郭勇(中國科學院上海有機化學研究所副研究員)

郭勇是浙江省中醫院教授，現為醫院腫瘤內科副主任，中華中醫藥學會腫瘤分會全國委員、浙江省醫學會腫瘤分會理事、浙江省中西醫結合腫瘤專業委員會主任委員，浙江省腫瘤康復專業委員會副主任，浙江省抗癌協會化療專業委員會副主任，浙江省藥理學會腫瘤化療和藥理專業委員會副主任等。

基本介紹

• 中文名：郭勇
• 國籍：中國
• 職業：中國科學院上海有機化學研究所副研究員
• 畢業院校：廈門大學
• 職務：醫院腫瘤內科副主任 

基本信息

姓 名: 　郭勇

性 別: 　男

職 稱: 　副研究員

學 歷: 　博士研究生

通訊地址: 　上海市零陵路345號

簡歷

教育背景

1992年－1996年，廈門大學，化學系，本科/學士；

1996年－2001年，中國科學院上海有機化學研究所，博士/研究生，陳慶雲（院士）；

2002年－2004年，日本岡山大學，自然科學研究科和工學部套用化學科，博士後，宇根山健治(Kenji Uneyama)教授；

2004年－2006年，日本岡山理科大學，高技術研究中心HTRC，博士後，村橋俊一(Shun-Ichi Murahashi)教授

2006年－2010年，美國愛達荷大學，化學系，博士後 ， Jean´ne M. Shreeve教授。

工作經歷

2010年－至今，中國科學院上海有機化學研究所，有機氟化學重點實驗室，研究生導師。

研究方向

有機氟化學

專家類別

副研究員

代表論著

1.Hu, H.; Huang, Y.; Guo, Y. “Henry reaction of fluorinated nitro compounds,” Journal of Fluorine Chemistry

2.Guo, C.; Wang R.-W.; Guo, Y.; Qing, F.-L. “Palladium-catalyzed direct α-arylation of α-fluoroketones: A straightforward route to α-fluoro-α-arylketones,” Journal of Fluorine Chemistry

3.Wang, W; Chen, Q.-Y.; Guo, Y. “TiCl4-Promoted Mukaiyama Aldol Reaction of Fluorinated Silyl Enolates for the Construction of a Quaternary Carbon Center,” Synlett

4.Lu, X.-Q.; Guo, Y.; Chen, Q.-Y. “Efficient Synthesis of meso-meso Linked Diporphyrins by Ni(0)-mediated Ullmann Homocoupling,” Synlett

5.Guo, Y.; Tao, G.-H.; Blumenfeld, A.; Shreeve, J. M. “Impact of Silyl Enol Ether Stability on Palladium-catalyzed Arylations,” Organometallics

6.Guo, Y.; Tao, G.-H.; Zeng, Z.; Gao, H.; Shreeve,J.M.“Energetic Salts Based on Monoanions of N,N-bis[1H-Tetrazol-5-yl]amine and 5,5’-Bis(tetrazole),” Chemistry - A European Journal

7.Wang, R.; Xu, H.; Guo, Y.; Sa, R.; Shreeve, J. M. “Bis[3-(5-nitroimino-1,2,4-triazolate)-based Energetic Salts: Synthesis and Promising Properties of a New Family of High Density Insensitive Materials,” Journal of the American Chemical Society

8.Zhang, Y.; Guo, Y.; Joo, Y-H.; Parrish, D. A.; Shreeve, J. M. 3,4,5-Trinitropyrazole-based Energetic Salts, Chemistry – A European Journal,

9.o, G.-H.; Guo, Y.; Parrish, D. A.; Shreeve, J. M. “Energetic 1,5-Diamino-4H-tetrazolium Nitro-substituted Azolates,” Jounral of Materials Chemistry

10.Wang, R.; Guo, Y.; Sa, R.; Shreeve, J. M. “Nitroguanidine-fused bicyclic guanidinium salts: A family of high density energetic materials,” Chemistry – A European Journal,

11.Zhang, Y.; Gao, H.; Guo, Y.; Joo, Y.-H.; Shreeve, J. M. “Hypergolic N,N-Dimethylhydrozimiun Ionic Liquids,” Chemistry – A European Journal,

12.Guo, Y.; Tao, G.-H., Joo, Y.-H., Wang, R.; Twanley, B.; Parrish, D. A.; Shreeve, J. M. “Impact Insensitive Dianionic Dinitrourea Salts: The CN4O52- Anion Paired with Nitrogen-Rich Cations,” Energy&Fuels

13.Guo,Y.; Zhao X.; Zhang, D.; Murahashi, S.−I. “Iridium−Catalyzed Reactions of Trifluoromethylated Compounds with Alkenes: A Csp3−H Bond Activation a-to the Trifluoromethyl Group,” Angewandte Chemie, 2009, 121, 2081-2083; Angewandte Chemie Internation Edition

14.Guo, Y.; Twamley, B.; Shreeve J. M. “Pd−Catalyzed Arylation of Silyl Enol Ethers of Substituted a−Fluoroketones,” Organic & Biomolecular Chemistry

15.Zeng, Z.; Guo, Y. Twamley, B.; Shreeve, J. M. “Energetic Polyazole Polynitrobenzenes and Their Coordination Complexes,” Chemical Communication

16.Wang, R.; Guo, Y.; Zeng, Z.; Shreeve, J. M. “Nitrogen−rich Nitroguanidine-functionalized Tetrazolate Energetic Salts,” Chemical Communications

17.Wang, R.; Guo, Y.; Zeng, Z.; Parrish, D. A.; Twamley, B.; Shreeve, J. M. “Furazan−functionalized Tetrazolate−based Salts: A New Family of Insensitive Energetic Materials,” Chemistry – A European Journal

18.Tao, G.−H.; Guo, Y.; Joo, Y.−H; Twamley, B.; Shreeve J. M. “Energetic Nitrogen−rich Salts and Ionic Liquids: 5−Aminotetrazole (AT) as a Weak Acid,” Journal of Materials Chemistry

19.Guo, Y.; Fujiwara, K.; Amii, H.; Uneyama, K. “Selective Defluorination Approach to N−Cbz−3,3−difluoro−2−difluoromethylenepyrrole and its Application to 3,3−Difluoroproline Dipeptide Synthesis,” Journal of Organic Chemistry

20.Guo, Y.; Shreeve, J. M. “Effect of Fluorine on Palladium−catalyzed Cross−coupling Reactions of Aryl Bromides with Trifluoromethyl Aryl Ketones via Difluoroenol Silyl or Monofluoroenol Silyl Ethers,” Chemical Communications,

21.Guo, Y.; Gao, H.; Twamley, B.; Shreeve, J. M. “Energetic Nitrogen Rich Salts of N, N−bis[1(2)H−tetrazol−5−yl]amine,” Advanced Materials,

22.Guo, Y.; Shreeve, J. M. “Difluoromethylene Compounds as Precursors to Ketones, Carboxylic Acids, Esters, Amides and Carbonates,” Journal of Fluorine Chemistry

23.Guo, Y.; Fujiwara, K.; Uneyama, K. “A Novel Route to Dipeptides via Noncondensation of Amino Acids: 2−Aminoperfluoropropene as a Synthon for Trifluoroalanine Dipeptides,” Organic Letters,

24.Xiao, J.−C.; Duan, J.−X.; Li, A.−R.; Guo, Y.; Chen Q.−Y. “A Simple Method for Preparing Difluorodiodomethane from Difluoro(fluorosulfonyl)acetyl Fluoride,” Collection of Czechoslovak Chemical Communications

25.Guo, Y.; Chen, Q.−Y. “Iododifluoromethyl Alkenes [ICF2CH=CHR]: a Labile System Generated from 1,1−Difluoro−1,3−Diiodoalkanes and its Trapping with Nucleophiles,” Journal of Fluorine Chemistry

26.Guo, Y.; Chen. Q.-Y “The Reaction and its Product Conversion of Diflourodiiodomethane with Ethyl Vinyl Ether,” Acta Chimica Sinica 《化學學報》

27.Guo, Y.; Chen. Q.-Y “The Electron Transfer Reactions of 1,3-Diiodohexafluoropropane,” Acta Chimica Sinica《化學學報》

28.Guo, Y.; Chen, Q.−Y. “The Reactions of Difluorodiiodomethane with Nucleophiles,” Journal of Fluorine Chemistry

會議論文

Uneyama, K.; Guo, Y.; Fujiwara, K.; Komatsu, Y. “A Novel Strategy for the Synthesis of Trifluoroalanine Oligopeptides,” Current Fluoroorganic Chemistry, 2007, ACS Symposium Series 949, Chapter.