《無機化學（第2版）》是1900年高等教育出版社出版的圖書，作者是高憶慈、史啟禎、曾克慰、李丙瑞。
基本介紹
- 書名：無機化學（第2版）
- 作者：高憶慈、史啟禎、曾克慰、李丙瑞
- ISBN：9787040059366
- 定價：60
- 出版社：高等教育出版社
- 出版時間：1900-01-01
圖書簡介,目錄,
圖書簡介
根據大學理科無機化學教學的要求，結合無機化學學科的發展，本書將無機化學內容分成化學原理、化學理論和描述化學三大部分，共20章。
本書重點敘述化學理論部分，加強介紹化學鍵理論、分子構型、晶體結構與配位化合物等在21世紀的化學中必須掌握的基礎理論知識。在描述化學部分，儘可能利用化學理論來闡述元素及其化合物的性質，反映出性質由結構決定的特點。 本書以張祖德教授多年教學經驗的結晶——《無機化學教案》為基礎編寫而成，可作為高等學校化學類專業的無機化學基礎課教材，也可作為相關人員和優秀中學生自學無機化學知識的參考書。本書配套出版《無機化學習題》。
目錄
總序i
前言iii
第1部分化學原理
Part 1Chemical Principles
第1章氣體、液體和溶液的性質3
Chapter 1The Behaviors of Gas， Liquid and Solution3
1.1氣體的性質3
The Properties of Gases3
1.2液體17
Liquids17
1.3溶液23
Solutions23
第2章化學熱力學基礎與化學平衡38
Chapter 2The Basis of Chemical Thermodynamics and Chemical Equilibrium38
2.1化學熱力學的體系與狀態38
System and State of Chemical Thermodynamics38
2.2熱力學第一定律42
First Law of Thermodynamics42
2.3熱化學47
Thermochemistry47
2.4熱力學第二定律51
Second Law of Thermodynamics51
2.5化學平衡61
Chemical Equilibrium61
第3章酸鹼理論與電離平衡71
Chapter 3The Theories of Acids & Bases and Ionization Equilibrium71
3.1酸鹼理論71
The Theories of Acids and Bases71
3.2弱酸弱鹼的電離平衡77
The Ionic Equilibrium of Weak Acids and Weak Bases77
3.3鹽的水解89
The Hydrolysis of Salts89
第4章沉澱反應92
Chapter 4The Precipitation Reactions92
4.1溶度積92
Solubility Product92
4.2沉澱溶解平衡的移動95
Equilibrium Shift between Precipitation and Dissolution95
4.3多種沉澱之間的平衡97
Equilibrium in Many Precipitants97
第5章氧化還原反應和電化學104
Chapter 5OxidationReduction Reaction and Electrochemistry104
5.1氧化還原反應104
OxidationReduction Reaction104
5.2電極電勢111
Electrode Potential111
5.3電極電勢的套用124
Applications of Electrode Potential124
第6章化學動力學基礎131
Chapter 6The Basis of Chemical Dynamics131
6.1化學反應速率131
The Rate of Chemical Reaction131
6.2化學反應機理154
Reaction Mechanism154
前言iii
第1部分化學原理
Part 1Chemical Principles
第1章氣體、液體和溶液的性質3
Chapter 1The Behaviors of Gas， Liquid and Solution3
1.1氣體的性質3
The Properties of Gases3
1.2液體17
Liquids17
1.3溶液23
Solutions23
第2章化學熱力學基礎與化學平衡38
Chapter 2The Basis of Chemical Thermodynamics and Chemical Equilibrium38
2.1化學熱力學的體系與狀態38
System and State of Chemical Thermodynamics38
2.2熱力學第一定律42
First Law of Thermodynamics42
2.3熱化學47
Thermochemistry47
2.4熱力學第二定律51
Second Law of Thermodynamics51
2.5化學平衡61
Chemical Equilibrium61
第3章酸鹼理論與電離平衡71
Chapter 3The Theories of Acids & Bases and Ionization Equilibrium71
3.1酸鹼理論71
The Theories of Acids and Bases71
3.2弱酸弱鹼的電離平衡77
The Ionic Equilibrium of Weak Acids and Weak Bases77
3.3鹽的水解89
The Hydrolysis of Salts89
第4章沉澱反應92
Chapter 4The Precipitation Reactions92
4.1溶度積92
Solubility Product92
4.2沉澱溶解平衡的移動95
Equilibrium Shift between Precipitation and Dissolution95
4.3多種沉澱之間的平衡97
Equilibrium in Many Precipitants97
第5章氧化還原反應和電化學104
Chapter 5OxidationReduction Reaction and Electrochemistry104
5.1氧化還原反應104
OxidationReduction Reaction104
5.2電極電勢111
Electrode Potential111
5.3電極電勢的套用124
Applications of Electrode Potential124
第6章化學動力學基礎131
Chapter 6The Basis of Chemical Dynamics131
6.1化學反應速率131
The Rate of Chemical Reaction131
6.2化學反應機理154
Reaction Mechanism154
第2部分化學理論
Part 2Chemical Theories
第7章原子結構和元素周期律163
Chapter 7The Atomic Structure and Periodic System of Elements163
7.1原子內部的發現164
Discovery of Structure in Atom164
7.2氫原子光譜和能級的概念170
The Spectrum of Atomic Hydrogen and Concept of Energy Levels170
7.3原子核外電子的運動狀態177
Moving Stations of Electrons outer the Atomic Nucleus177
7.4多電子原子結構和周期系185
Structure in ManyElectron Atoms and Periodic System185
7.5元素基本性質的周期性195
Periodic Properties of the Elements195
第8章化學鍵和分子、晶體結構202
Chapter 8Chemical Bonds and Structures of Molecules & Crystals202
8.1共價鍵與分子幾何構型202
Covalent Bond and Molecular Geometric Structure202
8.2金屬鍵與金屬晶體 232
Metallic Bond and Metallic Crystal232
8.3離子鍵與離子晶體243
Ionic Bond and Ionic Crystal243
8.4晶體學基礎257
Basic Crystallology257
第9章配位化合物267
Chapter 9The Coordination Compounds267
9.1配合物的基本概念268
Basic Concepts of Coordination Compounds268
9.2配位化合物的異構現象279
Isomerism of Coordination Compounds279
9.3配合物的化學鍵理論298
The Chemical Bond Theories of Complexes298
9.4配位平衡及配合物的穩定性315
Coordination Equilibrium and Stabilization of Complex315
9.5配位化合物的套用322
Application of Coordination Compounds322
第3部分描述化學
Part 3Descriptive Chemistry
s區和p區元素化學引言331
Introduction of the Chemistry of s and p Elements331
第10章稀有氣體334
Chapter 10The Rare Gases334
10.1稀有氣體的通性 334
General Properties of Rare Gases334
10.2氙的化學338
Chemistry of Xenon338
第11章氫、鹼金屬和鹼土金屬345
Chapter 11Hydrogen， Alkali and Alkaliearth Metals345
11.1氫及其化合物345
Hydrogen and Its Compounds345
11.2鹼金屬元素及其化合物351
Alkali Metals and Their Compounds351
11.3鹼土金屬及其化合物358
Alkaliearth Metals and Their Compounds358
11.4專題討論366
Discussion of Special Subjects366
第12章鹵素369
Chapter 12The Halogens369
12.1氟及其化合物370
Fluorine and Its Compounds370
12.2氯及其化合物374
Chlorine and Its Compounds374
12.3溴分族380
Bromine Subgroup380
12.4擬鹵素和擬鹵化物386
Pseudohalogen and Pseudohalide386
第13章氧族元素390
Chapter 13The Oxygen Family Elements390
13.1氧及其化合物391
Oxygen and Its Compounds391
13.2硫及其化合物398
Sulfur and Its Compounds398
13.3硒分族407
The Selenium Subgroup407
第14章氮族元素412
Chapter 14The Nitrogen Family Elements412
14.1氮及其化合物413
Nitrogen and Its Compounds413
14.2磷及其化合物423
Phosphorus and Its Compounds423
14.3砷分族430
The Arsenic Subgroup430
第15章碳族元素436
Chapter 15The Carbon Family Elements436
15.1碳及其化合物437
Carbon and Its Compounds437
15.2矽及其化合物445
Silicon and Its Compounds445
15.3鍺分族450
The Germanium Subgroup450
第16章硼族元素455
Chapter 16The Boron Family Elements455
16.1硼及其化合物456
Boron and Its Compounds456
16.2鋁及其化合物466
Aluminum and Its Compounds466
16.3鎵分族470
Gallium Subgroup470
16.4鹽的水解的討論474
Discussion of Salt Hydrolysis474
第17章銅、鋅分族476
Chapter 17The Copper Subgroup and Zinc Subgroup476
17.1銅分族476
The Copper Subgroup476
17.2鋅分族484
The Zinc Subgroup484
第18章過渡元素（Ⅰ）492
Chapter 18The Transition Elements（Ⅰ）492
18.1鈦分族495
The Titanium Subgroup495
18.2釩分族502
The Vanadium Subgroup502
18.3鉻分族507
The Chromium Subgroup507
18.4錳分族516
The Manganese Subgroup 516
第19章過渡元素（Ⅱ）526
Chapter 19The Transition Elements（Ⅱ）526
19.1鐵系元素526
The Ferrous Elements526
19.2鉑系元素538
The Platinum Elements538
第20章鑭系元素和錒系元素545
Chapter 20The Lanthanides and Actinides545
20.1鑭系元素545
The Lanthanides545
20.2錒系元素560
The Actinites560
Appendix 1An Element Crossword568
Appendix 2Thermodynamic Properties of Some Selected Inorganic Compounds572
Appendix 3Standard HalfCell Reduction Potentials of Selected Elements589
Appendix 4Charge Densities of Selected Ions593
Appendix 5Selected Bond Energies596
Appendix 6Ionization Energies of Selected Metals598
Appendix 7Electron Affinities of Selected Nonmetals600
Appendix 8Electronegativities of Selected Elements601
Appendix 9Selected Lattice Energies602
Appendix 10Selected Hydration Enthalpies603
Appendix 11Selected Ionic Radii604
Appendix 12Vapor Pressure of Water at Various Temperatures605
Appendix 13Boiling Point Elevation and Freezing Point Depression Constants606
Appendix 14Enthalpies of Combustion for Some Selected Organic Compounds607
Appendix 15Dissociation Constants of Weak Acids and Bases608
Appendix 16Solubility Product Constants of Selected Slightly Electrolytes609
Appendix 17Formation Constants of Some Selected Complex Ions in Aqueous Solution610
Appendix 18Physical and Chemical Constants611
元素周期表612
Part 2Chemical Theories
第7章原子結構和元素周期律163
Chapter 7The Atomic Structure and Periodic System of Elements163
7.1原子內部的發現164
Discovery of Structure in Atom164
7.2氫原子光譜和能級的概念170
The Spectrum of Atomic Hydrogen and Concept of Energy Levels170
7.3原子核外電子的運動狀態177
Moving Stations of Electrons outer the Atomic Nucleus177
7.4多電子原子結構和周期系185
Structure in ManyElectron Atoms and Periodic System185
7.5元素基本性質的周期性195
Periodic Properties of the Elements195
第8章化學鍵和分子、晶體結構202
Chapter 8Chemical Bonds and Structures of Molecules & Crystals202
8.1共價鍵與分子幾何構型202
Covalent Bond and Molecular Geometric Structure202
8.2金屬鍵與金屬晶體 232
Metallic Bond and Metallic Crystal232
8.3離子鍵與離子晶體243
Ionic Bond and Ionic Crystal243
8.4晶體學基礎257
Basic Crystallology257
第9章配位化合物267
Chapter 9The Coordination Compounds267
9.1配合物的基本概念268
Basic Concepts of Coordination Compounds268
9.2配位化合物的異構現象279
Isomerism of Coordination Compounds279
9.3配合物的化學鍵理論298
The Chemical Bond Theories of Complexes298
9.4配位平衡及配合物的穩定性315
Coordination Equilibrium and Stabilization of Complex315
9.5配位化合物的套用322
Application of Coordination Compounds322
第3部分描述化學
Part 3Descriptive Chemistry
s區和p區元素化學引言331
Introduction of the Chemistry of s and p Elements331
第10章稀有氣體334
Chapter 10The Rare Gases334
10.1稀有氣體的通性 334
General Properties of Rare Gases334
10.2氙的化學338
Chemistry of Xenon338
第11章氫、鹼金屬和鹼土金屬345
Chapter 11Hydrogen， Alkali and Alkaliearth Metals345
11.1氫及其化合物345
Hydrogen and Its Compounds345
11.2鹼金屬元素及其化合物351
Alkali Metals and Their Compounds351
11.3鹼土金屬及其化合物358
Alkaliearth Metals and Their Compounds358
11.4專題討論366
Discussion of Special Subjects366
第12章鹵素369
Chapter 12The Halogens369
12.1氟及其化合物370
Fluorine and Its Compounds370
12.2氯及其化合物374
Chlorine and Its Compounds374
12.3溴分族380
Bromine Subgroup380
12.4擬鹵素和擬鹵化物386
Pseudohalogen and Pseudohalide386
第13章氧族元素390
Chapter 13The Oxygen Family Elements390
13.1氧及其化合物391
Oxygen and Its Compounds391
13.2硫及其化合物398
Sulfur and Its Compounds398
13.3硒分族407
The Selenium Subgroup407
第14章氮族元素412
Chapter 14The Nitrogen Family Elements412
14.1氮及其化合物413
Nitrogen and Its Compounds413
14.2磷及其化合物423
Phosphorus and Its Compounds423
14.3砷分族430
The Arsenic Subgroup430
第15章碳族元素436
Chapter 15The Carbon Family Elements436
15.1碳及其化合物437
Carbon and Its Compounds437
15.2矽及其化合物445
Silicon and Its Compounds445
15.3鍺分族450
The Germanium Subgroup450
第16章硼族元素455
Chapter 16The Boron Family Elements455
16.1硼及其化合物456
Boron and Its Compounds456
16.2鋁及其化合物466
Aluminum and Its Compounds466
16.3鎵分族470
Gallium Subgroup470
16.4鹽的水解的討論474
Discussion of Salt Hydrolysis474
第17章銅、鋅分族476
Chapter 17The Copper Subgroup and Zinc Subgroup476
17.1銅分族476
The Copper Subgroup476
17.2鋅分族484
The Zinc Subgroup484
第18章過渡元素（Ⅰ）492
Chapter 18The Transition Elements（Ⅰ）492
18.1鈦分族495
The Titanium Subgroup495
18.2釩分族502
The Vanadium Subgroup502
18.3鉻分族507
The Chromium Subgroup507
18.4錳分族516
The Manganese Subgroup 516
第19章過渡元素（Ⅱ）526
Chapter 19The Transition Elements（Ⅱ）526
19.1鐵系元素526
The Ferrous Elements526
19.2鉑系元素538
The Platinum Elements538
第20章鑭系元素和錒系元素545
Chapter 20The Lanthanides and Actinides545
20.1鑭系元素545
The Lanthanides545
20.2錒系元素560
The Actinites560
Appendix 1An Element Crossword568
Appendix 2Thermodynamic Properties of Some Selected Inorganic Compounds572
Appendix 3Standard HalfCell Reduction Potentials of Selected Elements589
Appendix 4Charge Densities of Selected Ions593
Appendix 5Selected Bond Energies596
Appendix 6Ionization Energies of Selected Metals598
Appendix 7Electron Affinities of Selected Nonmetals600
Appendix 8Electronegativities of Selected Elements601
Appendix 9Selected Lattice Energies602
Appendix 10Selected Hydration Enthalpies603
Appendix 11Selected Ionic Radii604
Appendix 12Vapor Pressure of Water at Various Temperatures605
Appendix 13Boiling Point Elevation and Freezing Point Depression Constants606
Appendix 14Enthalpies of Combustion for Some Selected Organic Compounds607
Appendix 15Dissociation Constants of Weak Acids and Bases608
Appendix 16Solubility Product Constants of Selected Slightly Electrolytes609
Appendix 17Formation Constants of Some Selected Complex Ions in Aqueous Solution610
Appendix 18Physical and Chemical Constants611
元素周期表612
