黃小滎,男,中國科學院大學專職教師。
基本介紹
- 中文名:黃小滎
- 畢業院校:廈門大學
- 學位/學歷: 博士
- 職業:教師
人物經歷,教育背景,工作經歷,研究方向,主要成就,專利成果,出版信息,發表論文,科研項目,
人物經歷
教育背景
2001-09--2006-01 美國新澤西州州立羅格斯(Rutgers)大學 博士
1986-09--1990-07 廈門大學化學系 學士
1990年7月大學本科畢業於廈門大學化學系,獲理學學士學位;1994年至1998年為中國科學院福建物質結構研究所在職碩士生,導師盧紹芳研究員;2001年9月起在美國新澤西州州立羅格斯(Rutgers)大學攻讀博士學位,專業無機化學,導師李靜教授,2006年1月獲博士學位;2006年1月至2006年10月,在同一研究小組做博士後。
工作經歷
1990年9月至1998年10月間,在中國科學院福建物質結構研究所,結構化學國家重點實驗室工作,從事結構化學研究。1998年10月至2001年8月在美國新澤西州州立羅格斯(Rutgers)大學卡姆登(Camden)分校化學系做訪問學者,2006年11月年應邀回福建物質結構研究所工作,任課題組長。
研究方向
1. 無機-有機雜化金屬鹵化物基發光材料的研究;
2. 新型多孔材料的合成和性能研究;
3. 離子液體中的無機合成;
4. 鹼土金屬基功能配位聚合物。
主要成就
設計合成了一類新基於II-VI半導體的無機-有機雜化納米結構。這類化合物具有寬廣的帶隙可調性、高吸收係數和激子結合能、近乎零熱膨脹、發白光、結構高度有序等特性。
獲得了多個系列具有良好離子交換性能的新型硫屬多孔材料。
利用離子液體獲得了一系列硫屬化物半導體量子點材料以及硫屬化物多孔材料。
利用離子液體獲得了一類基於ns金屬離子的雜化發光鹵化物材料。
專利成果
( 1 ) 離子熱合成具有發光性能的銅銦/鎵硫量子點化合物及其用途, 發明, 2011, 第 1 作者, 專利號: 201110103803.6
( 2 ) 金屬硫屬化物晶態微孔材料的製備新方法, 發明, 2009, 第 2 作者, 專利號: 200910112276.8
( 3 ) 具有離子交換性能的鍺-銻微孔硫化物及其製備方法和用途, 發明, 2013, 第 2 作者, 專利號: 200810071790.7
( 4 ) 新型除銫微孔材料銀-錫硒化物的製備方法及用途, 發明, 2013, 第 2 作者, 專利號: 200910112276.8
出版信息
代表作:
1. Zeping Wang, Zhizhuan Zhang, Luqi Tao, Nannan Shen, Bing Hu,* Liaokuo Gong, Jianrong Li, Xianping Chen,* Xiaoying Huang* “Hybrid chloroantimonates(III): Thermally induced triple-mode reversible luminescent switching and laser-printable rewritable luminescent paper” Angew. Chem. Int. Ed. 2019, 58(29), 9974-9978; DOI: 10.1002/anie.201903945
2. Zhao-Feng Wu, Bin Tan, William P. Lustig, Ever Velasco, Hao Wang, X. Y. Huang,* Jing Li,* “Magnesium based coordination polymers: Syntheses, structures, properties and applications” Coord. Chem. Rev. 2019, 399, 213025; DOI 10.1016/j.ccr.2019.213025
3. Kai-Yao Wang, Mei-Ling Feng, Xiao-Ying Huang*, Jing Li, “Organically directed heterometallic chalcogenidometalates containing group 12(II)/13(III)/14(IV) metal ions and antimony(III)” Coord. Chem. Rev. 2016, 322, 41-68.
4. Ze-Ping Wang, Jin-Yun Wang, Jian-Rong Li, Mei-Ling Feng, Guo-Dong Zou, Xiao-Ying Huang* “[Bmim]2SbCl5: a main group metal-containing ionic liquid exhibiting tunable photoluminescence and white-light emission” Chem. Commun. 2015, 51, 3094-3097.
5. Wei-Wei Xiong, Jian-Rong Li, Bing Hu, Bin Tan, Ren-Fu Li, Xiao-Ying Huang* “Largest discrete supertetrahedral clusters synthesized in ionic liquids” Chem. Sci. 2012, 3, 1200-1204.
6. Jian-Rong Li, Zai-Lai Xie, Xiao-Wu He, Long-Hua Li, Xiao-Ying Huang* “Crystalline open-framework selenidostannates synthesized in ionic liquids” Angew. Chem. Int. Ed. 2011, 50, 11395-11399.
7. Bing Hu, Mei-Ling Feng, Jian-Rong Li, Qi-Pu Lin, Xiao-Ying Huang* “Lanthanide antimony oxohalides: From discrete nanoclusters to inorganic–organic hybrid chains and layers” Angew. Chem. Int. Ed. 2011, 50, 8110-8113.
8. Huang, X.-Y.; Roushan, M; Emge, T. J.; Bi, W.-H.; Thiagarajan, S.; Cheng, J.-H.; Yang, R.; Li, J.* “Flexible hybrid semiconductors with low thermal conductivity: the role of organic diamines” Angew Chem. Int. Ed. 2009, 48, 7871-7874.
9. Mei-Ling Feng, De-Nian Kong, Zai-Lai Xie, Xiao-Ying Huang*“Three-dimensional chiral microporous germanium antimony sulfide with ion-exchange properties” Angew. Chem. Int. Ed. 2008, 47, 8623-8626.(熱點文章)
10. Huang, X.-Y.; Li, J.* “From single to multiple atomic layers: A unique approach to the systematic tuning of structures and properties of inorganic-organic hybrid nanostructured semiconductors” J. Am. Chem. Soc. 2007, 129, 3157-3162.
11. Huang, X.-Y.; Li, J.; Zhang, Y.; Mascarenhas, A. “from 1D chain to 3D network: tuning hybrid II-VI nanostructures and their optical properties” J. Am. Chem. Soc. 2003, 125, 7049-7055.
12. Huang, X. -Y.; Li, J.; Fu, H.-X. “The first covalent organic-inorganic networks of hybrid chalcogenides: structures that may lead to a new type of quantum wells” J. Am. Chem. Soc. 2000, 122, 8789-8790.
發表論文
(1) Supramolecular organization of [TeCl6]2− with ionic liquid cations: Studies on the electrical conductivity and luminescent properties, Inorg. Chem., 2018, 通訊作者
(2) Discrete supertetrahedral T3 InQ clusters (Q = S, S/Se, Se, Se/Te): Ionothermal syntheses and tunable optical a-nd photodegradation properties, Cryst. Growth Des., 2018, 通訊作者
(3) α- and β-[Bmim][BiCl4(2,2'-bpy)]: Two polymorphic Bismuth Containing Ionic Liquids with Crystallisation Indu-ced Phosphorescence, Chem. Eur. J., 2017, 通訊作者
(4) Syntheses, crystal structures, and optical and photocatalytic properties of four small-amine-molecule-directed M−Sn−Q (M = Zn, Ag; Q = S, Se) compounds, Crystal Growth & Design, 2017, 通訊作者
(5) Organically directed heterometallic chalcogenidometalates containing group 12(II)/13(III)/14(IV) metal ions and antimony(III), Coordination Chemistry Reviews, 2016, 通訊作者
(6) [Bmim]2SbCl5: a main group metal-containing ionic liquid exhibiting tunable photoluminescence and white-light emission, Chem. Commun., 2015, 通訊作者
(7) Tunable photoluminescence and direct white-light emission in Mg-based coordination networks, Chem. Commun., 2015, 通訊作者
(8) New members of the family of In-Sb-S compounds: Different roles of organic amines, Cryst. Growth Des., 2015, 通訊作者
(9) A 3D Hybrid Praseodymium–Antimony–Oxochloride Compound: Single-Crystal-to-Single-Crystal Transformation and Photocatalytic Properties, Chem.-Eur. J., 2013, 通訊作者
(10) Recent Progress in Organic Hybrid Main Group Heterometallic Chalcogenides Based on Antimony, 無機化學學報, 2013, 通訊作者
(11) Ionothermal synthesis and characterization of two cluster chalcohalides: [Cr7S8Cl2(NH3)14.5(H2O)1.5]Cl3?H2O and [Emim]2[Sn2As2S4(S2)2Br2.43Cl1.56], CrystEngComm, 2013, 通訊作者
(12) [AEPH2][GeSb2S6]?CH3OH: a thiogermanate-thioantimonate featuring an infinite ribbon-like structure with an unusual {GeSb3S11} unit and exhibiting the ability of photocatalytic degradation of organic dye, CrystEngComm, 2013, 通訊作者
(13) Novel mercury selenidoantimonates with structures ranging from one-dimensional ribbon tothree-dimensional open-framework, Dalton Trans., 2013, 通訊作者
(14) [NH3CH3]4[In4SbS9SH]: A novel methylamine-directed indium thioantimonate with Rb+ ion-exchange property, J. Mater. Chem. A, 2013, 通訊作者
(15) Layered indium chalcogenidoantimonates [Me2NH2]2In2Sb2S7-xSex (x = 0, 2.20, 4.20, 7) with tunable band gaps and photocatalytic properties, CrystEngComm , 2012, 通訊作者
(16) Largest discrete supertetrahedral clusters synthesized in ionic liquids, Chem. Sci., 2012, 通訊作者
(17) A three-dimensionally microporous chalcogenide exhibiting framework flexibility upon ion-exchange, Dalton Trans. , 2011, 通訊作者
(18) Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to norganic–Organic Hybrid Chains and Layers, Angew Chem., Int. Ed. , 2011, 通訊作者
(19) Solvothermal syntheses, crystal structures, and characterizations of a series of one-dimensional organic-containing gallium polyselenides, CrystEngComm, 2011, 通訊作者
(20) Crystalline Open-Framework Selenidostannates Synthesized in Ionic Liquids, Angew Chem., Int. Ed. , 2011, 通訊作者
(21) A series of novel organically templated germanium antimony sulfides, Chem. Asian J., 2010, 通訊作者
(22) From One-Dimensional Ribbon to Three-Dimensional Microporous Framework: The Syntheses, Crystal Structures, and Properties of a Series of Mercury Antimony Chalcogenides, Cryst. Growth. Des, 2010, 通訊作者
(23) Flexible Hybrid Semiconductors with Low Thermal Conductivity: The Role of Organic Diamines, Angew Chem., Int. Ed., 2009, 第 1 作者
(24) Quaternary Tin(IV) Antimony(III) Sulfide Decorated with Lanthanum(III) Ethylenediamine Complexes: [La(en)4SbSnS5]2?0.5H2O, Inorg. Chem., 2009, 通訊作者
(25) Two Gallium Antimony Sulfides Built on a Novel Heterometallic Cluster, Inorg. Chem., 2009, 通訊作者
(26) Three-Dimensional Chiral Microporous Germanium Antimony Sulfide with Ion-Exchange Properties, Angew Chem., Int. Ed. , 2008, 通訊作者
(27) The first examples of lanthanide selenite-carboxylate compounds: syntheses, crystal structures and properties, Dalton Trans., 2008, 通訊作者
(28) From Single to Multiple Atomic Layers: A Unique Approach to the Systematic Tuning of Structures and Properties of Inorganic-Organic Hybrid Nanostructured Semiconductors, J. Am. Chem. Soc., 2007, 第 1 作者
(29) From 1D Chain to 3D Network: Tuning Hybrid II-VI Nanostructures and Their Optical Properties, J. Am. Chem. Soc., 2003, 第 1 作者
(30) Inorganic-Organic Hybrid Composites Containing MQ (II-VI) Slabs: A New Class of Nanostructures with Strong Quantum Confinement and Periodic Arrangement, Chem. Mater., 2001, 第 1 作者
(31) The First Covalent Organic-Inorganic Networks of Hybrid Chalcogenides: Structures That May Lead to A New Type of Quantum Wells, J. Am. Chem. Soc. , 2000, 第 1 作者
科研項目
( 1 ) 團簇多級結構的構築與功能調控, 參與, 國家級, 2014-01--2018-12
( 2 ) 有機配位鍵合的新型多元金屬硫屬化物的合成及其性能研究, 主持, 國家級, 2012-01--2015-12
( 3 ) 有機分子基框架多孔材料的前沿研究, 參與, 國家級, 2012-01--2016-12
( 4 ) 無機-有機雜化材料, 參與, 國家級, 2016-01--2018-12
( 5 ) 一類新型發光離子化合物的設計合成與性能研究, 主持, 國家級, 2017-01--2020-12