《粒狀填料對橡膠的補強》是2021年4月化學工業出版社出版的圖書，作者是王夢蛟，麥可·莫里斯，本書對於橡膠行業的工程師和產品開發人員，以及從事橡膠研究的技術人員、教師和學生是很好的參考資料。
基本介紹
- 中文名：粒狀填料對橡膠的補強
- 作者：王夢蛟、麥可·莫里斯
- 出版社：化學工業出版社
- ISBN：9787122383013
內容簡介,圖書目錄,作者簡介,
內容簡介
本書是主要闡述粒狀填料對橡膠補強的學術專著。填料對橡膠補強是橡膠工業中套用*為廣泛的技術之一，99%以上的橡膠製品均含填料，而炭黑和二氧化矽（白炭黑）是常用的填料。目前填料的研究和開發已成為橡膠科技研究中*活躍的領域。
本書除簡單介紹填料的製作過程外，著重詳細說明填料的微觀結構、基本性質及它們表征的原理和方法。在此基礎上，本書從理論上闡述了填料在橡膠中的各種效應及這些效應是如何影響填充橡膠的加工性能、硫化膠在溶劑中的溶脹行為和物理機械性能，諸如靜態及動態應力-應變特性及破壞特性，並從機理上論述了上述硫化膠性能與橡膠製品，尤其是輪胎的*終使用性能之間的關係。
本書對於橡膠行業的工程師和產品開發人員，以及從事橡膠研究的技術人員、教師和學生是很好的參考資料。
圖書目錄
Preface Ⅰ
About the Authors Ⅲ
1. Manufacture of Fillers 1
1.1 Manufacture of Carbon Black 3
1.1.1 Mechanisms of Carbon Black Formation 3
1.1.2 Manufacturing Process of Carbon Black6
1.1.2.1 Oil-Furnace Process 6
1.1.2.2 The Thermal Black Process 10
1.1.2.3 Acetylene Black Process11
1.1.2.4 Lampblack Process 11
1.1.2.5 Impingement (Channel, Roller) Black Process 12
1.1.2.6 Recycle Blacks12
1.1.2.7 Surface Modification of Carbon Blacks 13
1.1.2.7.1 Attachments of the Aromatic Ring Nucleus to Carbon Black 13
1.1.2.7.2 Attachments to the Aromatic Ring Structure through Oxidized Groups 13
1.1.2.7.3 Metal Oxide Treatment 14
1.2 Manufacture of Silica 14
1.2.1 Mechanisms of Precipitated Silica Formation 15
1.2.2 Manufacturing Process of Precipitated Silica 16
1.2.3 Mechanisms of Fumed Silica Formation 18
1.2.4 Manufacture Process of Fumed Silica18
References 19
2. Characterization of Fillers22
2.1 Chemical Composition23
2.1.1 Carbon Black 23
2.1.2 Silica 25
2.2 Micro-Structure of Fillers27
2.2.1 Carbon Black 27
2.2.2 Silica 29
2.3 Filler Morphologies 29
2.3.1 Primary Particles-Surface Area 29
2.3.1.1 Transmission Electron Microscope (TEM)30
2.3.1.2 Gas Phase Adsorptions 34
2.3.1.2.1 Total Surface Area Measured by Nitrogen Adsorption-BET/NSA 35
2.3.1.2.2 External Surface Area Measured by Nitrogen Adsorption-STSA41
2.3.1.2.3 Micro-Pore Size Distribution Measured by Nitrogen Adsorption46
2.3.1.3 Liquid Phase Adsorptions 51
2.3.1.3.1 Iodine Adsorptions 52
2.3.1.3.2 Adsorption of Large Molecules 56
2.3.2 Structure-Aggregate Size and Shape 61
2.3.2.1 Transmission Electron Microscopy 62
2.3.2.2 Disc Centrifuge Photosedimentometer 66
2.3.2.3 Void Volume Measurement 68
2.3.2.3.1 Oil Absorption 69
2.3.2.3.2 Compressed Volume 75
2.3.2.3.3 Mercury Porosimetry 80
2.3.3 Tinting Strength 83
2.4 Filler Surface Characteristics 92
2.4.1 Characterization of Surface Chemistry of Filler-Surface Groups 92
2.4.2 Characterization of Physical Chemistry of Filler Surface-Surface Energy 93
2.4.2.1 Contact Angle98
2.4.2.1.1 Single Liquid Phase98
2.4.2.1.2 Dual Liquid Phases 102
2.4.2.2 Heat of Immersion 106
2.4.2.3 Inverse Gas Chromatograph 111
2.4.2.3.1 Principle of Measuring Filler Surface Energy with IGC 111
2.4.2.3.2 Adsorption at Infinite Dilution 112
2.4.2.3.3 Adsorption at Finite Concentration 118
2.4.2.3.4 Surface Energy of the Fillers 123
2.4.2.3.5 Estimation of Rubber-Filler Interaction from Adsorption Energy of Elastomer Analogs 139
2.4.2.4 Bound Rubber Measurement 142
References143
3. Effect of Fillers in Rubber 153
3.1 Hydrodynamic Effect ? Strain Amplification 153
3.2 Interfacial Interaction between Filler and Polymer 155
3.2.1 Bound Rubber 155
3.2.2 Rubber Shell 159
3.3 Occlusion of Rubber 161
3.4 Filler Agglomeration 163
3.4.1 Observations of Filler Agglomeration163
3.4.2 Modes of Filler Agglomeration 164
3.4.3 Thermodynamics of Filler Agglomeration 167
3.4.4 Kinetics of Filler Agglomeration 170
References173
4. Filler Dispersion 177
4.1 Basic Concept of Filler Dispersion177
4.2 Parameters Influencing Filler Dispersion 179
4.3 Liquid Phase Mixing 187
References 191
5. Effect of Fillers on the Properties of Uncured Compounds193
5.1 Bound Rubber193
5.1.1 Significance of Bound Rubber 194
5.1.2 Measurement of Bound Rubber 195
5.1.3 Nature of Bound Rubber Attachment 197
5.1.4 Polymer Mobility in Bound Rubber202
5.1.5 Polymer Effects on Bound Rubber203
5.1.5.1 Molecular Weight Effects 203
5.1.5.2 Polymer Chemistry Effects 203
5.1.6 Effect of Filler on Bound Rubber 204
5.1.6.1 Surface Area and Structure 204
5.1.6.2 Specific Surface Activity of Carbon Blacks 206
5.1.6.3 Effect of Surface Characteristics on Bound Rubber210
5.1.6.4 Carbon Black Surface Modification 211
5.1.6.5 Silica Surface Modification 215
5.1.7 Effect of Mixing Conditions on Bound Rubber 215
5.1.7.1 Temperature and Time of Mixing 216
5.1.7.2 Mixing Sequence Effect of Rubber Ingredients218
5.1.7.2.1 Mixing Sequence of Oil and Other Additives219
5.1.7.2.2 Mixing Sequence of Sulfur, Sulfur Donor, and Other Crosslinkers 221
5.1.7.2.3 Bound Rubber of Silica Compounds 222
5.1.7.3 Bound Rubber in Wet Masterbatches 223
5.1.7.4 Bound Rubber of Fumed Silica-Filled Silicone Rubber 225
5.2 Viscosity of Filled Compounds227
5.2.1 Factors Influencing Viscosity of the Carbon Black-Filled Compounds 227
5.2.2 Master Curve of Viscosity vs. Effective Volume of Carbon Blacks 230
5.2.3 Viscosity of Silica Compounds 233
5.2.4 Viscosity Growth ? Storage Hardening 238
5.3 Die Swell and Surface Appearance of the Extrudate 241
5.3.1 Die Swell of Carbon Black Compounds 241
5.3.2 Die Swell of Silica Compounds 246
5.3.3 Extrudate Appearance 247
5.4 Green Strength 249
5.4.1 Effect of Polymers249
5.4.2 Effect of Filler Properties 252
References255
6. Effect of Fillers on the Properties of Vulcanizates 263
6.1 Swelling 263
6.2 Stress-Strain Behavior271
6.2.1 Low Strain 271
6.2.2 Hardness274
6.2.3 Medium and High Strains-The Strain Dependence of Modulus275
6.3 Strain-Energy Loss-Stress-Softening Effect 279
6.3.1 Mechanisms of Stress-Softening Effect 282
6.3.1.1 Gum282
6.3.1.2 Filled Vulcanizates 283
6.3.1.3 Recovery of Stress Softening287
6.3.2 Effect of Fillers on Stress Softening 288
6.3.2.1 Carbon Blacks 288
6.3.2.1.1 Effect of Loading288
6.3.2.1.2 Effect of Surface Area 289
6.3.2.1.3 Effect of Structure 290
6.3.2.2 Precipitated Silica 290
6.4 Fracture Properties 295
6.4.1 Crack Initiation 295
6.4.2 Tearing 296
6.4.2.1 State of Tearing 296
6.4.2.1.1 Effect of Filler 301
6.4.2.1.2 Effect of Polymer Crystallizability and Network Structure 302
6.4.2.2 Tearing Energy 306
6.4.2.2.1 Effect of Filler 306
6.4.2.2.2 Effect of Polymer Crystallizability and Network Structure 307
6.4.3 Tensile Strength and Elongation at Break 315
6.4.4 Fatigue 318
References321
7. Effect of Fillers on the Dynamic Properties of Vulcanizates 329
7.1 Dynamic Properties of Vulcanizates 329
7.2 Dynamic Properties of Filled Vulcanizates 332
7.2.1 Strain Amplitude Dependence of Elastic Modulus of Filled Rubber 332
7.2.2 Strain Amplitude Dependence of Viscous Modulus of Filled Rubber 340
7.2.3 Strain Amplitude Dependence of Loss Tangent of Filled Rubber 343
7.2.4 Hysteresis Mechanisms of Filled Rubber Concerning Different Modes of Filler Agglomeration 348
7.2.5 Temperature Dependence of Dynamic Properties of Filled Vulcanizates 350
7.3 Dynamic Stress Softening Effect 354
7.3.1 Stress-Softening Effect of Filled Rubbers Measured with Mode 2 355
7.3.2 Effect of Temperature on Dynamic Stress-Softening359
7.3.3 Effect of Frequency on Dynamic Stress-Softening 360
7.3.4 Stress-Softening Effect of Filled Rubbers Measured with Mode 3 362
7.3.5 Effect of Filler Characteristics on Dynamic Stress-Softening and Hysteresis 369
7.3.6 Dynamic Stress-Softening of Silica Compounds Produced by Liquid Phase Mixing371
7.4 Time-Temperature Superposition of Dynamic Properties of Filled Vulcanizates 376
7.5 Heat Build-up385
7.6 Resilience 387
References389
8. Rubber Reinforcement Related to Tire Performance 394
8.1 Rolling Resistance 394
8.1.1 Mechanisms of Rolling Resistance-Relationship between Rolling Resistance and Hysteresis394
8.1.2 Effect of Filler on Temperature Dependence of Dynamic Properties 396
8.1.2.1 Effect of Filler Loading396
8.1.2.2 Effect of Filler Morphology 397
因字數限制，僅展示部分目錄
作者簡介
王夢蛟，國家橡膠與輪胎工程技術研究中心任首席科學家，怡維怡橡膠研究院院長。美國卡博特公司前首席科學家。1984年，於法國國家科學研究中心（CNRS）獲得博士學位。曽任職於原化工部北京橡膠工業研究設計院、美國阿克隆大學、德國橡膠工業研究院（DIK）、德國Degussa公司。
王夢蛟在橡膠行業耕耘至今已達56年。發表科學論文共140餘篇，獲得55個美國和中國的授權專利及其相應的24個PCT專利。曾參與了《Carbon Black：Science and Technology》等10本專業書的章節編寫，主譯了5本橡膠專業書籍。曾擔任美國Rubber Chemistry and Technology雜誌編委。
Michael Morris現任美國卡博特公司高級科學家。1985年於南安普頓大學獲博士學位。先後任職於英國馬來西亞橡膠生產者研究協會（MRPRA）、馬來西亞橡膠研究院。1996年加入卡博特公司後，主要從事氣相法白炭黑、炭黑在橡膠中的補強研究。
Morris博士已發表18篇論文，參與兩本書的編寫，獲得12個美國授權專利和很多對應的PCT專利。
