卓春祥

卓春祥，廈門大學化學化工學院教授、博士生導師、課題組長。

基本介紹

  • 中文名：卓春祥
  • 畢業院校：中國科學院上海有機化學研究所
  • 主要成就：2017 國家自然科學二等獎（第五完成人）
  • 任職單位：廈門大學化學化工學院
  • 職稱：教授
個人簡歷：
2019.04-至今 廈門大學化學化工學院，教授、博士生導師
2014.12-2019.03 德國馬普煤炭所，洪堡學者，博士後（導師：Prof. Alois Fürstner）
2014.07-2014.10 中國科學院上海有機化學研究所，研究助理（導師：游書力 研究員）
2009.09-2014.07 中國科學院上海有機化學研究所，博士（導師：游書力 研究員）
2005.09-2009.07 湖南大學化學系，學士
榮譽與獲獎情況：
2017 國家自然科學二等獎（第五完成人）
2016 上海市自然科學一等獎（第五完成人）
2015 中國科學院優秀博士論文
2015 德國洪堡獎學金
2014 中國科學院院長獎學金特別獎
2014 中國科學院優秀畢業生
2013 “Lecture Award” of the Roche and RSC International Chemistry Symposium
2013 “Student Travel Award” of the Roche and RSC International Chemistry Symposium
2013博士生國家獎學金
2013 M. Braun獎學金
2013 汪猷獎學金
2008 湖南大學大學生創新實驗一等獎
2008 本科生國家獎學金
研究興趣：
有機合成方法學;不對稱催化;活性天然產物及藥物分子的合成
近期主要代表論著：
  1. Zhuo, C.-X.; Fürstner, A.* Catalysis-based total syntheses of pateamine A and DMDA-Pat A. J. Am. Chem. Soc.2018, 140, 10514–10523. (Top 20 most downloaded articles in September, 2018)
  2. Zhuo, C.-X.; Fürstner, A.* Concise synthesis of a pateamine A analogue with in vivo anticancer activity based on an iron catalyzed pyrone ring-opening/cross coupling.Angew. Chem. Int. Ed.2016, 55, 6051-6056.
  3. Zhuo, C.-X.; Zhang, X.; You, S.-L.* Enantioselective synthesis of pyrrole fused piperazine and piperazinone derivatives via Ir-catalyzed asymmetric allylic amination.ACS Catal.2016, 6, 5307−5310. (Highlighted by Synfacts 2016, 12, 1043.)
  4. Zhuo, C.-X.; Zhou, Y.; Cheng, Q.; Huang, L.; You, S.-L.* Enantioselective construction of spiroindolines with three contiguous stereogenic centers and chiral tryptamine derivative via the reactive spiroindolenine intermediates.Angew. Chem. Int. Ed.2015, 54, 14146-14149. (Highlighted by Synfacts 2016, 12, 151.)
  5. Zhuo, C.-X.; Cheng, Q.; Liu, W.-B.; Zhao, Q.; You, S.-L.* Enantioselective synthesis of pyrrole based spiro- and polycyclic derivatives via Ir-catalyzed asymmetric allylic dearomatization and controllable migration reactions.Angew. Chem. Int. Ed.2015, 54, 8475-8479. (Highlighted by Synfacts 2015, 11, 944.)
  6. Zhuo, C.-X.; Zhou, Y.; You, S.-L.* Highly regio- and enantioselective synthesis of poly-substituted 2H-pyrroles via Pd-catalyzed intermolecular asymmetric allylic dearomatization of pyrroles.J. Am. Chem. Soc.2014, 136, 6590-6593. [Highlighted by J. Am. Chem. Soc. Spotlights (J. Am. Chem. Soc.2014, 136, 6511.)] [(Highlighted by the highlight module located on the homepage of JACS (May 5, 2014 – May 15, 2014.)(Highlighted bySynfacts2014, 10, 820. &Organic Chemistry Portal))]
  7. Zhuo, C.-X.; Zheng, C.; You, S.-L.* Transition-metal catalyzed asymmetric allylic dearomatization reactions.Acc. Chem. Res.2014, 47, 2558-2573.
  8. Zhuo, C.-X.; You, S.-L.* Palladium-catalyzed intermolecular allylic dearomatization reaction of -substituted-β-naphthol derivatives: scope and mechanistic investigation.Adv. Synth. Catal.2014, 356, 2020-2028.
  9. Zhuo, C.-X.; You, S.-L.* Palladium-catalyzed intermolecular asymmetric allylic dearomatization reaction of naphthol derivatives.Angew. Chem. Int. Ed.2013, 52, 10056-10059. (Highlighted bySynfacts2013, 9, 1308. &Chin. J. Org. Chem.2013, 33, 2440.)
  10. Zhuo, C.-X.; Wu, Q.-F; Zhao, Q.; Xu, Q.-L.; You, S.-L.* Enantioselective functionalization of indoles and pyrroles via an in-situ formed spiro-intermediate.J. Am. Chem. Soc.2013, 135, 8169-8172. (Highlighted bySynfacts2013, 9, 874.)
  11. Zhuo, C.-X.; Zhang, W.*; You, S.-L.* Catalytic asymmetric dearomatization reactions.Angew. Chem. Int. Ed.2012, 51, 12662-12686.
  12. Zhuo, C.-X.; Liu, W.-B.; Wu, Q.-F.; You, S.-L.* Asymmetric dearomatization of pyrroles via Ir-catalyzed allylic substitution reaction: enantioselective synthesis of spiro-2H-pyrroles.Chem. Sci.2012, 3, 205-208.
  13. Zheng, C.*;Zhuo, C.-X.; You, S.-L.* Mechanistic insights into the Pd-catalyzed intermolecular asymmetric allylic dearomatization of multisubstituted pyrroles: understanding the remarkable regio- and enantioselectivity.J. Am. Chem. Soc.2014, 136, 16251-16259.
  14. Ye, K.-Y.; Cheng, Q.;Zhuo, C.-X.; You, S.-L.* An iridium(I) N-heterocyclic carbene complex catalyzes asymmetric intramolecular allylic amination reactions.Angew. Chem. Int. Ed.2016, 55, 8113-8116.
  15. Wu, Q.-F; Zheng, C.*;Zhuo, C.-X.; You, S.-L.* Highly efficient synthesis and stereoselective migration reactions of chiral five-membered aza-spiroindolenines: scope and mechanistic understanding.Chem. Sci.2016, 7, 4453-4459.
  16. Zhou, Y.;Zhuo, C.-X.; Gu, Q.; You, S.-L.* Intermolecular dearomatization reaction of pyrroles promoted by silica gel.Adv. Synth. Catal.2015, 357, 912-916 (VIP).
  17. Wang, S.-G.; Yin, Q.;Zhuo, C.-X.; You, S.-L.* Asymmetric dearomatization of β-naphthols through an amination reaction catalyzed by a chiral phosphoric acid.Angew. Chem. Int. Ed.2015, 54, 647-650.
  18. Yang, Z.-P.;Zhuo, C.-X.; You, S.-L.* Ruthenium-catalyzed intramolecular allylic dearomatization/migration reaction of indoles and pyrroles.Adv. Synth. Catal.2014, 356, 1731-1734.
  19. Zhao, Q.;Zhuo, C.-X.; You, S.-L.* Enantioselective synthesis of N-allylindoles via palladium-catalyzed allylic amination/oxidation of indolines.RSC Adv.2014, 4, 10875-10878.
  20. Xu, Q.-L.;Zhuo, C.-X.; You, S.-L.* Highly enantioselective synthesis of tetrahydrocarbolines via iridium-catalyzed intramolecular Friedel-Crafts type allylic alkylation reactions.Org. Lett.2013, 15, 5909-5911.
  21. Liu, W.-B.; Zheng, C.;Zhuo, C.-X.; Dai, L.-X.; You, S.-L.* Ir-catalyzed allylic alkylation reaction with N-aryl phosphoramidite ligands: scope and mechanistic studies.J. Am. Chem. Soc.2012, 134, 4812-4821.
  22. Wu, Q.-F.; Liu, W.-B.;Zhuo, C.-X.; Rong, Z.-Q.; Ye, K.-Y.; You, S.-L.* Iridium-catalyzed intramolecular asymmetric allylic dearomatization of phenols.Angew. Chem. Int. Ed.2011, 50, 4455-4458.

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