基本介紹
- 中文名：包明
- 國籍：中國
- 職業：教師
經歷,教學,兼職,研究,指導,論文,
經歷
1982.9—1986.7 東北師範大學化學系 理學學士
1986.9—1989.7 東北師範大學化學系 理學碩士
1997.10—2001.3 獲日本政府(文部省)獎學金資助，赴日本東北大學攻讀博士學位
有機化學專業 理學博士
1989.7—1997.10 碩士畢業後留校工作，歷任助教、講師。
2001.4—2002.10 日本產業技術綜合研究所 特別研究員
2002.11—2004.12 日本學術振興會(JSPS) 特別研究員
教學
本科課程：有機化學, 有機化學實驗。
碩士研究生課程：有機合成化學, 有機合成化學實驗。
博士研究生課程：工業催化過程化學與研究。
兼職
大連理工大學“分子的高效活化轉化與新物質創造”科研創新團隊成員。
教育部“光轉化功能分子設計合成及套用”創新團隊成員。
撫順精細化工套用技術研究院科技專家。
中國化學會會員。
中國化學會催化學會均相催化專業委員會委員。
研究
研究領域（研究課題）
1. 金屬有機化學
2. 有機合成化學
3. 套用化學
指導
碩、博士生研究方向
有機合成方法學
(2)鎳催化劑在氯代芳烴的偶聯反應、羰基化合物的加成反應及芳香鹵代烴的脫鹵反應中的活用
(3)不對稱催化反應—將手性催化劑套用於本組發現的新有機反應
綠色化學
(2) 超臨界二氧化碳介質中有機合成反應的研究
(3) 環境友好型精細化學品的合成研究
論文
（2000年以來的論文，SCI檢索）
40. Zhang, S.; Wang, Y.; Feng, X.; Bao, M., Palladium-Catalyzed Amination of Chloromethylnaphthalene and Chloromethylanthracene Derivatives with Various Amines. Journal of the American Chemical Society 2012, 134 (12), 5492–5495.
39. Dai, Y.; Feng, X.; Wang, B.; He, R.; Bao, M., Preparation and application of air-stable P,N-bidentate ligands for the selective synthesis of δ-lactone via the palladium-catalyzed telomerization of 1,3-butadiene with carbon dioxide. Journal of Organometallic Chemistry 2012, 696, (26), 4309-4314.
38. Lu, S.; Jin, T.; Bao, M.; Yamamoto, Y., Cobalt-Catalyzed Hydroalkylation of [60]Fullerene with Active Alkyl Bromides: Selective Synthesis of Monoalkylated Fullerenes. Journal of the American Chemical Society 2011, 133, (32), 12842-12848.
37. Lu, S.; Jin, T.; Kwon, E.; Bao, M.; Yamamoto, Y., Highly Efficient Cu(OAc)2-Catalyzed Dimerization of Monofunctionalized Hydrofullerenes Leading to Single-Bonded [60]Fullerene Dimers. Angewandte Chemie International Edition 2011, 51, (3), 802-806.
36. Dai, Y.; Feng, X.; Liu, H.; Jiang, H.; Bao, M., Synthesis of 2-Naphthols via Carbonylative Stille Coupling Reaction of 2-Bromobenzyl Bromides with Tributylallylstannane Followed by the Heck Reaction. The Journal of Organic Chemistry 2011, 76, (24), 10068-10077.
35. Xu, Z.; Yu, X.; Feng, X.; Bao, M., Propargylamine Synthesis by Copper-Catalyzed Oxidative Coupling of Alkynes and Tertiary Amine N-Oxides. The Journal of Organic Chemistry 2011, 76, (16), 6901-6905.
34. Peng, B.; Zhang, S.; Yu, X.; Feng, X.; Bao, M., Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via η3-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization. Organic Letters 2011, 13, (19), 5402-5405.
33. Feng, X.; Zhao, Z.; Yang, F.; Jin, T.; Ma, Y.; Bao, M., 1,3-Diynes synthesis by homo-coupling of terminal alkynes using a Pd(PPh3)4/Ag2O simple catalyst system. Journal of Organometallic Chemistry 2011, 696, (7), 1479-1482.
32. Zhou, X.-Y.; Wang, D.-S.; Bao, M.; Zhou, Y.-G., Palladium-catalyzed asymmetric hydrogenation of simple ketones activated by Br?nsted acids. Tetrahedron Letters 2011, 52, (22), 2826-2829.
31. Zhou, X.-Y.; Bao, M.; Zhou, Y.-G., Palladium-Catalyzed Asymmetric Hydrogenation of Simple Ketimines Using a Br?nsted Acid as Activator. Advanced Synthesis & Catalysis 2011, 353, (1), 84-88.
30. Yang, F.; Jin, T.; Bao, M.; Yamamoto, Y., Facile synthesis of 3,4-dihalofurans via electrophilic iodocyclization. Chemical Communications 2011, 47, (15), 4541-4543.
29. Yang, F.; Jin, T.; Bao, M.; Yamamoto, Y., Facile synthesis of diiodinated dihydronaphthalenes and naphthalenes via iodine mediated electrophilic cyclization. Chemical Communications 2011, 47, (13), 4013-4015.
28. Feng, X. J.; Yan, M.; Zhang, X.; Bao, M., Preparation and application of SBA-15-supported palladium catalyst for Heck reaction in supercritical carbon dioxide. Chinese Chemical Letters 2011, 22, (6), 643-646.
27. Yang, F.; Jin, T.; Bao, M.; Yamamoto, Y., Facile synthesis of 3,4-diiododihydrothiophenes via electrophilic iodocyclization. Tetrahedron Letters 2011, 52, (8), 936-938.
26. Dai, Y.; Liu, H.; Feng, X.; Bao, M., Preparation and Application of New P, N-Ligands for Palladium-Catalyzed C-N Bond Coupling Reaction. Chinese Journal of Catalysis 2011, 32, (10), 1617-1623.
25. Yu, X.; Ma, Y.; Zhao, Z.; Xu, Z.; Bao, M., Cross-Coupling Reaction of Benzylic Halides with Allyltributylstannane Catalyzed by Cu(OTf)(2). Chinese Journal of Catalysis 2011, 32, (3), 472-476.
24. Peng, B.; Feng, X.; Zhang, X.; Ji, L.; Bao, M., Regioselective control using a catalyst switch in the reaction of diarylmethyl chlorides with allyltributylstannane. Tetrahedron 2010, 66, (32), 6013-6018.
23. Liu, Y.; Feng, X. J.; Bao, D. C.; Li, K. X.; Bao, M., Preparation of microcapsule-supported palladium catalyst using SPG (Shirasu Porous Glass) emulsification technique. Chinese Chemical Letters 2010, 21, (8), 979-982.
22. Du, X.; Feng, X. J.; Liu, Y.; He, R.; Bao, M., Suzuki reaction of bromoallenes with arylboronic acids using an air-stable palladium complex Pd(Ph2PCH2CO2)2 as a precatalyst. Chinese Chemical Letters 2010, 21, (6), 641-645.
21. Liu, Y.; Feng, X.; Bao, D.; Li, K.; Bao, M., A new method for the preparation of microcapsule-supported palladium catalyst for Suzuki coupling reaction. Journal of Molecular Catalysis A: Chemical 2010, 323, (1-2), 16-22.
20. Peng, B.; Feng, X.; Zhang, X.; Zhang, S.; Bao, M., Propargylic and Allenic Carbocycle Synthesis through Palladium-Catalyzed Dearomatization Reaction. The Journal of Organic Chemistry 2010, 75, (8), 2619-2627.
19. Lu, S.; Jin, T.; Bao, M.; Yamamoto, Y., Palladium-Catalyzed Three-Component [3 + 2] Cycloaddition of Propargyl Trifluoroacetates, Ethylidene Malononitriles, and Allyltributylstannane. Organic Letters 2010, 12, (4), 864-866.
18. Feng, X.; Yan, M.; Zhang, T.; Liu, Y.; Bao, M., Preparation and application of SBA-15-supported palladium catalyst for Suzuki reaction in supercritical carbon dioxide. Green Chemistry 2010, 12, (10), 1758-1766.
17. Zhou, L.; Du, X.; He, R.; Ci, Z.-H.; Bao, M. Nickel Salt-catalyzed Addition Reaction of Arylboronic Acids to Aromatic Aldehydes, Tetrahedron Lett. 2009, 50, 406–408.
16. Lu, S.-R.; Xu, Z.-W.; Bao, M.; Yamamoto, Y. Carbocycle Synthesis through Facile and Efficient Palladium-Catalyzed Allylative Dearomatization of Naphthyl- and Phenanthryl-Allyl Chlorides, Angew. Chem. Int. Ed. 2008, 47, 4366-4369.
15. Zhou, L.; Miao,Q.-Q.; He, R.; Feng, X.-J.; Bao, M. Ni-catalyzed Cross-Coupling Reaction of Aryl Chlorides with Arylboronic Acids in IPA without Using a Reducing Reagent, Tetrahedron Lett., 2007, 48, 7899-7902.
14. Du, X.; Dai, Y.; He, R.; Lu, S.-R.; Bao, M. A New Application of N- Halosuccinimide/PPh3 for the Halogenation of Propargyl Alcohols to Haloallenes, Synth. Commun. 2009, 39, (21), 3940-3949.
13. Zhou, L.; Feng, X.-J.; He, R.; Bao, M. X-ray Structure of trans-Chloro(1-naphthyl) bis(triphenylphosphane)nickel(II) and its Application for Catalytic Dehalogenation of Aryl Chlorides, J. Coord. Chem. 2009, 62, (17), 2824-2831.
12. 陸仕榮，彭勃，包明*，芳香族化合物的脫芳構化反應研究進展，化學進展, 2007, 19, 1529-1536.
11. 張濤，馮秀娟，王春霞，包明*，超臨界二氧化碳介質中鈀催化的一些交叉偶聯反應的研究，有機化學，2007, 27, 1463-1472.
10. Bao, M.; Hayashi, T.; Shimada, S. Cationic Organobismuth Complex with 5,6,7,12-Tetrahydrodibenz[c,f][1,5] azabismocine Framework and Its Coordination Complexes with Neutral Molecules, Organometallics, 2007, 26, 1816-1822.
9. Bao, M.; Shimizu, M.; Shimada, S; Inoue, J.; Konakahara, T. Reactions of N-Sulfenyl-1,2-benzisothiazolin-3-ones with Nucleophiles, Tetrahedron, 2004, 60, 11359-11366.
8. Bao, M.; Hayashi, T.; Shimada, S. Synthesis and Structural Characterization of a Cationic Trinuclear Organobismuth Complex with an Unprecedented Coordination Mode of Hydrotris(2-mercaptoimidazolyl)borate Ligands, Dalton Transactions, 2004, 2055-
2056.
7. Bao, M.; Hatanaka, Y.; Shimada, S. The First Synthesis and X-ray Structure of [1.1]Silaferrocenophane Containing Pentacoordinate Silicon Moieties, Chem. Lett., 2004, 33 (5), 520-521.
6. Bao, M.; Shimizu, M. N-Trifluoroacetyl Arenesulfenamides, Efficient Precursors for Synthesis of Unsymmetrical Disulfides and Sulfenamides, Tetrahedron, 2003, 59, 9655-9659.
5. Bao, M.; Shimizu, M.; Shimada, S.; Tanaka, M. Efficient Synthesis of N-Acylarenesulfenamides by Acylation of Arenesulfenamides, Tetrahedron, 2003, 59, 303-309.
4. Bao, M.; Nakamura, H.; Inoue, A.; Yamamoto, Y. Nucleophilic Allylation-Heterocyclization via Bis-π-allylpalladium Complexes: Synthesis of Five- and Six-Membered Heterocycles, Chem. Lett., 2002, 2, 158-159.
3. Nakamura, H.; Bao, M.; Yamamoto, Y. The Fate of Bis(η3-allyl)palladium Complexes in the Coexistence of Aldehydes (or Imines) and Allylic Chlorides. Stille Coupling versus Allylation of Aldehydes (or Imines), Angew. Chem. Int. Ed., 2001, 40, 3208-3210.
2. Bao, M.; Nakamura, H.; Yamamoto, Y. Facile Allylative Dearomatization Catalyzed by Palladium, J. Am. Chem. Soc., 2001, 123, 759-760.
- Bao, M.; Nakamura, H.; Yamamoto, Y. Preparation and Application of Polymer-Supported Chiral π-allylpalladium Catalyst for the Allylation of Imines, Tetrahedron Lett., 2000, 41, 131-134.
獎勵工作成果（獎勵、專利等）
鑑定成果：
吉林省科委項目“有機錫新農藥的合成和生物活性的研究”，登記號: 96128-1, 1996年10月, 第一完成人。
專利成果：
1. 獲日本專利成果6項。
2. 申請中國專利5項。
獎勵情況：
1. 楊帆畢業論文被評大連理工大學優秀碩士畢業論文；
2. 許占威、郝丹畢業設計被評大連理工大學優秀畢業設計；
3. 陸仕榮碩士畢業論文被評為遼寧省優秀碩士畢業論文。
4.大連理工大學化工與環境生命學部2010年度“優秀教師”稱號
5.大連理工大學化工與環境生命學部2009-2010年度“優秀共產黨員”稱號 - 在讀學生人數
- 碩士生10人，博士生8人
- 畢業學生人數
- 碩士生10人,博士生6人
