趙蓓，女，現任蘇州大學材料與化學化工學部有機化學研究所教授、博士生導師。
基本介紹
- 中文名：趙蓓
- 國籍：中國
- 民族：漢族
- 出生地：蘇州
- 職業：高校教師
- 畢業院校：蘇州大學
- 學位/學歷：博士研究生/博士學位
- 專業方向：有機化學
- 職務：教授、博士生導師
人物經歷,研究方向,主要貢獻,
人物經歷
1992年蘇州大學化學教育專業本科畢業，1995年蘇州大學有機化學專業畢業，獲碩士學位，期間赴南開大學做訪問學者1年。1995年留校工作，2006年獲有機化學博士學位。
2011年獲得江蘇政府留學基金資助，赴新加坡訪學。
2011年獲得江蘇政府留學基金資助，赴新加坡訪學。
研究方向
稀土金屬有機化合物的合成、結構及其催化性質，導向有機合成的金屬有機化學，不對稱合成等。
主要貢獻
主持國家自然科學基金2項，江蘇省高校自然科學研究項目1項，參加2項國家自然科學基金項目和1項省部級項目。在國內外化學核心期刊如Green Chem., Org. Lett., Org. Chem. Front., Dalton Trans., Organometallics, Catal. Sci. Technol., J. Polym. Sci. Polym. Chem.等發表論文數十篇，授權發明專利4項。2009年度獲江蘇省科學技術進步獎二等獎，2010年獲得中國石油和化學工業協會科學技術進步獎一等獎。
主要論文：
1. Intermolecular addition of alcohols to carbodiimides catalyzed by rare-earth metal amides
L. J. Hu,C. R. Lu,B. Zhao*, Y. M. Yao
Org. Chem. Front.,2018, DOI: 10.1039/C7QO00991G
2. An amidato divalent ytterbium cluster: synthesis and molecular structure, its reactivity to carbodiimides and application in the guanylation reaction
C. Gong, H. Ding, C. R. Lu,B. Zhao*, Y. M. Yao
Dalton Trans.,2017,46, 6031-6038.
3.Efficient asymmetric hydrophosphonylation of unsaturated amides catalyzed by rare-earth metal amides [(Me3Si)2N]3RE(m-Cl)Li(THF)3with phenoxy-functionalized chiral prolinols
Z. H. Fei, C. Zeng, C. R. Lu,B. Zhao*, Y. M. Yao
RSC Adv.2017,7, 19306-19311.
4.Synthesis and characterization of bridged bis(amidato) rare earth metal amides and their applications in C–N bond formation reactions
B. Zhao,* Y. Xiao, D. Yuan, C. R. Lu, Y. M. Yao
Dalton Trans.2016,45, 3880-3887.
5. Asymmetric michael addition of malonates to unsaturated ketones catalyzed by rare earth metal complexes bearing phenoxy functionalized chiral diphenylprolinolate ligands
Q. Q. Qian, W. G. Zhu, C. R. Lu,B. Zhao*, Y. M. Yao
Tetrahedron: Asy.2016,27, 911-917.
6.Synthesis and characterization of amidato divalent lanthanide complexes and their use in forming 2,4-quinazolidinones from CO2and 2-aminobenzonitriles
Q. Y.Wang,C. R.Lu,B.Zhao*,Y. M.Yao
Eur. J. Org. Chem.,2016, 2555-2559.
7. Carboxylation of terminal alkynes with CO2catalyzed by bis(amidate) rare-earth metal amides
H. Cheng,B. Zhao,* Y. M. Yao, C. R. Lu
Green Chem.,2015,17, 1675-1682.
8.Highly enantioselective epoxidation ofα,β-unsaturated ketones catalyzed by rare-earth amides [(Me3Si)2N]3RE(μ-Cl)Li(THF)3with phenoxy-functionalized chiral prolinols
C. Zeng, D. Yuan,B. Zhao,* Y. M. Yao
Org. Lett.,2015,17, 2242-2245.
9. Synthesis and characterization of bis(amidate) rare-earth metal amides and their application in catalytic addition of amines to carbodiimides
H. Cheng, Y. Xiao, C. R. Lu,B. Zhao,* Y. R. Wang, Y. M. Yao
New J. Chem.,2015,39, 7667-7671.
10. Synthesis and characterization of rare-earth metal complexes supported by a new pentadentate Schiff base and their application in heteroselective polymerization of rac-lactide
Y. Cui, W. K. Gu, Y. R. Wang,*B. Zhao,* Y. M. Yao, Q. Shen
Catal. Sci. Technol.,2015,5, 3302-3312.
11.Synthesis and characterization of rare-earth metal guanidinates stabilized by amine-bridged bis(phenolate) ligands and their application in the controlled polymerization ofrac-lactide andrac-b-butyrolactone
T. H. Zeng, Q. Q. Qian,B. Zhao,* D. Yuan, Y. M. Yao*, Q. Shen
RSC Adv.2015,5, 53161-53171.
12.C-N bond formation reaction catalyzed by Organo-rare-earth metal amides (Invited Review)
Y. Xiao, Q. Y. Wang,B. Zhao*, Y. M. Yao*
Chin. J. Org. Chem.2015,35, 1598-1614.
13.Asymmetric epoxidation of unsaturated ketones catalyzed by heterobimetallic rare-earth-lithium complexes bearing phenoxy functionalized chiral diphenylprolinolate ligand
Q. Q. Qian, Y. F. Tan,B. Zhao,* T. Feng, Q. Shen, Y. M. Yao*
Org. Lett.,2014,16,4516-4519.
14.Synthesis and characterization of amidate rare-earth metal amides and their catalyticactivities towardhydrophosphonylation of aldehydes and unactivated ketones
L. Zhao, H. Ding,B. Zhao,* C. R. Lu, Y. M. Yao
Polyhedron,2014,83, 50-59.
15. Asymmetric hetero-Diels-Alder reaction of Danishefsky’s dienes witha-carbonyl esters catalyzed by an indium(III)-PyBox complex
B. Zhao, T. P. Loh
Org. Lett.,2013,15, 2914-2917.
16.Unexpected C−H bond activation promoted by bimetallic lanthanide amido complexes bearing a META-phenylene bridged bis(β-diketiminate) ligand
S. Sun, Q. Sun,B. Zhao*, Y. Zhang, Q. Shen, Y. M. Yao*
Organometallics,2013,32, 1876-1881.
17.Bimetallic lanthanide amido complexes as highly active initiators for the ring-opening polymerization of lactides
S.Sun, K. Nie, Y. F. Tan,B. Zhao*, Y. Zhang, Q. Shen, Y. M. Yao*
Dalton Trans.,2013,42, 2870-2878.
18.Synthesis and structural diversity of lanthanide amidate complexes and their catalytic activities for the ring-opening polymerization ofrac-lactide
X.L. Hu, C. R. Lu, B. Wu, H. Ding,B. Zhao*, Y. M. Yao*, Q. Shen
J. Organomet. Chem.,2013,732, 92-101.
19.Addition of terminal alkynes to aromatic nitriles catalyzed by divalent lnathanide amides supported by amidates: synthesis of ynones
H. Ding, C. R. Lu, X. L. Hu,B. Zhao*, B. Wu, Y. M. Yao*
Synlett,2013,24, 1269-1274.
20.Ring-opening polymerization of trimethylenecarbonate by the bridged diphenoxo ytterbium (II) complex
B. Zhao, X. L. Hu, C. R. Lu
J. Appl. Polym. Sci.,2011,120, 2693.
21.One-pot synthesis of salicylanilides by direct amide bond formation from salicyclic acid under microwave irradiation
C. R. Lu,B. Zhao*, Y. P. Jiang, H. Ding, S. Yang
Syn. Commun.,2011,41, 1257.
22.Ring-opening polymerization of trimethylenecarbonate and its copolymerization withe-caprolactone by lanthanide (II) aryloxide complexes
B. Zhao, C. R. Lu, Q. Shen
J. Appl. Polym. Sci.,2007,106, 1383.
23. Metallomacrocycle complexes of lanthanides with bridged amide ligands: syntheses and molecular structures of [{μ2-p-(Me3SiN)2C6H4}YbCl(THF)2]2and [{μ2-p-(Me3SiN)2C6H4}Nd(μ2-Cl)(THF)]4·2PhMe
B. Zhao, H. H. Li, Q. Shen, Y. Zhang, Y. M. Yao, C. R. Lu
Organometallics,2006,25, 1824.
24.Polymerization of N-phenyl maleimide by lanthanide complexes
B. Zhao, Y. R. Wang, C. R. Lu, Q. Shen, M. Y. Deng
J.Polym. Sci. Polym. Chem.,2005,43, 3966.
