沈美慶,男,博士研究生學位,天津大學化工學院院長助理,教授,博士研究生導師.
基本介紹
- 中文名:沈美慶
- 性別:男
- 學位:博士研究生學位
- 職業:教授,博士研究生導師
- 研究方向:生態環境材料、稀土催化化學
- 論文:DeNOx催化劑研究進展
主要經歷,學術兼職,研究方向及課題,科研項目:,論文,專利,
主要經歷
1985.9-1989.7 天津大學化學工程系工業催化專業本科學習,獲工學學士學位
1989.8-1993.8 江蘇省宜興市非金屬化工機械廠工作
1993.9-1998.6 天津大學化學工程系工業催化專業研究生,獲工學碩士、博士學位
1998.7-現在 天津大學化工學院化學工藝系任教
學術兼職
中國稀土學會理事、中國稀土學會催化專業委員會副主任委員、全國稀土催化協作網副理事長
研究方向及課題
生態環境材料、稀土催化化學、能源、環境催化
國家"十五"攻關項目:"散糧儲運裝備技術與套用"課題"高效熏蒸劑發生及輸配技術的研究開發(課題任務書編號:2001BA208B05)
天津市科技攻關項目:環境友好的熏蒸劑發生與殘渣再資源化技術(項目編號:033180911)
天津市基金:稀燃條件下機動車尾氣淨化稀土催化劑的研究(項目編號:013606411)
日本五十鈴國際合作子課題:柴油機尾氣De-NOx催化劑的研究
碳一化工國家重點實驗室開放基金: 高溫催化燃燒機理及機內排放控制技術研究
汽車尾氣淨化催化劑評價系統開發研究
車用尾氣淨化催化劑評價系統開發研究
高效能二氧化氮還原催化劑的開發研究
國家基金青年基金:內燃機排氣中氮氧化物的催化反應機理及控制技術研究
天津市青年基金:工業有機廢氣催化燃燒機理及控制技術研究
天津市基金:納米鈣鈦礦型催化材料的結構與性能研究
機車尾氣淨化催化劑評價系統開發研究
氟化催化劑的開發與研製
工業有機廢氣淨化催化劑評價系統開發研製
甲烷部分氧化制合成氣用金屬蜂窩催化劑研究
儲氧材料的合成與儲放氧機理的研究
苯系物烷基化反應催化劑與催化精餾工藝研究
醇類混合燃料排放特性與控制對策研究
科研項目:
1. 863計畫重大項目課題/2011AA03A405“高性能汽車尾氣催化劑製備及套用技術”(2011-2013)
2. 國家自然科學基金面上項目/50972104 “高性能NOx存儲還原材料及結構與性能的研究”(2010-2012)
3. 天津市重點基金/09JCZDJC26600 “富氧條件下氮氧化物催化脫除的基礎研究”(2009-2012)
4. 工業和信息化部稀土專項課題/2009第9號 “稀土催化材料在汽油車尾氣淨化套用中的示範工程”(2009-2010)
5. 863計畫課題子課題/2006AA060301“乙醇汽油車發動機排放特性及催化劑匹配研究”(2006-2010)
6. 863計畫課題子課題/2006AA060305“寬空燃比視窗三效稀土-低貴金屬催化淨化技術”(2006-2010)
7. 天津市重點基金/07JCZDJC01600 “機動車尾氣淨化用鈰鋯儲氧材料的催化基礎研究”(2007-2009)
8. 教育部新世紀優秀人才支持計畫/NCET-06-0243“機動車排放淨化用稀土材料的催化基礎研究”(2007-2009)
9. 973計畫課題子課題/2004CB719503D “稀土-金屬催化材料的功能調控及在移動源尾氣淨化中的作用”(2004-2009)
10. GM Global R&D GRANT “Manganese Ceria Mixed Oxides NOx Storage Materials: Kinectics and Mechanism” (Dec 6, 2012)
11. GM Global R&D FUNDING PROJECT “Development and Understanding of the Next Generation Lean NOx Catalysts” (2011-2014)
12. GM Global R&D GRANT “Investgation of NO Oxidation Kinetics on Manganese-based Rare-Earths Compounds” (Aug 15, 2011)
13. GM Global R&D GRANT “Synthesis of Silicoaluminophosphate based SCR Catalysts with Improved Catalyst Performance” (Oct 14, 2010)
14. GM Global R&D GRANT “Pt free/ Perovskite-based LNT Catalysts” (Nov 14, 2010)
15. GM Global R&D FUNDING PROJECT “Pt free/ Perovskite-based LNT Catalysts for Optimized Formulations and Improved Catalyst Performance” (USD 2009-2011)
論文
1. 沈美慶等,汽油車用蜂窩陶瓷載體催化劑性能的研究,汽車技術,No 7 1999,P17-19
2. 沈美慶等,DeNOx催化劑研究進展,燃燒科學與技術,4: 333-339(1997)(EI收錄)
3. 王軍、沈美慶等, 催化燃燒法控制有機廢氣污染的研究,燃燒科學與技術,Vol.7 No.3 2001
4. 王軍、沈美慶等,La2O3對Pd催化劑載體的改性效應,天津大學學報,Vol.34 No.3 2001,P1-4
5. 王軍、沈美慶等,整體式催化劑物化性能研究,化學工業與工程,Vol17 No6 2000,P326-329
11. 金複合LaCeMn稀土催化劑在富氧下NOx催化還原性能研究 中國稀土學報Vol.19 No.5 2001
13. 王軍、沈美慶,油煙污染及其排放控制技術,化工進展,Vol.23 No.1 2004,P44-46
14. 王軍、沈美慶等,聚丙烯在超臨界水中的降解反應初探,高分子材料科學與工程,Vol.20 No.2 2004,P65-68
15. 許全瑞、沈美慶、王軍,油煙污染及其排放控制技術,中國稀土學報,Vol.21 2003,P22-25
16. 沈美慶、王軍等,堇青石蜂窩陶瓷載體塗層與熱穩定性研究-(Ⅰ)塗層的製備研究,中國稀土學報,Vol.21 2003,P30-34
17. 翟燕萍、沈美慶、王軍,磷化氫熏蒸劑的研究進展,化學工業與工程,Vol.20 N0.4 2003,P248-251
18. 梁新義、沈美慶等,NO分解納米催化劑LaMnO3的聲化學製備及性質研究,中國稀土學報,Vol.20 2002,P39-42
19. 翟燕萍、沈美慶、王軍,磷化氫高效發生技術的套用研究,糧油加工與機械,2004年5月
20. 沈美慶、翟燕萍、王軍,環境友好熏蒸劑發生工藝的研究研究,糧油加工與機械,2004年6月
2014年:
1. Study of Pt dispersion on Ce based supports and the influence on the CO oxidation reaction,Chemical engineering journal, 2014, 255, 40-48
2. Effects of Two Different CeO2 Materials on Lean NOx Trap Performance below 300 degrees C , Acta Physico-Chimica Sinica, 2014, 30(8), 1559-1566
3. Effect of NO2 on the Selective Catalytic Reduction of NO with NH3 over Cu/SAPO-34 Molecular Sieve Catalyst, Acta Physico-Chimica Sinica, 2014, 30(8), 1567-1574
4. NH3 Oxidation Mechanism over Cu/SAPO-34 Catalysts Prepared by Different Methods, ChemCatChem, 2014, 6(7) , 2074-2083
5. The effect of various templates on the NH3-SCR activities over Cu/SAPO-34 catalysts, Chemical engineering journal, 2014, 243, 159-168
6. Recent NH3-SCR Mechanism Research over Cu/SAPO-34 Catalyst, Journal of Physical Chemistry C, 2014, 118(13), 6565-6575
7. The migration of Cu species over Cu-SAPO-34 and its effect on NH3 oxidation at high temperature, Catalysis Science & Technology, 2014, 4(9), 3004-3012
8. The role of various iron species in Fe-beta catalysts with low iron loadings for NH3-SCR, Catalysis Science & Technology, 2014, 4(5), 1350-1356
2013年:
1. The effect of synthesis methods on Cu species and active sites over Cu/SAPO-34 for NH3-SCR reaction[J] Catalysis Science & Technology, 2013, 3, 2357-2364
2. Catalytic performance of NO oxidation over LaMeO3 (Me = Mn, Fe, Co) perovskite prepared by the sol-gel method[J] Catalysis Communications, 2013, 37, 105-108
3. Properties and Roles of Adsorbed NH3 and NOx over Cu/SAPO-34 Zeolite Catalyst in NH3-SCR Process[J] Acta Physico-Chimica Sinica, 2013, 29(7): 1550-1557
4. Regeneration of SO2-poisoned diesel oxidation Pd/CeO2 catalyst[J] Catalysis Communications, 2013, 36, 5-9
5. The influence of nonstoichiometry on LaMnO3 perovskite for catalytic NO oxidation[J] Applied Catalysis B-Environment, 2013, 134, 251-257
6. The lean NOx traps behavior of (1-5%) BaO/CeO2 mixed with Pt/Al2O3 at low temperature (100-300°C): The effect of barium dispersion[J] Chemical engineering journal, 2013, 222: 401-410
7. The effect of CO on NO reduction over Pt/Pd-based NSR catalysts at low temperature[J] Catalysis Science & Technology, 2013, 3 (4): 1069-1077
8. Characterization of copper species over Cu/SAPO-34 inselective catalytic reduction of NOx with ammonia: Relationships between active Cu sites and de-NOx performance at low temperature[J] Journal of Catalysis, 2013, 297, 56-64
9. The different NOx trap performance on ceria and barium/ceria containing LNT catalysts below 200 degrees C[J] Catalysis Science & Technology, 2013, 3 (1):200-207
10. Different selections of active sites for CO, C3H6, and C10H22 oxidation on Pd/CeO2 Catalysts[J] Fuel, 2013, 103, 869-875
11. Properties and Roles of Adsorbed NH3 and NOx over Cu/SAPO-34 Zeolite Catalyst in NH3-SCR Process, Acta Phys. -Chim. Sin. 2013, 29 (7), 1550-1557
13. NH3-SCR over Cu/SAPO-34 catalysts with various acid contents and low Cu loading, Catalysis Science & Technology, 2013, 3 (12): 3234-3241
202012年:
1. The influence of silicon on the catalytic properties of Cu/SAPO-34 for NOx reduction by ammonia-SCR[J] Applied Catalysis B-environmental, 2012, 127, 137-147
2. Effect of cobalt doping on ceria-zirconia mixed oxide: Structural characteristics, oxygen storage/release capacity and three-way catalytic performance[J] Journal of Rare Earths, 2012, 30(9):878-883
3. The effect of partial substitution of Co in LaMnO3 synthesized by sol-gel methods for NO oxidation[J] Catalysis Communications, 2012, 25, 106-109
4. Steam effects over Pd/Ce067Zr033O2-Al2O3 three-way catalyst[J] Journal of Rare Earths, 2012, 30 (8): 748-752
5. Improved palladium only three-way catalysts using phosphorus modified alumina support[J]Catalysis Communication, 2012, 22, 28-33
6. Performance and hydrothermal durability of CeO2-V2O5-ZrO2/WO3-TiO2 based NH3-SCR catalysts[J] Catalysis Science & Technology, 2012, 2 (7): 1386-1395
7. Preparation of FexCe1-xOy solid solution and its application in Pd-only three-way catalysts[J] Journal of Environmental Sciences-China, 2012, 24 (4): 757-764
2011年:
1. CeO2-CoOx mixed oxides: Structural characteristics and dynamic storage/release capacity[J] Catalysis Today, 2011, 175 (1): 65-71
2. Controlled Protein Delivery Based on Enzyme-Responsive Nanocapsules[J] Advanced Materials, 2011, 23 (39), 4549
3. The effect of zirconia additive on the activity and structure stability of V2O5/WO3-TiO2 ammonia SCR catalysts[J] Applied Catalysis B-Environmental, 2011, 106 (3-4): 359-369
4. High-Performance Supercapacitors Based on Hierarchically Porous Graphite Particles[J] Advanced Energy Materials, 2011, 1 (4): 551-556
5. Synthesis of Monodisperse CexZr1-xO2 Nanocrystals and the Size-Dependent Enhancement of Their Properties[J] Nano Research, 2011, 4(5): 494-504
6. Effects of Fe-doping of ceria-based materials on their microstructural and dynamic oxygen storage and release properties[J] Journal of Sol-gel Science And Technology, 2011, 58(1): 259-268
7. Steam effects over Pd/Ce067Zr033O2 three-way catalyst[J] Jounal of Rare Earths, 2011, 29 (3): 217-224
8. Effect of iron doping into CeO2-ZrO2 on the properties and catalytic behaviour of Pd-only three-way catalyst for automotive emission control[J] Jounal of Hazardous Materials, 2011, 186 (1): 911-920
9. Modified textures and redox activities in Pt/Al2O3 + BaO/CexZr1-xO2 model NSR catalysts[J] Applied Catalysis B-environmental, 2011, 101 (3-4): 355-365
10. Single-Crystal-like Titania Mesocages[J] Angewandte Chemie-International Edition, 2011, 50(5): 1105-1108
11. Surface basicity on bulk modified phosphorus alumina through different synthesis methods[J], Physical Chemistry Chemical Physics, 2011, 13(34): 15589-15596
專利
授權發明專利:
1. 用於丙烯腈氧化尾氣NOx淨化的Fe分子篩催化劑和製備方法,專利號:CN102513145A
2. 釩基SCR催化劑和製備及在丙烯腈氧化後尾氣NOx脫除中的套用,專利號:CN102500359A
3. 磷酸矽鋁分子篩SCR催化劑和製備及脫除丙烯腈氧化尾氣NOx的套用,專利號:CN102513150A
4. 一種NOx選擇性催化還原分子篩催化劑及製備方法,專利號:CN102416343A
5. 用於脫除稀燃發動機尾氣中的氮氧化物存儲還原催化劑及製備方法,專利號:CN 102172526B
6. 一種用於脫除柴油車尾氣中氮氧化物的選擇性催化劑及其製備方法,專利號:CN101912775A
7. 乙醇燃料汽油機尾氣淨化催化劑及其製備方法,申請PCT國際專利號:PCT/CN2009/070086
8. 間歇式流化床磷化鋁水解法製備活性氧化鋁的工藝和裝置,申請PCT國際專利號:PCT/CN2009/070087
9. 機動車尾氣淨化催化材料強制老化的裝置和工藝方法,申請專利號:200810154195X
10. 鈰基複合氧化物負載貴金屬三效催化劑及其製備方法,申請專利號:2008101541926
11. 共沉澱法製備均一固溶體鈰鋯鋁塗層材料及其工藝方法,申請專利號:2008101541907
12. 寬活性溫度視窗的SCR催化劑及其製備方法和套用,申請專利號:2008101541875
13. 間歇式流化床磷化鋁水解法製備活性氧化鋁的工藝和裝置,申請專利號:2008101541930
14. 自換熱型催化劑評價反應器,專利號:CN 2005100137772
15. 磷化鋁熏蒸殘渣的無害化處理並回收氧化鋁的方法,專利號:CN 2004100203163
16. 以磷化鋁製備活性氧化鋁的方法,專利號:CN 2004100203178
17. 用於甲烷部分氧化制合成氣的Ni基催化劑及其製備方法,專利號:CN 101049566
18. 自換熱型催化劑評價反應器,專利號:CN 100336598
202010年:
1. Performance of dynamic oxygen storage capacity, water-gas shift and steam reforming reactions over Pd-only three-way catalysts[J] Catalysis Today, 2010, 158 (3-4): 481-489
2. The effect of La doping on the structure of Ce02Zr08O2 and the catalytic performance of its supported Pd-only three-way catalyst[J] Applied Catalysis B-environmental, 2010, 101 (1-2): 150-159
3. Effects of Ni-Doping of Ceria-Based Materials on Their Micro-Structures and Dynamic Oxygen Storage and Release Behaviors[J] Catalysis Letters, 2010, 140 (1-2): 38-48
4. Complete Oxidation of Ethanol and Thermal Stability of Ceria-Based Materials Modified by Doping Cu[J] Acta Physico-Chimica Sinica, 2010, 26 (8): 2249-2254
5. Enhanced Oxygen Buffering by Substitutional and Interstitial Ni Point Defects in Ceria:A First-Principles DFT+U Study[J] Journal of Physical Chemistry C, 2010, 114, 10221–10228
6. Effects of CO2 and steam on Ba/Ce-based NOx storage reduction catalysts during lean aging[J] Journal of Catalysis, 2010, 271, 228-238
202009年:
1. Effect of SO2 Treatment at High Temperature on Soot Oxidation Activity of Cu-Ce-Al Mixed Oxides[J] Catalysis Letters, 2009, 131 (3-4): 463-468
2. Pd-support interaction defined selective redox activities in Pd-Ce07Zr03O2-Al2O3 model three-way catalysts[J] Journal of Physical Chemistry C, 2009, 113 (29): 12778-12789
3. Effect of phosphorus introduction strategy on the surface texture and structure of modified alumina[J] Microporous and Mesoporous Materials, 2009, 121 (1-3): 208-218
4. Dynamic oxygen storage and release over Cu01Ce09Ox and Cu01Ce06Zr03Ox complex compounds and structural characterization[J] Journal of Alloys and Compounds, 2009, 473 (1-2): 293-297
5. Pd/support interface-promoted Pd-Ce07Zr03O2-Al2O3 automobile three-way catalysts: studying the dynamic oxygen storage capacity and CO, C3H8, and NO conversion[J] Journal of Physical Chemistry C, 2009, 113 (8): 3212-3221
6. Modification ceria-zirconia mixed oxides by doping Sr using the reversed microemulsion for improved Pd-only three-way catalytic performance[J] Journal of Physical Chemistry C, 2009, 113 (4): 1543-1551
7. Synthesis and properties of thermostable γ-alumina prepared by hydrolysis of phosphide aluminum[J] Journal of Alloys and Compounds, 2009, 467 (1-2): 405-412
202008年:
1. Durability of three-way and close-coupled catalysts for Euro IV regulation[J] Jounal of Rare Earths, 2008, 26 (6): 827-830
2. Ce-Zr-Sr mixed oxide prepared by the reversed microemulsion method for improved Pd-only three-way catalysts[J] Catalysis Communications, 2008, 10 (1): 103-107
3. Effect of different mixing ways in palladium/ceria-zirconia/alumina preparation on partial oxidation of methane[J] Jounal of Rare Earths, 2008, 26 (4): 523-527
4. Redox behaviors and structural characteristics of Mn01Ce090Ox and Mn01Ce06Zr03Ox[J] Jounal of Rare Earths, 2008, 26 (4): 523-527
5. Ce–Zr–Sr ternary mixed oxides structural characteristics and oxygen storage capacity[J] Journal of Alloys and Compounds, 2008, 457 (1-2): 578-586
6. Partial oxidation of methane on Ni/CeO2-ZrO2/gamma-Al2O3 prepared using different processes[J] Jounal of Rare Earths, 2008, 26 (3): 347-351
7. Dynamic oxygen storage and release over Mn01Ce09Ox and Mn01Ce06Zr03Ox complex compounds and structural characterization[J] Journal of Alloys and Compounds, 2008, 454 (1-2): 321-326
8. Effect of interaction between Ce07Zr03O2 and Al2O3 on structural characteristics, thermal stability, and oxygen storage capacity[J] Journal of Physical Chemistry C, 2008, 112 (13): 5113-5122