趙育磊

趙育磊

趙育磊，曲阜師範大學化學與化工學院教師。

基本介紹

  • 中文名：趙育磊
  • 畢業院校：華東師範大學 
  • 學位/學歷：博士 
  • 職業：教師
  • 任職院校：曲阜師範大學
個人簡介,科研項目,發表論文,專利,

個人簡介

趙育磊，青年教授，綠色有機合成課題組組長，碩士生導師。主要從事二氧化碳利用、有機電合成、高附加值分子構建研究。2017年6月於華東師範大學獲理學博士學位，同年7月加入曲阜師範大學（2017年7月-2019年12月，講師；2019年12月-，副教授；2023年12月-，青年教授；2019年7月-，有機教研室主任；2022年11月-，工會青年工作委員）；主講《有機化學》、《有機合成化學》、《有機化學實驗》、《中級化學實驗》等課程；擔任國家自然科學基金委項目評議人（通訊評審專家）、美國化學會期刊審稿人、英國皇家化學會期刊審稿人等。獲山東省化學化工學會“自然科學獎”二等獎（首位，2022年），山東省優秀碩士學位論文指導教師（2023年），山東省第十屆高校青年教師教學比賽優秀獎（2023年）；獲曲阜師範大學“優秀研究生指導教師”（2022年、2023年）、“優秀碩士學位論文指導教師”（2022年）、“優秀學士學位論文指導教師”（2023年）、第十三屆青年教師教學比賽一等獎（2023年）、第十二屆青年教師教學比賽二等獎（2022年）、第十屆青年教師教學比賽三等獎（2020年）等。

科研項目

  1. 主持“國家自然科學基金面上項目”（2024-2027）；
  2. 主持“山東省自然科學基金面上項目”（2022-2024）；
  3. 主持“山東省自然科學基金青年類項目”（2018-2020）；
  4. 主持“曲阜師範大學科研啟動基金項目”（2017-）；
  5. 主持“曲阜師範大學教學改革項目”；
  6. 指導“國家級大創項目”（2021-2023）；
  7. 指導“省級大創項目”（2019-2021）；
  8. 指導“曲阜師範大學大創項目”（2018-2019）。

發表論文

  1. Ruiqing Wang, Lingkai Kong, Xinyu Zong, Minghui Zhang, Wenyi Chen, Yaxin Liu, Lingjuan Ma, Yulei Zhao, Diazenylation of active methyne compounds via arylazo sulfones, Org. Chem. Front. 2024, 11, 2815-2820.
  2. Yuhang Fan, Zhanshuo Zhang, Yulei Zhao, Self-detachable protecting group function of CO2 in the electrochemical reduction of aryl azides, Org. Chem. Front. 2024, 11, 1184-1191.
  3. Yuhang Fan, Chao Chen, Zhanshuo Zhang, Xiaohan Meng, Xiaonuo Liu, Jun Cao, Yuan-Ye Jiang, Yulei Zhao, CO2 Transient Promotion Function Enabled the Selective Electrochemical Transformation of Imines, Org. Lett. 2023, 25, 9202–9206.
  4. Xiaotong Dong, Xiaonuo Liu, Lei Wang, Yixuan Zhang, Jiale Li, Laijin Tian, Yulei Zhao,Catalyst-Free gem-Difluorination/Spirocyclization of Indole-2-carboxamides: Synthesis of C2-Spiroindoline Derivatives, Org. Lett. 2023, 25, 8771–8776.
  5. Yulei Zhao, Shuai Li, Yuhang Fan, Jun Cao, Xiaotong Dong, Ruiqing Wang, Laijin Tian, Csp3–H Imination Using Arylazo Sulfone as a N Source: An Approach to Access Imines, Org. Lett. 2023, 25, 5911-5915.
  6. Yulei Zhao, Shuai Li, Yuhang Fan, Chao Chen, Xiaotong Dong, Ruiqing Wang, Yuan-Ye Jiang, Mild diazenylation of Csp2-H and Csp3-H bond via arylazo sulfones, Org. Chem. Front. 2023, 10, 5923-5932.
  7. Yulei Zhao, Xuqiang Guo, Shuai Li, Yuhang Fan, Guo-Cui Ji, Mengmeng Jiang, Yin Yang, Yuan-Ye Jiang, Transient Stabilization Effect of CO2 in the Electrochemical Hydrogenation of Azo Compounds and the Reductive Coupling of α-Ketoesters, Angew. Chem. Int. Ed. 2022, 61, e202213636.
  8. Yulei Zhao, Huimin Wang, Xin Kang, Ruihua Zhang, Nan Feng, Qi Su, Controllable Methylenation with Ethylene Glycol as Methylene Source: Bridging Enaminones and Synthesis of Tetrahydropyrimidines, Org. Chem. Front. 2022, 9, 5935-5941.
  9. Yulei Zhao, Yuhang Fan, Xiaohan Meng, Xin Kang, Zhongyin Ji, Shina Yan, Laijin Tian, Electrochemical Cyclization of Alkynyl Enaminones: Controllable Synthesis of Indeno[1,2-c]pyrroles or Indanones, J. Org. Chem. 2022, 87, 11131-11140.
  10. Yulei Zhao, Shuai Li, Yuhang Fan, Huimin Wang, Xin Kang, Zhongyin Ji, Laijin Tian, Synthesis of Polycyclic 3,3ʹ-Biindoles via AgOTf-Catalyzed Nucleophilic Addition and Cycloisomerization, J. Org. Chem. 2022, 87, 6418-6425.
  11. Yulei Zhao, Shuai Li, Jinjie Cui, Huimin Wang, Xin Kang, Yan Wang, Laijin Tian, Selectfluor-Mediated Oxidative Dehydrogenation of Hydrazines: A Process for the Synthesis of Azo Compounds, Synthesis-Stuttgart 2022, 54, 5245-5252.
  12. Xuqiang Guo, Xuejun Sun, Mengmeng Jiang, Yulei Zhao, Switchable Synthesis of Sulfoxides, Sulfones and Thiosulfonates through Selectfluor-Promoted Oxidation with H2O as O-Source, Synthesis-Stuttgart 2022, 54, 1996-2004.
  13. Yulei Zhao, Xuqiang Guo, Shuai Li, Yuhang Fan, Xuejun Sun, Laijin Tian, PhB(OH)2 Promoted Electrochemical Sulfuration-Formyloxylation of Styrenes and Selectfluor Mediated Oxidation-Olefination, Org. Lett. 2021, 23, 9140–9145.
  14. Yulei Zhao, Xuqiang Guo, Ruihua Zhang, Shuai Li, Tingting Chen, Xuejun Sun, CF3CO2H-Catalyzed Synthesis of 3-Alkynylpyrrole Derivatives and Their Controlled Reduction, J. Org. Chem. 2021, 86, 15568-15576.
  15. Yulei Zhao, Shuai Li, Yuhang Fan, Xuqiang Guo, Xin Jiao, Laijin Tian, Xuejun Sun, Synthesis of 10H-indolo[1,2-a]indole Derivatives via Intramolecular Cycloaddition and H-Migration, Eur. J. Org. Chem. 2021, 4358–4363.
  16. Xiao-Yuan Cui, Yu-Lei Zhao, Yan-Mei Chen, Su-Zhen Dong, Feng Zhou, Hai-Hong Wu, Jian Zhou, Au-Catalyzed Formal Allylation of Diazo(thio)oxindoles: Application to Tandem Asymmetric Synthesis of Quaternary Stereocenters, Org. Lett. 2021, 23, 4864–4869.
  17. Duyi Shen, Hongyan Wang, Yanan Zheng, Xinjing Zhu, Peiwei Gong, Bin Wang, Jinmao You, Yulei Zhao, Mianran Chao, Catalyst-Free and Transition-Metal-Free Approach to 1,2-Diketones via Aerobic Alkyne Oxidation, J. Org. Chem. 2021, 86, 5354-5361.
  18. Yulei Zhao, Xuqiang Guo, Xin Ding, Zheng Zhou, Man Li, Nan Feng, Bowen Gao, Xu Lu, Yunlin Liu, Jinmao You, Reductive CO2 Fixation via the Selective Formation of C−C Bonds: Bridging Enaminones and Synthesis of 1,4-Dihydropyridines, Org. Lett. 2020, 22, 8326−8331.
  19. Yulei Zhao, Xuqiang Guo, Zhiyao Si, Yanan Hu, Ying Sun, Yunlin Liu, Zhongyin Ji, Jinmao You, Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines, J. Org. Chem. 2020, 85, 13347−13353.
  20. Yulei Zhao, Xu Liu, Lijun Zheng, Yulan Du, Xinrui Shi, Yunlin Liu, Zhengquan Yan, Jinmao You, Yuanye Jiang, One-Pot Methylenation−Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones, J. Org. Chem. 2020, 85, 912-923.
  21. Yulei Zhao, Xuqiang Guo, Yulan Du, Xinrui Shi, Shina Yan, Yunlin Liu, Jinmao You, Synthesis of fused-tetrahydropyrimidines: one-pot methylenation-cyclization utilizing two molecules of CO2, Org. Biomol. Chem. 2020, 18, 6881–6888.
  22. Yuanyang Mu, Yang Yuan, Ye Wang, Murong Xu, Ye Feng, Yulei Zhao, Yanzhong Li, Synthesis of indoline-fused eight-membered azaheterocycles through Zn-catalyzed dearomatization of indoles and subsequent base-promoted C-C activation, Org. Biomol. Chem. 2020, 18, 6916–6926.
  23. Yulei Zhao, Xuqiang Guo, Zongkang Wang, Duyi Shen, Tingting Chen, Nan Wu, Shina Yan, Jinmao You, TBAF-Catalyzed Cyclization Reactions of o-(Alkynyl)phenyl Propargyl Alcohols with Malonate Esters: A Possible Cation–π Interaction as The Activation Approach, Eur. J. Org. Chem. 2020, 978–984.
  24. Yulei Zhao, Zheng Zhang, Xu Liu, Zongkang Wang, Ziping Cao, Laijin Tian, Mingbo Yue, Jinmao You, TBAF-Catalyzed O‑Nucleophilic Cyclization of Enaminones: A Process for the Synthesis of Dihydroisobenzofuran Derivatives, J. Org. Chem. 2019, 84, 1379−1386.
  25. Shu-Jie Chen, Guo-Shu Chen, Jia-Wei Zhang, Zhao-Dong Li, Yu-Lei Zhao, Yun-Lin Liu, Phosphine-catalyzed [3+2] cycloadditions of trifluoromethyl enynes/enediynes with allenoates: access to cyclopentenes containing a CF3-substituted quaternary carbon center, Org. Chem. Front. 2020, 7, 3399-3405.
  26. Jian Luo, Guo-Shu Chen, Shu-Jie Chen, Zhao-Dong Li, Yu-Lei Zhao, Yun-Lin Liu, One-Pot Tandem Protocol for the Synthesis of 1,3-Bis(βaminoacrylate)-Substituted 2-Mercaptoimidazole Scaffolds, Adv. Synth. Catal. 2020, 362, 3635– 3643.
  27. Jian Luo, Yu-Bo Fang, Xiang-Yu Mao, Meng Yang, Yu-Lei Zhao, YunLin Liu, Guo-Shu Chen, Yong-Fei Ji, Organocatalytic Asymmetric Cyclization Reaction of 2-Alkynyl3,3-Difluoro-3H-Indoles and 2-Mercaptoimidazoles: Access to gem-Difluorinated C2-Spiro Indolines, Adv. Synth. Catal. 2019, 361, 1408-1413.
  28. Zhengquan Yan, Hua Yuan, Qi Zhao, Lin Xing, Xiaoyu Zheng, Weiguo Wang, Yulei Zhao, Yang Yu, Lei Hu Wenli Yao, Recent developments of nanoenzyme-based colorimetric sensors for heavy metal detection and the interaction mechanism, Analyst 2020, 145, 3173-3187.
  29. Ling Zhu, Ling-Jun Liu, Yuan-Ye Jiang, Peng Liu, Xia Fan, Qi Zhang, Yulei Zhao, Siwei Bi, Mechanism and Origin of Ligand-Controlled Chemo- and Regioselectivities in Palladium-Catalyzed Methoxycarbonylation of Alkynes, J. Org. Chem. 2020, 85, 7136-7151.
  30. 顏世娜，孫敏，許麗榮，孫學軍，趙育磊，師範院校有機化學實驗教學改革探討，《科技視界》，2022，第25期，100-112.
  31. Yulei Zhao, Murong Xu, Zhong Zheng, Yang Yuan, Yanzhong Li Tertiary amine self-catalyzed intramolecular Csp3-H functionalization with in situ generated allenes for the formation of 3-alkenyl indolines, Chem. Commun. 2017, 53, 3721-3724.
  32. Yu-Lei Zhao, Zhong-Yan Cao, Xing-Ping Zeng, Jia-Meng Shi, Yi-Hua Yu, Jian Zhou, Asymmetric sequential Au(I)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles, Chem. Commun. 2016, 52, 3943-3946.
  33. Zhong-Yan Cao, Yu-Lei Zhao, Jian Zhou, Sequential Au(I)/chiral tertiary amine catalysis: a tandem C–H functionalization of anisoles or a thiophene/asymmetric Michael addition sequence to quaternary oxindoles, Chem. Commun. 2016, 52, 2537-2540.
  34. Yulei Zhao, Yang Yuan, Xiaoyu Wang, Yanzhong Li, Synthesis of Polycyclic Benzo[b]indolo[3,2,1-de]acridines via Sequential Allenylation, Diels−Alder Cyclization, and Hydrogen Migration Reaction, J. Org. Chem. 2017, 82, 11198-11205.
  35. Yulei Zhao, Yang Yuan, Murong Xu, Zhong Zheng, Runhua Zhang, Yanzhong Li, Selective synthesis of pyrrolo[1,2-a]azepines or 4,6-dicarbonyl indoles via tandem reactions of alkynones with pyrrole derivatives, Org. Biomol. Chem. 2017, 15, 6328-6332.
  36. Yulei Zhao, Yang Yuan, Lingkai Kong, Fangfang Zhang, Yanzhong Li, Synthesis of 1-Alkyl-3-(2-oxo-2-aryl/alkyl-ethyl)indolin-2-ones through Gold/Brønsted Acid Relay Actions: Observation of Selective C=C Bond Cleavage of Enaminones, Synthesis-Stuttgart 2017, 49, 3609-3618.
  37. Yulei Zhao, Qizhao Duan, Yuanyuan Zhou, Qiyi Yao, Yanzhong Li, Gold-catalyzed chemo- and diastereoselective C(sp2)–H functionalization of enaminones for the synthesis of pyrrolo[3,4-c]-quinolin-1-one derivatives, Org. Biomol. Chem. 2016, 14, 2177-2181.
  38. Yulei Zhao, Fangfang Zhang, Wenjun Yao, Chengyu Wang, Yuanyuan Liu, Yanzhong Li, Base-Promoted Approach to Highly Functionalized Conjugated Dienes through Enamine Migration, Eur. J. Org. Chem. 2015, 7984-7991.
  39. Yun-Lin Liu, Xin Wang, Yu-Lei Zhao, Feng Zhu, Xing-Ping Zeng, Long Chen, Cui-Hong Wang, Xiao-Li Zhao, Jian Zhou, One-Pot Tandem Approach to Spirocyclic Oxindoles Featuring Adjacent Spiro-Stereocenters, Angew. Chem. Int. Ed. 2013, 52, 13735-13739.
  40. Wei-Ming Gao, Jin-Sheng Yu, Yu-Lei Zhao, Yun-Lin Liu, Feng Zhou, Hai-Hong Wu, Jian Zhou, Highly enantioselective Michael addition of 3-arylthio- and 3-alkylthiooxindoles to nitroolefins catalyzed by a simple cinchona alkaloid derived phosphoramide, Chem. Commun. 2014, 50, 15179-15182.
  41. Fangfang Zhang, Zhengchen Qin, Lingkai Kong, Yulei Zhao, Yuanyuan Liu, Yanzhong Li, Metal/Benzoyl Peroxide (BPO)-Controlled Chemoselective Cycloisomerization of (o‑Alkynyl)phenyl Enaminones: Synthesis of α‑Naphthylamines and Indeno[1,2‑c]pyrrolones, Org. Lett. 2016, 18, 5150-5153.
  42. Yuanyuan Zhou, Xianghua Tao, Qiyi Yao, Yulei Zhao, Yanzhong Li, Insertion of Isolated Alkynes into Carbon–Carbon s-Bonds of Unstrained Cyclic b-Ketoesters via Transition-Metal-Free Tandem Reactions: Synthesis of Medium-Sized Ring Compounds, Chem. Eur. J. 2016, 22, 17936-17939.

專利

  1. 趙育磊，劉旭，鄭麗君，郭旭強，杜鈺蘭，師欣蕊，萬竹婷，陳婷婷，丁鑫，周政，一種四氫嘧啶類衍生物的合成方法，專利號：ZL201910657604.6，授權號：CN110218190B，申請日：2019.07.20，授權日：2021.02.12
  2. 趙育磊，王宗康，郭旭強，陳婷婷，張瑞華，馮楠，呂夢，胡雅楠，孫瑩，董永平，何夢瑤，劉振翠，一種異苯並呋喃雙酯類衍生物及其合成方法，專利號：ZL201910882550.3，授權號：CN110669030B，申請日：2019.09.18，授權日：2021.05.18
  3. 趙育磊，司志姚，郭旭強，胡雅楠，孫瑩，董永平，高博文，盧旭，武博翰，成倩倩，臧青，一種脲類衍生物及其合成方法，專利號：ZL201911069763.0，授權號：CN110683969B，申請日：2019.11.05，授權日：2022.05.17
  4. 趙育磊，張正，王宗康，司志姚，傅德斌，劉旭，鄭麗君，李曼，李慧婷，孟占乾，劉璐，李瑞，吳楠，一種1,3-二氫異苯並呋喃衍生物及其合成方法和套用，專利號：ZL201810991246.8，授權號：CN108947945B，申請日：2018.08.28，授權日：2022.08.02
  5. 趙育磊，李曼，丁鑫，周政，馮楠，盧旭，高博文，郭旭強，杜鈺蘭，師欣蕊，陳婷婷，一種1,4-二氫吡啶類衍生物及其合成方法，專利號 ZL201911334044.7，授權號：CN110981790B，申請日：2019.12.23，授權日：2022.10.14
  6. 趙育磊，李帥，蔣蒙蒙，王慧敏，康欣，蘇琦，崔金潔，焦鑫，孟曉含，紀淑欣，秦譽真，唐堉森，一種稠環3,3’-聯吲哚衍生物及其合成方法，申請號：202210090490.3，申請日：2022.01.25
  7. 趙育磊，王慧敏，康欣，馮楠，張瑞華，蘇琦，陳麗薈，陳文靜，一種四氫嘧啶類衍生物及其製備方法，專利號：ZL202210873953.3，申請日：2022.07.21。
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