium/(R,R)-DIOP complex. Tetrahedron, 2018, 74, 2174-2181.
[29] Fan Yang, Jingchao Chen*, GuoliShen, Xuexin Zhang, Baomin Fan*. Asymmetric Transfer Hydrogenation Reactions of N-Sulfonylimines by Using Alcohols as Hydrogen Sources. Chem.Comm., 2018, 54, 4963-4966.
[30] Jingchao Chen,* Lingling Zou, ChaoyuanZeng, Yongyun Zhou, Baomin Fan*. Rhodium-Catalyzed Asymmetric ArylativeRing-Opening Reactions ofHeterobicyclic Alkenes with Anilines. Org. Lett., 2018, 20, 1283−1286.
[31] Yongyun Zhou, Lu Yu,Jingchao Chen, Jianbin Xu, Zhenxiu He, Guoli Shen, and Baomin Fan*. Rhodium-Catalyzed Asymmetric Cyclization/Addition Reactions of 1,6-Enynes and Oxa/Azabenzonorbornadienes. Org. Lett., 2018, 20, 1291−1294.
[32] Yun Li, Jingchao Chen,* Zhenxiu He, Hongyu Qin, Yongyun Zhou, Ruhima Khan, Baomin Fan*.Cobalt-catalyzed asymmetric reactions of heterobicyclic alkenes with in situ generated organozinc halides. Org. Chem. Front., 2018, 5, 1108-1112.
[33] Jingchao Chen, Xin Xu,* Zhenxiu He, Hongyu Qin, Weiqing Sun, Baomin Fan*. Nickel/Zinc Iodide Co-catalytic Asymmetric [2+2] Cycloaddition Reactions of Azabenzonorbornadienes with Terminal Alkynes. Adv. Synth. Catal., 2018, 3, 427-431.
[34] Fujie Ma, Jingchao Chen,* Fan Yang, Madhuri Vikas Shinde, Yongyun Zhou, Baomin Fan*. Palladium/Zinc Co-catalyzed Asymmetric Transfer Hydrogenation of Oxabenzonorbornadienes with Alcohols as Hydrogen Sources. Org. Biomol. Chem., 2017, 15, 2359-2362.
[35] Meina Zhu, Jingchao Chen,* Xiaobo He, Cuiping Gu, Jianbin Xu, Baomin Fan*. Iridium-Catalyzed Anti-Stereoselective Asymmetric Ring Opening Reactions of Azabenzonorbornadienes with Carboxylic Acids. J. Org. Chem., 2017, 82, 3167-3172.
[36] Wei Zhang, Jingchao Chen,*Guangzhi Zeng, Fan Yang, Jianbin Xu, Weiqing Sun, Madhuri Vikas hinde, Baomin Fan*. Asymmetric Ring-Opening Reactions of Aza- and Oxa-bicyclic Alkenes with Boronic Acids Using a Palladium/Zinc Co-catalytic System. J. Org. Chem., 2017, 82, 2641-2647.
[37] Xiaobo He, Jingchao Chen*, Xin Xu, Fan Yang, Cuiping Gu, Yongyun Zhou, Baomin Fan*. Rhodium/zinc co-catalyzed asymmetric ring opening reactions of oxabenzonorbornadienes with carboxylic acids. Tetrahedron: Asymmetry, 2017, 28, 62-68.
[38] Fan Yang, Jingchao Chen ,Jianbin Xu, Fujie Ma, Yongyun Zhou, Madhuri Vikas Shinde, Baomin Fan*. Palladium/Lewis Acid Co-catalyzed Divergent Asymmetric Ring-Opening Reactions of Azabenzonorbornadienes with Alcohols. Org. Lett., 2016, 18, 4832-4835.
[39] Yongyun Zhou, Cuiping Gu, Jingchao Chen, Meina Zhu, Fan Yang, Jianbin Xu, and Baomin Fan*. Enantioselective Ring Opening Reactions of Azabenzonorbornadienes with Carboxylic Acids. Adv. Synth. Catal., 2016, 358, 3167-3172.
[40] Qingjing Yang, Pui Ying Choy, Yinuo Wu,* Baomin Fan* and Fuk Yee Kwong*. Oxidative coupling between C(sp2)–H andC(sp3)–H bonds of indoles and cyclic ethers/cycloalkanes. Org. Biomol. Chem., 2016, 14, 2608-2612.
[41] Xin Xu, Jingchao Chen, Zhenxiu He, Yongyun Zhou and Baomin Fan*. Rhodium-catalyzed a symmetric ring openingreaction of oxabenzonorbornadienes with amines using ZnI2 as the activator. Org. Biomol. Chem., 2016, 14, 2480-2486.
[42] Yongyun Zhou, Zhiwu Lu, Baiqiu Han, Chaoyuan Zeng, Zhenhua Zhang, Baomin Fan*. Iridium-catalyzed highly enantioselective ring opening reaction of oxabenzonorbornadienes with amines. Tetrahedron: Asymmetry, 2015, 26, 1354-1359.
[43] Zhiwu Lu, Jun Wang,* Baiqiu Han, Sifeng Li, Yongyun Zhou, Baomin Fan*. Palladium-Catalyzed
Asymmetric Ring Opening Reaction of Azabenzonorbornadienes with Aromatic Amines. Adv. Synth. Catal. ,2015, 357, 3121 -3125.
[44] Chaoyuan Zeng, Fan Yang, Jingchao Chen, Jun Wang,* Baomin Fan*. Iridium/Copper-Cocatalyzed Asymmetric Ring Opening Reaction of Azabenzonorbornadienes with Amines. Org. Biomol. Chem., 2015, 13, 8425-8428.
[45] Jingchao Chen, Shanshan Liu, Yongyun Zhou, Sifeng Li, Chengyuan Lin, Zhaoxiang Bian, Baomin Fan*. Palladium/Silver Cocatalyzed Tandem Reactions of Oxabenzonorbornadienes with Substituted Arylacetylenes: A Simple Method for the Preparation of 1,2-Diarylethanones and 1,2-Diarylacetylenes. Organometallics, 2015, 34, 4318-4322.
[45] Yongyun Zhou, Shanshan Liu, Hualei Chen, Jingchao Chen, Weiqing Sun, Sifeng Li, Qingjing Yang, Baomin Fan*. AgOTf-Catalyzed Tandem Reaction of Oxabenzonorbornadienes With Arylacetylenes. Chin. J. Chem.,2015, 33, 1115-1118.
[46] Qingjing Yang, Yongyun Zhou, Jingchao Chen, Xiaobo He, Jianbin Xu, Fuk Yee Kwong, Baomin Fan*. Pd-Catalyzed Allylic Alkynylation of Allylic Acetates with Terminal Alkynes. Eur. J. Org. Chem., 2015, 5330-5333.
[47] Qingjing Yang, Puiying Choy, Baomin Fan,* and Fukyee Kwong*. Enantioselective Hydroalkynylation of Non-Polar Carbon-Carbon Double Bonds: Iridium-Catalyzed Asymmetric Addition Reaction of Terminal Alkyne C-H Bonds to Substituted Norbornadienes. Adv. Synth. Catal., 2015, 357, 2345 -2350.
[48] Sifeng Li, Jianbin Xu, Baomin Fan,* Zhiwu Lu, Chaoyuan Zeng, Zhaoxiang Bian, Yongyun Zhou, and Jun Wang*. Palladium/Zinc Co-Catalyzed syn-StereoselectivelyAsymmetricRing-Opening Reaction of Oxabenzonorbornadienes with Phenols. Chem. Eur. J., 2015, 21, 9003 -9007.
三、申請和授權部分專利
授權專利:
[1] Zhaoxiang Bian, Baomin Fan, Chengyuan Lin, Yongyun Zhou, Jingchao Chen. Method for The Preparation of Iodoalkanes. 2018.08.07. USA. US10040740B2.
[2] Zhaoxiang Bian, Chengyuan Lin, Huaixue Mu, Baomin Fan, Yongyun Zhou, Jingchao Chen, Aiping Lu, Albert Sun-Chi Chan. Palladium/Silver Co-Catalyzed Tandem Reactions Syntheis of Phenylacetophenone Derivatives by Oxabenzonorborn Adienes and Their Anti-tumor or Anti-cancer Activities. 2017.10.10. USA. US9783519B2.
[3] Zhaoxiang Bian, Chengyuan Lin, Baomin Fan, Huaixue Mu, Yongyun Zhou, Weimin Zeng, Aiping Lu, Albert Sun-Chi Chan. Oxanorbornadiene Derivatives and Their Anticancer Activities. 2015.09.01. USA. US9120816B2.
[4] Albert Sun-Chi Chan, Baomin Fan, Jun Wang, Chengyuan Lin, Chao Huang, Qingjing Yang, Jianbin Xu, Zhaoxiang Bian, Aiping Lu, Jun Hu. Asymmetric Synthesis of Norcantharidin Analogues by Alkynylation of Oxabenzonorbornadienes and Their Anticancer Activities. 2014.09.16. USA. US8835658B2.
[5]樊保敏, 徐歆, 周永雲, 陳景超.一種新型化合物及其製備方法和套用. 2019.03.15.CN.ZL201510740517.9
申請專利:
1、樊保敏,陳景超,周永雲,曾廣智,尹俊林,林成源,孫蔚青, 一種銠催化製備碘代烷烴方法. 2017.11.14.201711122416.0
2、樊保敏,陳景超,周永雲,曾廣智,尹俊林,林成源,孫蔚青,一種銠催化製備碘代烷烴方法, 201711122416.0
3、樊保敏、陳景超、樊瑞峰、周永雲、孫蔚青、尹俊林,一種高效製備碘化苄及其衍生物的方法,201711420291.X
4、樊保敏,陳景超,周永雲,樊瑞峰,孫蔚青,曾廣智,尹俊林,林成源,郝朝威,一種特異性檢測銅離子和硫離子的多肽、化學螢光感測器及其製備方法與套用,201811048532.7
5、樊保敏,陳景超,周永雲,樊瑞峰,孫蔚青,曾廣智,尹俊林,林成源,呂海平,一種矽醇類有機化合物及製備方法,201910176111.0
6、樊保敏、周永雲、陳景超、曾廣智、尹俊林、徐麗娟、李瑞濤,一種鳳尾茶天然涼茶飲料及其製備方法,201910291387.3
7、樊保敏,陳景超,周永雲,樊瑞峰,孫蔚青,林成源,呂海平,一種芳香偶氮苯類有機化合物的製備方法,201910827116.5
8、樊保敏,楊大堅,詹永,羅楊,李娟,陳景超,周永雲,沈國禮,一種製備手性胺基酸酯和手性氘代胺基酸酯的方法,201911225569.7
9、樊保敏,陳景超,周永雲,和振秀,樊瑞峰,孫蔚青,沈國禮,一種以重水為製備氘代胺基酸酯的方法,2019112975912

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