《Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials》是一本圖書，作者是Harrod, J. F.; Laine, R. M.; Harrod, John F.。
基本介紹
- 外文名：Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials
- 作者： Harrod, J. F.、Laine, R. M.、Harrod, John F.
- ISBN：9780792336778
內容簡介
In the ten years since the scientific rationale for the design, synthesis and application of inorganic and organometallic polymers (IOPs) was first conceptualised, we have witnessed the first tentative exploration of IOPs as precursors to new materials, with efforts focusing on the design and synthesis of novel ceramic precursors. Developing expertise led to precursor studies combined with the characterisation of the transformation processes that occur when IOPs are converted to ceramic materials. Now at maturity, the science presented in this volume reveals the polymer precursor approach to materials synthesis together with examples of processing ceramic shapes for a range of mechanical properties, the development of sophisticated, noninvasive analytical techniques, and IOP design rationales relying on well-defined processing-property relationships. The production of multifunctional IOPs is described, providing ion conductivity, gas sensing, bioactivity, magnetic properties, etc., combined with processability. The existence of well-defined IOPs and the exquisite control that can be exerted on sol-gel systems now provide access to such a variety of mixed organic-organometallic and/or inorganic hybrid systems that their exploitation is likely to develop into an entirely new field of materials chemistry. Future exciting avenues of research are also being opened up with the advent of buckyballs, Met-Cars, dopable preceramics, rigid-rod organometallics, and molecular tinkertoys.
簡譯：自無機和有機金屬聚合物（IOP）的設計、合成和套用的科學原理首次被概念化以來的十年里，我們見證了首次將IOP作為新材料的前體進行初步探索，重點是新型陶瓷前體的設計和合成。發展專業知識導致了前驅體研究，並結合了IOP轉化為陶瓷材料時發生的轉化過程的特徵。現在已經成熟，本卷中介紹的科學揭示了材料合成的聚合物前體方法，以及加工陶瓷形狀以獲得一系列機械性能的例子，複雜的非侵入性分析技術的發展，以及依賴於明確的加工性能關係的IOP設計理據。介紹了多功能IOP的生產，提供離子導電性、氣體感測、生物活性、磁性能等，並結合可加工性。定義明確的IOP的存在和可以施加在溶膠-凝膠系統上的精細控制現在提供了對各種混合的有機-有機-金屬和/或無機雜化系統的訪問，它們的開發可能會發展成為材料化學的一個全新領域。隨著buckyballs、Met Cars、多巴前程學、剛性棒有機金屬學和分子修補玩具的出現，未來令人興奮的研究途徑也在開闢。
