許新華(湖南大學教授)

許新華，男，1964年11月出生，博士，湖南大學化學化工學院教授、博士生導師。

基本介紹

• 中文名：許新華
• 畢業院校：日本岡山理工大學
• 學位/學歷：博士
• 專業方向：有機化學
• 任職院校：湖南大學

人物經歷

教育經歷

1981.9-1984.6，湖南邵陽師範專科學校化學科學習。

1988.9-1991.6，湖南師範大學化學系有機專業碩士生，指導老師:俞善信教授。

1995.9-1998.6，杭州大學化學系有機化學專業博士生，指導老師：黃憲院士。

1998.9-2000.6，南開大學元素所藥物化學專業博士後，合作老師：陳茹玉院士。

2002年度在日本岡山理工大學套用研究所從事超分子研究。

工作經歷

1984.6-1988.8，湖南武岡泉塘鄉中學、武岡灣頭橋區中學擔任國中、高中化學教學。

1991.6-1995.8，湖南農學院基礎部擔任本科《有機化學》理論、實驗教學。

2000.6-至今， 湖南大學化工學院擔任本科《有機化學》理論、實驗教學；擔任碩士生《金屬有機》、《元素有機》、《超分子化學》教學。

科研項目

1、國家自然科學基金面上項目：對水穩定的金屬Lewis acid研製與套用研究， 2004.1-2006.12。

2、國家自然科學基金面上項目：對空氣穩定的新穎的有機金屬Lewis acid製備、表征及套用研究， 2012.1-2013.12。

3、國家自然科學基金面上項目：新型有機銫配合物合成、表征及其在碳-雜鍵形成反應中的催化套用研究， 2013.1-2016.12。

4、國家自然科學基金重點項目：“化學溶劑吸收法捕獲二氧化碳過程降低熱能消耗關鍵科學問題研究”子課題“新型有機胺合成研究”負責人， 2016.1-2020.12

5、湖南省重大科技專項：“4- ADl綠色生物合成與甾體類藥物研發”子課題“度他雄胺原料藥註冊申報及原料藥產業化研究”負責人，2014.6-2017.6。

學術成果

發表論文

[1] Linghui Lu, Sijia Zhou, Meng Sun, Jialiang Chen, Wen Xia, Xianyong Yu, Xinhua Xu*, and Wei-Min He*, Metal- and Solvent-Free Ultrasonic Multicomponent Synthesis of (Z)-β-Iodo Vinylthiocyanates, ACS Sustainable Chem. Eng., 7 (1), 1574–1579, 2019.(IF=6.140)

[2] Yanxia Nan, Wenjie Zhao*, Ningbo Li, Zhiwu Liang*, Xinhua Xu*, Chemiluminescence-triggered fluorophore release: Approach for in vivo fluorescence imaging of hydrogen peroxide, Sensors & Actuators: B. Chemical., 281, 296–302, 2019.(IF=5.667)

[3] Zheng‐Jun Wang , Jing‐Jing Lv, Rong‐Nan Yi, Min Xiao, Jiu‐Ju Feng, Zhi‐Wu Liang*,? Ai‐Jun Wang*, Xinhua Xu*, Nondirecting Group sp3 C?H Activation for Synthesis of Bibenzyls via Homo‐coupling as Catalyzed by Reduced Graphene Oxide Supported PtPd@Pt Porous Nanospheres, Adv. Synth. Catal., 360, 932–941, 2018.(IF=5.123)

[4] Ningbo Li, Lingxiao Wang, Liting Zhang, Wenjie Zhao, Jie Qiao, Xinhua Xu*, Zhiwu Liang, Air‐stable Bis(pentamethylcyclopentadienyl) Zirconium Perfluorooctanesulfonate as an Efficient and Recyclable Catalyst for the Synthesis of N‐substituted Amides, Chem.Cat.Chem., 10, 3532, 2018.(IF=4.674)

[5] Ling-Hui Lu, Si-Jia Zhou, Wei-Bao He, Wen Xia, Ping Chen, Xianyong Yu, Xinhua Xu* and Wei-Min He*, Metal-free difunctionalization of alkynes leading to alkenyl dithiocyanates and alkenyl diselenocyanates at room temperature, Org. Biomol. Chem., 16, 9064, 2018.(IF=3.423)

[6] Rongnan Yi, Jinyang Chen, Xueyan Wang, Zhiwu Liang*, Xinhua Xu*,A Rapid and Highly Efficient Method for the Synthesis of Benzofulvenes via CsOH‐Catalyzed Condensation of Indene and Aldehydes, Eur.J.Org.Chem., 11, 1347–1351, 2018.(IF=2.882)

[7] Ningbo Li, Lingxiao Wang, Haojiang Wang, Jie Qiao, Zhiwu Liang, Wenjie Zhao*, Xinhua Xu*, Synthesis and structure of an air-stable bis(pentamethylcyclopentadienyl) zirconium pentafluorbezenesulfonate and its application in catalytic epoxide ring-opening reactions, Tetrahedron, 74, 1033-1039, 2018.(IF=2.377)

[8] Xiaohong Zhang, Xinhua Xu*, Ningbo Li, Zhiwu Liang*, Zilong Tang, Air-stable μ2-hydroxyl bridged cationic binuclear complexes of zirconocene perfluorooctanesulfonates: their structures, characterization and application, Tetrahedron, 74, 1926-1932, 2018.(IF=2.377)

[9] Ningbo Li, Jiao Yao, Lingxiao Wang, Jiancong Wei*, Wen Liu, Wenqi Liu*, Xinhua Xu*, Zhiwu Liang,Titanocene perfluorobutanesulfonate catalyzed reduction of disulfides in the presence of zinc to synthesize unsymmetrical sulfides, Inorganic Chemistry Communication., 98, 99?104, 2018.(IF=1.810)

[10] Zhi Tang, Qiutao Jiang, Lifen Peng, Xinhua Xu*, Jie Li*, Renhua Qiu* and Chak-Tong Au, Zirconocene-catalyzed direct (trans)esterification of acyl acids (esters) and alcohols in a strict 1 : 1 ratio under solvent-free conditions, Green Chem., 19, 5396–5402, 2017. (IF= 9.125)

[11] Zheng-Jun Wang, Xue-Yan Wang, Xia Wanga, Zhi-Wu Liang, Xinhua Xu*, Carbonylative Suzuki cross-coupling reaction catalyzed by bimetallic Pd-Pt nanodendrites under ambient CO pressure, Catal. Commun., 101, 10-14, 2017. (IF= 3.33)

[12] Zheng-Jun Wang, Xia Wang, Jing-Jing Lv, Jiu-Ju Feng, Xinhua Xu*, Ai-Jun Wang* and Zhiwu Liang, Bimetallic Au–Pd nanochain networks: facile synthesis and promising application in biaryl synthesis, New J. Chem., 41, 3894, 2017. (IF= 3.269）

[13] Lifen Peng, Rongzhen Li, Zilong Tang*, Jingyang Chen, Rongnan Yi, Xinhua Xu*, Cesium-catalyzed highly regioselective synthesis of (Z)-vinylic selenosulfides via thioselenation of alkynes with unsymmetrical diorganoyl dichalcogenides, Tetrahedron., 73, 3099-3105, 2017. (IF= 2.651)

[14] 毛冀川, 申玉良, 曹春雨, 舒志堅, 鄭良彬, 許新華*, 利用過二硫酸鹽氧化消除 2-碘雙氫非那雄胺製備非那雄胺[J]. 有機化學, 2017, 37, 2430-2434.

[15] 陳錦楊, 吳小波, 易榮楠, 許新華*, 鎳催化格氏試劑與二芳基乙炔偶聯反應製備四取代萘[J]. 有機化學, 2017, 37, 1850-1854.

[16] Jinyang Chen, Sihai Chen, Xinhua Xu*, Zhi Tang, Chak-Tong Au, and Renhua Qiu*, Nickel-Catalyzed Regioselective Cleavage of Csp2?S Bonds: Method for the Synthesis of Tri- and Tetrasubstituted Alkenes, J. Org. Chem., 81, 3246?3255, 2016. (IF= 4.849)

[17] Jing-Jing Lv, Zheng-Jun Wang, Jiu-Ju Feng, Renhua Qiu*, Ai-Jun Wanga*, Xinhua Xu*, Facile synthesis of highly active Pd-Cu nanowires catalyst through a simple wet-chemical strategy for ligand-free Suzuki cross coupling reaction, Applied Catalysis A: General., 522, 188-193, 2016. (IF= 4.339)

[18] Penghui Wang, Jinying Wang, Chak-Tong Au, Renhua Qiu*, Xinhua Xu*, Shuang-Feng Yin*, Air-stable organobismuth(V) bisperfluorooctanesulfonate as an efficient catalyst for the synthesis of N-containing compounds, Adv. Synth. Catal., 358, 1302-1308, 2016. (IF= 5.646)

[19] Sihai Chen, You Li, Jinyang Chen, Xinhua Xu*, Lebin Su, Zhi Tang, Chak-Tong Au, Renhua Qiu*, Iodine-Promoted Synthesis of Thioamides from 1,2-Dibenzylsulfane and Difurfuryl Disulfide, Synlett., 27(16), 2339-2344, 2016. (IF= 2.151)

[20] Sihai Chen, Jinyang Chen, Xinhua Xu*, Yunhua He, Rongnan Yi, Renhua Qiu*, Calix[4]arene-assisted KOH-catalyzed synthesis of O,O-dialkyl-Se-aryl phosphoroselenoates, J. Org. Chem., 818, 123-127, 2016. (IF= 2.184)

[21] Xie Wang, Longzhi Zhu, Sihai Chen, Xinhua Xu,* Chak-Tong Au, and Renhua Qiu*, Nickel-Catalyzed Direct C (sp3)?H Arylation of Aliphatic Amides with Thiophenes, Org. Lett., 17, 5228?5231, 2015. (IF= 6.579)

[22] Xie Wang, Renhua Qiu,* Chunyang Yan, Vutukuri Prakash Reddy, Longzhi Zhu, Xinhua Xu,* and Shuang-Feng Yin*, Nickel-Catalyzed Direct Thiolation of C(sp3)?H Bonds in Aliphatic Amides, Org. Lett., 17, 1970-1973, 2015. (IF= 6.579)

[23] Jinyang Chen, Zhi Tang, Renhua Qiu,* Yunhua He, Xie Wang, Ningbo Li, Haibo Yi,* Chak-Tong Au, Shuang-Feng Yin, and Xinhua Xu*, Cesium-Catalyzed Regioselective Synthesis of Trisubstituted Heteroatom Alkenes: A New Strategy for the Preparation of Functional Alkenes, Org. Lett., 17, 2162?2165, 2015. (IF= 6.579)

[24] Xiaohong Zhang, Renhua Qiu*, Congcong Zhou, Jingxing Yu, Ningbo Li, Shuangfeng Yin*, Xinhua Xu*, Synthesis and structure of an air-stable bis(isopropylcyclopentadienyl) zirconium perfluorooctanesulfonate and its catalyzed benzylation of 1,3-dicarbonyl derivatives with alcohols, Tetrahedron., 71, 1011-1017, 2015. (IF= 2.651)

[25] Ningbo Li, Renhua Qiu*, Xiaohong Zhang, Yun Chen, Shuang-Feng Yin*, Xinhua Xu*, Strong Lewis acids of air-stable binuclear triphenylantimony(V) complexes and their catalytic application in CeC bond-forming reactions, Tetrahedron., 71, 4275-4281, 2015. (IF= 2.651)

[26] Jinying Wang, Ningbo Li, Renhua Qiu*, Xiaohong Zhang, Xinhua Xu*,Shuang-Feng Yin*, Air-stable zirconocene bis(perfluorobutanesulfonate) as a highly efficient catalyst for synthesis of N-heterocyclic compounds, J. Org. Chem., 785, 61-67, 2015. (IF= 2.184)

[27] Qizhi Dong, Ningbo Li, Renhua Qiu*, Jinying Wang, Cancheng Guo*, Xinhua Xu*, Silver-containing microemulsion as a high-efficient and recyclable catalytic system for hydration of alkynes, J. Org. Chem., 799-800, 122-127, 2015. (IF= 2.184)

[28] Zheng-Jun Wang, Jing-Jing Lv, Jiu-Ju Feng, Ningbo Li, Xinhua Xu*, Ai-Jun Wang* and Renhua Qiu*, Enhanced catalytic performance of Pd–Pt nanodendrites for ligand-free Suzuki crosscoupling reactions, RSC Adv., 5, 28467–28473, 2015. (IF= 3.108)

[29] Zheng-Jun Wang, Peng-Hui Wang, Jing-Jing Lv, Jiu-Ju Feng, Xinhua Xu,* Ai-Jun Wang,* Chak-Tong Au and Renhua Qiu*, Cu(II)@Luviset clear as recyclable catalyst for the formation of C–C bond in homo-coupling of terminal alkynes, RSC Adv., 5, 96372–96376, 2015. (IF= 3.108)

[30] Yanxia Nan, Wenjie Zhao, Xinhua Xu,* Chak-Tong Au and Renhua Qiu*, Synthesis, characterization and applications of selenocysteine-responsive nanoprobe based on dinitrobenzene sulfonyl-modified poly(carbonate) micelles, RSC Adv., 5, 69299–69306, 2015. (IF= 3.108)

[31] You Li, Jinyang Chen, Renhua Qiu*, Xie Wang, Jinguo Long, Longzhi Zhu, Chak-Tong Au, Xinhua Xu*, Cesium hydroxide-catalyzed isomerization of terminal alkynes for the synthesis of O-allenes and N-allenes, Tetrahedron Lett., 56, 5504–5507, 2015. (IF= 2.193)

發明專利

[1] 許世鏜，許新華，陳錦楊，邱仁華，散煤燃燒廢氣與機動車廢氣淨化裝置及污染物資源化方法，ZL 201610905643.X

[2] 梁志武，王雪艷，許新華，肖珉，一種合成炔丙胺類化合物的新方法，ZL 201711095532.8

[3] 梁志武，王正軍，許新華，肖珉，石墨烯負載鈀/鉑催化spC-H鍵偶聯合成1,2-二苯乙烷衍生物的方法，ZL 201711095556.3

[4] 梁志武，王正軍，許新華，肖珉，一種通過sp3C-H鍵活化合成丙咪嗪前驅體2,2-二溴聯苄的新方法，ZL 201711095713.0

[5] 許新華，張秋林，李言傑，陳雄，張青麗，含硒替加氟的內鹽式硫代磷酸酯類化合物及其合成，ZL 200410047110.X

[6] 許新華，張秋林，周冰，甘油骨架上含硒的替加氟的硫代磷脂類化合物及其合成，ZL200410046925.6

[7] 許新華， 劉鳳偉， 齊建勇，臧中林， 李言傑，碳酸銫催化、乙腈為溶劑烷基芳醚的製備，ZL 200610031357.1

[8] 許新華，度他雄胺及其中間體雙鍵形成新方法，ZL 201710232764.7

[9]湖南大學化學化工學院著作權所有 2017