周雙六，博士，安徽師範大學化學與材料科學學院教授。
基本介紹
- 中文名：周雙六
- 畢業院校：安徽師範大學
- 學位/學歷：博士
- 職業：教師
- 任職院校：安徽師範大學化學與材料科學學院
- 職稱：教授
人物經歷,研究方向,主講課程,科研項目,學術論文,
人物經歷
學士（1991-1995）安徽工程大學
碩士（2000-2003）安徽師範大學
博士（2004-2007）安徽師範大學
1995年－2000年蕪湖永康食品廠助理工程師
2003年－現在安徽師範大學講師，副教授，教授（2012年）
2007年－2009年台灣中興大學化學系博士後研究員
2008年11月－現在安徽師範大學碩士生導師
2017年12月－現在安徽師範大學博士生導師
研究方向
1. 金屬有機化學
2. 不對稱催化合成
主講課程
1. 化工基礎
2. 套用有機合成
3. 化學文獻檢索與利用
4. 工程製圖
5. 應化專業實驗
科研項目
1. 含氮、氧原子側鏈吡咯基多齒配體稀土金屬配合物的合成及其反應性研究，國家自然科學基金(21672004)，2017-2020，項目主持人。
2. 新型手性稀土金屬胺基配合物的合成及其催化碳-磷鍵選擇性形成反應研究，國家自然科學基金(21372009)，2013-2017，項目主持人，已結題。
3. 手性稀土金屬配合物催化芳香基（或雜芳香基）鋁試劑對醛酮的不對稱加成反應研究，國家自然科學基金(21172003)，2012-2015，項目主持人，已結題。
4. 單磺醯基聯萘酚基鋅鎂鋁金屬配合物催化丙交酯開環聚合反應研究，安徽省自然科學基金(11040606M36)，2011-2013，項目主持人，已結題。
5. 外消旋稀土金屬有機配合物的控制性合成及其催化烯烴可控聚合研究，國家自然科學基金(20802001)，2009-2011，項目主持人，已結題。
6. 氮原子配位促進稀土金屬-氮鍵均裂反應研究，安徽省高校青年教師資助計畫（2004jq120），項目主持人，已結題。
學術論文
25. Wei Wang, Xiaojia Wang,Shuangliu Zhou,*Xiaolong Xu, Jun Du, Lijun Zhang, Xiaolong Mu, Yun Wei, Xiancui Zhu, and Shaowu Wang.*“Syntheses, Structures, and Catalytic Activities of the Anionic Heterobimetallic Rare-Earth Metal Complexes Supported by Pyrrolyl-Substituted 1,2-Diimino Ligands”,Inorg. Chem.2018,57, 10390-10400.
24. Hong Fang, Zhiyong Yang, Lijun Zhang, Wei Wang, Yimei Li, Xiaolong Xu, andShuangliu Zhou.*“Transmetal-Catalyzed Enantioselective Cross-Coupling Reaction of Racemic Secondary Benzylic Bromides with Organoaluminum Reagents”,Org. Lett.2016,18, 6022-6025.
23.Shuangliu Zhou*, Zhiyong Yang, Xu Chen, Yimei Li, Lijun Zhang, Hong Fang, Wei Wang, Xiancui Zhu, Shaowu Wang*, “Copper-Catalyzed Electrophilic Amination of Organoaluminum Nucleophiles withO-Benzoyl Hydroxylamines”,J. Org. Chem.2015,80, 6323-6228.
22. Lijun Zhang,* Bing Tu, Min Ge, Yimei Li, Liangyu Chen, Wei Wang, andShuangliu Zhou*, “Asymmetric Addition of Pyridyl Aluminum Reagents to Aldehydes Catalyzed by a Titanium(IV) Catalytic System of (R)‑H8‑BINOLate”,J. Org. Chem.2015,80, 8307-8313.
21. Hui Miao,Fenhua Wang,Shuangliu Zhou,*Guangchao Zhang, Yang Li,"Palladium-catalyzed Hiyama coupling reaction of arylsulfonyl hydrazides under oxygen",Org. Biomol. Chem.,2015,13, 4647-4651.
20. Liping Guo, Xiancui Zhu, Guangchao Zhang, Yun Wei, Lixin Ning,Shuangliu Zhou,* Zhijun Feng, Shaowu Wang,* Xiaolong Mu, Jun Chen, “Synthesis and Characterization of Organo-Rare-Earth Metal Monoalkyl Complexes Supported by Carbon σ-Bonded Indolyl Ligands: High Specific Isoprene 1,4-Cis Polymerization Catalysts”,Inorg. Chem.2015, 54, 5725-5731.
19.Yun Wei, Shaowu Wang,*Shuangliu Zhou,* Zhijun Feng, Liping Guo, Xiancui Zhu, Xiaolong Mu, Fangshi Yao, “Aluminum Alkyl Complexes Supported by BidentateN,NLigands: Synthesis, Structure, and Catalytic Activity for Guanylation of Amines”,Organometallics2015,34, 1882-1889.
18. Qingbing Yuan,Shuangliu Zhou,*Xiancui Zhu, Yun Wei, Shaowu Wang,* Xiaolong Mu, Fangshi Yao, Guangchao Zhang and Zheng Chen, Heterometallic rare-earth metal complexes with imino-functionalized 8-hydroxyquinolyl ligands: synthesis, characterization and catalytic activity towards hydrophosphinylation oftrans-β-nitroalkene,New J. Chem., 2015,39, 7626-7632
17. Xu Chen, Lingmin Zhou, Yimei Li, Tao Xie,Shuangliu Zhou*, “Synthesis of Heteroaryl Compounds through Cross-Coupling Reaction of Aryl Bromides or Benzyl Halides with Thienyl and Pyridyl Aluminum Reagents”,J. Org. Chem.2014,79, 230-239.
16. Liping Guo,Xiancui Zhu,Shuangliu Zhou,*Xiaolong Mu,Yun Wei,Shaowu Wang,*Zhijun Feng,Guangchao Zhang, Baojia Deng, "Rare-earth alkyl complexes supported by formamidinate ligands: synthesis, structure, and catalytic activity for isoprene polymerization",Dalton Trans.,2014,43, 6842-6847.
15.Shuangliu Zhou,* Zhangshuan Wu, Lingmin Zhou, Shaowu Wang,* Lijun Zhang, Xiancui Zhu, Yun Wei, Jinhua Zhai, and Jie Wu, Controlled Synthesis of Racemic Indenyl Rare-Earth Metal Complexes via the Cooperation between the Intramolecular Coordination of Donor Atoms and a Bridge,Inorg. Chem.2013,52, 6417−6426.
14. Qinghai Li,Shuangliu Zhou,* Shaowu Wang,* Xiancui Zhu, Lijun Zhang, Zhijun Feng, Liping Guo, Fenhua Wang and Yun Wei, Dehydrogenation of secondary amines: synthesis, and characterization of rare-earth metal complexes incorporating imino- or amido-functionalized pyrrolyl ligands,Dalton Trans.2013,42, 2861-2869.
13.Shuangliu Zhou, Zhangshuan Wu,Jiewei Rong, Shaowu Wang,* Gaosheng Yang, Xiancui Zhu, Lijun Zhang, Highly Efficient Hydrophosphonylation of Aldehydes and Unactivated Ketones Catalyzed by Methylene-Linked Pyrrolyl Rare Earth Metal Amido Complexes,Chem. Eur. J.2012,18, 2653-2659.
12.Shuangliu Zhou, Hengyu Wang,Jian Ping, Shaowu Wang,* Lijun Zhang,* Xiancui Zhu, Yun Wei, Fenhua Wang, Zhijun Feng, Xiaoxia Gu, Song Yang, and Hui Miao, Synthesis, Characterization of Organolanthanide Complexes with Calix[4]-pyrrolyl Ligand and Their Catalytic Activities towards Hydrophosphonylation of Aldehydes and Unactivated Ketones, Organometallics2012,31, 1696-1702.
11.Shuangliu Zhou,* Yongyao Jiang, Tao Xie, Zhanshuan Wu, Linmin Zhou, Wenjing Xu, Lijun Zhang, Shaowu Wang*, Synthesis, Structure of Zinc Complexes Containing Sulfonylated Binaphtholate Ligands and Their Catalytic Activities towards Ring-Opening Polymerization of Lactide ande-Caprolactone,Chin. J. Chem.2012,30, 2176-2182.
10.Shuangliu Zhou, Chengwei Yin, Hui Wang, Xiancui Zhu, Gaosheng Yang, Shaowu Wang*, Synthesis, characterization, and catalytic activities of rare-earth metal complexes with iminopyrrolyl ligands,Inorg. Chem. Commun.2011,14, 1194-1120.
9.Shuangliu Zhou, Shihong Wu, Hong Zhu, Shaowu Wang,* Xiancui Zhu, Lijun Zhang, Gaosheng Yang, Daohui Cui, Hengyu Wang,Synthesis, structure and catalytic activity of alkali metal-free bent-sandwiched lanthanide amido complexes with calix[4]-pyrrolyl ligands,Dalton Trans.2011,40, 9447-9453.
8.Shuangliu Zhou,Chi-Ren Chen, Han-Mou Gau*,Highly Enantioselective 3-Furylation of Ketones Using(3-Furyl)titaniumNucleophile,Org. Lett.2010,12, 48-51.
7. Chao Liu,Shuangliu Zhou,*Shaowu Wang,*Lijun Zhang,Gaosheng Yang,Rare earth metal bis(trimethylsilyl)amido complexes bearing pyrrolyl-methylamide ligand. Synthesis, structure, and catalytic activity towards guanylation of amines,Dalton Trans.2010,39, 8994-8999.
6.Shuangliu Zhou, Kuo-Hui Wu, Chien-An Chen, Han-Mou Gau,*Highly Enantioselective Arylation of Aldehydes and Ketones Using AlArEt2(THF) as Aryl Sources,J. Org. Chem.2009,74, 3500-3505.
5.Shuangliu Zhou,Da-Wei Chuang, Shih-Ju Chang, Han-Mou Gau,*Synthesis, Characterization, and Structures of Arylaluminum Reagents and Asymmetric Arylation of Aldehydes Catalyzed by a Titanium Complex ofN-Sulfonylated Amino Alcohol,Tetrahedron: Asymmetry2009,20, 1407-1412.
4.Shuangliu Zhou, Shaowu Wang,* Gaosheng Yang, Qinghai Li, Lijun Zhang, Zijian Yao, Zhangkai Zhou, and Haibin Song, Synthesis, Structure and Diverse Catalytic Activities of Ethylenebis(indenyl)lanthanide(III) Amides on the N-H, C-H Addition to Carbodiimides ande-Caprolactone Polymerization,Organometallics2007,26,3755-3761.
3.Shuangliu Zhou, Shaowu Wang,* Enhong Sheng, Lijun Zhang, Zeyan Yu, Xiaobing Xi, Guodong Chen, Wei Luo, and Yan Li, Synthesis, Characterization and Catalytic Activity of Some Neodymium(III) and Ytterbium(II) and Europium(II) Complexes With Pyrrolidinyl- and Piperidinyl-Functionalized Indenyl Ligands,Eur. J. Inorg. Chem.2007, 1519-1528.
2. Shaowu Wang,*Shuangliu Zhou,Enhong Sheng, Meihua Xie, Kehua Zhang, Lin Cheng, Yan Feng, Lili Mao, and Zixiang Huang, Homolysis of the Eu-N Bond. “Synthesis, Structural Characterization, and Catalytic Activity of Novel Europium(II) Complexes,Organometallics2003,22, 3546-3552.
1.Shuangliu Zhou, Shaowu Wang,* Gaosheng Yang, Xinyuan Liu, Enhong Sheng, Kehua Zhang, Lin Cheng, Zixiang Huang, Synthesis, structure, and catalytic activity of tetracoordinate lanthanide amides [(Me3Si)2N]3Ln(m-Cl)Li(THF)3(Ln = Nd, Sm, Eu),Polyhedron2003,22, 1019-1024.
會議論文及報告
1.周雙六，“有機鋁試劑在有機合成中的套用”，第十四屆江淮有機論壇。2016年11月，徐州，報告。
2. Hong Fang, Xiaolong Xu, Yangyang Jiang, Xiaojia Wang,Shuangliu Zhou*,“Organoaluminum Reagents’ Application on Asymmetric Cross-coupling Reaction”.第九屆全國金屬有機化學學術會議。2015年8月，蘭州，牆報。
3. 姜永要，周雙六*，周凌敏，吳章栓，王紹武*，“磺醯基取代聯萘酚鋅配合物的合成、結構及其催化性質”，第七屆全國有機化學學術討論會。2011年11月，南京，牆報。
4. 吳章栓，周雙六*，周凌敏，姜永要，王紹武*，“稀土胺基化合物催化a,b-不飽和羰基化合物的氫膦化反應”，第七屆全國有機化學學術討論會。2011年11月，南京，牆報。
5.Shuangliu Zhouand Han-Mou Gau*, “Application of the Aluminum Reagents in Enantioselective Arylation of Aldehydes”,第五屆海峽兩岸生物無機與材料研討會。2008年7月，台南，牆報。
