譚澤,男,1973年1月23日出生於湖南省長沙市寧鄉縣,本科畢業於湖南大學化學化工學院分析化學專業。博士畢業於Purdue University化學系。2007年1月回國在湖南大學化學化工學院任教授,成為湖南大學“985工程”化學生物創新平台郭燦城教授負責的教育部仿生催化工程中心引進人員。入選2009年教育部新世紀優秀人才計畫。
基本介紹
- 中文名:譚澤
- 國籍:中國
- 出生地:湖南省長沙市寧鄉縣
- 出生日期:1973年1月23日
- 職業:教授;博士導師
- 畢業院校:湖南大學;Purdue University
個人介紹,研究成果,近期發表論文,項目,
個人介紹
譚澤,男,1973年1月23日出生於湖南省長沙市寧鄉縣,1990-1994在湖南大學化學化工學院分析化學專業學習並取得學士學位。1994年去美國Bowling Green State University化學系學習有機化學並在2年後轉去Purdue University化學系攻讀博士並於2002年8月取得理學博士學位。師從世界上著名的金屬有機化學家,2010年諾貝化學獎獲得者Ei-ichi Negishi教授並在博士畢業後繼續在Negishi教授組從事博士後研究工作4年多。曾參加美國國家衛生所(NIH)和美國國家自然科學基金(NSF)研究項目多項並為數個子項目的主要研究成員。
於2007年1月回國在湖南大學化學化工學院任教授,成為湖南大學“985工程”化學生物創新平台郭燦城教授負責的教育部仿生催化工程中心引進人員。2007年7月獲準為博士導師。
現主持湖南大學引進人才基金,國家自然科學基金項目“運用鈀催化的甲酯或乙酯等簡單酯類化合物的Suzuki偶聯合成酮類化合物” (批准號20702012),教育部回國留學基金,湖南大學化學計量學與感測技術國家重點實驗室開放基金項目“一氧化氮(NO)表面增強拉曼散射探針研究” (批准號2007017)等多項研究項目, 並於2008年8月成為2008年湖南省普通高校學科帶頭人培養對象。併入選2009年教育部新世紀優秀人才計畫。
研究成果
研究主要集中在金屬催化和不對稱合成領域,取得了許多成果,近幾年已在世界有名的化學期刊上發表多篇論文,其中包括:美國科學院雜誌一篇 (PNAS)、美國化學學會會志二篇 (JACS)、德國套用化學二篇 (ACIE)、有機快報三篇 (OL)、英國化學通訊二篇(CC)。來湖南大學後已發表30多篇。 分別參與了Handbook of Organopalladium Chemistry for Organic Synthesis、Metal-catalyzed Cross-Coupling Reactions、Topics in Organometallic Chemistry (2004)三著作中三章節的撰寫。前兩著作已成為全世界關於鈀催化和偶聯反應的權威參考書籍。
近期發表論文
- Selective Synthesis of Aryl Nitriles and 3-Imino-1-oxoisoindolines via Nickel-Promoted C(sp)–H Cyanations. Lin Yu, Xiang Chen, Ze-Nan Song, Da Liu,Liang Hu, Yongqi Yu, Ze Tan*, and Qingwen Gui.Org. Lett. 20, 3206-3210,2018. (IF=6.579)
- Direct Synthesis of Primary Anilines via Nickel‐mediated C(sp)‐H Aminations. Lin Yu, Xiang Chen, Da Liu, Liang Hu, Yongqi Yu, Hang Huang, Ze Tan,*and Qingwen Gui. Adv. Synth. Catal. 360, 1346– 1351, 2018. (IF=6.453)
- Highly mono-selectiveortho-methylthiolation of benzamidesviacobalt-catalyzed spC–H activation. Liang Hu,Xiang Chen,Lin Yu,Yongqi Yu,Ze Tan,*Gangguo Zhu andQingwen Gui. Org. Chem. Front., 5, 216-221,2018. (IF=4. 955)
- Synthesis of 4-benzylpyridinesviaPd-catalyzed CH3-arylation of 4-picoline. Jing Wu,Dadian Wang,Xiang Chen,Qingwen Gui,Hua Li,Ze Tan*,Genping Huang andGuangwei Wang, Org. Biomol. Chem., 15, 7509-7512, 2017. (IF=3.559)
- Copper-catalyzed decarboxylative methylthiolation of aromatic carboxylate salts with DMSO. Liang Hu,Dadian Wang,Xiang Chen,Lin Yu,Yongqi Yu,Ze Tan* andGangguo Zhu, Org. Biomol. Chem., 15, 5674-5679,2017. (IF=3.559)
- Efficient syntheses of 3-hydroxyimino-1-isoindolinones and 3-methylene-1-isoindolinonesvia Cu-promoted C–H activation–nitroalkylation–intramolecular cyclization tandem processes. Lin Yu,Hang Huang,Xiang Chen,Liang Hu,Yongqi Yu and Ze Tan*, Chem. Commun.,53, 4597-4600, 2017.(IF=6.567)
- Cobalt-promoted selective arylation of benzamides and acrylamides with arylboronic acids,Liang Hu,Qingwen Gui,Xiang Chen, Ze Tan* andGangguo Zhu,Org. Biomol.Chem.,14, 11070-11075, 2016.(IF=3.559)
- HOTf-Catalyzed, Solvent-Free Oxyarylation of Ynol Ethers and Thioethers,Liang Hu,Qingwen Gui,Xiang Chen,Ze Tan*, and Gangguo Zhu, J. Org. Chem., 81(11), 4861–4868,2016(IF=4.785)
- Highly mono-selective ortho-trifluoromethylation of benzamides via 8-aminoquinoline assisted Cu-promoted C–H activations.Liang Hu, Xiang Chen, Qingwen Gui,Ze Tan* and Gangguo Zhu. Chem. Commun., 52, 6845--6848 | 6845,2016.(IF=6.567)
- Photocatalytic/Cu-promoted CH-activations: Visible light induced ortho-selective perfluoroalkylation of benzamides, Xiang Chen,Ze Tan,* Qingwen Gui,Liang Hu, Jidan Liu,Jing Wu and Guangwei Wang,* .Chem. Eur. J, 22, 6218 – 6222, 2016.(IF=5.771)
- Copper-Catalyzed or Mediated C-H bond Functionalizations Assisted by Bidentate Directing Groups,Jidan Liu,* Guoshu Chen,Ze Tan,* Adv. Synth. Catal., 358,1174 –1194 2016.(IF=6.453)
- Copper-Mediated ortho-Arylation of Benzamides with Arylboronic Acid, Qingwen Gui, Xiang Chen, Liang Hu, Dadian Wang, Jidan Liu,Ze Tan,*Adv. Synth. Catal., 358, 509-514, 2016(IF=6.453).
- Stereoselective synthesis of vinylphosphonates and phosphine oxides via silver-catalyzed phosphorylation of styrenes,Qingwen Gui, Liang Hu, Xiang Chen, Jidan Liu,Ze Tan,* Chem. Commun., 51, 13922-13924, 2015.(IF=6.567)
- Copper-mediated ortho C-H sulfonylation of benzoic acid derivatives with sodium sulfinates,Jidan Liu, Lin Yu, Shaobo Zhuang, Qingwen Gui, Xiang Chen, Wenduo Wang,Ze Tan,* Chem. Commun., 51, 6418-6421, 2015.(IF=6.567)
- A rapid and selective synthesis of α,α-fluorohalo esters via fluorohalogenative or difluorinative hydration of ynol ethers, Liang Hu, Chao Che,Ze Tan,* Gangguo Zhu,*Chem. Commun., 51, 16641-16644, 2015.(IF=6.567)
- Copper-Mediated ortho-Nitration of Arene and Heteroarene C-H Bonds Assisted by an 8-Aminoquinoline Directing Group,Jidan Liu, Shaobo Zhuang, Qingwen Gui, Xiang Chen, Zhiyong Yang,Ze Tan,* Adv. Synth. Catal., 357, 732-738, 2015.(IF=6.453)
- Synthesis of 2-Acylated Indoles through Palladium-Catalyzed Dehydrogenative Coupling of N-Pyrimidine-Protected Indoles with Aldehydes and Ethyl Glyoxylate, Wenduo Wang, Jidan Liu, Qingwen Gui,Ze Tan,*Synlett, 26, 771-778, 2015.(IF=2.323)
- Synthesis of Oxindoles via Iron-Mediated Hydrometallation-Cyclization of N-Arylacrylamides,Qingwen Gui, Liang Hu, Xiang Chen, Jidan Liu,Ze Tan,* Asian. J. Org. Chem., 4, 870-874, 2015.(IF=3.275)
- Synthesis of Vinylsulfones Via Palladium-Catalyzed Decarboxylative Coupling of Cinnamic Acids with Aromatic Sulfinic Acid Sodium Salts,Ruqing Guo, Qingwen Gui, Dadian Wang,Ze Tan,*Catal. Lett., 144, 1377-1383,2014.
- Synthesis of Oxindoles via Silver-Catalyzed Trifluoromethylation-, Difluoromethylation- and Arylsulfonylation-Cyclization of N-Arylacrylamides,Jidan Liu, Shaobo Zhuang, Qingwen Gui, Xiang Chen, Zhiyong Yang, andZe Tan,* Eur. J. Org. Chem., 3196-3202, 2014.
- Synthesis of N-alkyl isatins via oxdativecyclization of N-alkyl 2-bromo(chloro)acetanilides,Qingwen Gui, Fenglin Dai,Jidan Liu, Peixing Chen, Zhiyong Yang, Xiang Chen,Ze Tan,*Org. Biomol. Chem., 12, 3349-3353, 2014.
- Pd-catalyzed decarboxylative ortho-acylation of O-methyl oximes with phenylglyoxylic acids,Zhiyong Yang,Xiang Chen, Jidan Liu,Qingwen Gui, Kai Xie,Miaomiao Li,Ze Tan,* Chem. Commun., 1560-1562, 2013.
- Pd-Catalyzed C3-selective Arylation of Pyridines with Phenyl Tosylates,Fenglin Dai, Qingwen Gui, Jidan Liu, Zhiyong Yang, Xiang Chen, Ruqing Guo andZe Tan,*Chem. Commun,4634-4636, 2013.
- Synthesis of 2-substituted benzothiazoles via copper-catalyzed one-pot three-component reaction from 2-iodonitrobenzenes, Jidan Liu, Qingwen Gui, Zhiyong Yang,Ze Tan,* Ruqing Guo, Ji-Cheng Shi,*Synthesis,45(7): 943-951, 2013.
- Synthesis of phenanthridin-6(5H)-ones via Cu-catalyzed cyclization of 2-phenylbenzamides,Qingwen Gui, Zhiyong Yang, Xiang Chen, Jidan Liu,Ze Tan,*Ruqing Guo, Wei Yu,* Synlett, 24, 1016-1020, 2013.
- Synthesis of 2-aryl benzothiazoles via K2S2O8-mediated oxidative condensation of benzothiazoles with benzylamines,Zhiyong Yang, Anwei Wang, Xiang Chen, Qingwen Gui, Jidan Liu,Ze Tan*, Hua Wang, Ji-Cheng Shi*, Synlett, 24, 1549-1554, 2013.
- Synthesis of 1,2-disubstituted acetylenes via copper-catalyzed Suzuki coupling of organoboronic acids with 1,1-dibromo-1-alkenes, Jidan Liu, Fenglin Dai, Zhiyong Yang, Sizhuo Wang, Kai Xie, Anwei Wang, Xiang Chen,Ze Tan,*Tetrahedron Lett., 53, 5678-5683,2012.
- Efficient synthesis of anthranilic esters via Pd-catalyzed dehydrogenative/decarbonylative coupling of anilides and glyoxylates, Sizhuo Wang, Zhiyong Yang, Jidan Liu, Kai Xie, Anwei Wang, Xiang Chen andZe Tan*,Chem. Commun., 9924-9926,2012.
- Synthesis of 2-Aryl Benzothiazoles via K2S2O8‑mediated Oxidative Condensation of Benzothiazoles with Aryl Aldehydes, Zhiyong Yang, Xiang Chen, Sizhuo Wang, Jidan Liu, Kai Xie, Anwei Wang, andZe Tan*,J. Org. Chem., 77, 7086−7091,2012.
- Synthesis of Biaryls by Pd-Catalyzed Decarboxylative Homo- and Heterocoupling of Substituted Benzoic Acids,Kai Xie, Sizhuo Wang, Zhiyong Yang, Jidan Liu, Anwei Wang, Xiujian Li, Ze Tan,* Can-Cheng Guo, and Wei Deng*,Eur. J. Org. Chem. 2011, 5787-5790.
- Synthesis of tetralin and chromane derivatives via In-catalyzed intramolecular hydroarylation,Kai Xie, Sizhuo Wang, Ping Li, Xiujian Li, Zhiyong Yang, Xiangyu An, Can-Cheng Guo, Ze Tan ,* Tetrahedron Lett.2010,51, 4466-4469.
- Pd-catalyzed decarboxylative arylation of thiazole, benzoxazole and polyfluorobenzene with substituted benzoic acids”, Kai Xie, Zhiyong Yang, Xingjian Zhou, Xiujian Li, Sizhuo Wang, Ze Tan,* Xiangyu An and Can-Cheng Guo, Org. Lett. 2010, 1564-1567.
- One-step preparation of xanthones via Pd-catalyzed annulation of 1,2-dibromoarenes and salicylaldehydes, Sizhuo Wang, Kai Xie, Ze Tan,* Xiangyu An, Xingjian Zhou, Can-Cheng Guo, Zhihong Peng*, Chem. Commun., 2009, 6469-6471.
- Efficient Cu-catalyzed oxidative Mannich reaction between tertiary amines and methyl ketones, Youming Shen, Mo Li, Sizhuo Wang, Tianguang Zhan, Ze Tan*, Can-Cheng Guo*, Chem. Commun., 2009, 953–955.
- Highly Efficient Cu-Catalyzed Oxidative Coupling of Tertiary Amines and Siloxyfurans, Youming Shen, Ze Tan*, De Chen, Xunbo Feng, Mo Li, Can-Cheng Guo*, and Chengliang Zhu, Tetrahedron, 2009, 65,158-163.
- Quantitative structure-activity relationship studies on ironporphyrin-catalyzed cyclohexane oxidation with PhIO, Nian Liu, Guo-Fang Jiang, Can-Cheng Guo*, Ze Tan, Journal of Molecular Catalysis A: Chemical, 2009,304(1), 40-46.
- Novel phosphoramidates with porphine and nitrogenous drug: One-pot synthesis and orientation to cancer cells, Zhi-Wei Wang, Can-Cheng Guo*, Wen-Zhong Xie, Chao-Zhou Liu, hun-Guang Xiao and Ze Tan, Eur. J. Med. Chem.2009, 45, 890-895.
- Synthesis of tetrasubstituted furans via In-catalyzed propargylation of 1,3-dicarbonyl compounds─cyclization tandem process, Feng, X.; Tan, Z*.; Chen, D.; Shen, Y.; Guo, C-C.*; Xiang, J.; Zhu, C. Tetrahedron Lett.2008, 49, 4110-4112.
- Aerobic oxidation of p-xylene over metalloporphyrin and cobalt acetate: Their synergy and mechanism, Quan Jiang, Yang Xiao, Ze Tan, Qing-Hong Li, Can-Cheng Guo*, Journal of Molecular Catalysis A: Chemical, 2008, 285, 162-168.
- Zirconium-Catalyzed Asymmetric Carboalumination of Alkenes(ZACA)-Lipase-Catalyzed Acetylation Synergy, Huang, Z.; Tan, Z.; Novak, T.; Zhu, G.; Negishi, E. Adv. Synth. Catal.2007, 539-545.
- Selective Synthesis of Epolactaene Featuring Efficient Construction of Methyl (Z)-2-Iodo-2- butenoate and (2R,3S,4S)-2-Trimethylsilyl-2,3-epoxy-4-methyl-g-butyrolactone, Tan, Z.; Negishi, E. Org. Lett. 2006, 8, 2783-2785.
- Widely Applicable Pd-catalyzed trans-selective Monoalkylation of Unactivated 1,1-Dichloro-1-alkenes and Pd-Catalyzed Second Substitution for the Selective Synthesis of Eor ZTrisubstituted Alkenes, Tan, Z.; Negishi, E. Angew. Chem. Int. Ed. 2006, 45, 762-765.
- Catalytic, Efficient, and syn-Selective Construction of Deoxypolypropionates and Other Chiral Compounds via Zr-Catalyzed Asymmetric Carboalumination of Allyl Alcohol, Liang, B.; Novak, T.; Tan, Z.; Negishi, E. J. Am. Chem. Soc. 2006, 128, 2770-2771.
- All-catalytic, Efficient and Asymmetric Synthesis of α,ω-Diheterofunctional Reduced Polypropionates via “One-pot” Zr-catalyzed Asymmetric Carboalumination-Pd-catalyzed Cross-coupling Tandem Process, Novak, T.; Tan, Z.; Liang, B.; Negishi, E. J. Am. Chem. Soc. 2005, 127, 2838-2839.
- An Efficient and General Method for the Synthesis of α,ω-Difunctional Reduced Polypropionates by Zr-catalyzed Asymmetric Carboalumination: Synthesis of the Scyphostatin Sidechain, Tan, Z.; Negishi, E. Angew. Chem. Int. Ed.2004, 43, 2911-14.
- A New, Efficient, and General Route to Reduced Polypropionates via Zr-Catalyzed Asymmetric C-C Bond Formation, Negishi, E.; Tan, Z. Liang, B.; Novak, T. Proc. Natl. Acad. Sci. USA, 2004, 101, 5782-87.
項目
1. 2008湖南省普通高校學科帶頭人培養對象 2.7萬
2. 教育部回國留學基金3萬
3. 國家自然科學基金項目批准號:20702012(2008-2010)項目名稱: 運用鈀催化的甲酯或乙酯等簡單酯類化合物的Suzuki偶聯合成酮類化合物,項目經費:19萬元
4.2009年教育部新世紀優秀人才計畫(已公示),50萬元
5.一氧化氮(NO)表面增強拉曼散射探針研究,湖南大學化學計量學與感測技術國家重點實驗室開放基金, 1.5 萬元