金屬卡賓經由的炔烴以及聯烯的催化反應研究

科研成果

序號	標題	類型	作者
1	Sequential catalytic process: synthesis of quinoline derivatives by AuCl3/CuBr-catalyzed three-component reaction of aldehydes, amines, and alkynes	期刊論文	Chen, Yulin\|Wang, Jianbo\|Xiao, Fengping\|Liu, Yu\|
2	Rh(I)-Catalyzed Carbonylative Carbocyclization of Tethered Ene- and Yne-cyclopropenes	期刊論文	Zhang, Yan\|Zhang, Hang\|Li, Changkun\|Feng, Jiajie\|Wang, Jianbo\|
3	Enantioselective synthesis of condensed and transannular ring skeletons containing pyrrolidine moiety	期刊論文	Li, Fei\|Wang, Jianbo\|Mo, Fanyang\|Qiu, Di\|
4	Recent studies on the reactions of alpha-diazocarbonyl compounds	期刊論文	Zhang, Zhenhua\|Wang, Jianbo\|
5	Nano-Fe2O3-catalyzed direct borylation of arenes	期刊論文	Kuang, Chunxiang\|Jiang, Yubo\|Wang, Jianbo\|Wang, Shuai\|Zhang, Yan\|Liu, Haichao\|Yan, Guobing\|
6	Pd-Catalyzed C=C Double-Bond Formation by Coupling of N-Tosylhydrazones with Benzyl Halides	期刊論文	Yang, Yang\|Zhang, Yan\|Wang, Jianbo\|Xiao, Qing\|Ma, Jian\|
7	Microwave-Assisted, Pd(0)-Catalyzed Cross-Coupling of Diazirines with Aryl Halides	期刊論文	Li, Hui, Zhang, Yan\|Wang, Jianbo\|Zhao, Xia, Wu, Guojiao, Yan, Chong, Lu, Kui\|
8	Direct Conversion of Arylamines to Pinacol Boronates: A Metal-Free Borylation Process	期刊論文	Qiu, Di\|Mo, Fanyang\|Zhang, Yan\|Jiang, Yubo\|Wang, Jianbo\|
9	Gold(III)-Catalyzed Halogenation of Aromatic Boronates with N-Halosuccinimides	期刊論文	Wang, Jianbo\|Zhang, Yan, and\|Qiu, Di, Mo, Fanyang, Zeng, Zhitong\|
10	Palladium-Catalyzed Direct Cyanation of Indoles with K-4[Fe(CN)(6)]	期刊論文	Wang, Jianbo\|Zhang, Yan\|Kuang, Chunxiang\|Yan, Guobing\|
11	Sequential Copper(I)-Catalyzed Reaction of Amines with o-Acetylenyl-Substituted Phenyldiazoacetates	期刊論文	Peng, Cheng, Cheng, Jiajia\|Wang, Jianbo\|
12	Palladium-catalyzed cyclopropanation of electron-deficient olefins with aryldiazocarbonyl compounds	期刊論文	Chen, Shufeng\|Ma, Jian\|Wang, Jianbo\|
13	Diastereoselective addition of lithium enolate of gamma-substituted alpha-diazoacetoacetate to N-sulfinyl imines	期刊論文	Wang, JianBo\|Li, Fei\|Mo, Fanyang\|
14	Catalytic [2,3]-sigmatropic rearrangement of sulfur ylide derived from metal carbene	期刊論文	Zhang, Yan\|Wang, Jianbo\|
15	Palladiun-Catalyzed Coupling Reaction of a-Diazocarbonyl Compounds with Aromatic Boronic Acids and Halides	期刊論文	Wang, Jianbo\|Peng, Cheng, Yan, Guobin, Wang, Yan\|Zhang, Yan\|
16	InI3- or ZnI2-Catalyzed Reaction of Hydroxylated 1,5-Allenynes with Thiols: A New Access to 3,5-Disubstituted Toluene Derivatives	期刊論文	Zhang, Zhe, Campbell, Melody \|Wang, Jianbo\|Ma, Jie, Peng, Lingling, Zhang, Xiu\|
17	Highly diastereoselective addition of the lithium enolate of alpha-diazoacetoacetate to N-sulfinyl imines: Enantioselective synthesis of 2-oxo and 3-oxo pyrrolidines	期刊論文	Dong, Changqing\|Wang, Jianbo\|Mo, Fanyang\|
18	Gold-Catalyzed Halogenation of Aromatics by N-Halosuccinimides	期刊論文	Qiu, Di\|Yan, Jerry Mingtao\|Wang, Jianbo\|Zhang, Yan\|Mo, Fanyang\|Li, Fei\|
19	Au-catalyzed isomerization of cyclopropenes: a novel approach to indene derivatives	期刊論文	Li, Changkun\|Zeng, Yi\|Wang, Jianbo\|
20	Gold(I)-Catalyzed Cycloisomerization of Enynes Containing Cyclopropenes	期刊論文	Zeng, Yi\|Wang, Jianbo\|Zhang, Hang\|Feng, Jiajie\|Li, Changkun\|Zhang, Yan\|
21	Rh(II)-catalyzed Sommelet-Hauser rearrangement	期刊論文	Peng, Lingling\|Liao, Mingyi\|Wang, Jianbo\|
22	Arylation and Vinylation of alpha-Diazocarbonyl Compounds with Boroxines	期刊論文	Yan, Guobing\|Zhang, Wei\|Peng, Cheng\|Wang, Jianbo\|
23	Recent Progress in Pd-Catalyzed Reactions of Diazo Compounds	期刊論文	Kuang, Chunxiang\|Wang, Jianbo\|Peng, Cheng\|Yan, Guobing\|
24	AuPPh3Cl/AgOTf-catalyzed reaction of terminal alkynes: nucleophilic addition to activated C=O bond	期刊論文	Li, Changkun\|Mo, Fanyang\|Li, Weibin\|Wang, Jianbo\|
25	Pd-catalyzed oxidative cross-coupling of N-tosylhydrazones with arylboronic acids	期刊論文	Zhang, Yan\|Wang, Jianbo\|Jing, Jing\|Zhao, Xia\|Lu, Kui\|
26	Recent development of reactions with alpha-diazocarbonyl compounds as nucleophiles	期刊論文	Zhang, Yan\|Wang, Jianbo\|
27	Palladium-catalyzed cross-coupling of alpha-diazocarbonyl compounds with arylboronic acids	期刊論文	Peng, Cheng\|Wang, Yan\|Wang, Jianbo\|
28	Pd-Catalyzed Three-Component Coupling of N-Tosylhydrazone, Terminal Alkyne, and Aryl Halide	期刊論文	Wang, Jianbo\|Zhou, Lei, Ye, Fei, Zhang, Yan\|
29	Au(PPh3)Cl-AgSbF6-catalyzed rearrangement of propargylic 1,3-dithianes: formation of 8-membered 1,3-bisthio-substituted cyclic allenes	期刊論文	Peng, Lingling\|Wang, Jianbo\|Zhong, Zhenzhen\|Zhang, Wenxiong\|Zhao, Xia\|
30	Synthesis of furan from allenic sulfide derivatives	期刊論文	Ma, Jie\|Zhong, ZhenZhen\|Zhang, Zhe\|Zhang, Yan\|Wang, JianBo\|Peng, LingLing\|Zhang, Xiu\|
31	Gold(I)-catalyzed arylmethylation of terminal alkynes	期刊論文	Wang, Jianbo\|Li, Changkun\|Li, Weibin\|
32	Palladium-catalyzed reaction of allyl halides with alpha-diazocarbonyl compounds	期刊論文	Chen, Shufeng\|Wang, Jianbo\|
33	Rh-II-Catalyzed Reaction of alpha-Diazocarbonyl Compounds Bearing beta-Trichloroacetylamino Substituent: C-H Insertion versus 1,2-H Shift	期刊論文	Zhang, Bo\|Wang, Jianbo\|Shi, Weifeng\|Zhang, Jian\|Xu, Feng\|Liu, Bingge\|Xiao, Fengping\|Fan, Bo\|Zhang, Zhenhua\|Liu, Yiyang\|
34	Palladium-Catalyzed Carbonylation/Acyl Migratory Insertion Sequence	期刊論文	Liu, Yiyang\|Zhang, Yan\|Wang, Jianbo\|Zhang, Zhenhua\|Zhao, Xiaokun\|Gong, Mingxing\|

項目摘要

金屬卡賓經由的催化反應是一類重要的反應，在有機合成中得到了廣泛的套用。重氮化合物通常被用作金屬卡賓的前體。金屬卡賓中間體可以發生烯烴複分解反應，環丙烷化，X-H鍵插入反應，形成葉立德以及1，2－遷移反應等。這些多樣的反應性可以通過反應條件，包括金屬催化劑，配體，底物，反應介質等來進行有效的控制。近年的研究表明過渡金屬催化的炔烴和聯烯的反應有部分是經過了金屬卡賓中間體。本項研究是通過金屬催化的炔烴和聯烯的反應尋找形成金屬卡賓的新方法，並研究通過這種途徑形成的金屬卡賓的各類反應，包括C-H鍵插入反應，環丙烷化反應以及葉立德反應等。特別是通過親核試劑的分子間反應形成金屬卡賓具有十分重要的意義。此外，還將研究金屬卡賓和重氮化合物結合在一起的連續催化反應，以拓展金屬卡賓反應的套用。

金屬卡賓經由的炔烴以及聯烯的催化反應研究

基本介紹

科研成果

項目摘要

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