徐海兵

徐海兵，男，博士，湖北大學化學化工學院教授、博士生導師。中國工程物理研究院任研究員(2015)。

基本介紹

• 中文名：徐海兵
• 職業：教師
• 學位/學歷：博士
• 專業方向：化學化工
• 任職院校：湖北大學化學化工學院

主講課程

分子光化學與材料(研究生)，本科實驗

人物經歷

教育經歷

2003/09–2006/06，中國科學院福建物質結構研究所，結構化學國家重點實驗室，博士

2000/09–2003/06，福州大學，化學化工學院，碩士

1995/09–1999/06，吉林大學，套用化學系，學士

工作經歷

2017/02–至 今，湖北大學，化學化工學院，教授

2011/03–2017/01，中國工程物理研究院，化工材料研究所，副研究員，研究員。

2009/01–2011/02，中國科學院福建物質結構研究所，結構化學國家重點實驗室， 副研究員

2006/12–2008/12，中山大學與香港大學聯合，化學與化學工程學院，博士後

1999/07–2000/08，中國科學院長春套用化學研究所，稀土資源利用國家重點實驗室，實驗員

學術成果

主持項目

1.主持項目: 國家自然科學基金-面上項目晚嬸禁市(NSFC-21571165)《動態可逆結構稀土配合物設計合成及其光譜行為研究》，60萬元；起止時間：2016.01-2019.12

2.主持項目:中國工程物理研究院×××重大培育專項子課題《用於光纖製備中超純稀土螯合物xxx製備與表征研究》，117萬元；起止時間：2014.08-2015.12

3.主持項目:中國工程物理研究院軍轉民項目(JMRH-201504)《環菌醯胺研發》，20萬元；起止時間：2015.01-2016.12

4.主持項目: 中國工程物理研究院科學技術發展基金(CAEP2012B0302039)《量子點效應螢光化合物的合成及其硝基炸藥感測研究》，18萬元；起止時間：2012.07-2014.07

5.主持項目: 中國工程物理研究院化工材料研究所創新基金(KJCX-201204)《寬光譜高回響染料設計、製備及其在染料敏化太陽能電池中光電性能研和促擔遷究》，30萬元；起止時間：2013.01-2014.12

6.主持項目: 福建省青年基金(2011J01065)《異金屬稀土化合物的可控合成及其發光性能研究》，7萬元；起止時間：2011.01-2013.12

7.主持項目: 國家自然科學基金-青年科學基金(NSFC-20901077)《金屬配位分子白光發射材料》，22萬元；起止時間：2010.01-2012.12

8.主持項目:《固氧發生器研發》，10萬元；起止時間：2011.07-2012.12

9.主持項目: 第41批中國博士後科學基金面上一等資助，(2007-31000-4109337)《有機匪備滲電致發光新材料技術在顯示、照明和背景光中的套用》。 5萬元；起止時間：2007.03-2008.12

10. 參與項目: 國家自然科學循端凳基金重點項目(20931006/B0103) 《具有開關效應的金屬有機光電挨犁估功能材料研究》。170萬元；起止時間：2010.01-2012.12

11.參與項目: 國家科技部973項目(2007CB815304)《物質照尋淋性能的分子設計與結構調控–光電功能分子的組裝與構效關係》。437萬元；起止時間：2007.07-2011.12

12.參與項目: 粵港合作項目(GHP/062/05)《稀土和過渡金屬高發光材料的研製》。25萬港元；起止時間：2006.12-2008.12

13.參與項目：國家計委產業化工程攀西礦乘凳鈰釷分離安全、清潔流程。參與時間1999/07-2000/08，500萬元，已結題。

代表性論文

1. Yana Liu, Cheng Zhang, Chen Xu, Caixue Lin, Keke Sun, Jie Wang, Xueli Chen, Ling Li*, Andrew K. Whittaker*, and Hai-Bing Xu*, Controlled synthesis of up-conversion luminescent Gd/Tm-MOFs for pH-responsive drug delivery and UCL/MRI dual-modal imaging, Dalton Trans., 2018, 47, 11253-11263.

2.Hai-Bing Xu,* Jie Wang, Xue-Li Chen, Xu Peng, Kang-Tai Xiong, Dao-Bin Guan, Jian-Guo Deng, Zhi-Hua Deng, Mohamedally Kurmoo, and Ming-Hua Zeng*, Regulating structural dimensionality and emission colors by organic conjugation between Smat fixed distance, Dalton Trans., 2018, 47, 6908-6916. (Front Cover)

3.Hai-Bing Xu*, Xue-Li Chen, Jian-Guo Deng, Zhi-Hua Deng, Shi-Liang Huang, Mohamedally Kurmoo, and Ming-Hua Zeng*, Sensitized near infrared emission through supramolecular d-f energy transfer within an ionic Ru(II) – Er(III) pair, Dalton Trans., 2018,47, 2073-2078.

4.Xue-Li Chen, Hai-Bing Xu, Xing-Xing Shi, Yuexing Zhang, Tao Yang, Mohamedally Kurmoo, and Ming-Hua Zeng*. Hierarchical Assembly and Aggregation-Induced Enhanced Emission of a Pair of Isostructural Zn14 Clusters, Inorg. Chem., 2017, 56, 14069–14076.

5. Yan Zhang, Peng-Chong Jiao, Hai-Bing Xu,* Ming-Jing Tang, Xiao-Ping Yang, Shaoming Huang, and Jian-Guo Deng. Switchable sensitizers stepwise lighting up lanthanide emissions, Sci. Rep., 2015, 5, 9335.

6. Xuefeng Peng, Jian-Guo Deng, and Hai-Bing Xu,* Substituent and solvent effects on the fluorescent and photochromic properties of 2-(2-pyridyl) imidazole containing diarylethene derivatives, RSC Adv., 2013, 3 (46), 24146 - 24153.

7.Hai-Bing Xu,* Peng-Chong Jiao, Bin Kang, Jian-Guo Deng and Yan Zhang, walkable dual emissions, Sci. Rep. 2013, 3, 2199.

8.Hai-Bing Xu,* Jian-Guo Deng, Li-Yi Zhang, and Zhong-Ning Chen, Structural and Photophysical Studies on Geometric (Er2Yb2/Yb2Er2) and Configurational (EuTb3/Eu3Tb) Isomers of Heterotetranuclear Lanthanide(III) Complexes, Crys Growth & Des., 2013, 13(2), 849–857

9.Hai-Bing Xu*,Jia Li, Lin-Xi Shi, and Zhong-Ning Chen, “Sensitized luminescence in dinuclear lanthanide(III) complexes of bridging 8-hydroxyquinoline derivatives with different electronic properties” Dalton Trans., 2011, 40, 5549-5556.

10.Hai-Bing Xu, Jia Li, Li-Yi Zhang, Xin Huang, Zhong-Hui Chen, Bing Li, and Zhong-Ning Chen, “Structures and Photophysical Properties of Homo- and Heteronuclear Lanthanide(III) Complexes with Bridging 2-Methyl-8-Hydroxylquinoline Featuring μ–Phenol Mode” Crys Growth & Des., 2010, 10, 4101-4108.

11.Hai-Bing Xu,* Ye-Teng Zhong, Wei-Xiong Zhang, Zhong-Ning Chen*, and Xiao-Ming Chen*, “Syntheses, Structures and Photophysical Properties of Heterotrinuclear Zn2Ln Clusters (Ln = Nd, Eu, Tb, Er, Yb)” Dalton Trans., (Hot article) 2010,39, 5676-5682.

12.Hai-Bing Xu,* Hui-Min Wen, Zhong-Hui Chen, Jia Li, Lin-Xi Shi, and Zhong-Ning Chen*, “Square Structures and Photophysical Properties of Zn2Ln2complexes (Ln = Nd, Eu, Sm, Er, Yb)”, Dalton Trans., (Top article)2010, 39, 1948-1953.

13.Hai-Bing Xu, Xiao-Ming Chen*, Qi-Sheng Zhang, Li-Yi Zhang, and Zhong-Ning Chen*. “Fluoride-enhanced lanthanide luminescence and white-light emitting in multifunctional Al3Ln2(Ln = Nd, Eu, Yb) heteropentanuclear complexes”, Chem. Commun., 2009, 7318-7320.

14.Hai-Bing Xu, Xiao-Ming Chen, Xiu-Ling Li, Li-Yi Zhang, and Zhong-Ning Chen*, “Modulation of Pt→Ln Energy Transfer in PtLn2 (Ln = Nd, Er, Yb) Complexes with 2,2’-Bipyridyl/2,2’:6’2”-Terpyridyl Ethynyl Ligands”, Crys. Growth & Des., 2009, 9, 569-576.

15.Hai-Bing Xu, Li-Yi Zhang, Lin-Xi Shi, En Ma，Hsiu-Yi Chao, and Zhong-Ning Chen*, “Conformation Changes and Luminescence of Au-Ln(Ln = Nd, Eu, Er, Yb) Arrays with 5-Ethynyl-2,2’-Bipyridine”,Inorg. Chem., 2008, 47, 10744-10752.

16.Hai-Bing Xu, Jun Ni, Kun-Jiao Chen, Li-Yi Zhang, and Zhong-Ning Chen*, “Preparation, Characterization and Photophysical Properties of cis- or trans-PtLn2(Ln = Nd, Eu, Yb) Arrays with 5-Ethynyl-2,2’-bipyridine”,Organometallics, 2008, 27, 5665-5671.

17.Hai-Bing Xu, Li-Yi Zhang, Zhong-Hui Chen, Lin-Xi Shi, and Zhong-Ning Chen*, “Sensitization of lanthanide luminescence by two different Pt→Ln energy transfer pathways in PtLn3heterotetranuclear complexes with 5-ethynyl-2,2’-bipyridine”,Dalton Trans., 2008, 4664-4670.

18.Hai-Bing Xu, Li-Yi Zhang, Zai-Lai Xie, En Ma, and Zhong-Ning Chen*, “Heterododecanuclear Pt6Ln6(Ln = Nd, Gd, Yb) Arrays of 4-Ethynyl-2,2’-Bipyridine with Sensitized Near-Infrared Lanthanide Luminescence by Pt→Ln Energy Transfer”, Chem. Commun., 2007, 2744-2746.

19.Hai-Bing Xu, Lin-Xi Shi, En Ma, Li-Yi Zhang, Qiao-Hua Wei, and Zhong-Ning Chen*, “PtAlkynyl Chromophores as Sensitizers for Lanthanide Luminescence in Pt2Ln2and Pt2Ln4 (Ln = Eu, Nd, Yb) Arrays with Acetylide-functionlized Bipyridine/Phenanthroline”, Chem. Commun., (Hot paper), 2006, 1601-1603.

綜述論文

20.Hai-Bing Xu,* Ting He, Ming-Jing Tang, Xuefeng Peng, Jian-Guo Deng. progress on photochromic propeties of metal (Ru, Pt, Ln)-diarylethene. Chin. Sci. Bull (Chin Ver), 2014,59, 2900–2917.

21.Hai-Bing Xu,* Jian-Guo Deng, and Bin Kang, Designed synthesis and photophysical properties of multifunctional hybrid lanthanide complexes, RSC Adv., 2013, 3 (29), 11367–11384.

專著成果

1.Zhong-Ning Chen and Hai-Bing Xu, (2010) Near-Infrared (NIR) Luminescence from Lanthanide(III) Complexes, in Rare Earth Coordination Chemistry: Fundamentals and Applications (ed C. Huang), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470824870.ch12 (473-527).

授權專利

1.徐海兵、鄧建國、田勇、黃輝、唐明靜。《異四核f-f’同分異構和/或構型異構化合物的製備方法》，專利號ZL-2011-1-0200598.5，申請日：20110718，授權日20140108

2.徐海兵、鄧建國、康彬、黃輝。《系列聚集誘導移動雙重發射光譜的環狀稀土配合物及其製備方法》，專利號：ZL-2012-1-0302683.7，申請日：20120823，授權日20150204

3.徐海兵、鄧建國、康彬、黃輝。《一種濃度、溫度感測材料》，專利號：ZL-2013-1-0127970.3，申請日：20130412，授權日20150401

4.徐海兵、張衍、焦鵬沖、鄧建國、黃輝。《具有集聚誘導螢光增強效應稀土配合物、探針及製備方法》，專利號：ZL-2012-1-0483743.X，申請日：20121123，授權日：2015.08.26

5.徐海兵、焦鵬沖、張衍、鄧建國。《一類近紅外寬光譜金屬配合物染料及其製備方法》專利號：ZL-2014-1-0193081.1，申請日：2014.05.08，授權日：2015.12.30

6.張衍、鄧建國、徐海兵。《大容量全固態氧氣發生器》專利號：ZL-2014-1-0407992.X，申請日：2014.08.18，授權日：2016.08.17

7.徐海兵、焦鵬沖、張衍、鄧建國。《一種雙重異稀土螢光探針化合物的製備方法》, 專利號：ZL-2014-1-0455753.1；申請日：2014.09.09，授權日：2016.08.17

8.焦鵬沖、徐海兵、何亭、張衍、鄧建國。《環金屬配體染料，染料敏化電極和太陽能電池》專利號：ZL-2014-1-0436437.X; 申請日：2014.08.29，授權日：2017.06.06

9.徐海兵、焦鵬沖、唐明靜、陳瑩、杜雲巍、鄧建國、蔣道建等《純化高穩定易揮發性金屬螯合物的方法》，專利號：ZL-2015-1-0183819.0; 申請日：2015.04.17,授權日：2017.10.20.

10. 焦鵬沖，徐海兵，鄧建國，《一種稀土氧化物分離純化的前處理方法》，專利號：ZL-2016-1-0082065.4, 申請日：20160205，授權日：20180501

榮譽獎項

在中國科學院福建物構所工作期間獲得福建省科學技術二等獎；在中國工程物理研究院工作期間獲得所先進個人、所年度優秀論文、所年度優秀團隊、第二屆中國科學城綿陽創新創業大賽一等獎、中物院科學技術發展基金優秀獎。授權國家專利10項。

11.參與項目: 國家科技部973項目(2007CB815304)《物質性能的分子設計與結構調控–光電功能分子的組裝與構效關係》。437萬元；起止時間：2007.07-2011.12

12.參與項目: 粵港合作項目(GHP/062/05)《稀土和過渡金屬高發光材料的研製》。25萬港元；起止時間：2006.12-2008.12

13.參與項目：國家計委產業化工程攀西礦鈰釷分離安全、清潔流程。參與時間1999/07-2000/08，500萬元，已結題。

代表性論文

1. Yana Liu, Cheng Zhang, Chen Xu, Caixue Lin, Keke Sun, Jie Wang, Xueli Chen, Ling Li*, Andrew K. Whittaker*, and Hai-Bing Xu*, Controlled synthesis of up-conversion luminescent Gd/Tm-MOFs for pH-responsive drug delivery and UCL/MRI dual-modal imaging, Dalton Trans., 2018, 47, 11253-11263.

2.Hai-Bing Xu,* Jie Wang, Xue-Li Chen, Xu Peng, Kang-Tai Xiong, Dao-Bin Guan, Jian-Guo Deng, Zhi-Hua Deng, Mohamedally Kurmoo, and Ming-Hua Zeng*, Regulating structural dimensionality and emission colors by organic conjugation between Smat fixed distance, Dalton Trans., 2018, 47, 6908-6916. (Front Cover)

3.Hai-Bing Xu*, Xue-Li Chen, Jian-Guo Deng, Zhi-Hua Deng, Shi-Liang Huang, Mohamedally Kurmoo, and Ming-Hua Zeng*, Sensitized near infrared emission through supramolecular d-f energy transfer within an ionic Ru(II) – Er(III) pair, Dalton Trans., 2018,47, 2073-2078.

4.Xue-Li Chen, Hai-Bing Xu, Xing-Xing Shi, Yuexing Zhang, Tao Yang, Mohamedally Kurmoo, and Ming-Hua Zeng*. Hierarchical Assembly and Aggregation-Induced Enhanced Emission of a Pair of Isostructural Zn14 Clusters, Inorg. Chem., 2017, 56, 14069–14076.

5. Yan Zhang, Peng-Chong Jiao, Hai-Bing Xu,* Ming-Jing Tang, Xiao-Ping Yang, Shaoming Huang, and Jian-Guo Deng. Switchable sensitizers stepwise lighting up lanthanide emissions, Sci. Rep., 2015, 5, 9335.

6. Xuefeng Peng, Jian-Guo Deng, and Hai-Bing Xu,* Substituent and solvent effects on the fluorescent and photochromic properties of 2-(2-pyridyl) imidazole containing diarylethene derivatives, RSC Adv., 2013, 3 (46), 24146 - 24153.

7.Hai-Bing Xu,* Peng-Chong Jiao, Bin Kang, Jian-Guo Deng and Yan Zhang, walkable dual emissions, Sci. Rep. 2013, 3, 2199.

8.Hai-Bing Xu,* Jian-Guo Deng, Li-Yi Zhang, and Zhong-Ning Chen, Structural and Photophysical Studies on Geometric (Er2Yb2/Yb2Er2) and Configurational (EuTb3/Eu3Tb) Isomers of Heterotetranuclear Lanthanide(III) Complexes, Crys Growth & Des., 2013, 13(2), 849–857

9.Hai-Bing Xu*,Jia Li, Lin-Xi Shi, and Zhong-Ning Chen, “Sensitized luminescence in dinuclear lanthanide(III) complexes of bridging 8-hydroxyquinoline derivatives with different electronic properties” Dalton Trans., 2011, 40, 5549-5556.

10.Hai-Bing Xu, Jia Li, Li-Yi Zhang, Xin Huang, Zhong-Hui Chen, Bing Li, and Zhong-Ning Chen, “Structures and Photophysical Properties of Homo- and Heteronuclear Lanthanide(III) Complexes with Bridging 2-Methyl-8-Hydroxylquinoline Featuring μ–Phenol Mode” Crys Growth & Des., 2010, 10, 4101-4108.

11.Hai-Bing Xu,* Ye-Teng Zhong, Wei-Xiong Zhang, Zhong-Ning Chen*, and Xiao-Ming Chen*, “Syntheses, Structures and Photophysical Properties of Heterotrinuclear Zn2Ln Clusters (Ln = Nd, Eu, Tb, Er, Yb)” Dalton Trans., (Hot article) 2010,39, 5676-5682.

12.Hai-Bing Xu,* Hui-Min Wen, Zhong-Hui Chen, Jia Li, Lin-Xi Shi, and Zhong-Ning Chen*, “Square Structures and Photophysical Properties of Zn2Ln2complexes (Ln = Nd, Eu, Sm, Er, Yb)”, Dalton Trans., (Top article)2010, 39, 1948-1953.

13.Hai-Bing Xu, Xiao-Ming Chen*, Qi-Sheng Zhang, Li-Yi Zhang, and Zhong-Ning Chen*. “Fluoride-enhanced lanthanide luminescence and white-light emitting in multifunctional Al3Ln2(Ln = Nd, Eu, Yb) heteropentanuclear complexes”, Chem. Commun., 2009, 7318-7320.

14.Hai-Bing Xu, Xiao-Ming Chen, Xiu-Ling Li, Li-Yi Zhang, and Zhong-Ning Chen*, “Modulation of Pt→Ln Energy Transfer in PtLn2 (Ln = Nd, Er, Yb) Complexes with 2,2’-Bipyridyl/2,2’:6’2”-Terpyridyl Ethynyl Ligands”, Crys. Growth & Des., 2009, 9, 569-576.

15.Hai-Bing Xu, Li-Yi Zhang, Lin-Xi Shi, En Ma，Hsiu-Yi Chao, and Zhong-Ning Chen*, “Conformation Changes and Luminescence of Au-Ln(Ln = Nd, Eu, Er, Yb) Arrays with 5-Ethynyl-2,2’-Bipyridine”,Inorg. Chem., 2008, 47, 10744-10752.

16.Hai-Bing Xu, Jun Ni, Kun-Jiao Chen, Li-Yi Zhang, and Zhong-Ning Chen*, “Preparation, Characterization and Photophysical Properties of cis- or trans-PtLn2(Ln = Nd, Eu, Yb) Arrays with 5-Ethynyl-2,2’-bipyridine”,Organometallics, 2008, 27, 5665-5671.

17.Hai-Bing Xu, Li-Yi Zhang, Zhong-Hui Chen, Lin-Xi Shi, and Zhong-Ning Chen*, “Sensitization of lanthanide luminescence by two different Pt→Ln energy transfer pathways in PtLn3heterotetranuclear complexes with 5-ethynyl-2,2’-bipyridine”,Dalton Trans., 2008, 4664-4670.

18.Hai-Bing Xu, Li-Yi Zhang, Zai-Lai Xie, En Ma, and Zhong-Ning Chen*, “Heterododecanuclear Pt6Ln6(Ln = Nd, Gd, Yb) Arrays of 4-Ethynyl-2,2’-Bipyridine with Sensitized Near-Infrared Lanthanide Luminescence by Pt→Ln Energy Transfer”, Chem. Commun., 2007, 2744-2746.

19.Hai-Bing Xu, Lin-Xi Shi, En Ma, Li-Yi Zhang, Qiao-Hua Wei, and Zhong-Ning Chen*, “PtAlkynyl Chromophores as Sensitizers for Lanthanide Luminescence in Pt2Ln2and Pt2Ln4 (Ln = Eu, Nd, Yb) Arrays with Acetylide-functionlized Bipyridine/Phenanthroline”, Chem. Commun., (Hot paper), 2006, 1601-1603.

綜述論文

20.Hai-Bing Xu,* Ting He, Ming-Jing Tang, Xuefeng Peng, Jian-Guo Deng. progress on photochromic propeties of metal (Ru, Pt, Ln)-diarylethene. Chin. Sci. Bull (Chin Ver), 2014,59, 2900–2917.

21.Hai-Bing Xu,* Jian-Guo Deng, and Bin Kang, Designed synthesis and photophysical properties of multifunctional hybrid lanthanide complexes, RSC Adv., 2013, 3 (29), 11367–11384.

專著成果

1.Zhong-Ning Chen and Hai-Bing Xu, (2010) Near-Infrared (NIR) Luminescence from Lanthanide(III) Complexes, in Rare Earth Coordination Chemistry: Fundamentals and Applications (ed C. Huang), John Wiley & Sons, Ltd, Chichester, UK. doi: 10.1002/9780470824870.ch12 (473-527).

授權專利

1.徐海兵、鄧建國、田勇、黃輝、唐明靜。《異四核f-f’同分異構和/或構型異構化合物的製備方法》，專利號ZL-2011-1-0200598.5，申請日：20110718，授權日20140108

2.徐海兵、鄧建國、康彬、黃輝。《系列聚集誘導移動雙重發射光譜的環狀稀土配合物及其製備方法》，專利號：ZL-2012-1-0302683.7，申請日：20120823，授權日20150204

3.徐海兵、鄧建國、康彬、黃輝。《一種濃度、溫度感測材料》，專利號：ZL-2013-1-0127970.3，申請日：20130412，授權日20150401

4.徐海兵、張衍、焦鵬沖、鄧建國、黃輝。《具有集聚誘導螢光增強效應稀土配合物、探針及製備方法》，專利號：ZL-2012-1-0483743.X，申請日：20121123，授權日：2015.08.26

5.徐海兵、焦鵬沖、張衍、鄧建國。《一類近紅外寬光譜金屬配合物染料及其製備方法》專利號：ZL-2014-1-0193081.1，申請日：2014.05.08，授權日：2015.12.30

6.張衍、鄧建國、徐海兵。《大容量全固態氧氣發生器》專利號：ZL-2014-1-0407992.X，申請日：2014.08.18，授權日：2016.08.17

7.徐海兵、焦鵬沖、張衍、鄧建國。《一種雙重異稀土螢光探針化合物的製備方法》, 專利號：ZL-2014-1-0455753.1；申請日：2014.09.09，授權日：2016.08.17

8.焦鵬沖、徐海兵、何亭、張衍、鄧建國。《環金屬配體染料，染料敏化電極和太陽能電池》專利號：ZL-2014-1-0436437.X; 申請日：2014.08.29，授權日：2017.06.06

9.徐海兵、焦鵬沖、唐明靜、陳瑩、杜雲巍、鄧建國、蔣道建等《純化高穩定易揮發性金屬螯合物的方法》，專利號：ZL-2015-1-0183819.0; 申請日：2015.04.17,授權日：2017.10.20.

10. 焦鵬沖，徐海兵，鄧建國，《一種稀土氧化物分離純化的前處理方法》，專利號：ZL-2016-1-0082065.4, 申請日：20160205，授權日：20180501

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