徐嘉麒,四川大學副研究員(專職科研)。
基本介紹
學習經歷,工作經歷,研究方向,研究成果,所獲榮譽,社會任職,主持科研項目,代表性成果,專利,
學習經歷
2010.09–2014.06,天津大學,套用化學,學士,導師:張兵教授
工作經歷
2022.07-至今,四川大學,無機化學,副研究員(專職科研)
2023.03-至今,瑞士聯邦理工學院(洛桑),訪學,導師:Michael Grätzel院士
2019.07-2022.06,四川大學,無機化學,助理研究員
2019.07-2023.03,四川大學,無機化學,專職博士後,導師:李瑞祥教授
研究方向
1. 二氧化碳轉化體系研究;
2. 低維固體材料的設計、精準製備以及表征;
3. 催化劑的動態變化過程和反應機理研究;
4. DFT理論計算。
研究成果
隨著社會的發展,人類的能源需求和碳排放量都在不斷增長。以二氧化碳(CO2)為指標,2019年全球碳排放總量達到了364.41億噸。CO2的過量排放會造成氣候變暖、海水酸化等一系列問題。為了降低社會發展對環境的影響,實現CO2的“淨零排放”,我們需要大力發展清潔的碳中和技術。其中,利用半導體催化劑,通過電催化或者光催化的方式將二氧化碳(CO2)和水(H2O)還原得到碳基燃料,是可持續並且環境友好的能源轉化與儲存方式, 因而具有重要的研究意義。近幾年基於電、光催化CO2轉化製備碳基燃料及低維固體材料製備等方向開展了系列研究,目前總共在Nat. Energy、Natl. Sci. Rev.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Adv. Mater.等國際著名期刊上發表學術論文20餘篇,被引3500餘次(H-index 13),申請發明專利10項(授權8項),主持國家自然科學基金青年項目、中國博士後科學基金面上項目等7項科研項目。擔任J. Renew. Mater.專刊的客座編輯(2021~至今),擔任Sci. Adv.、Nat. Commun.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chem. Eng. J.、ACS Catal.、Small等知名期刊的審稿人。入選2019年博士後創新人才支持計畫,曾獲中國科學院院長優秀獎和蘇州育才獎等獎勵。
所獲榮譽
2019年博士後創新人才支持計畫
2019 中國科學院院長優秀獎
2018 蘇州育才獎學金
2016 第二屆能源化學與材料國際研討會:最佳海報獎
2014 新鴻基郭氏勵學金
2012 天津大學大學生創新年會優秀項目獎
社會任職
擔任J. Renew. Mater. (IF 2.1)專刊的客座編輯(2021~至今);
擔任Sci. Adv.、Nat. Commun.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chem. Eng. J.、ACS Catal.、Small等知名期刊的審稿人。
主持科研項目
5. 國家自然科學基金委青年科學基金項目(22105133):超薄金屬性鈷基材料的構築及其紅外光催化二氧化碳還原性能研究(2022.01-2024.12, 30萬)
4. 四川大學專職博士後研發基金項目(20826041E4211,2021SCU12150):超薄鉍基材料的構築及其工業級電流密度下的電催化CO2還原製備液體燃料性能研究(2021.01-2022.12, 12.8萬)
3. 博士後創新人才支持計畫(BX20190222):超薄MXenes材料的電子結構調控及其電催化CO2還原性能的研究(2019.07-2021.06, 60萬)
2. 中國博士後科學基金面上項目(2019M663490):Cu/MXenes電催化CO2還原材料的設計和製備(2019.12-2021.12, 8萬)
1. 四川大學博士後交叉學科創新啟動基金項目:煙氣CO2高效沸石捕集及其電催化製備液體燃料研究(2019.12-2021.12, 10萬,共同負責人:王邦達,四川大學建築與環境學院)
代表性成果
22. Siheng Yang, Woo Jin Byun, Fangming Zhao, Dingwen Chen, Jiawei Mao, Wei Zhang, Jing Peng, Chengyuan Liu, Yang Pan, Jun Hu, Junfa Zhu, Xueli Zheng, Haiyan Fu, Maolin Yuan, Hua Chen, Ruixiang Li, Meng Zhou,* Wei Che,* Jong-Beom Baek, Jae Sung Lee,* and Jiaqi Xu*.CO2 Enrichment Boosts Highly Selective Infrared-Light-Driven CO2 Conversion to CH4 by UiO-66/Co9S8 Photocatalyst, Adv. Mater. 2024, 2312616.
21. Jiaqi Xu, Siheng Yang,Li Ji, Jiawei Mao,Wei Zhang, Xueli Zheng, Haiyan Fu, Maolin Yuan, Hua Chen, Ruixiang Li*. High current CO2 reduction realized by edge/defect-richbismuth nanosheets, Nano Res. 2023, 16, 53-61.
20. Xufeng Nie, Mei Wang, Yihua Fu, Jiaqi Xu, Xueli Zheng, Hua Chen, Zhishan Su,* Haiyan Fu,* Ruixiang Li*. A new facet of amide synthesis by tandem acceptorless dehydrogenation of amines and oxygen transfer of DMSO, J. Catal. 2023, 417, 153-163.
19. Huihua Gong, Tianhua Cui, Xufeng Nie, YanlingZheng,Xueli Zheng, Haiyan Fu, Maolin Yuan, Hua Chen, Jiaqi Xu,*Ruixiang Li*. Nitrogen-Nitrogen-Functionalized N-Heterocyclic Carbene Ruthenium(II) Complexes Realized Efficient CO2 Hydrogenation to Formate, Catal. Sci. Technol. 2022,12,6213-6218.
18. Jiaqi Xu,Xingchen Jiao, Kai Zheng, Weiwei Shao, Shan Zhu,Xiaodong Li, Junfa Zhu, Yang Pan, Yongfu Sun,* Yi Xie, Plastics-to-SyngasPhotocatalysed by Co-Ga2O3 Nanosheets, Natl. Sci. Rev. 2022, 9, nwac011.
17. Yanling Zheng, Yang Long, Huihua Gong, Jiaqi Xu,Chunchun Zhang, Haiyan Fu,* Xueli Zheng, Hua Chen, Ruixiang Li*. Ruthenium-Catalyzed Divergent AcceptorlessDehydrogenative Coupling of 1,3-Diols with Arylhydrazines: Synthesis ofPyrazoles and 2‑Pyrazolines. Org.Lett. 2022, 24, 3878-3883.
16. Jiaqi Xu,*Zhengyu Ju, Wei Zhang, Yang Pan, Junfa Zhu, Jiawei Mao, Xueli Zheng, Haiyan Fu,Maolin Yuan, Hua Chen, Ruixiang Li*. Efficient Infrared‐Light‐Driven CO2 ReductionOver Ultrathin Metallic Ni‐doped CoS2 Nanosheets,Angew. Chem. Int. Ed. 2021, 61, 8705‒8709. (Hot Paper)
15. Li Ji, Tianhua Cui,Xufeng Nie, Yanling Zheng, Xueli Zheng, Haiyan Fu, Maolin Yuan, Hua Chen, Jiaqi Xu,* Ruixiang Li*. Catalytic Hydrogenation of CO2 byUnsymmetric N-Heterocyclic Carbene-Nitrogen-Phosphine Ruthenium Complexes,Catal. Sci. Technol. 2021, 11, 6965-6969.
14. JiaqiXu,Xiaodong Li, Zhengyu Ju, Yongfu Sun,* Xingchen Jiao, Ju Wu,Chengming Wang, Wensheng Yan, Huanxin Ju, Junfa Zhu, and Yi Xie*. Visible-Light-Driven Overall Water Splitting Boosted byTetrahedrally-coordinated Blende CoO Atomic Layers. Angew. Chem. Int. Ed.2019, 58, 3032-3036.
13. Jiaqi Xu, Xiaodong Li, Wei Liu, Yongfu Sun,* Zhengyu Ju,Tao Yao, Chengming Wang, Huanxin Ju, Junfa Zhu, Shiqiang Wei,* and Yi Xie*.Carbon Dioxide Electroreduction into Syngas Boosted by a Partially DelocalizedCharge in Molybdenum Sulfide Selenide Alloy Monolayers. Angew. Chem. Int. Ed.2017, 56, 9121‒9125. (Hot Paper)
12. Ling Zhao, Xiaochun He, Tianhua Cui, Xufeng Nie,Jiaqi Xu, Xueli Zheng, Weidong Jiang, Maolin Yuan, Hua Chen, Haiyan Fu,*and Ruixiang Li*. Acceptorless Dehydrogenative Cross-Coupling of PrimaryAlcohols Catalyzed by an N‑Heterocyclic Carbene−Nitrogen−Phosphine ChelatedRuthenium(II) Complex. J. Org. Chem. 2022,87, 4550-4559.
11. Shaokun Tao, Shanyong Chen, Meilin Feng, JiaqiXu, Maolin Yuan, Haiyan Fu, Ruixiang Li, Hua Chen, Xueli Zheng,* Xiaoqi Yu,Electrochemical Cross-Dehydrogenative Aromatization Protocol for the Synthesisof Aromatic Amines. Org. Lett.2022, 24, 1011-1016.
10. Wenjing Li, Shun Li, Lihua Luo, Yicen Ge, JiaqiXu, Xueli Zheng, Maolin Yuan, Ruixiang Li, Hua Chen and Haiyan Fu*.Visible-Light-Initiated Catalyst-Free Oxidative Cleavage of(Z)-Triaryl-Substituted Alkenes Containing Pyridyl Motif under AmbientConditions. Green Chem. 2021, 23, 3649-3655.
9. Xingchen Jiao, Kai Zheng, QingxiaChen, Xiaodong Li, Yamin Li, Weiwei Shao, JiaqiXu, Junfa Zhu, Yang Pan, Yongfu Sun,* Yi Xie*. Photocatalyzing WastePlastics into C2 Fuels under Simulated NaturalEnvironments.Angew. Chem. Int. Ed. 2020, 59,15497-15501.
8. Xiaodong Li, Yongfu Sun,* Jiaqi Xu, Yanjie Shao, Ju Wu, XiaoliangXu, Yang Pan, Huanxin Ju, Junfa Zhu, and Yi Xie*. SelectiveVisible-Light-Driven Photocatalytic CO2 Reduction to CH4Mediated by Atomically-thin CuIn5S8 Layers. Nat.Energy 2019, 4, 690-699.
7. Xiaodong Li, LiangLiang, Yongfu Sun,* Jiaqi Xu,Xingchen Jiao, Xiaoliang Xu, Huanxin Ju, Yang Pan, Junfa Zhu, Yi Xie*.Ultrathin Conductor Enabling Efficient IR Light CO2 Reduction. J. Am. Chem. Soc. 2019, 141, 423-430.
6. Xiaolong Zu, XiaodongLi, Wei Liu, Yongfu Sun,* JiaqiXu, Tao Yao, Wensheng Yan, Shan Gao, Chengming Wang, Shiqiang Wei, and YiXie*. Efficient and Robust Carbon Dioxide Electroreduction Enabled byAtomically Dispersed Sn Sites. Adv. Mater. 2019, 31, 1808135.
5. Ju Wu,Xiaodong Li, Wen Shi, Peiquan Ling, Yongfu Sun,*Xingchen Jiao, Shan Gao, Liang Liang, JiaqiXu, Wensheng Yan, Chengming Wang, and Yi Xie*. EfficientVisible-Light-Driven CO2 Reduction Mediated by Defect-EngineeredBiOBr Atomic Layers. Angew. Chem. Int. Ed. 2018, 57, 8719-8723.
4. Katong Liu, Xiaodong Li, Liang Liang, Ju Wu, XingchenJiao, Jiaqi Xu, Yongfu Sun,* and YiXie*. Ni-doped ZnCo2O4 Atomic Layersto Boost the Selectivity in Solar-Driven Reduction of CO2. NanoRes. 2018, 11, 2897-2908.
3. Xingchen Jiao, XiaodongLi, Xiuyu Jin, Yongfu Sun,* Jiaqi Xu, Liang Liang, Huanxin Ju,Junfa Zhu,Yang Pan, Wensheng Yan, Yue Lin, and Yi Xie*. Partially Oxidized SnS2Atomic Layers Achieving Efficient Visible-Light-Driven CO2Reduction. J. Am. Chem. Soc. 2017,139, 18044-18051.
2. Fengcai Lei, Wei Liu, YongfuSun,* Jiaqi Xu, Katong Liu, LiangLiang, Tao Yao,* Bicai Pan, Shiqiang Wei, Yi Xie*. Metallic Tin Quantum SheetsConfined in Graphene toward High-efficiency CO2 Electroreduction. Nat.Commun. 2016, 7:12697.
1. Fengcai Lei, Lei Zhang,Yongfu Sun,* Liang Liang, Katong Liu, JiaqiXu, Qun Zhang,* Bicai Pan, Yi Luo, and Yi Xie*. Atomic-Layer-ConfinedDoping for Atomic-Level Insights into Visible-Light Water Splitting. Angew.Chem. Int. Ed. 2015, 54, 9266-9270.
專利
11. 付海燕,陳華,李順,李瑞祥,鄭學麗,徐嘉麒,袁茂林;吡啶環的氮的間位引入硫苯基的方法和含硫苯基的吡啶類化合物;申請號CN 2023111331100;申請日:2023年09月04日
10. 李瑞祥,浩濤濤,袁茂林,陳華,徐嘉麒,鄭學麗,付海燕;一種回收三氯化銠的方法;申請號CN 202311017568.X;申請日:2023年08月14日
9. 徐嘉麒,楊思恆,毛佳偉,李瑞祥,陳華,袁茂林,付海燕,鄭學麗;二氧化碳還原催化劑、製備方法、套用;申請號 CN 202310386828.4;申請日:2023年04月12日
8. 徐嘉麒,李瑞祥,陳華,付海燕,鄭學麗;具有豐富活性位點的金屬鉍納米片及其製備方法和套用;專利號ZL 202210307152.0;授權公告日2023年08月11日; 授權公告號:CN 114540882 B
7. 毛佳偉,朱敏,張占元,劉志偉,朱海,李銘,徐嘉麒,張喜翠,韓渝,竇維;一種懸臂大環雙核鎳金屬配合物、其製法和套用;專利號ZL 202310483772.4;授權公告日2023年08月01日;授權公告號:CN 116178353 B
6. 熊蘭,毛佳偉,徐嘉麒,陳麗先,楊旭東,劉榮,陳思,嚴峻,郝星傑;一種四核銅配合物及其製備方法和套用;專利號:ZL 202111248730.X;授權公告日2022年05月06日;授權公告號:CN 113801100 B
5. 毛佳偉,朱敏,吳宇,徐嘉麒,田華,丁勁松,李銘,王美娜,朱海;一種雙核鎘配合物及其製備方法和套用;專利號:ZL 202111249975.4;授權公告日:2022年03月08日;授權公告號:CN 113845535 B
4. 孫永福,徐嘉麒,謝毅;一種氧化亞鈷薄片、其製備方法和其在可見光催化全分解水中的套用;專利號:ZL 201810338954 .1; 授權公告日:2022年04月19日;授權公告號:CN 110386626 B
3. 徐嘉麒,李瑞祥,陳華;一種元素摻雜的過渡金屬硫化物超薄片及其製備和套用;專利號:ZL 202011518682.7; 授權公告日:2022年01月25日;授權公告號:CN 112756002 B
2. 孫永福, 徐嘉麒,謝毅;氧化鎵超薄片,其製備方法以及用途;申請號CN 201910388370.X;申請日2019年05月10日
1. 孫永福,徐嘉麒,謝毅;一種過渡金屬硫族化合物及其製備方法和套用;專利號:ZL 201710149449.8;授權公告日2020年03月31日;授權公告號:CN 108569678 B