張永明(上海交通大學化學化工學院特聘教授)

張永明，祖籍河南安陽，1960年4月生。上海交通大學博士後，上海交通大學化學化工學院特聘教授，山東東嶽集團首席科學家，十二屆、十三屆全國人大代表，全國勞動模範，獲2011年國家技術發明獎，獲2012年度何梁何利科學與技術進步獎。長期從事含氟功能高分子材料及其功能膜材料研究，

基本介紹

• 中文名：張永明
• 畢業院校：上海交通大學
• 學位/學歷：博士
• 專業方向：聚合物分子設計及合成、聚合物結構、形態和性能研究

人物經歷

教育經歷

1978-1982：河南師範大學，學士
1984-1986：南京大學化學系，碩士
1995-1999：華東理工大學材料學院，博士

工作經歷

1977-1978：河南省榿縣各崗國小
1982-1998：河南省安陽師範學院
1999-2001：上海交通大學化學化工學院，博士後
2001-2002：上海有機氟材料研究所
2002-2006：上海交通大學化學化工學院，副教授
2006-至今：上海交通大學化學化工學院，研究員

上海交通大學化學化工學院特聘教授，山東東嶽集團首席科學家，山東省泰山學者，十二屆、十三屆全國人大代表，全國勞動模範，上海市領軍人才。

研究方向

1、全氟離聚物及全氟離子交換膜。

2、全氟離子交換膜性能評價及其在燃料電池、釩液流電池、工業催化、水處理等領域的套用。

3、燃料電池催化劑及其載體。

4、含氟功能高分子材料研究、特種化學品研究與套用技術。

5、光電功能材料研究。

發布論文

1 Yuan, W. Z.; Tan, Y.; Gong, Y.; Lu, P.; Lam, J. W. Y.; Shen, X. Y.; Feng, C.; Sung, H. H-Y.; Lu, Y.; Williams, I. D.; Sun, J. Z.; Zhang Y*.; Tang, B. Z*. “Synergy between Twisted Conformation and Effective Intermolecular Interactions: Strategy for Efficient Mechanochromic Luminogens with High Contrast” Adv. Mater. 2013, 25, 2837.

Gong, Y.; Tan, Y.; Liu, J.; Lu, P.; Feng, C.; Yuan, W. Z*.; Lu, Y.; Sun, J. Z.; He, G*.; Zhang, Y*. “Twisted D–pi–A Solid Emitters: Efficient Emission and High Contrast Mechanochromism” Chem. Commun. 2013, 49, 4009.

Wang, C.; Gao, H.; Li, H.; Zhang, Y.; Huang, B.; Zhao, J.; Zhu, Y.; Yuan, W. Z*.; Zhang, Y*. “Graphene Nanoribbons Hybridized Carbon Nanofibers: Remarkably Enhanced Graphitization and Conductivity, and Excellent Performance as Support Material for Fuel Cell Catalysts” Nanoscale 2014, in press.

Wang, C.; Li, H.; Zhao, J.; Zhu, Y.; Yuan, W. Z*.; Zhang, Y*. “Graphene Nanoribbons as A Novel Support Material for High Performance Fuel Cell Electrocatalysts” Int. J. Hydrogen Energy 2013, 38, 13230.

Zhu, Y.; Pei, S.; Tang, J.; Li, H.; Wang, L.; Yuan, W. Z*.; Zhang, Y*. “Enhanced Chemical Durability of Perfluorosulfonic Acid Membranes through Incorporation of Terephthalic Acid as Radical Scavenger” J. Membrane Sci. 2013, 432, 66.

Yang, L.; Li, H.; Ai, F.; Chen, X.; Tang, J.; Zhu, Y.; Wang, C.; Yuan, W. Z*.; Zhang, Y*. “A New Method to Prepare High Performance Perfluorinated Sulfonicacid Ionomer/Porous Expanded Polytetrafluoroethylene Composite Membranes Based on Perfluorinated Sulfonyl Fluoride Polymer Solution” J. Power Sources 2013, 243, 392.

Yang, L.; Tang, J.; Li, L.; Ai, F.; Chen, X.; Yuan, W. Z*.; Zhang, Y*. “Properties of Precursor Solution Cast PFSI Membranes with Various Ion Exchange Capacities and Annealing Temperatures” RSC Adv. 2013, 3, 7289.

Tang, J.; Yuan, W.; Zhang, Z.; Li, H*.; Zhang, Y*. “Evidence for A Crystallite-Rich Skin on Perfluorosulfonate Ionomer Membranes” RSC Adv. 2013, 3, 8947.

Gong, YY.; Tan, YQ.; Mei, J.; Zhang, YR.; Yuan, WZ*.; Zhang, YM*.; Sun, JZ.; Tang, B. Z*. “Room Temperature Phosphorescence from Natural Products: Crystallization Matters” Sci. China Chem. 2013, 56, 1178.

Gong, YY.; Tan, YQ.; Li, H.; Zhang, YR.; Yuan, WZ*.; Zhang, YM*.; Sun, JZ.; Tang, B. Z*. “Crystallization-Induced Phosphorescence of Benzils at Room T emperature” Sci. China Chem. 2013, 56, 1183.

. Lu, YW.; Tan, YQ.; Gong, YY.; Li, H.; Yuan, WZ*.; Zhang, YM*.; Tang, B. Z*. “High Efficiency D-A Structured Luminogen with Aggregation-Induced Emission and Mechanochromic Characteristics” Chinese Sci. Bull. 2013, 58, 2719.

2012

Tang, J.; Yuan, W.; Wang, J.; Tang, J.; Li, H*.; Zhang, Y*. “Perfluorosulfonate Ionomer Membranes with Improved Through-Plane Proton Conductivity Fabricated under Magnetic Field” J. Membrane Sci. 2012, 423–424, 267.

Qin, S.; Li, H*.; Yuan, W. Z.; Zhang, Y*. “Fluorine-Containing Block Copolymer Particles with Surface and Internal Hierarchical Microphase Separation Structures” Soft Matter 2012, 8, 2471.

Qin, S.; Yuan, W. Z.; Li, H*.; Zhang, Y*. “Order–Order Phase Transition and Transformation in Co-assembled Particles from Fluorinated FA/FB Type Diblock Copolymers” Soft Matter 2012,8, 8405.

. Li, L*.; Su, L.; Zhang, Y*. “Enhanced Performance of Supercritical CO2 Treated Nafion 212 Membranes for Direct Methanol Fuel Cells” Int. J. Hydrogen Energy 2012, 37, 4439.

Cai, Z.; Liu, Y.; Liu, S.; Li, L*.; Zhang, Y*. “High Performance of Lithium-Ion Polymer Battery Based on Non-aqueous Lithiated Perfluorinated Sulfonic Ion-Exchange Membranes” Energ. Environ. Sci. 2012, 5, 5690.

Zhu, H.; Tong, H. ; Gong, Y.; Shao, S.; Deng, C.; Yuan, W. Z*.; Zhang, Y*. “Fluorene- and Benzimidazole-Based Blue Light-Emitting Copolymers: Synthesis, Photophysical Properties, and PLED Applications” J. Polym. Sci. Polym. Chem. 2012, 50, 2172.

Yang, L.; Tang, J.; Li, L.; Chen, X.; Ai, F.; Yuan, W. Z*.; Wang, L.; Zhang, Y*. “High Quality Pristine Perfluorosulfonated Ionomer Membranes Prepared from Perfluorinated Sulfonyl Fluoride Solution” RSC Adv. 2012, 2, 5950.

2011

Qin, S.; Li, H.; Yuan, W.; Zhang, Y*. “Hierarchical Self-Assembly of Fluorine-Containing Diblock Copolymer: From Onion-like Nanospheres to Superstructured Microspheres” Polymer 2011, 52, 1191.

Xu, A.; Zhao, J.; Yuan, W. Z.; Li, H.; Zhang, H.; Wang, L.; Zhang, Y*. “Tetrafluoroethylene Copolymers with Sulfonyl Fluoride Pendants: Syntheses in Supercritical Carbon Dioxide, Polymerization Behaviors, and Properties” Macromol. Chem. Phys. 2011, 212, 1497.

Zhao, J.; Xu, A.; Yuan, W. Z.; Gao, J.; Tang, J.; Wang, L.; Ai, F.; Zhang, Y*. “Evaluation of electrospun nanofiber formation of perfluorosulfonic acid and poly (N-vinylpyrrolidone) through solution rheology” J. Mater. Sci. 2011, 46, 7501.

2010

Li, L*.; Shang, F.; Wang, L.; Pei, S.; Zhang, Y*. “Transport Properties of PFSA Membranes with Various Ion Exchange Capacities for Direct Methanol Fuel Cell Application” Energ. Environ. Sci. 2010, 3, 114.

Wen, X. W.; Pei, S. P.; Li, H.; Ai, F.; Chen, H.; Li, K. Y.; Wang, Q.; Zhang, Y. M*. “Study on An Antifouling and Blood Compatible Poly(Ethylene–Vinyl acetate) Material with Fluorinated Surface Structure” J. Mater. Sci. 2010, 45, 2788.

2009

Su, L.; Li, L.; Li, H.; Zhang, Y*.; Yu, W*.; Zhou, C. “Perfluorosulfonic Acid Membranes Treated by Supercritical Carbon Dioxide Method for Direct Methanol Fuel Cell Application” J. Membrane Sci. 2009, 335, 118.

Li, W.; Li, H.; Zhang, Y. M*. “Preparation and Investigation of PVDF/PMMA/TiO2 Composite Film” J. Mater. Sci.2009, 44, 2977.

. Su, L.; Li, L.; Li, H.; Tang, J.; Zhang, Y*.; Yu, W*.; Zhou, C. “Preparation of Polysiloxane Modified Perfluorosulfonic Acid Composite Membranes Assisted by Supercritical Carbon Dioxide for Direct Methanol Fuel Cell” J. Power Sources 2009, 194, 220.

Su, L.; Pei, S.; Li, L.; Li, H.; Zhang, Y*.; Yu, W*.; Zhou, C. “Preparation of Polysiloxane/Perfluorosulfonic Acid Nanocomposite Membranes in Supercritical Carbon Dioxide System for Direct Methanol Fuel Cell” Int. J. of Hydrogen Energy 2009, 34, 6892.

. Shang, F.; Li, L.; Zhang, Y*.; Li, H. “PWA/Silica/PFSA Composite Membrane for Direct Methanol Fuel Cells” J. Mater. Sci. 2009, 44, 4383.

Chen, H.; Li, H.; Pei, S.; Wen, X.; Zhang, Y*. “Synthesis and Characterization of Fluoropoly (Amide–Sulfonamide) s via Polycondensation” Polymer2009, 50, 4317.

Chen, H.; Huang, Z.; Li, H.; Zhang, Y*.; Liu, Y. “Synthesis of Pure (Co) Polymers via Supported Cobalt (II)-Catalyzed Controlled/“Living” Radical Polymerization” Polym. Bull. 2009, 62, 151.

Han, L.; Zhang, Y*.; Li, H.; Li, L. “The Synthesis and Surface Activity of Perfluoro-2,5-dimethyl-3,6-dioxanonanoic Acid Ester Fluorocarbon Surfactants’’ Colloid Surf. A2009, 334, 176.

2008

Luan, Y.; Zhang, Y*.; Zhang, H.; Li, L.; Li, H.; Liu, Y. “Annealing Effect of Perfluorosulfonated Ionomer Membranes on Proton Conductivity and Methanol Permeability” J. Appl. Polym. Sci. 2008, 107, 396.

Huang, Z. X.; Zhang, Y. M*.; Li, H.; Liu, Y. G. “Controlled/“Living” Radical Polymerization of Methyl Methacrylate Catalyzed by Cobalt Acetate” Macromol. Chem. Phys. 2008,209, 825.

Luan, Y.; Zhang, H.; Zhang, Y*.; Li, L.; Li, H.; Liu, Y. “Study on Structural Evolution of Perfluorosulfonic Ionomer from Concentrated DMF-based Solution to Membranes” J. Membrane Sci. 2008, 319, 91.

Huang, Z. X.; Zhang, Y. M*.; Li, H.; Luan, Y. H.; Liu, Y. G. “Atom Transfer Radical Polymerization of Methyl Methacrylate Catalyzed by Ion Exchange Resin Immobilized Co (II) Hybrid Catalyst” J. Polym. Sci. Polym. Chem. 2008, 46 , 1416.

2007

Huang, Z.; Zhang, Y*.; Li, H.; Liu, Y. “A Novel Immobilized Cobalt (II)/Copper (II) Bimetallic Catalyst for Atom Transfer Radical Polymerization (ATRP) of Methyl methacrylate” Appl. Cat. A-Gen. 2007, 332, 192.

2006

Li, H.; Zhang, Y. M*.; Zhang, H.; Xue, M. Z.; Liu, Y. G. “Novel, Well-Defined Polystyrene with A Fluorine Cluster End-Capped Group: Synthesis, Characterization, and Surface Properties” J. Polym. Sci.Polym. Chem. 2006, 44, 3853.

Huang, Z.; Zhang, Y*.; Zhao, C.; Qin, J.; Li, H.; Xue, M.; Liu, Y. “Direct Gas-Phase Epoxidation of Hexafluoropropylene with Molecular Oxygen using Ag Catalyst” Appl. Cat. A-Gen. 2006, 303, 18.

2005

Dou, H. Y.; Ni, H.-B.; Zhao, C.-X*.; Zhang, Y. M*. “EPR Studies on H-Abstraction from Methylbenzenes by “Magic Blue” Reagent” J. Fluorine Chem. 2005, 126, 1130.

Li, Z. H.; Zhang, Y. M*.; Xue, M. Z.; Zhou, L.; Liu, Y. G. “Atom Transfer Radical Polymerization of Methyl Methacrylate Catalyzed by Cobalt Catalyst System” J. Polym. Sci.Polym. Chem. 2005, 43, 5207.

Li, Z.; Li, H.; Zhang, Y*.; Xue, M.; Zhou, L.; Liu, Y. “A Hybrid Supported Nickel Catalyst for the Controlled Radical Polymerization of Methyl Methacrylate” Appl. Cat. A-Gen. 2005, 292, 61.

出版專著

“Aggregation-Induced Emission: Applications” Tang, B. Z.; Qin, A. Eds. Chapter 2, “Crystallization-Induced Phosphorescence for Purely Organic Phosphors at Room Temperature and Liquid Crystals with Aggregation-Induced Emission Characteristics” by Yuan, W. Z.; Zhang, Y.; Tang, B. Z. Wiley-Blackwell, 2013.

“PEM Fuel Cell Failure and Mode Analysis” Wang, H.; Li, H.; Yuan, X.-Z. Eds. Chapter 4, “Membrane Degradation” by Luan. Y.; Zhang, Y. Boca Raton: CRC Press, Taylor & Francis Group, 2011, December.

《含氟功能材料》，張永明，李虹，張恆，化學工業出版社，2008.

獲獎記錄

1、 2007年山東省“泰山學者”。

2、 2009年山東省技術發明一等獎（排名第一）。

3、 2010全國勞動模範。

4、 2010年享受國務院特殊津貼專家。

5、 2010年所著《含氟功能材料》獲中國石化工業優秀出版物獎（圖書獎）一等獎（排名第一）。

6、 2010年“全氟離子交換膜工程技術研究”入選“十一五”國家重大科技成就。

7、 2011年“全氟離子膜工程技術研究團隊”獲“十一五”國家科技計畫執行優秀團隊獎。

8、 2011年獲中國石化聯合會科技進步二等獎（排名第一）。

9、 2011年獲國家技術發明二等獎（排名第一）。

10、2012年獲“何梁何利科學與技術進步獎”。

11、2012年“何梁何利科學與技術成就獎”唯一提名。

12、2012年獲“上海市領軍人才”稱號。

13、2013年上海交通大學特聘教授、凱原十佳教師。