毛宗萬,男,1962年7月生於四川南充,博士,現任中山大學化學與化學工程學院院長,教授,博士生導師。
基本介紹
- 中文名:毛宗萬
- 國籍:中國
- 出生日期:1962年7月
- 畢業院校:南京大學
- 學位/學歷:博士
- 職務:中山大學化學與化學工程學院院長
- 職稱:教授
人物經歷,教育經歷,工作經歷,講授課程,科研方向,學術成果,科研項目,獲得獎項,論著一覽,相關成果,
人物經歷
教育經歷
1982年獲四川大學學士學位
1991年獲南京大學碩士學位
1994年獲南京大學博士學位
工作經歷
1995-96年在中山大學作博士後研究
1997-98年在德國埃爾蘭根-紐倫堡大學作洪堡訪問學者
現任中山大學化學與化學工程學院院長,教授,博士生導師。
講授課程
《無機化學》、《配位化學與生物無機化學》、《綜合化學實驗》、《現代化學研究方法與技術》等本科生、研究生課程,參加編寫《生物無機化學》研究生教材(科學出版社,2006),獲中山大學許崇清教學獎,獲省部級教學成果獎勵2項。
科研方向
金屬酶結構與功能的關係及其模擬、疾病診斷試劑及金屬藥物等。
學術成果
科研項目
目前在研項目有:國家自然科學基金重點項目1項、港澳青年學者合作研究基金項目1項,廣東省自然科學基金面上項目1項,已在國內外各類雜誌上發表論文50餘篇,獲專利1項,獲省部級科技成果獎勵1項。多次在國內外會議作邀請報告,多次參與組織國際性和全國性的學術會議。
獲得獎項
獲省部級科技成果獎勵1項。
論著一覽
1. Fu H, Zhou YH, Chen WL, Deqing ZG., Tong ML, Ji LN, Mao ZW*, ‘Complexation, structure and SOD activity of the imidazolate-bridged dinuclear copper moiety with β-cyclodextrin and its guanidinium-containing derivative’ J. Am.Chem. Soc. 2006, in press.
2. An Y, Tong ML, Ji LN Mao ZW*, ‘Double-strand DNA cleavage by copper complexes of 2,2’-dipyridyl with electropositive pendants’. J. Chem. Soc., Dalton Trans. 2006, in press.
3. Ding BB, Weng YQ, Mao ZW, Lam CK, Chen XM, Ye BH, ‘Pillared-layer microporous metal-organic frameworks constructed by robust hydrogen bonds. Synthesis, characterization, and magnetic and adsorption properties of 2,2 '-biimidazole and carboxylate complexes’, Inorg. Chem. 2005, 28, 8836.
4. Liu XW, Li J, Deng H, Zheng KC, Mao ZW, Ji LN, ‘Experimental and DFT studies on the DNA-binding trend and spectral properties of complexes [Ru(bpy)2L]2+’. Inorg. Chem. Acta, 2005, 358, 3311.
5. Fu H, Chen WL, Fu DG, Tong ML, Chen XM, Ji LN, Mao ZW*, ‘Synthesis, structure and magnetism of a ?3-carbonato bridged nickel(II) complex with 2, 2’, 2’’-tris(2-aminoethyl)amine ligand: a new coordination mode of carbonato bridge’. Inorg. Chem. Commun. 2004, 7, 1285.
6. Fu H, Liu XW, Zhou ZY, Mao ZW*, Zheng KC, Chen XM*, ‘A novel perchlorate-bridged tetranuclear zinc(II) structure with tris(2-aminoethyl)amine ligand’.Inorg. Chem. Commun. 2004, 7, 906.
7. Xu XM, Yao JH, Mao ZW*, Yu KB, Ji LN*, ‘DNA cleavage by a novel acyclic copper(II) complex’.Inorg. Chem. Commun. 2004, 7, 803.
8. Wei QH, Yin GQ, Zhang LY, Shi LX, Mao ZW*, Chen ZN*, ‘Luminescent AgI-CuI Heterometallic Hexa-, Octa-, and Hexadecanuclear Alkynyl Complexes”. Inorg. Chem. 2004, 43, 3484.
9. Xu XM, Mao ZW*, Ji LN, ‘Syntheses, characteriation and DNA cleavage studies of acyclic copper(II) complexes’. Transition Metal Chem. 2004, 29, 658.
10. Wang L, Cai JW, Mao ZW, Feng XL, Huang JW, ‘Dinickel complexes bridged by unusual (N,O,O ')-coordinated alpha-amino acids: syntheses, structural characterization and magnetic properties’. Transition Metal Chem. 2004, 29, 411.
11. Mao ZW, Fu H, Xu XM, Li J, Liu SD, Deng SY, Ji LN. ‘Model study for the bio-coordination sphere of active center in carbonic anhydrase and application into DNA cleasvage study’.J. Inorg. Biochem. 2003, 96, 59.
12. Lu TB, Chen S, Mao ZW, Martell AE, Ji LN. ‘Macrocyclic dinuclear copper(II) complex with a novel chloride bridged zigzag chain’. Inorg. Chem. Commun. 2003, 6, 1068.
13. Erras-Hanauer H, Mao ZW, Liehr G, Clark T, van Eldik R. ‘Structures of carbonato and bicarbonato complexes of bis(1,10-phenanthroline)zinc(II): Experiment and theory’. Eur. J. Inorg. Chem. 2003, 1562.
14. Lu TB, Xiang H, Luck RL, Jiang L, Mao ZW, Ji LN. ‘[NiL](3)[BTC](2)center dot 14H(2)O [L=3,10-bis(2-ethyl)-1,3,5,8,10,12-exaazacyclotetradecane, BTC = 1,3,5- benzenetricarboxylate]: synthesis, structure and unique selective guest molecule absorption properties’. New J. Chem. 2002, 26, 969.
15. Chen S, Lu TB, Feng XL, Li YW, Mao ZW, Ji LN. ‘Synthesis, structure and stability of binuclear metal complexes with macrocyclic ligand’. Chem. J. Chinese U. 2002, 23, 1004.
16. Liu J, Lu TB, Xiang H, Mao ZW, Ji LN. ‘Synthesis and X-ray crystal structures of one-dimensional coordination polymers of macrocyclic copper(II) and nickel(II) complexes’. Crystengcomm, 2002, 1.
17.Mao ZW, Heinemann FW, Liehr G, van Eldik R. ‚Complex-formation reactions of Cu(II) and Zn(II) 2,2 '-bipyridine and 1,10-phenanthroline complexes with bicarbonate. Identification of different carbonate coordination modes’. J Chem Soc Dalton Trans. 2001, 3652.
18. Chen HJ, Mao ZW, Gao S, Chen XM., ‘Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits. Chem Commun’. 2001, 2320.
19. Lu TB, Xiang H, Luck RL, Mao ZW, Wang D, Chen C, Ji LN. ‘A two-dimensional coordination polymer with a brick wall structure and hydrophobic channels: synthesis and structure of a macrocyclic nickel(II) complex with 1,3,5-benzenetricarboxylate’.Crystengcomm, 2001, 41.
20. Xiang H, Gao S, Lu TB, Luck RL, Mao ZW, Chen XM, Ji LN. ‘[NiL1](3)[Cr(CN)(6)](2)center dot 18H(2)O [L-1=3,10-bis(2-hydroxyethyl)- 1,3,5,8,10,12-hexaazacyclotetradecane]: a two-dimensional bimetallic assembly exhibiting antiferromagnetic ordering and metamagnetic behavior’. New J. Chem. 2001, 25, 875.
21.Mao ZW, Liehr G, van Eldik R ‘Structural and mechanistic information on the reaction of bicarbonate with Cu(II) and Zn(II) complexes of tris(2-aminoethyl)amine. Identification of intermediate and product species’. J. Chem. Soc. Dalton Trans. 2001, 1593.
22. Lu TB, Xiang H, Ouyang FQ, Mao ZW, Ji LN. ‘Synthesis, crystal structure and magnetic behaviour of three dimensional iron-cerium cyanide bridged bimetallic assembly’. J. Rare Earth: 2001, 19, 81.
23. Xiang H, Lu TB, Chen S, Mao ZW, Feng XL, Yu KB. ‘Macrocyclic nickel(II) complexes with a folded conformation. Synthesis, properties and structures of [NiL(en)][Ni(en)(3)] (ClO4)(4) and [(NiL)(2)(mu-ox)](ClO4)(2) (L=3,10-bis(2-hydroxyethyl) 1,3,5,8,10,12- hexaazacyclotetradecane, en = ethylenediamine, ox = ...’. Polyhedron 2001, 20, 313.
24. Lu TB, Xiang H, Su CY, Cheng P, Mao ZW, Ji LN. ‘[NiL](2)[Fe(CN)(6)]center dot 4H(2)O [L=3,10-bis(2-hydroxyethyl)- 1,3,5,8,10,12-hexaazacyclotetradecane]: a novel three-dimensional iron(II)-nickel(II) cyanide-bridged bimetallic assembly with a vat-like structure’. New J. Chem. 2001, 25, 216.
25.Mao ZW, Liehr G, van Eldik R ‘Isolation and characterization of the first stable bicarbonato complexes of bis(1,10-phenanthroline)copper(II). Identification of Lipscomb- and Lindskog-like intermediates’. J. Am. Chem. Soc. 2000, 122, 4839.
2. An Y, Tong ML, Ji LN Mao ZW*, ‘Double-strand DNA cleavage by copper complexes of 2,2’-dipyridyl with electropositive pendants’. J. Chem. Soc., Dalton Trans. 2006, in press.
3. Ding BB, Weng YQ, Mao ZW, Lam CK, Chen XM, Ye BH, ‘Pillared-layer microporous metal-organic frameworks constructed by robust hydrogen bonds. Synthesis, characterization, and magnetic and adsorption properties of 2,2 '-biimidazole and carboxylate complexes’, Inorg. Chem. 2005, 28, 8836.
4. Liu XW, Li J, Deng H, Zheng KC, Mao ZW, Ji LN, ‘Experimental and DFT studies on the DNA-binding trend and spectral properties of complexes [Ru(bpy)2L]2+’. Inorg. Chem. Acta, 2005, 358, 3311.
5. Fu H, Chen WL, Fu DG, Tong ML, Chen XM, Ji LN, Mao ZW*, ‘Synthesis, structure and magnetism of a ?3-carbonato bridged nickel(II) complex with 2, 2’, 2’’-tris(2-aminoethyl)amine ligand: a new coordination mode of carbonato bridge’. Inorg. Chem. Commun. 2004, 7, 1285.
6. Fu H, Liu XW, Zhou ZY, Mao ZW*, Zheng KC, Chen XM*, ‘A novel perchlorate-bridged tetranuclear zinc(II) structure with tris(2-aminoethyl)amine ligand’.Inorg. Chem. Commun. 2004, 7, 906.
7. Xu XM, Yao JH, Mao ZW*, Yu KB, Ji LN*, ‘DNA cleavage by a novel acyclic copper(II) complex’.Inorg. Chem. Commun. 2004, 7, 803.
8. Wei QH, Yin GQ, Zhang LY, Shi LX, Mao ZW*, Chen ZN*, ‘Luminescent AgI-CuI Heterometallic Hexa-, Octa-, and Hexadecanuclear Alkynyl Complexes”. Inorg. Chem. 2004, 43, 3484.
9. Xu XM, Mao ZW*, Ji LN, ‘Syntheses, characteriation and DNA cleavage studies of acyclic copper(II) complexes’. Transition Metal Chem. 2004, 29, 658.
10. Wang L, Cai JW, Mao ZW, Feng XL, Huang JW, ‘Dinickel complexes bridged by unusual (N,O,O ')-coordinated alpha-amino acids: syntheses, structural characterization and magnetic properties’. Transition Metal Chem. 2004, 29, 411.
11. Mao ZW, Fu H, Xu XM, Li J, Liu SD, Deng SY, Ji LN. ‘Model study for the bio-coordination sphere of active center in carbonic anhydrase and application into DNA cleasvage study’.J. Inorg. Biochem. 2003, 96, 59.
12. Lu TB, Chen S, Mao ZW, Martell AE, Ji LN. ‘Macrocyclic dinuclear copper(II) complex with a novel chloride bridged zigzag chain’. Inorg. Chem. Commun. 2003, 6, 1068.
13. Erras-Hanauer H, Mao ZW, Liehr G, Clark T, van Eldik R. ‘Structures of carbonato and bicarbonato complexes of bis(1,10-phenanthroline)zinc(II): Experiment and theory’. Eur. J. Inorg. Chem. 2003, 1562.
14. Lu TB, Xiang H, Luck RL, Jiang L, Mao ZW, Ji LN. ‘[NiL](3)[BTC](2)center dot 14H(2)O [L=3,10-bis(2-ethyl)-1,3,5,8,10,12-exaazacyclotetradecane, BTC = 1,3,5- benzenetricarboxylate]: synthesis, structure and unique selective guest molecule absorption properties’. New J. Chem. 2002, 26, 969.
15. Chen S, Lu TB, Feng XL, Li YW, Mao ZW, Ji LN. ‘Synthesis, structure and stability of binuclear metal complexes with macrocyclic ligand’. Chem. J. Chinese U. 2002, 23, 1004.
16. Liu J, Lu TB, Xiang H, Mao ZW, Ji LN. ‘Synthesis and X-ray crystal structures of one-dimensional coordination polymers of macrocyclic copper(II) and nickel(II) complexes’. Crystengcomm, 2002, 1.
17.Mao ZW, Heinemann FW, Liehr G, van Eldik R. ‚Complex-formation reactions of Cu(II) and Zn(II) 2,2 '-bipyridine and 1,10-phenanthroline complexes with bicarbonate. Identification of different carbonate coordination modes’. J Chem Soc Dalton Trans. 2001, 3652.
18. Chen HJ, Mao ZW, Gao S, Chen XM., ‘Ferrimagnetic-like ordering in a unique three-dimensional coordination polymer featuring mixed azide/carboxylate-bridged trinuclear manganese(II) clusters as subunits. Chem Commun’. 2001, 2320.
19. Lu TB, Xiang H, Luck RL, Mao ZW, Wang D, Chen C, Ji LN. ‘A two-dimensional coordination polymer with a brick wall structure and hydrophobic channels: synthesis and structure of a macrocyclic nickel(II) complex with 1,3,5-benzenetricarboxylate’.Crystengcomm, 2001, 41.
20. Xiang H, Gao S, Lu TB, Luck RL, Mao ZW, Chen XM, Ji LN. ‘[NiL1](3)[Cr(CN)(6)](2)center dot 18H(2)O [L-1=3,10-bis(2-hydroxyethyl)- 1,3,5,8,10,12-hexaazacyclotetradecane]: a two-dimensional bimetallic assembly exhibiting antiferromagnetic ordering and metamagnetic behavior’. New J. Chem. 2001, 25, 875.
21.Mao ZW, Liehr G, van Eldik R ‘Structural and mechanistic information on the reaction of bicarbonate with Cu(II) and Zn(II) complexes of tris(2-aminoethyl)amine. Identification of intermediate and product species’. J. Chem. Soc. Dalton Trans. 2001, 1593.
22. Lu TB, Xiang H, Ouyang FQ, Mao ZW, Ji LN. ‘Synthesis, crystal structure and magnetic behaviour of three dimensional iron-cerium cyanide bridged bimetallic assembly’. J. Rare Earth: 2001, 19, 81.
23. Xiang H, Lu TB, Chen S, Mao ZW, Feng XL, Yu KB. ‘Macrocyclic nickel(II) complexes with a folded conformation. Synthesis, properties and structures of [NiL(en)][Ni(en)(3)] (ClO4)(4) and [(NiL)(2)(mu-ox)](ClO4)(2) (L=3,10-bis(2-hydroxyethyl) 1,3,5,8,10,12- hexaazacyclotetradecane, en = ethylenediamine, ox = ...’. Polyhedron 2001, 20, 313.
24. Lu TB, Xiang H, Su CY, Cheng P, Mao ZW, Ji LN. ‘[NiL](2)[Fe(CN)(6)]center dot 4H(2)O [L=3,10-bis(2-hydroxyethyl)- 1,3,5,8,10,12-hexaazacyclotetradecane]: a novel three-dimensional iron(II)-nickel(II) cyanide-bridged bimetallic assembly with a vat-like structure’. New J. Chem. 2001, 25, 216.
25.Mao ZW, Liehr G, van Eldik R ‘Isolation and characterization of the first stable bicarbonato complexes of bis(1,10-phenanthroline)copper(II). Identification of Lipscomb- and Lindskog-like intermediates’. J. Am. Chem. Soc. 2000, 122, 4839.
相關成果
先後承擔了省部級項目7項,目前在研項目有:國家自然科學基金重點項目1項、港澳青年學者合作研究基金項目1項,廣東省自然科學基金面上項目1項,已在國內外各類雜誌上發表論文50餘篇,獲專利1項,獲省部級科技成果獎勵1項。多次在國內外會議作邀請報告,多次參與組織國際性和全國性的學術會議。