黃鑫，男，博士，浙江師範大學化學與生命科學學院副教授，碩士生導師，2016年5月博士畢業於美國麻薩諸塞州大學（波士頓），導師Wei Zhang教授，浙江省 “高校領軍人才培養計畫”青年優秀人才。
基本介紹
- 中文名：黃鑫
- 畢業院校：美國麻薩諸塞州大學（波士頓）
- 學位/學歷：博士
- 職業：教師
- 職務：碩士生導師
研究方向,主要成就,科研項目,發表論文,專利申請,
研究方向
主要開展有機合成方法學，有機氟化學研究；
主要成就
先後以第一作者或者通訊作者在Angew. Chem. Int. Ed.（3篇）, Chem. Sci.（1篇）, Chem. Commun., Org. Lett., Adv. Synth. Catal., J Org. Chem.等國際重要期刊上發表SCI論文10餘篇，相關研究成果多次被科學評論性網站X-mol、Synfact等科研評論性媒體進行專題報導。
主持國家自然科學基金青年項目、浙江省基礎公益項目等省部級以上項目3項，申請發明專利4項。指導本科生獲得浙江省化學競賽一等獎一項，在研國家大學生創新創業項目一項。
科研項目
原位構建高價碘型二氟烷基化親電試劑及其相關反應研究
國家自然科學基金青年項目，21901232，主持
芳基高價碘促進的氟烷基反應研究
浙江省基礎公益項目，LQ19B020005，主持
自由基導向官能團的設計與開發
“先進催化材料”教育部重點實驗室開放基金，主持
發表論文
（1）Recyclable Fluorous Cinchona Organocatalysts for Asymmetric Synthesis of Biologically Interested Compounds.（Invited Feature Article）Xin Huang,* Wei Zhang.* Chem. Commun., 2021, DOI: 10.1039/D1CC03722F.
（2）α-C–H Difluoroalkylation of Alkyl Sulfoxides via Intermolecular Pummerer Reaction. Xin Huang, Weizhao Zhao, Yuchen Liang, Minghui Wang, Yalin Zhan, Yage Zhang, Lichun Kong, Zhi-Xiang Wang,* Bo Peng* Org. Chem. Front., 2021, 8, 1280.
（3）Dearomatization of Aryl Sulfoxides: A Switch between Mono- and Dual-Difluoroalkylation. Xin Huang, Yage Zhang, Weijian Liang, Qifeng Zhang, Yaling Zhan, Lichun Kong, Bo Peng* Chem. Sci., 2020, 11, 3048.
（4）ortho Difluoroalkylation of Aryliodanes with Enol Silyl Ethers through a Rearrangement Enabled by a Fluorine Effect. Xin Huang, Yage Zhang, Chaoshen Zhang, Lei Zhang, Ying Xu, Lichun Kong, Zhi-Xiang Wang,* Bo Peng*. Angew.Chem. Int. Ed. 2019, 58, 5956.
（5）Selective ortho C-H Cyanoalkylation of（Diacetoxyiodo）arenes via [3,3]-Sigmatropic Rearrangement.
Tian, J.; Luo, F.; Zhang, C.; Huang, X.（通訊作者）;* Zhang, Y.; Zhang, L.; Kong, L.; Hu, X.; Wang, Z.-X.;* Peng, B.* Angew. Chem. Int. Ed. 2018, 57, 9078.
（6）Benzyne-mediated trichloromethylation of chiral oxazolines. Xin Huang, Weizhao Zhao, De-Li Chen, Yaling Zhan, TingtingZeng, Huiquan Jin, Bo Peng* Chem. Commun., 2019, 55, 2070.
（7）Huang, X. *; Zhao, W.; Zhang, X.; Liu, M.; Vasconcelos, S. N. S.; Zhang, W.* One-pot Fluorination and Organocatalytic Robinson Annulation for Asymmetric Synthesis of Mono- and Difluorinated Cyclohexenones. Molecules2018, 23, 2251.
（8）Huang, X.*; Liu, M.; Jasinski, J. P.; Peng, B.; Zhang, W.* Recyclable Organocatalysts for a One-Pot Asymmetric Synthesis of 2-Fluorocyclohexanols Bearing Six Contiguous Stereocenters. Adv. Synth. Catal. 2017, 359, 1919.
（9）Huang, X.; Liu, M.; Pham, K.; Zhang, X.; Yi, W.-B.; Jasinski, J. P.; Zhang, W. Organocatalytic One-Pot Asymmetric Synthesis of Thiolated Spiro-γ-lactam Oxindoles Bearing Three Stereocenters. J. Org. Chem., 2016, 81, 5362.
（10） Huang, X.; Yi, W.-B.; Zhang, W. One-Pot Reactions for Modular Synthesis of Polysubstituted and Fused Pyridines. Org. Lett. 2016, 18, 5640
（11）Huang, X.; Pham, K.; Zhang, X.-F.; Yi, W.-B.; Hyatt, J.; Tran, A.; Jasinski, P. J.; Zhang, W. Recyclable Organocatalyst-promoted One-pot Michael/Aza-Henry/Lactamization Reactions for Fluorinated 2-Piperidinones bearing Four Stereogenic centres. RSC Adv. 2015, 5, 71071.
（12）Huang, X.; Pham, K.; Yi, W.-B.; Zhang, X.-F.; Clamens, C.; Hyatt, J.; Jasinski, P. J.; Tayvah, U.; Zhang, W. Recyclable Organocatalyst-Promoted One-Pot Asymmetric Synthesis of Spirooxindoles Bearing Multiple Stereogenic Centers. Adv. Synth. Catal. 2015, 357, 3820.
（13）Huang, X.; Yi, W.-B.; Ahad, D.; Zhang, W. Recyclable Cinchona Alkaloid Catalyzed Asymmetric Michael Addition Reaction. Tetrahedron Lett. 2013, 6064.
其他論文:
（14）Mengyuan Chen,+ Yuchen Liang,+ Taotao Dong, Weijian Liang, Yanping Liu, Yage Zhang, Xin Huang, Lichun Kong, Zhi-Xiang Wang,* Bo Peng. Z-Selective α-Arylation of α,β-Unsaturated Nitriles via [3,3]-Sigmatropic Rearrangement. Angew. Chem. Int. Ed. 2021, 60, 2339.
（15）Weizhao Zhao,+ Xin Huang,+ Yaling Zhan, Qifeng Zhang, Dongyang Li, Yage Zhang, Lichun Kong, Bo Peng. earomative Dual-Functionalization of Aryl Iodanes. Angew. Chem. Int. Ed. 2019, 25, 17210.
（16）Lei Zhang,+ Jia-Ni He,+ Yuchen Liang,+ Mengjie Hu, Li Shang, Xin Huang, Lichun Kong, Zhi-Xiang Wang,* Bo Peng.* Selective [5,5]-Sigmatropic Rearrangement by Assembly of Aryl Sulfoxides with Allyl Nitriles. Angew. Chem. Int. Ed. 2019, 58, 5316.
（17）Li Shang,+ Yonghui Chang,+ Fan Luo, Jia-Ni He, Xin Huang, Lei Zhang, Lichun Kong, Kaixiao Li, Bo Peng.* J. Am. Chem. Soc., 2017, 139, 4211.
（18）De-Li Chen,+ Yan Sun,+ Mengyuan Chen, Xiaojin Li, Lei Zhang, Xin Huang, Yihui Bai, Fang Luo, Bo Peng.* Desulfurization of Diaryl（heteroaryl）Sulfoxides with Benzyne. Org. Lett. 2019, 21, 3986.
（19）Yan Sun, Xin Huang, Xiaojin Li, Fan Luo, Lei Zhang, Mengyuan Chen, Shiya Zheng, Bo Peng. Mild Ring Contractions of Cyclobutanols to Cyclopropyl Ketones via Hypervalent Iodine Oxidation. Adv. Synth. Catal. 2017, 360, 1082.
（20）Li, X.; Sun, Y.; Huang, X.; Zhang, L.; Kong, L.; Peng, B. Synthesis of o-Aryloxy Triarylsulfonium Salts via Aryne Insertion into Diaryl Sulfoxides. Org. Lett. 2017, 19, 838.
專利申請
（3）黃鑫、陳孟源、彭勃，一種無金屬催化直接合成聯芳烴化合物的方，CN110015942A
（2）黃鑫、張亞鴿、許瀅、彭勃，一種鄰位含二氟亞甲基的芳基碘化合物及製備方法，CN109776295A
（1）黃鑫、張亞鴿、曾婷婷、靳慧全、許瀅，一種製備α-芳基腈化合物的方法CN108409602A
