龔軍芳

龔軍芳，女，博士、鄭州大學化學與分子工程學院教授，河南省教育廳學術技術帶頭人。主持完成教育部留學回國人員科研啟動費、河南省自然科學基金、國家自然科學基金等項目；目前主持河南省高校科技創新人才基金等項目。先後在Adv. Synth. Catal.; J. Org. Chem.; Organometallics; Dalton Trans.; Tetrahedron Lett.; J. Mol. Catal. A: Chem.等國內外期刊上發表學術論文60多篇，參與翻譯、編寫著作3部。

基本介紹

  • 中文名：龔軍芳
  • 職業：教師
  • 畢業院校：南開大學
  • 學位/學歷：博士
  • 專業方向：金屬有機化學
人物經歷,科研項目,代表論文,學術成果,獲獎記錄,

人物經歷

1992年獲得南開大學理學學士學位，
1995年獲得南開大學理學碩士學位，
1998年中國科學院化學研究所畢業，獲得博士學位。
1999/10–2001/09鄭州大學化學系博士後
2001/10–2003/02法國巴黎國家高等化學學校(ENSCP)博士後
2003年–至今鄭州大學化學與分子工程學院(原化學系)工作

科研項目

1.2010.1－2012.12“混合給體鉗形鎳化合物的合成、結構及其在催化反應中的套用”編號20972141國家自然科學基金資助項目
2.2012.1－2014.12“手性鉗形鈀化合物催化劑的合成與套用研究”編號2012HASTIT003河南省高校科技創新人才支持計畫資助項目
3.2009.1－2012.12“非對稱三齒配位鈀化合物的催化性能研究”編號102101210200河南省科技攻關重大項目
4.2010.1－2012.12“含氮雜環卡賓的鈀和鎳化合物的合成與催化性能研究”編號2010GGJS-015河南省高等學校青年骨幹教師資助計畫
5.2006.01-2007.12“新型氮磷配體的合成及其在催化反應中的套用研究”編號0611012100河南省自然科學基金
6.2004.01-2005.12“多取代四氫吡喃的立體選擇性合成、新型二茂鐵衍生物的合成及其套用”教育部留學回國人員科研啟動基金

代表論文

  1. Xin-QiHao,Yong-WeiZhao,Jing-JingYang,Jun-LongNiu,Jun-FangGong*,Mao-PingSong*.“EnantioselectiveHydrophosphinationofEnoneswithDiphenylphosphineCatalyzedbyBis(imidazoline)NCNPincerPalladium(II)Complexes.”Organometallics2014,33(7),1801-1811.
  2. ZhaoWang,ZhemingSun,Xin-QiHao,Jun-LongNiu,DonghuiWei,TaoTu,Jun-FangGong*,Mao-PingSong*.“NeutralandCationicNCNPincerPlatinum(II)Complexeswith1,3-Bis(benzimidazol-2'-yl)benzeneLigands:Synthesis,Structures,andTheirPhotophysicalProperties.”Organometallics2014,33(7),1563-1573.
  3. TaoWang,Xin-QiHao,Juan-JuanHuang,KaiWang,Jun-FangGong*,Mao-PingSong*.“ChiralCNNPincerPalladium(II)Complexeswith2-Aryl-6-(Oxazolinyl)pyridineLigands:Synthesis,Characterization,andApplicationtoEnantioselectiveAllylationofIsatinsandSuzuki-MiyauraCouplingReaction.”Organometallics2014,33(1),194-205.
  4. TaoWang,Xin-QiHao,Juan-JuanHuang,Jun-LongNiu,Jun-FangGong*,Mao-PingSong*.“ChiralBis(imidazolinyl)phenylNCNPincerRhodium(III)CatalystsforEnantioselectiveAllylationofAldehydesandCarbonyl-EneReactionofTrifluoropyruvates.”J.Org.Chem.2013,78(17),8712-8721.
  5. TaoWang,Jun-LongNiu,Shuang-LiangLiu,Juan-JuanHuang,Jun-FangGong*,Mao-PingSong*.“ChiralNCNPincerRhodium(III)ComplexeswithBis(imidazolinyl)phenylLigands:SynthesisandEnantioselectiveCatalyticAlkynylationofTrifluoropyruvateswithTerminalAlkynes.”Adv.Synth.Catal.2013,355(5),927-937.(HighlightedbySynfacts2013,9(6),0636)
  6. 研究專題：郝新奇,牛俊龍,趙雪梅,龔軍芳*,宋毛平*.“第VIII族鉗形金屬催化劑的研究進展.”有機化學2013,33(4),663-674.
  7. Xin-QiHao,Yan-XiaoXu,Ming-JunYang,LiWang,Jun-LongNiu,Jun-FangGong*,Mao-PingSong*.“ACationicNCNPincerPlatinum(II)AquoComplexwithaBis(imidazolinyl)phenylLigand:StudiestowarditsSynthesisandAsymmetricFriedel−CraftsAlkylationofIndoleswithNitroalkenes.”Organometallics2012,31(3),835-846.
  8. Ming-JunYang,Yan-JingLiu,Jun-FangGong*,Mao-PingSong*.“UnsymmetricalChiralPCNPincerPalladium(II)andNickel(II)ComplexeswithAryl-BasedAminophosphine-ImidazolineLigands:SynthesisviaArylC-HActivation,andAsymmetricAdditionofDiarylphosphinestoEnones.”Organometallics2011,30(14),3793-3803.
  9. InvitedPerspective:Jun-LongNiu,Xin-QiHao,Jun-FangGong*,Mao-PingSong*.“Symmetricalandunsymmetricalpincercomplexeswithgroup10metals:SynthesisviaarylC–Hactivationandsomecatalyticapplications.”DaltonTrans.2011,40(19),5135-5150.
  10. TaoWang,Xin-QiHao,Xiao-XueZhang,Jun-FangGong*,Mao-PingSong*.“Synthesis,structureandcatalyticpropertiesofCNNpincerpalladium(II)andruthenium(II)complexeswithN-substituted-2-aminomethyl-6-phenylpyridines.”DaltonTrans.2011,40(35),8964-8976.(封面文章)
  11. Dan-DanShao,Jun-LongNiu,Xin-QiHao,Jun-FangGong*,Mao-PingSong*.“NeutralandcationicchiralNCNpincernickel(II)complexeswith1,3-bis(2'-imidazolinyl)benzenes:synthesisandcharacterization.”DaltonTrans.2011,40(35),9012-9019.
  12. Ben-ShangZhang,WeiWang,Dan-DanShao,Xin-QiHao,Jun-FangGong*,Mao-PingSong*.“UnsymmetricalChiralPCNPincerPalladium(II)andNickel(II)Complexesof(Imidazolinyl)arylPhosphiniteLigands:SynthesisviaLigandC-HActivation,CrystalStructuresandCatalyticStudies.”Organometallics2010,29(11),2579-2587.
  13. Jun-LongNiu,Qing-TaoChen,Xin-QiHao,Qing-XiangZhao,Jun-FangGong*,Mao-PingSong*.“Diphenylprolinol-derivedSymmetricalandUnsymmetricalChiralPincerPalladium(II)andNickel(II)Complexes:SynthesisviaOne-PotPhosphorylation/metalationReactionandC-HActivation.”Organometallics2010,29(9),2148-2156.
  14. Li-YuanWu,Xin-QiHao,Yan-XiaoXu,Min-QiangJia,Ya-NanWang,Jun-FangGong*,Mao-PingSong*.“ChiralNCNPincerPt(II)andPd(II)Complexeswith1,3-Bis(2'-imidazolinyl)benzene:SynthesisviaDirectMetalation,Characterization,andCatalyticActivityintheFriedel-CraftsAlkylationReaction.”Organometallics2009,28(12),3369-3380.
  15. Jun-FangGong,Yan-HuiZhang,Mao-PingSong*,ChenXu.“NewPCNandPCPPincerPalladium(II)Complexes:ConvenientSynthesisviaFacileOne-potPhosphorylation/PalladationReactionandStructuralCharacterization.”Organometallics2007,26(25),6487-6492.
  16. An-TingHou,Yan-JingLiu,Xin-QiHao,Jun-FangGong*,Mao-PingSong*.“SynthesisandCharacterizationofnew(pyrazolyl)arylphosphinitePCNpincerpalladium(II)complexes.”J.Organomet.Chem.2011,696(15-16),2857-2862.
  17. Xin-QiHao,Ya-NanWang,Jun-RuiLiu,Kun-LunWang,Jun-FangGong,*Mao-PingSong*.“Unsymmetrical,oxazolinyl-containingachiralandchiralNCNpincerligandprecursorsandtheircomplexeswithpalladium(II).”J.Organomet.Chem.2010,695(1),82-89.
  18. Ben-ShangZhang,ChaoWang,Jun-FangGong*,Mao-PingSong*.“FacilesynthesisofachiralandchiralPCNpincerpalladium(II)complexesandtheirapplicationintheSuzukiandcopper-freeSonogashiracross-couplingreactions.”J.Organomet.Chem.2009,694(16),2555-2561.
  19. Xin-QiHao,Jun-FangGong*,Chen-XiaDu,Li-YuanWu,Yang-JieWu,Mao-PingSong*.“Synthesis,characterizationandphotoluminescentpropertiesofplatinumcomplexeswithnovelbis(imidazoline)pincerligands.”TetrahedronLett.2006,47(29),5033-5036.
  20. ChenXu,Jun-FangGong*,Su-FangYue,YuZhu,Yang-JieWu*.“Tricyclohexylphosphine-cyclopalladatedferrocenyliminecomplexes:synthesis,crystalstructuresandapplicationinSuzukiandHeckreactions.”DaltonTrans.2006,(39),4730-4739.
  21. ChenXu,Jun-FangGong*,TaoGuo,Yan-HuiZhang,Yang-JieWu*.“Cyclopalladatedferrocenyliminecomplexeswithdicyclohexylphosphinobiphenylligands:Synthesis,crystalstructuresandtheiruseashighlyefficientcatalystsforSuzukireactionofarylchlorides.”J.Mol.Catal.A:Chem.2008,279(1),69-76.
  22. ChenXu,Jun-FangGong*,Yang-JieWu*.“Aminationofarylchloridesinwatercatalyzedbycyclopalladatedferrocenyliminecomplexeswithcommerciallyavailablemonophosphinobiarylligands.”TetrahedronLett.2007,48(9),1619-1623.
  23. Jun-FangGong*,Xin-HengFan,ChenXu,Jin-LeiLi,Yang-JieWu*,Mao-PingSong.“Newcycloplatinatedcomplexeswith2-arylimidazolines:synthesis,crystalstructuresandphotophysicalproperties.”J.Organomet.Chem.2007,692(10),2006-1013.
  24. JunfangGong,GuangyuLiu,ChenxiaDu,YuZhu,YangjieWu*.“EfficientSuzukicouplingofarylchloridescatalyzedbytricyclohexylphosphineadductsofcyclopalladatedferrocenylimines.”J.Organomet.Chem.2005,690(17),3963-3969.
  25. KaiXu,Xin-QiHao,Jun-FangGong*,Mao-PingSong*,andYang-JieWu.“RoomTemperatureSuzukiReactionsinAqueousMediaunderAirbyPalladium(II)ComplexeswithPyrazoleDerivedLigands.”Aust.J.Chem.2010,63(2),315-320.
  26. ChenXu,Jun-FangGong*,Yan-HuiZhang,YuZhu,Yang-JieWu*.“Synthesis,CharacterizationandCrystalStructuresofThreecis/transPyridine-CyclopalladatedFerrocenylimineComplexes,andTheirCatalysisinSuzukiReactions.”Aust.J.Chem.2007,60(3),190-195.
  27. Xin-QiHao,FangLiu,BiZhang,Mei-LingJiang,Jun-FangGong*,Mao-PingSong*.“Cyclopalladatedcomplexesof2-(m-nitrophenyl)imidazolines:synthesis,characterizationandcatalyticactivityintheSuzukireactionundermildconditions.”TransitionMet.Chem.2010,35(3),271-277.
  28. ChenXu,Jun-FangGong*,Mao-PingSong,Yang-JieWu*.“Catalysisofthecouplingreactionofarylchlorideswithbis(pinacolato)diboronbytricyclohexylphosphine-cyclopalladatedferrocenyliminecomplexes.”TransitionMet.Chem.2009,34(2),175-179.
  29. Jun-FangGong*,ChenXu,Yan-HuiZhang,YuZhu,Yang-JieWu*.“Synthesis,characterizationandcrystalstructuresoftwocis/transpyridine-cyclopalladatedferrocenyliminecomplexes.”Transit.MetalChem.2007,32(7),1000-1004.
  30. Xin-QiHao,Jun-FangGong*,Wen-TaoSong,Yang-JieWu,Mao-PingSong*.“Synthesisandcrystalstructuresofmono-,bis-aswellastris-mercuratedcomplexeswithferrocenylazines.”Inorg.Chem.Commun.2007,10(3),371-375.
  31. GONGJun-fang*,ZHANGYan-hui,FANXin-heng,WANGDa-wei,SONGMao-ping,WUYang-jie.“Synthesis,StructuralCharacterizationofFerrocenylIminophosphinesandAmidophosphinesasWellasTheirApplicationintheSuzukiReaction.”Chem.Res.ChineseU.2007,23(6),683-687.
  32. Jun-FangGong*,Da-WeiWang,Yan-HuiZhang,YuZhu,Yang-JieWu*.“SynthesisandStructuralCharacterizationofMercury(II)ComplexeswithaNovelFerrocenyliminophosphine.”Inorg.Chim.Acta2006,359(7),2115-2120.
  33. ChenXu,Jun-FangGong,Yan-HuiZhang,YuZhu,Chen-XiaDu,Yang-JieWu*.“Synthesis,characterizationandcrystalstructuresofanovel1,1’-bisferrocenylimineanditsmonocyclopalladatedderivative.”Inorg.Chem.Commun.2006,9(5),456-459.
  34. Ling-ZhiDu,Jun-FangGong*,ChenXu,YuZhu,Yang-JieWu,Mao-PingSong*.“Synthesisandstructuresofnoveldiastereomericcyclopalladatedferrocenyliminesderivedfromchiralb-aminoalcohols.”Inorg.Chem.Commun.2006,9(4),410-414.
  35. Ling-ZhiDu,Jun-FangGong*,YuZhu,Yang-JieWu,Mao-PingSong*.“Synthesis,characterizationandthecrystalstructuresofnovelachiralandchirala-ferrocenyla-aminophosphineoxides.”Inorg.Chem.Commun.2006,9(5),529-532.
  36. JunfangGong,GuangyuLiu,YuZhu,ChenxiaDu,MaopingSong,YangjieWu*.“Synthesis,CharacterizationandCatalyticActivityinSuzukiReactionofCyclopalladatedFerrocenylimineTriphenylphosphinecomplexes.”Chem.J.Chin.Univ.2006,27(7),1266-1271.
  37. JunfangGong,ChenXu,YangjieWu*.“Transition-MetalCatalyzedα-ArylationofCarbonylDerivativesandCompoundswithAcidicHydrogen.”ProgressinChem.2006,18(6),752-760.
  38. JunfangGong,EricBonfand,EricBrown,GillesDujardin*,VéroniqueMichelet*,Jean-PierreGenêt.“Remarkablestereocontrolinthesynthesisof1,2,3,5-tetrasubstitutedtetrahydropyransviaanasymmetricheterocycloadditionofaketone-derivedenolether.”TetrahedronLett.2003,44(10),2141-2144.
  39. JunfangGong,QinghuaFanandDazhiJiang*.“Nickel-catalyzedcarbonylationofmethylacetatetoaceticanhydride.”J.Mol.Catal.A:Chem.1999,147(1-2),113-124.

學術成果

1.宋毛平,毛璞,廖新成,張雁冰,龔軍芳.有機立體化學導論(譯著,國外名校名著系列),化學工業出版社,2007.1
2.龔軍芳.傅瑞德爾-克拉夫茲反應(現代有機反應第5卷金屬催化反應胡躍飛林國強主編)，化學工業出版社，2008.12
3.龔軍芳,宋毛平.玉尾-熊田-弗萊明立體選擇性羥基化反應(現代有機反應第8卷碳-雜原子鍵參與的反應II胡躍飛林國強主編)，化學工業出版社，2013.1

獲獎記錄

獲得2008年度寶鋼優秀教師獎、河南省教育系統2010教學技能競賽一等獎並獲“河南省教學標兵”稱號。

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