《高性能單離子磁體的製備與磁構關係研究》是王炳武為項目負責人，北京大學為依託單位的面上項目。
基本介紹
- 中文名：高性能單離子磁體的製備與磁構關係研究
- 項目類別：面上項目
- 項目負責人 ：王炳武
- 依託單位 ：北京大學
科研成果,項目摘要,
科研成果
序號 | 標題 | 類型 | 作者 |
|---|---|---|---|
1 | Two-Coordinate Co(II) Imido Complexes as Outstanding Single Molecule Magnets | 期刊論文 | Yao, Xiao-Nan(#); Du, Jing-Zhen; Zhang, Yi-Quan; Leng, Xue-Bing; Yang, Mu-Wen; Jiang, Shang-Da; Wang, Zhen-Xing; Ouyang, Zhong-Wen; Deng, Liang(*); Wang, Bing-Wu(*); Gao, Song(*) |
2 | A soft phosphorus atom to harden an erbium(iii) single-ion magnet | 期刊論文 | Chen Shi-Ming(#); Xiong Jin; Zhang Yi-Quan; Yuan Qiong; Wang Bing-Wu; Gao Song |
3 | Evaporable lanthanide single-ion magnet | 期刊論文 | Gao, Chen(#); Yang, Qian; Wang, Bing-Wu(*); Wang, Zhe-Ming; Gao, Song(*) |
4 | A distinct magnetic anisotropy enhancement in mononuclear dysprosium-sulfur complexes by controlling the Dy-ligand bond length | 期刊論文 | Liu, Shan-Shan(#); Lang, Ke; Zhang, Yi-Quan; Yang, Qian; Wang, Bing-Wu(*); Gao, Song(*) |
5 | High symmetry or low symmetry, that is the question - high performance Dy(III) single-ion magnets by electrostatic potential design | 期刊論文 | Sun, Wen-Bin(#); Yan, Peng-Fei; Jiang, Shang-Da; Wang, Bing-Wu(*); Zhang, Yi-Quan; Li, Hong-Feng; Chen, Peng; Wang, Zhe-Ming; Gao, Song |
6 | Hydroxide-bridged five-coordinate Dy-III single-molecule magnet exhibiting the record thermal relaxation barrier of magnetization among lanthanide-only dimers | 期刊論文 | Xiong, Jin(#); Ding, Hai-Yan; Meng, Yin-Shan; Gao, Chen; Zhang, Xue-Jing; Meng, Zhao-Sha; Zhang, Yi-Quan; Shi, Wei; Wang, Bing-Wu(*); Gao, Song(*) |
7 | Two half-sandwich organometallic single-ion magnets with toluene coordinated to the Dy(III) ion: The [(C7H8)Dy(AlCl4)(3)] and [(C7H8)Dy(AlBr4)(3)] complexes | 期刊論文 | Liu, Shan-Shan(#)(*); Yan, Bing; Meng, Zhao-Sha; Gao, Chen; Wang, Bing-Wu(*); Gao, Song(*) |
8 | Weak Ligand-Field Effect from Ancillary Ligands on Enhancing Single-Ion Magnet Performance | 期刊論文 | Meng, Yin-Shan(#); Zhang, Yi-Quan(*); Wang, Zhe-Ming; Wang, Bing-Wu(*); Gao, Song(*) |
9 | Low-{Coordinate} {Single}-{Ion} {Magnets} by {Intercalation} of {Lanthanides} into a {Phenol} {Matrix} | 期刊論文 | Meng Yin-Shan(#); Xu Ling; Xiong Jin; Yuan Qiong; Liu Tao; Wang Bing-Wu; Gao Song |
10 | Two Magnetic Switching Complexes Based on the Fe-II Ion | 期刊論文 | Yang, Qian(#); Gao, Chen; Wang, Ye-Xin; Wang, Bing-Wu(*); Wang, Zhe-Ming; Gao, Song(*) |
11 | A Six-Coordinate Dysprosium Single-Ion Magnet with TrigonalPrismatic Geometry | 期刊論文 | Liu, Shan-Shan(#)(*); Meng, Yin-Shan; Zhang, Yi-Quan; Meng, Zhao-Sha; Lang, Ke; Zhu, Zhen-Liang; Shang, Chang-Fang; Wang, Bing-Wu(*); Gao, Song(*) |
12 | Thermostability and photoluminescence of Dy(III) single-molecule magnets under a magnetic field | 期刊論文 | Bi, Ye(#); Chen, Cheng; Zhao, Yi-Fang; Zhang, Yi-Quan; Jiang, Shang-Da; Wang, Bing-Wu(*); Han, Jun-Bo; Sun, Jun-Liang; Bian, Zu-Qiang; Wang, Zhe-Ming; Gao, Song(*) |
13 | Understanding the Magnetic Anisotropy toward Single-Ion Magnets | 期刊論文 | Meng, Yin-Shan(#); Jiang, Shang-Da(*); Wang, Bing-Wu(*); Gao, Song(*) |
14 | Design principle of half-sandwich type erbium single-ion magnets through crystal field engineering: a combined magnetic and electronic structure study | 期刊論文 | Meng, Yin Shan(#)(*); Yang, Mu Wen; Xu, Ling; Xiong, Jin; Hu, Ji Yun; Liu, Tao; Wang, Bing Wu(*); Gao, Song(*) |
15 | Magnetic anisotropy investigation on light lanthanide complexes | 期刊論文 | Xu, Mei-Xing(#); Meng, Yin-Shan; Xiong, Jin; Wang, Bing-Wu(*); Jiang, Shang-Da(*); Gao, Song(*) |
16 | Multiple magnetic relaxation pathways in T- shaped N- heterocyclic carbene- supported Fe( I) single- ion magnets | 期刊論文 | Meng, Yin Shan(#); Ouyang, Zhengwu; Yang, Mu Wen; Zhang, Yi Quan; Deng, Liang(*); Wang, Bing Wu(*); Gao, Song(*) |
17 | Can Non-Kramers Tm-III Mononuclear Molecules be Single-Molecule Magnets (SMMs)? | 期刊論文 | Meng, Yin-Shan(#); Qiao, Yu-Sen; Zhang, Yi-Quan; Jiang, Shang-Da; Meng, Zhao-Sha; Wang, Bing-Wu(*); Wang, Zhe-Ming; Gao, Song(*) |
項目摘要
尋找新材料，構建新的自旋電子學器件，理解和實現自旋的調控和操縱，是無機化學、材料化學、信息科學等學科共同關心和亟待解決的關鍵科學問題之一。單分子磁體，從合成、製備和組裝角度講，是一種可以理性設計、精細製備和多尺度組裝的新型磁性分子；從結構和物性關係上講，單分子磁體也非常適合研究分子自旋電子學器件的多功能集成和構效關係，是一類非常有套用潛力和研究價值的體系。單離子磁體是指只含有一個磁性中心的單分子磁體，是分子磁性研究領域近年來的重要突破。本項目以設計合成高性能單離子磁體、研究結構與磁性能關係為目標，從磁性金屬離子選擇、配位場調控、配體端基修飾等方面研究磁性金屬離子電子結構、配位場對稱性與電荷分布等對提高單離子磁弛豫能壘與阻塞溫度的影響，探索調控單離子磁體磁各向異性的方法，為分子自旋電子學器件製備與套用提供材料和理論基礎。
