張繼坦

張繼坦，男，博士，安徽師範大學化學與材料科學學院碩士生導師。

基本介紹

人物經歷,研究方向,學術成果,

人物經歷

教育經歷
2005年9月-2009年7月安徽師範大學理學學士（導師：謝美華教授）
2009年9月-2012年7月安徽師範大學理學碩士（導師：謝美華教授）
2012年9月-2016年3月浙江大學理學博士（導師：張玉紅教授）
工作經歷
2016年7月-2017年7月中山大學特聘副研究員
2017年8月-至今安徽師範大學

研究方向

過渡金屬催化惰性鍵斷裂
不對稱催化
有機合成方法學

學術成果

經費項目
  • “基於鈷催化碳氫鍵活化的手性胺基酸衍生物的合成反應研究”，中央高校基本科研業務費中山大學青年教師培育項目(31000-31610766)，2017年01月-2017年12月，項目負責人。
  • “廉價金屬催化的基於碳氫鍵活化的不對稱串聯反應”，國家自然科學基金青年項目(21702237)，2018年01月-2020年12月，項目負責人。
  • 安徽師範大學博士科研啟動基金，2018年01月-2020年12月，項目負責人。
  • “基於不對稱鈷催化碳氫鍵雜原子化的軸手性構建反應研究”，安徽省自然科學基金面上項目(2208085MB23)，2022年01月-2024年12月，項目負責人。
  • “基於不對稱Catellani型反應的手性氮/磷原子構建及其合成套用研究”，安徽省高校科研編制重大項目(2023AH040028)，2023年09月-2026年08月，項目負責人。
代表性論文
(33) Rh(III)-catalyzed selective C2 C–H acyloxylation of indoles, Chaoying Fang, Li Li, Haitao Yang, Caiyang Kong, Jitan Zhang*, Meihua Xie* and Jiping Wu*, Chem. Commun. 2024, DOI: 10.1039/D3CC05799B.
(32) Electrochemical Oxidation of Indoles to Access Tryptanthrins at Room Temperature, Ziyi Guo, Yi Liu, Hang Li, Jiping Wu*, Meihua Xie* and Jitan Zhang*, Adv. Synth. Catal. 2024, DOI: 10.1002/adsc.202301027.
(31) Construction of Fully Substituted Cyclobutanes by Tandem Reaction of 1,4-Diyn-3-ols and Anhydrides, Ziyi Guo, Yue Yin, Xiao-Cong Xu, Chang-Qing Liu, Jitan Zhang* and Meihua Xie*, J. Org. Chem. 2023, DOI: 10.1021/acs.joc.3c00530.
(30) Palladium-catalyzed Interannular C-H Amination of Biaryl Amines, Jiaping Wu,* Pengpeng Sun, Yuwen Hong, Haitao Yang, Meihua Xie,* Jitan Zhang,* Chem. Commun. 2022, DOI: 10.1039/D2CC05129J.
(29) Electrochemical Rhodium-catalyzed C-H Cyclodimerization of Alkynes to Access Diverse Functionalized Naphthalenes: Involvement of RhIV/V and RhI Dual Catalysis, Ziyi Guo, Junjie Zhang, Jitan Zhang,* Meihua Xie,* Org. Lett. 2022, DOI: 10.1021/acs.orglett.2c03122.
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(28) Palladium-catalyzed Atroposelective Interannular C-H Arylation of Biaryl Aldehydes with Aryl Iodides Enabled by a Transient Directing Group Strategy, Jitan Zhang,* Jian Fan, Ziyi Guo, Yehe Wu, Jiaping Wu,* Meihua Xie,* Adv. Synth. Catal. 2022, DOI: 10.1002/adsc.202200659.
(27) Acid-Promoted C-C Triple Bond Cleavage of Ynones for the Synthesis of Benzo[d]oxazoles/Benzo[d]thiazoles and 1-Arylethan-1-ones, Zi-Yi Guo, Ke-Ru Li, Hang Li, Xu Wang, Ji-Tan Zhang,* Mei-Hua Xie,* Eur. J. Org. Chem. 2022, DOI: 10.1002/ejoc.202200858.
(26) Cu-catalyzed Diarylthiolation of Ynones with Aryl Iodides and Elemental Sulfur: An Access to Tetrasubstituted (Z)-1,2-Bis(arylthio)alkenes and Benzo[b][1,4]dithiines, Yiming Zhao, Xu Wang, Ziyi Guo, Hang Li, Jitan Zhang,* Meihua Xie,* J. Org. Chem. 2022, DOI: 10.1021/acs.joc.2c01575.
(25) Pd-Catalyzed Atroposelective C-H Acyloxylation Enabling Access to an Axially Chiral Biaryl Phenol Organocatalyst, Jitan Zhang,* Jian Fan, Yehe Wu, Ziyi Guo, Jiaping Wu,* Meihua Xie*, Org. Lett. 2022, DOI: 10.1021/acs.orglett.2c01981.
(24) Catalytic Ring Expansion of Indole toward Dibenzoazepine Analogues Enabled by Cationic Palladium(II) Complexes, Jiaping Wu,* Yanfei Liu, Baiyang Qian, Haitao Yang, Lili Lu, Jitan Zhang,* Yongjia Shang*, ACS Catal. 2022, 12, 6216−6226.
(23) Temperature controlled di- and monosulfonylation of propargyl alcohols with sodium sulfinates: switchable access to (E)-allyl, vinyldisulfones and propargyl sulfones, Changqing Liu, Hang Li, Bo Wang, Ziyi Guo, Yu Wang, Jitan Zhang,* and Meihua Xie*, Org. Chem. Front. 2022, DOI: 10.1039/d1qo01906f.
(22) K2S2O8-mediated acylarylation of unactivated alkenes via acyl radical addition/C-H annulation cascade of N-allyl-indoles with silver cocatalysis, Jitan Zhang,* Manyi Wu, Hu Ju, Haitao Yang, Ke Ding, Li Zhu, Jiaping Wu,* and Meihua Xie*, Org. Chem. Front. 2022, DOI: 10.1039/d1qo01069g.
(21) Pd(II)-catalyzed enantioconvergent twofold C-H annulation to access atropisomeric aldehydes: A platform for diversity-orientedsynthesis, Jitan Zhang,* Qiaoqiao Xu, Jian Fan, Lan Zhou, Nannan Liu, Li Zhu, Jiaping Wu,* and Meihua Xie*, Org. Chem. Front. 2021, DOI: 10.1039/D1QO00183C.
(20) Construction of 3-Sulfonyl Naphthalenes via Tandem Reaction of 1,4-Diyn-3-yl Esters with Sodium Sulfinates, Ziyi Guo, Yiming Zhao, Yu Wang, Meihua Xie* and Jitan Zhang*, J. Org. Chem. 2021, DOI: 10.1021/acs.joc.1c00038.
(19) Access to C2 C-H olefination, alkylation and deuteration of indoles by rhodium(III) catalysis: An entry for diverse synthesis, Jiaping Wu,* Baiyang Qian, Haitao Yang, Lili Lu, Yongjia Shang,* Jitan Zhang, Org. Chem. Front. 2021, DOI: 10.1039/D1QO00133G.
(18) Expeditious synthesis of phenanthridines through a Pd/MnO2-mediated C–H arylation/oxidative annulation cascade from aldehydes, aryl iodides and amino acids, Jian Fan, Li Li, Jitan Zhang*, Meihua Xie*, Chem. Commun. 2020, DOI: 10.1039/d0cc00300j.
(17) Acid-Controlled Access to β‑Sulfenyl Ketones and α,β-Disulfonyl Ketones by Pummerer Reaction of β‑Keto Sulfones and Sulfoxides, Jian Fan, Yiming Zhao, Jitan Zhang, Meihua Xie*, Yuzhong Zhang*, J. Org. Chem. 2020, 85, 691.
(16) Construction of N−C Axial Chirality through Atroposelective C−H Olefination of N‑Arylindoles by Palladium/Amino Acid Cooperative Catalysis, Jitan Zhang，* Qiaoqiao Xu, Jiaping Wu, Jian Fan, Meihua Xie*, Org. Lett. 2019, 21, 6361. (Highlighted by Synfacts, 2019, 15, 1156)
(15) Metal-free cascade rearrangement/radical addition/oxidative C–H annulation of propargyl alcohols with sodium sulfinates: access to 2-sulfenylindenones, Changqing Liu, Bo Wang, Ziyi Guo, Jitan Zhang, Meihua Xie*, Org. Chem. Front. 2019, 6, 2796.
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(14) Selective C–H acylation of indoles with a-oxocarboxylic acids at the C4 position by palladium catalysis, Jitan Zhang，* Manyi Wu, Jian Fan, Qiaoqiao Xu, Meihua Xie,* Chem. Commun. 2019, DOI: 10.1039/c9cc03893k.
(13) NH4I-promoted N-acylation of amines via the transamidation of DMF and DMA under metal-free conditions, Jiahui Chen, Jin Jia, Ziyi Guo, Jitan Zhang,* Meihua Xie*, Tetrahedron Lett. 2019, 60, 1426.
(12) Synthesis of 2-Acetyl Trisubstituted Furans via Copper-Mediated Deacylation Cleavage of Unstrained C(sp3)-(sp2) Bonds, Jian Fan, Shengke Wang, Jiahui Chen, Manyi Wu, Jitan Zhang,* Meihua Xie*, Org. Chem. Front. 2019, 6, 437.
(11) Metal-Free Functionalized Tetrasubstituted Alkenes by Three-Component Reaction of Alkynes, Iodine, and Sodium Sulfinates, Jitan Zhang,* Zhenda Liang, Jun Wang, Ziyi Guo, Changqing Liu, Meihua Xie,* ACS Omega 2018, 3, 18002.
(10) Enantioselective Synthesis of C–N Axially ChiralN-Aryloxindoles by Asymmetric Rhodium-Catalyzed Dual C-H Activation, Honghe Li,# Xiaoqiang Yan,# Jitan Zhang, Weicong Guo, Jijun Jiang, and Jun Wang,* Angew. Chem. Int. Ed.2019, DOI: 10.1002/anie.201901619.
(9) Copper(II)/Silver(I)-Catalyzed Sequential Alkynylation and Annulation of Aliphatic Amides with Alkynyl Carboxylic Acids: Efficient Synthesis of Pyrrolidones, Jitan Zhang, Danyang Li, Hui Chen, Binjie Wang, Zhanxiang Liu, Yuhong Zhang,* Adv. Synth. & Catal. 2016, 358, 792.
(8) An Approach to Five-Membered Lactams from Aliphatic Amides and Terminal Acetylenes by Nickel Catalysis, Cong Lin, Jitan Zhang, Zhengkai Chen, Yue Liu, Zhanxiang Liu, Yuhong Zhang,* Adv. Synth. & Catal. 2016, 358, 1778.
(7) Cobalt-Catalyzed Cyclization of Aliphatic Amides and Terminal Alkynes with Silver Cocatalyst, Jitan Zhang, Hui Chen, Cong Lin, Zhanxiang Liu, Chen Wang, Yuhong Zhang,* J. Am. Chem. Soc. 2015, 137, 12990.
(6) Copper-Mediated Aryloxylation and Vinyloxylation of β-(sp3)-H Bond of Propionamides with Organosilanes, Jitan Zhang, Hui Chen, Binjie Wang, Zhanxiang Liu, Yuhong Zhang,* Org. Lett. 2015,17, 2768.
(5) Rhodium(III)-Catalyzed One-Pot Access to Isoquinolines and Heterocycle-Fused Pyridines in Aqueous Medium through C-H Cleavage, Jitan Zhang, Hongsheng Qian, Zhanxiang Liu, Chunhua Xiong, Yuhong Zhang*, Eur. J. Org. Chem. 2014, 2014, 8110.
(4) Regio-and stereoselective synthesis of highly functionalized vinyl ethers via coiodination of acetylenic ketones, Meihu Xie,* Jitan Zhang, Peng Ning, Zhannan Zhang, Xing Liu, Linbo Wang, Tetrahedron Lett. 2014, 55, 1065.
(3) Pd(II)-catalyzed C(sp2)-H carbonylation of biaryl-2-amine: synthesis of phenanthridinones, Zunjun Liang, Jitan Zhan, Zhanxiang Liu, Kai Wang, Yuhong Zhang,* Tetrahedron 2013, 69, 6519.
(2) Transition metal-catalyzed C-H bond functionalizations by the use of diverse directing groups, Zhengkai Chen, Binjie Wang, Jitan Zhang, Wenlong Yu, Zhanxiang Liu, Yuhong Zhang,* Org. Chem. Front. (Review), 2015，2, 1107.
(1) Synthesis of Benzyl Esters via Functionalization of Multiple C-H Bonds by Palladium Catalysis, Danyang Li, Ming Yu, Jitan Zhang, Zhanxiang Liu, Yuhong Zhang,* Org. Lett. 2015, 17, 5300.

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