舒興中,男,理學博士,蘭州大學“萃英學者”特聘教授,博士生導師。
基本介紹
- 中文名:舒興中
- 學位/學歷:博士
- 職業:教師
- 專業方向:高性能均相、多相金屬催化劑,開展(不對稱)催化和反應機理研究
- 任職院校:蘭州大學
個人經歷,研究方向,學術成果,榮譽獎項,
個人經歷
1982年生於浙江衢州,2005年畢業於紹興文理學院。於2005-2010年在蘭州大學攻讀博士學位,從事藥物小分子骨架高效合成方法學研究,師從梁永民教授。於2010-2012年在威斯康辛大學麥迪遜分校(University of Wisconsin-Madison)從事博士後研究,開發新型Rh催化[5+2]環加成反應,師從Weiping Tang教授。於2012-2015年,在加州大學伯克利分校(University of California Berkeley)和勞倫斯伯克利國家實驗室(Lawrence Berkeley National Laboratory)從事博士後研究,探索新能源、新材料與有機化學學科的交叉研究,師從著名有機化學家F. Dean Toste教授和材料學家Paul Alivisatos教授(勞倫斯伯克利國家實驗室主任,美國科學院院士);合作導師:光化學家Heinz Frei教授和“表面催化之父”Gabor Somorjai院士。於2015年起在蘭州大學化學化工學院、功能有機分子化學國家重點實驗室從事教學科研工作。
研究方向
研究以能源、環保、醫藥等行業為嚮導,開發高性能均相、多相金屬催化劑,開展(不對稱)催化和反應機理研究。主要包括:(1)新型廉價金屬催化劑的設計、製備和催化活性研究,用於解決合成反應中傳統方法難以實現的化學轉化和反應選擇性問題;(2)整合過渡金屬催化與新型材料技術,開發高性能納米金屬有機材料催化劑;(3)探索過渡金屬(均相/多相)催化參與的人工光合作用研究。
學術成果
迄今為止,已在Chem. Soc. Rev.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed. 、NanoLett.等國際著名刊物上發表論文三十餘篇,他引800餘次, H因子19。成果被Synfacts、Organic Chemistry Portal等多家專業媒體報導。是多家國際一流期刊的應邀審稿人,美國化學會會員。
近期代表性論文:
[15] Xing-zhong Shu, Miao Zhang, Ying He, Heinz, Frei*, F. Dean Toste*, “Dual Visible Light Photoredox and Gold-catalyzed ArylativeRing Expansion”, J. Am. Chem. Soc. 2014, 136, 5844.
[14] Elad Gross, Xing-Zhong Shu, SelimAlayoglu, Hans A. Bechtel, Michael C. Martin, F. Dean Toste,* Gabor A. Somorjai*, “In situ IR and X‑ray High Spatial-resolution MicrospectroscopyMeasurements of Multistep Organic Transformation in Flow MicroreactorCatalyzed by Au Nanoclusters”, J. Am. Chem. Soc., 2014, 136, 3624.
[13] Qiao Zhang, Xing-Zhong Shu, J. Matthew Lucas,F. Dean Toste*, Gabor A. Somorjai*, A. Paul Alivisatos*, “Inorganic Micelle as an Efficient and Recyclable Micellar Catalyst”, NanoLett. 2014,14, 379.
[12] Xing-zhong Shu, Casi M. Schienebeck, Wangze Song, Ilia A. Guzei, and Weiping Tang*, “Transfer of Chirality in Rhodium-Catalyzed Intramolecular (5+2) Cycloaddition of 3-Acyloxy-1,4-enyne (ACE) and Alkyne: Enantioselective Synthesis of Bicyclo[5.3.0]decatrienes”, Angew. Chem. Int. Ed.2013, 52, 13601.
[11] Xiufang Xu*, Peng Liu, Xing-Zhong Shu; Weiping Tang*; Houk, K. N.*, “Rh-Catalyzed (5+2) Cycloadditions of 3-Acyloxy-1,4-enynes and Alkynes: Computational Study of Mechanism, Reactivity, and Regioselectivity”, J. Am. Chem. Soc., 2013, 135, 9271.
[10] Xing-Zhong Shu, Dongxu Shu, Casi M. Schienebeck and Weiping Tang*, “Rhodium-catalyzed AcyloxyMigration of PropargylicEsters in Cycloadditions, Inspiration from the Recent "Gold Rush"”, Chem. Soc. Rev.2012, 41, 7698.
[9] Xing-Zhong Shu, Xiaoxun Li, Dongxu Shu, Suyu Huang, Casi Mae Schienebeck, Xin Zhou, Patrick J. Robichaux, Weiping Tang, “Rhodium-Catalyzed Intra- and Intermolecular 5+2 Cycloaddition of 3-Acyloxy-1,4-enyne and Alkyne with Concomitant 1,2-Acyloxy Migration”, J. Am. Chem. Soc., 2012, 134, 5211.
[8] Xing-Zhong Shu, Suyu Huang, Dongxu Shu, Ilia A. Guzei, Weiping Tang*, “Interception of a Rautenstrauch Intermediate by Alkynes for 5+2 Cycloaddition: Rhodium-Catalyzed Cycloisomerization of 3-Acyloxy-4-ene-1,9-diynes to Bicyclo 5.3.0 decatrienes”, Angew. Chem. Int. Ed.2011, 50, 8153.
[7] Xing-Zhong Shu, Yan-Fang Yang, Xiao-Feng Xia, Ke-Gong Ji, Xue-Yuan Liu, Yong-Min Liang*, “Platinum-catalyzed Cross-dehydrogenativeCoupling Reaction in the Absence of Oxidant”, Org. Biomol. Chem.2010, 8, 4077.
[6] Xing-Zhong Shu, Xiao-Feng Xia, Yan-Fang Yang, Ke-Gong Ji, Xue-Yuan Liu, Yong-Min Liang*, “Selective Functionalization of Sp(3) C-H Bonds Adjacent to Nitrogen Using (Diacetoxyiodo)benzene (DIB)”, J. Org. Chem. 2009, 74, 7464.
[5] Xing-Zhong Shu, Shu-Chun Zhao, Ke-Gong Ji, Zhao-Jing Zheng, Xue-Yuan Liu, Yong-Min Liang*, “Platinum-Catalyzed Cyclization of o-Alkynyl(oxo)benzenes with Alkenes by 1,2-Migration of Benzene: Synthesis of 8-Oxabicyclo 3.2.1 octane Derivatives”, Eur. J. Org. Chem. 2009, 117.
[4] Xing-Zhong Shu, Ke-Gong Ji, Shu-Chun Zhao, Zhao-Jing Zheng, Jing Chen, Li Lu, Xue-Yuan Liu, Yong-Min Liang*, “Synthesis of Naphthalenyl Acetate by Platinum-Catalyzed 1,5-Sigmatropic Hydrogen Shift of Propargylic Esters”, Chem. Eur. J. 2008, 14, 10556.
[3]Xing-Zhong Shu, Xue-Yuan Liu, Ke-Gong Ji, Hui-Quan Xiao, Yong-Min Liang*, “Au-catalyzed Tandem Cyclization/1,2 -alkyl Migration Reaction of Epoxy Alkynes: Synthesis of Spiropyranones”, Chem. Eur. J.2008, 14, 5282.
[2] Xing-Zhong Shu, Xue-Yuan Liu, Hui-Quan Xiao, Ke-Gong Ji, Li-Na Guo, Yong-Min Liang*, “Tandem Gold(III)-catalyzed Amination-intramolecular HydroaminationReactions of 1-En-4-yn-3-ols with Sulfonamides: Efficient Approach to Highly Substituted Pyrroles”, Adv. Synth. Catal. 2008, 350, 243.
[1] Xing-Zhong Shu, Xue-Yuan Liu, Hui-Quan Xiao, Ke-Gong Ji, Li-Na Guo, Chen-Ze Qi, Yong-Min Liang*, “Gold-catalyzed Tandem Cycloisomerization of Alkynyloxiranes with Nucleophiles: An Efficient Approach to 2,5-Disubstituted Furans”, Adv. Synth. Catal. 2007, 349, 2493.
榮譽獎項
曾獲2009年中國青少年科技創新獎、2009年中國科學院獎學金、2008年寶鋼教育獎學金、2005年浙江省優秀畢業生等。