《纖維素高效轉化製備化學品的催化基礎》是劉海超為項目負責人，北京大學為依託單位的重點項目。
基本介紹
- 中文名：纖維素高效轉化製備化學品的催化基礎
- 項目類別：重點項目
- 項目負責人 ：劉海超
- 依託單位 ：北京大學
科研成果,項目摘要,
科研成果
序號 | 標題 | 類型 | 作者 |
|---|---|---|---|
1 | Enzyme-inorganic nanoflowers/alginate microbeads: An enzyme immobilization system and its potential application | 期刊論文 | Fuhua Zhao; Qiao Wang; Jianjun Dong; Mo Xian; Junhong Yu; Hua Yin; Zongming Chang; Xindong Mu; Tonggang Hou; Jianxun Wang |
2 | Tuningthe catalytic selectivity in biomass-derived succinic acid hydrogenation on FeOx-modifiedPd catalysts | 期刊論文 | Xiaoran Liu(#); Xicheng Wang; Guoqiang Xu; Xindong Mu(*); Haichao Liu(*) |
3 | Efficient aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid on Ru/C catalysts | 期刊論文 | Zheng Lufan(#); Zhao Junqi; Du Zexue; Zong Baoning; Liu Haichao |
4 | Nickel Catalyzed Conversion of Cyclohexanol into Cyclohexylamine in Water and Low Boiling Point Solvents | 期刊論文 | Yunfei Qi; Huaiyun Yu; Quan Cao; Bo Dong; Xindong Mu; Qiqing Mao |
5 | Show more Influence of the functional groups of multiwalled carbon nanotubes on performance of Ru catalysts in sorbitol hydrogenolysis to glycols | 期刊論文 | Xingcui Guo; Huihuan Dong; Bin Li; Linlin Dong; Xindong Mu(*); Xiufang Chen |
6 | Preparation and characterization of thermally stable cellulose nanocrystals via a sustainable approach of FeCl3-catalyzed formic acid hydrolysis | 期刊論文 | Haishun Du; Chao Liu; Xindong Mu(*); Wenbo Gong; Dong Lv; Chuanling Si; Bin Li |
7 | DFT Studies of the Selective C-O Hydrogenolysis and Ring-Opening of Biomass-Derived Tetrahydrofurfuryl Alcohol over Rh(111) surfaces | 期刊論文 | Guan, Jing(#); Li, Jing; Yu, Yifeng; Mu, Xindong; Chen, Aibing |
8 | Selective upgrading of ethanol with methanol in water for the production of improved biofuel-isobutanol | 期刊論文 | Qiang Liu; Guoqiang Xu; Xicheng Wang; Xindong Mu(*) |
9 | Selective Hydrogenolysis of α‑C−O Bond in Biomass-Derived 2‑Furancarboxylic Acid to 5‑Hydroxyvaleric Acid on Supported Pt Catalysts at Near-Ambient Temperature | 期刊論文 | Qianhui Sun(#); Shuai Wang; Haichao Liu(*) |
10 | Preparation of concrete water reducer via fractionation and modification of lignin extracted from pine wood by formic acid | 期刊論文 | Shuangyang Li; Zhenqiu Li; Yuedong Zhang; Chao Liu; Guang Yu; Bin Li; Xindong Mu; Hui Peng |
11 | Reduced Graphene Oxide/alumina, a Good Accelerant for Cellulose-based Artificial Nacre with Excellent Mechanical, Barrier and Conductive Properties | 期刊論文 | Shahzadi Kiran; Zhang Xueming; Mohsin Imran; Ge Xuesong; Jiang Yijiun; Peng Hui; Liu Huizhou; Li Hui; Mu Xindong(*) |
12 | 鈰鋯複合氧化物負載氧化釕催化甲醇選擇氧化合成甲酸甲酯 | 期刊論文 | 陳文龍(#); 劉海超 |
13 | Review of alkali-based pretreatment to enhance enzymatic saccharification for lignocellulosic biomass conversion | 期刊論文 | Huanfei Xu; Bin Li; Xindong Mu |
14 | Influence of the functional groups of multiwalled carbon nanotubes on performance of ru catalysts in sorbitol hydrogenolysis to glycols | 期刊論文 | Xingcui Guo; Huihuan Dong; Bin Li; Linlin Dong; Xingdong Mu(*); Xiufang Chen |
15 | Kinetic insight into the effect of the catalytic functions on selectiveconversion of cellulose to polyols on carbon-supported WO3 and Ru catalysts | 期刊論文 | Yue Liu(#); Haichao Liu(*) |
16 | Role of MoO3 on a Rhodium Catalyst in the Selective Hydrogenolysis of Biomass-Derived Tetrahydrofurfuryl Alcohol into 1,5-Pentanediol | 期刊論文 | Jing Guan(#); Gongming Peng; Quan Cao; Xindong Mu(*) |
17 | Controllable in Situ Surface Restructuring of Cu Catalysts and Remarkable Enhancement of Their Catalytic Activity | 期刊論文 | He Xiaohui(#); Wang Yong; Zhang Xun; Dong Mei; Wang Guofu; Zhang Bingsen; Niu Yiming; Yao Siyu; He Xin; Liu Haichao(*) |
18 | A sustainable process for the production of 2-methyl-1,4-butanediol by hydrogenation of biomass-derived itaconic acid | 期刊論文 | Liu, Xiaoran(#); Wang, Xicheng(*); Liu, Qiang; Xu, Guoqiang; Li, Xuemin; Mu, Xindong(*) |
19 | Properties of nanocellulose isolated from corncob residue using sulfuric acid, formic acid, oxidative and mechanical methods | 期刊論文 | Liu Chao; Li Bin; Du Haishun; Dong Lv; Zhang Yuedong; Yu Guang; Mu Xindong(*); Peng Hui |
20 | Aromatization and isomerization of methylcyclohexane over Ni catalysts supported on different supports | 期刊論文 | Ye Song; Wei Lin; Xingcui Guo; Linlin Dong; Xindong Mu(*); Huiping Tian; Lei Wang |
21 | Tunable and selective hydrogenation of furfural to furfuryl alcohol and cyclopentanone over Pt supported on the biomass-derived porous heteroatom doped carbon | 期刊論文 | Xiuyun Liu; Bo Zhang; Benhua Fei; Xiufang Chen; Junyi Zhang; Xindong Mu(*) |
22 | Hydrogenolysis of lignin model compounds into aromatics with bimetallic Ru-Ni supported onto nitrogen-doped activated carbon catalyst | 期刊論文 | Hu Yinghui(#); Jiang Guangce; Xu Guoqiang(*); Mu Xindong(*) |
23 | Iridium Clusters Encapsulated in Carbon Nanospheres as Nanocatalysts for Methylation of (Bio)Alcohols | 期刊論文 | Qiang Liu; Guoqiang Xu; Zhendong Wang; Xiaoran Li; Xicheng Wang; Linlin Dong; Xindong Mu(*); Huizhou Li |
24 | Selective hydrogenolysis of sorbitol to ethylene glycol and propylene glycol on ZrO2-supported bimetallic Pd-Cu catalysts | 期刊論文 | Yuqing Jia(#); Haichao Liu(*) |
25 | Aqueous-phase hydrogenation of biomass-derived itaconic acid to methyl-γ-butyrolactone over Pd/C catalysts: Effect of pretreatments of active carbon | 期刊論文 | Sha Li; Xicheng Wang; Xiaoran Liu; Guoqiang Xu; Sheng Han; Xindong Mu(*) |
26 | Properties of nanocelluloses and their application as rheology modifier in paper coating | 期刊論文 | Chao Liu; Haishun Du; Lv Dong; Xin Wang; Yuedong Zhang; Guang Yu; Bin Li; Xindong Mu; Hui Peng; Huizhou Liu |
27 | Iridium nanoparticles supported on hierarchical porous N-doped carbon: an efficient watertolerant catalyst for bio-alcohol condensation in water | 期刊論文 | Di Liu; Xiufang Chen; Guoqiang Xu; Jing Guan; Quan Cao; Bo Dong; Yunfei Qi; Chunhu Li; Xindong Mu |
28 | Highly Selective Upgrading of Biomass-Derived Alcohol Mixtures for Jet/Diesel Fuel Components | 期刊論文 | Qiang Liu; Guoqiang Xu; Xicheng Wang; Xiaoran Liu; Xindong Mu(*) |
29 | Mechanistic insight into the selective hydrogenolysis of sorbitol to propylene glycol and ethylene glycol on supported Ru catalysts | 期刊論文 | Jia, Yuqing; Liu, Haichao(*) |
30 | Highly selective hydrogenation of furfural to furfuryl alcohol over Pt nanoparticles supported on g-C3N4 nanosheets catalysts in water | 期刊論文 | Xiufang Chen; Ligang Zhang; Bo Zhang; Xingcui Guo; Xindong Mu(*) |
31 | Controlled Hydrodeoxygenation of Phenolic Components in Pyrolysis Bio-oil to Arenes | 期刊論文 | Jiang Guangce(#); Hu Yinghui; Xu Guoqiang(*); Mu Xindong(*); Liu Huizhou |
32 | Immobilization of proline-specific endoprotease on nonporous silica nanoparticles functionalized with amino group | 期刊論文 | Fuhua Zhao; Tonggang Hou; Jianxun Wang; Yijun Jian; Shuxia Huang; Qiao Wang; Mo Xian; Xindong Mu(*) |
33 | Selective Conversion of Furfural to Cyclopentanone or Cyclopentanol Using Co-Ni Catalyst in Water | 期刊論文 | Li Yaru(#); Guo Xingcui(*); Liu Daosheng; Mu Xindong; Chen Xiufang; Shi Yan(*) |
34 | A novel hierarchical porous nitrogen-doped carbon derived from bamboo shoot for high performance supercapacitor | 期刊論文 | Xiufang Chen; Junyi Zhang; Bo Zhang; Shanmu Dong; Xingcui Guo; Xindong Mu(*); Benhua Fei |
35 | MgO負載金屬雙功能催化劑用於生物基山梨醇氫解制丙二醇、乙二醇和甘油(英文) | 期刊論文 | 王喜成(#); 劉曉然; 徐悅; 彭功名; 曹泉; 牟新東(*) |
36 | Selective N-Monomethylation of Amines and Nitroarenes using Methanol over an Encapsulated Iridium Nanocatalyst | 期刊論文 | Aixiao Fu; Qiang Liu; Mingxiang Jiang; Guoqiang Xu(*) |
37 | The influence of pore structure and Si/Al ratio of HZSM-5 zeolites on the product distributions of alpha-cellulose hydrolysis | 期刊論文 | Chu Shuang(#); Yang Li'na; Guo Xingcui(*); Dong Linlin; Chen Xiufang; Li Yaru; Mu Xindong(*) |
38 | Selective Hydrogenolysis of Glycerol to Propylene Glycol on Supported Pd Catalysts: Promoting Effects of ZnO and Mechanistic Assessment of Active PdZn Alloy Surfaces | 期刊論文 | Sun Qianhui(#); Wang Shuai; Liu Haichao(*) |
39 | Tunable and selective hydrogenation of furfural to furfuryl alcohol and cyclopentanone over Pt supported on the biomass-derived porous heteroatom doped carbons | 期刊論文 | Xiuyun Liu; Bo Zhang; Benhua Fei; Xiufang Chen; Junyi Zhang; Xindong Mu(*) |
40 | Insights into the Inhibition of Acidic Hydrolysis of Cellulose by Its Solation | 期刊論文 | Chen Gongzhe; Wang Xicheng; Jiang Yijun; Mu Xindong(*); Liu Haichao(*) |
41 | Insights into deactivation mechanism of sulfonated carbonaceous solid acids probed by cellulose hydrolysis | 期刊論文 | Chen Gongzhe; Wang Xicheng; Jiang Yijun; Mu Xindong(*); Liu Haichao(#)(*) |
42 | Insights into the structural requirements for oxidative dehydrogenation of propane on crystalline Mg-V-O catalysts | 期刊論文 | Zhang Shenghong(#); Liu Haichao(*) |
項目摘要
纖維素是自然界最豐富的生物質且不可食用，將其轉化為燃料和化學品是發展可再生能源的一個重要方向。本項目將圍繞纖維素高效轉化為化學品，構築納米結構仿酶功能固體酸催化劑和能夠產生可逆質子酸的固體金屬鹽體系，實現溫和條件下纖維素的綠色高效水解；構築具有特定結構與功能的分子篩、金屬和金屬氧化物催化劑，與纖維素水解步驟耦合，將生成的葡萄糖中間體高效加氫、脫水或選擇斷裂其C-C與C-O鍵，實現纖維素定向轉化為山梨醇、異山梨醇、甘油、丙二醇、羥基丙酮等多元醇目標產物。揭示甘油特定C-O鍵活化機理，實現選擇氫解合成1,3-丙二醇，實現甘油和羥基丙酮選擇氧化合成1,3-丙二醇和乳酸等目標產物。利用Raman、XAFS等譜學、同位素標記和動力學等手段在接近反應條件下研究催化劑活性位結構和反應機理等，並結合理論計算，認識催化劑活性位結構、酸鹼性等因素與其催化性能間的關係，為纖維素和其它生物質高效利用奠定科學基礎。
