劉勁剛(華東理工大學化學與分子工程學院校特聘教授)

劉勁剛(華東理工大學化學與分子工程學院校特聘教授)

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劉勁剛，男，博士，華東理工大學化學與分子工程學院校特聘教授、博士生導師。

基本介紹

  • 中文名：劉勁剛
  • 畢業院校：中山大學
  • 學位/學歷：博士
  • 職業：教師
  • 專業方向：生物無機化學
  • 職務：華東理工大學化學與分子工程學院博士生導師
  • 任職院校：華東理工大學化學與分子工程學院
  • 職稱：教授
個人經歷,研究方向,學術成果,榮譽獎勵,

個人經歷

2000年6月畢業於中山大學，獲理學博士學位(Ph.D.)。隨後於同濟大學化學系任教。2001年8月至2011年8月於日本九州大學先後任日本學術振興會（JSPS）外國人特別研究員、學術研究員、特任準教授及WPI準教授。2011年9月起華東理工大學校特聘教授。無機化學博士點導師組組長。

研究方向

研究領域： 生物無機化學。
研究方向：
1.氧分子的活化還原與燃料電池仿生電催化劑。基於仿生催化原理設計不含貴金屬的氧分子還原催化劑，作為新型電催化劑最終套用於燃料電池，實現化學能與電能的高效轉換。
2.無機納米藥物光控釋放。研究無機藥物（一氧化氮、一氧化碳、金屬釕、鉑配合物等）的光控釋放及其抗腫瘤特性，構建具有靶向可控投遞集診斷與治療於一體的多功能無機納米藥物體系。
3.二氧化碳的光催化轉換。通過有機-無機複合光催化劑將CO2光催化轉換成可利用的化工原料，闡明CO2光催化還原的過程和機理，實現太陽能的儲存和轉移。

學術成果

在J. Am. Chem. Soc., Angew Chem. Int. Ed.; Chem. Commun., Chem. Eur. J., Coord. Chem. Rev.等國內外期刊發表SCI收錄論文六十餘篇，論文總引用2300餘次。
代表論文:
  1. F.-F. Wang, Y.-M. Zhao, P.-J. Wei, Q.-L. Zhang and J.-G. Liu,* Efficient electrocatalytic O2 reduction at copper complexes grafted onto polyvinylimidazole coated carbon nanotubes, Chem. Commun. 2017，53, 1514–1517.
  2. G.-Q. Yu, P.-J. Wei,* F.-F. Wang, and J.-G. Liu,* Doping Copper Ions into an Fe/N/C Composite Promotes Catalyst Performance for the Oxygen Reduction Reaction, ChemElectroChem 2017, 4, 1509-1515.
  3. F.-F. Wang, P.-J. Wei, G.-Q. Yu and J.-G. Liu,* Titanium Dioxide-Grafted Copper Complexes: High-Performance Electrocatalysts for the Oxygen Reduction Reaction in Alkaline Media, Chem. Eur. J. 2016, 22, 382–389 (hot paper).
  4. W. Chen, M. Sin, P.-J. Wei, Q.-L. Zhang* and J.-G. Liu,* Synergistic Enhancement of Electrocatalytic Activity toward the Oxygen Reduction Reaction in Alkaline Electrolytes with Pentabasic (Fe, B, N, S, P)-Doped Reduced Graphene Oxide, Chin. J. Chem. 2016, 34, 878–886 (cover paper).
  5. Y.-T. Xi, P.-J. Wei, R.-C. Wang and J.-G. Liu,* Bio-inspired multinuclear copper complexes covalently immobilized on reduced graphene oxide as efficient electrocatalysts for the oxygen reduction reaction, Chem. Commun. 2015, 51, 7455–7458.
  6. T. Ohta,* J.-G. Liu,* P. Nagaraju, T. Ogura and Y. Naruta,* A cryo-generated ferrous–superoxo porphyrin: EPR, resonance Raman and DFT studies, Chem. Commun. 2015, 51, 12407–12410.
  7. R.-C. Wang, T.-L. Yin, P.-J. Wei and J.-G. Liu,* A copper complex covalently grafted on carbon nanotubes and reduced graphene oxide promotes oxygen reduction reaction activity and catalyst stability, RSC Adv. 2015, 5, 66487–66493.
  8. P.-J. Wei, G.-Q. Yu, Y. Naruta and J.-G. Liu,* Covalent Grafting of Carbon Nanotubes with a Biomimetic Heme Model Compound To Enhance Oxygen Reduction Reactions, Angew. Chem. Int. Ed. 2014, 53, 6659–6663.
  9. J.-G. Liu, Y. Shimizu, T. Ohta and Y. Naruta*, “Formation of an End-On Ferric Peroxo Intermediate upon One-Electron Reduction of a Ferric Superoxo Heme”, J. Am. Chem. Soc. 2010, 132, 3672-3673.
  10. J.-G. Liu, T. Ohta, S. Yamaguchi, T. Ogura, S. Sakamoto, Y. Maeda and Y. Naruta*, “Spectroscopic Characterization of a Hydroperoxo–Heme Intermediate: Conversion of a Side-On Peroxo to an End-On Hydroperoxo Complex”, Angew. Chem. Int. Ed. 2009, 48, 9262-9267. VIP paper. Highlighted by Nature 2010, 463, 168-169; Angew.Chem. Int. Ed. 2010, 49, 2099-2101.
  11. J.-G. Liu, Y. Naruta* and F. Tani, “A Functional Model of the Cytochrome c Oxidase Active Site: Unique Conversion of a Heme–μ-peroxo–CuII Intermediate into Heme– superoxo/CuI”, Angew. Chem. Int. Ed. 2005, 44, 1836-1840.
  12. J.-G. Liu, Y. Naruta* and F. Tani, “Synthetic Models of the Active Site of Cytochrome c Oxidase: Influence of a Tridentate or Tetradentate Copper Chelate Bearing a His-Tyr Linkage Mimic on Dioxygen Adduct Formation by Heme/Cu Complexes”, Chem. Eur. J. 2007, 13, 6365-6378.
  13. J.-G. Liu, Y. Naruta*, F. Tani, T. Chishiro and Y. Tachi, “Formation and spectroscopic characterization of the dioxygen adduct of a heme–Cu complex possessing a cross-linked tyrosine–histidine mimic: modeling the active site of cytochrome c oxidase”, Chem. Commun. 2004, (1), 120-121.
  14. Y. Nagano, J.-G. Liu, Y. Naruta,* T. Ikoma, S. Tero-Kubota, and T. Kitagawa*, “Characterization of the Phenoxyl Radical in Model Complexes for the CuB Site of Cytochrome c Oxidase: Steady-State and Transient Absorption Measurements, UV Resonance Raman Spectroscopy, EPR Spectroscopy, and DFT Calculations for MII-BIAIP”, J. Am. Chem. Soc. 2006, 128, 14560-14570.
  15. T. Ohta*, J.-G. Liu, Y. Naruta, “Resonance Raman characterization of mononuclear heme-peroxo intermediate models”, Coord. Chem. Rev. 2013, 257, 407-413.
  16. Y.-H. Li, M. Guo, S.-W. Shi, Q.-L. Zhang, S.-P. Yang, and J.-G. Liu,* Ruthenium-Nitrosyl-Functionalized Nanoplatform for the Targeting of Liver Cancer Cells and NIR-Light Controlled Delivery of Nitric Oxide Combined with Photothermal Therapy, J. Mater. Chem. B 2017, DOI: 10.1039/C7TB02059G.
  17. M. Guo, H.-J. Xiang, Y. Wang, Q.-L. Zhang,* L. An, S.-P. Yang, Y. Ma, Y. Wang and J.-G. Liu,* Ruthenium nitrosyl functionalized graphene quantum dots as an efficient nanoplatform for NIR-light-controlled and mitochondria-targeted delivery of nitric oxide combined with photothermal therapy, Chem. Commun. 2017, 53, 3253–3256.
  18. H.-J. Xiang, H. P. Tham, M. D. Nguyen, S. Z. F. Phua, W. Q. Lim, J.-G. Liu* and Y. L. Zhao,* An aza-BODIPY based near-infrared fluorescent probe for sensitive discrimination of cysteine/homocysteine and glutathione in living cells, Chem. Commun. 2017, 53, 5220-5223.
  19. H.-J. Xiang, H. Chen, H. P. Tham, S. Z. F. Phua, J.-G. Liu*, and Y. Zhao*, Cyclometalated Iridium(III)-Complex-Based Micelles for Glutathione-Responsive Targeted Chemotherapy and Photodynamic Therapy, ACS Appl. Mater. Interfaces 2017, 9, 27553−27562.
  20. H.-J. Xiang, M. Guo, and J.-G. Liu,* Transition-Metal Nitrosyls for Photocontrolled Nitric Oxide Delivery, Eur. J. Inorg. Chem. 2017, 1586–1595 (review).
  21. H.-J. Xiang, J.-G. Liu,* and Y. Zhao,* Recent Research Advancements of NO-Releasing Nanomaterials, Acta Phys. -Chim. Sin. 2017, 33 , 903–917(review).
  22. H.-J. Xiang, Q. D., L. An, M. Guo, S.-P. Yang and J.-G. Liu,* Tumor cell specific and lysosome-targeted delivery of nitric oxide for enhanced photodynamic therapy triggered by 808 nm near-infrared light, Chem. Commun. 2016, 52, 148–151.
  23. H.-J. Xiang, M. Guo, L. An, S.-P. Yang, Q.-L. Zhang* and J.-G. Liu,* A multifunctional nanoplatform for lysosome targeted delivery of nitric oxide and photothermal therapy under 808 nm near-infrared light, J. Mater. Chem. B 2016, 4, 4667–4674.
  24. Q. Deng, H.-J. Xiang, W.-W. Tang, L. An, S.-P. Yang, Q.-L. Zhang and J.-G. Liu,* Ruthenium Nitrosyl Grafted Carbon Dots as a Fluorescence-Trackable Nanoplatform for Visible Light-Controlled Nitric Oxide Release and Targeted Intracellular Delivery, J. Inorg. Biochem. 2016, 165, 152–158.
  25. H.-J. Xiang, L. An, W.-W. Tang, S.-P. Yang* and J.-G. Liu,* Photo-controlled targeted intracellular delivery of both nitric oxide and singlet oxygen using a fluorescence-trackable ruthenium nitrosyl functional nanoplatform, Chem. Commun. 2015, 51, 2555–2558.
  26. X.-D. Yang, H.-J. Xiang, L. An, S.-P. Yang and J.-G. Liu,* Targeted delivery of photoactive diazido PtIV complexes conjugated with fluorescent carbon dots, New J. Chem. 2015, 39, 800–804.
  27. W.-D. Wei, X.-Y. Liu, S.-C. Cui,* and J.-G. Liu,* Loading of Co3O4 onto Pt-modified Nitrogen-doped TiO2 Nanocomposites Promotes Photocatalytic Hydrogen Production, RSC Adv. 2017, 7, 25650–25656.
  28. L. Liu, and J.-G. Liu,* “Encyclopedia of Physical Organic Chemistry”, 6 Volume Sets, Vol. 6, Chapter 70, Artificial Photosynthesis, pp3813–3884. Z. Wang, U. Wille, and E. Juaristi, Eds., Wiley, 2017.
  29. S.-C. Cui, X.-Z. Sun, and J.-G. Liu,* Photo-reduction of CO2 Using a Rhenium Complex Covalently Supported on a Graphene/TiO2 Composite, ChemSusChem 2016, 13, 1698–1703.X.-Y. Liu, W.-D. Wei, S.-C. Cui,* and J.-G. Liu,* A Heterojunction Cu2O/N–TiO2 Photocatalyst for Highly Efficient Visible Light-Driven Hydrogen Production, Catal. Lett. 2016, 146, 1655–1662.
  30. P. Sun, L. Liu, S.-C. Cui, and J.-G. Liu,* Synthesis, Characterization of Ce-doped TiO2 Nanotubes with High Visible Light Photocatalytic Activity, Catal. Lett. 2014, 144, 2107–2113.

榮譽獎勵

先後入選“浦江人才計畫”和“上海市高校特聘教授”。

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