陳鐵橋(海南大學教師)

陳鐵橋，男，博士，海南大學高聘教授（副教授）。

基本介紹

• 中文名：陳鐵橋
• 畢業院校：湖南大學
• 學位/學歷：博士
• 專業方向：化學

人物經歷

2004年，考入湖南大學化學化工學院化學專業，2005年因成績優異轉入化學本碩連讀班，2009年轉為碩博連讀生，2010年4月赴日本產業技術綜合研究所（AIST）學習工作三年，2013年博士畢業，2014年1月以助理研究員身份留校工作，2017年1月晉升副教授。2017年10月以C類高層次人才調入海南大學，高聘教授（副教授）。碩士生導師是郭燦城教授，博士生導師是郭燦城教授和韓立彪教授。碩士論文期間（9/2008-3/2009），測量了多種仿生催化劑（卟吩和金屬卟啉）在DMF中於不同溫度下的溶解度，研究了卟吩金屬化的反應動力學，為仿生催化劑的中試生產試驗提供了堅實的實驗數據，並於同一年組織六位同學在實驗室進行放大實驗，完成了公斤級的仿生催化劑合成。碩士論文期間（3/2009-11/2009），在湖南大學先進教育部催化工程中心沅江中試基地參與中試設備的安裝與調試，期間協助安裝了整個實驗車間的電力系統、控制系統、物料傳輸系統。並作為主要實驗人員全程參與仿生催化劑的中試生產：蒸汽的準備（鍋爐的燃燒）與傳輸、物料的導入與輸送、反應的升溫與終止、產物的分離（結晶）與純度分析、溶劑的回收（精餾塔分餾），為仿生催化劑工業生產技術的形成做出了貢獻。2010年4月赴日本產業技術綜合研究所（AIST）作為Technique Staff學習工作三年，從事炔烴金屬氫化反應及其在有機合成中的套用研究（學術成就中第一部分工作）。另外，還進行了套用開發研究，獨自承擔了高阻燃性能有機磷玻璃單體的合成以及核廢液中鈀、鉑等貴金屬的高效萃取劑的開發。2013年3月回國，撰寫博士論文並於2013年12月通過博士論文答辯，取得博士學位。在湖南大學與海南大學工作期間，繼續從事有機化學的基礎研究，通過機理研究指導化學反應的設計，圍繞有機磷化合物的綠色合成與套用展開研究工作。

學術成果

目前承擔國家自然科學基金（青年基金）1項，湖南省自然科學基金（青年基金）1項。自2011年以來，以第一作者和通訊作者身份在J. Am. Chem. Soc. (4篇), Angew. Chem. Int. Ed. (1篇), Chem. Commun. (6篇), Org. Lett. (3篇), Adv. Synth. Catal. (1篇), Chem. Eur. J. (1篇), Catal. Sci. Tech. (3篇),J. Org. Chem.(3篇), Organometallics (1篇), Dalton Trans. (3篇)等高水平國際期刊發表論文42篇，其中JCR 1區論文32篇,被引670次，H-index為16.

發表論文

[1]Chen T Q,Zhao C-Q, Han L-B.*Hydrophosphorylation of Alkynes Catalyzed by Palladium: Generality and Mechanism.Journal of the American Chemical Society, 2018, 140, 3139–3155 (JCR一區,IF: 13.858).

[2] Zhu Y Y,Chen T Q,*Li S, Shimada S, Han L-B.*Efficient Pd-Catalyzed Dehydrogenative Coupling of P(O)H with RSH: a Precise Construction of P(O)-S Bonds.Journal of the American Chemical Society, 2016, 138, 5825–5828 (Organic Chemistry Portal highlights, JCR一區,IF: 13.858).

[3] Yang J,Chen T Q,*Han L-B.*C-P Bond-Forming Reactions via C-O/P-H Cross Coupling Catalyzed by Nickel.Journal of the American Chemical Society, 2015, 137: 1782-1785(JCR一區,IF: 13.858).

[4]Chen T Q,*Han L-B.*Nickel-Catalyzed C-O/C-H Cross-Coupling Reactions for C-C Bond Formation.Angewandte Chemie International Edition,2015, 54: 8600-8602 (JCR一區, Wiley-VCH Hot Topics: C-H activation, C-C coupling,IF: 11.994).

[5] Shen R W,b?Chen T Q,a?Zhao Y L, Qiu R H, Zhou Y B, Yin S F,*Wang X B, Goto M, Han L-B.*Facile Regio- and Stereoselective Hydrometalation of Alkynes with a Combination of Carboxylic Acids and Group 10 Transition Metal Complexes: Selective Hydrogenation of Alkynes with Formic Acid.Journal of the American Chemical Society, 2011, 133: 17037-17044 (?:並列第一作者,第一單位第一作者)(Synfacts, ChemInform and ACIE highlight) (JCR一區,IF: 13.858).

[6] Xi X X,Chen T Q,*Zhang J-S, Han L-B. Efficient and Selective Hydrogenation of C-O Bonds with a Simple Sodium Formate Catalyzed by Nickel.Chemical Communications, 2018, 54, 1521-1524 (JCR一區,IF: 6.567).

[7] Xiao J, Yang J,Chen T Q,*Han L-B.*Nickel-Catalyzed Synthesis of (E)-Olefins from Benzylic Alcohol Derivatives and Arylacetonitriles via C-O Activation.Chemical Communications, 2016, 52, 2157-2160 (JCR一區,IF: 6.567).

[8] Yang J, Xiao J,Chen T Q,*Yin S-F,*Han L-B.*Efficient Nickel-catalyzed Phosphinylation of C-S Bonds Forming C-P Bonds.Chemical Communications, 2016, 52, 12233-12236 (JCR一區,IF: 6.567).

[9] Zhang J-S,Chen T Q,*Yang J, Han L-B.*Nickel-Catalysed P-C Bond Formation via P-H/C-CN Cross Couplings.Chemical Communications, 2015, 51, 7540-7542 (JCR一區,IF: 6.567).

[10] Yang J,Chen T Q,*Zhou Y B, Yin S F, Han L-B.*Palladium-Catalyzed Dehydrogenative Coupling of Terminal Alkynes with Secondary Phosphine Oxides.Chemical Communications,2015, 51, 3549-3551(JCR一區,IF: 6.567).

[11]Chen T Q,Guo C C,*Goto M, Han L -B.*A Br?nsted acid-catalyzed generation of palladium complexes: efficient head-to-tail dimerization of alkynes.Chemical Communications,2013, 49: 7498-7500 (ChemInform highlight)(JCR一區,IF: 6.567).

[12] Zhang J Q,Chen T Q,*Zhang J.-S., Han L.-B.*Silver-Free Direct Synthesis of Alkynylphosphine Oxides via spC-H/P(O)-H Dehydrogenative Coupling Catalyzed by Palladium.Organic Letters, 2017,19, 4692-4695. (JCR一區,IF: 6.732).

[13] Xiao J,Chen T Q,*Han L-B.*Nickel-Catalyzed Direct C-H/C-O Cross Couplings Generating Fluorobenzenes and Heteroarenes.Organic Letters, 2015, 17: 812–815 (JCR一區,IF: 6.732).

[14] Zhao Y L,Chen T Q,*Han D Q, Zhao C-Q,*Han L-B.*Facile Base-Mediated Redox Transformation: An Efficient Strategy for the Synthesis ofα?Acyloxyphosphoryl Compounds.Organic Letters, 2014, 16: 6152-6155 (JCR一區,IF: 6.732).

[15] Xiao J, Yang J,Chen T Q,*Han L-B.*Nickel-Catalyzed α-Benzylation of Arylacetonitriles via C-O Activation.Advanced Synthesis & Catalysis, 2016, 358, 816-819 (JCR一區,IF: 6.453).

[16] Liu M,Chen T Q,*Yin S F.*Copper-Catalysed Aerobic Oxidative Esterification of N-Heteroaryl Methanes with Alcohols.Catalysis Science & Technology, 2016, 6, 690-693 (JCR一區,IF: 5.287).

[17] Liu M,Chen T Q,*Zhou Y B, Yin S F.*Transition Metal-Free Oxidative ortho-Acylation of Phenols with N-Heteroarylmethanes via Double C-H Activation.Catalysis Science & Technology, 2016, 6, 5792-5796 (JCR一區,IF: 5.287) .

[18] Chen X L,?Chen T Q,?Ji F Y, Zhou Y B,*Yin S-F.*Iron-Catalyzed Aerobic Oxidative Functionalization of sp3C-H Bonds: a Versatile Strategy for the Construction of N-Heterocycles,Catalysis Science & Technology, 2015,5, 2197-2202 (?:並列第一作者) (JCR一區,IF: 6.453).

[19] Chen X L,?Chen T Q,?Li Q, Zhou Y B, Han L-B, Yin S-F.*Copper-Catalyzed Aerobic Oxidative Inert C-C and C-N Bond Cleavage: A New Strategy for the Synthesis of Tertiary Amides.Chemistry - A European Journal, 2014, 20: 12234-12238 (?:並列第一作者) (JCR一區,IF: 5.771).

[20] Huang T,Chen T Q,*Han L-B.*Oxidative Dephosphorylation of Benzylic Phosphonates with Dioxygen Generating Symmetrical trans-Stilbenes.The Journal of Organic Chemistry, 2018, DOI:10.1021/acs.joc.7b03148(JCR一區,IF: 4.849).

[21] Zhang M-Z,* Luo N, Long, R-Y, Gou X-T, Shi W-B, He S-H, Jiang Y, Chen J-Y,Chen, T Q.*Transition-Metal-Free Oxidative Aminooxyarylation of Alkenes: Annulations toward Aminooxylated Oxindoles.The Journal of Organic Chemistry, 2018,83, 2369-2375(JCR一區,IF: 4.849).

[22] Yang J,?Xiao J,?Chen T Q,*Han L-B.*Nickel-Catalyzed Phosphorylation of Phenol Derivatives via C-O/P-H Cross Coupling.The Journal of Organic Chemistry, 2016, 81: 3911-3916(Organic Chemistry Portal highlights，JCR一區,IF: 4.894).

[23] Yang J,Chen T Q,*Zhou Y B, Yin S F, Han L-B.*Mechanistic Studies on the Palladium Catalyzed Cross Dehydrogenative Coupling of P(O)-H Compounds with Terminal Alkynes: Stereochemistry and Reactive Intermediates.Organometallics, 2015, 34: 5095-5098 (JCR一區，strongly support the acceptance, very impressive and well suited for publication,IF: 4.186).

[24] Li C Y,Chen T Q,*Han L-B.*Iron-Catalyzed Clean Dehydrogenative Coupling of Alcohols with P(O)-H Compounds: a New Protocol for ROH Phosphorylation.Dalton Transactions, 2016,45, 14893-14897(JCR一區,IF: 4.177).

[25]Chen T Q,Zhang J-S, Han L-B.*Dehydrogenative Coupling Involving P(O)-H Bonds: a Powerful Way for the Preparation of Phosphoryl Compounds.Dalton Transactions, 2016, 45, 1843-1849 (JCR一區,2016年3月-2017年6月高被引論文,IF: 4.177).

[26] Li X,Chen T Q,*Saga Y, Han L-B.*Iron-Catalyzed Cross Coupling of P-H/C-O Bonds: Efficient Synthesis of α-Alkoxyphosphorus Compounds.Dalton Transactions, 2016, 45, 1877-1880 (JCR一區,IF: 4.177).

[27] Huang Y,Chen T Q,*Li Q, Zhou Y B, Yin S F.*Copper Catalysed Direct Amidation of Methyl Groups with N-H Bonds.Organic & Biomolecular Chemistry, 2015, 13: 7289-7293 (JCR一區,IF: 3.559).

[28] Liu M, Chen X,Chen T Q,*Yin S F.*Facile and General Acid-Catalyzed Deuteration at Methyl Groups of N-Heteroarylmethanes.Organic & Biomolecular Chemistry, 2017, 15, 2507-2511 (JCR一區,IF: 3.559).

[29] Zhang J-S, Zhang J-Q,Chen T Q,*Han L-B.*t-BuOK-Mediated Reductive Addition of P(O)-H Compounds to Terminal Alkynes Formingβ-Arylphosphine oxides.Organic & Biomolecular Chemistry, 2017, 15, 5462-5467 (JCR一區,IF: 3.559).

[30] Liu M, Chen X,Chen T Q,*Xu Q, Yin S F.*Metal-Free Oxidativepara-Acylation of Unprotected Anilines with N-Heteroarylmethanes.Organic & Biomolecular Chemistry, 2017, accepted (JCR一區,IF: 3.559).

[31]Xiao J, Yang J,Chen T Q,*Han L-B.* Nickel-Catalyzed α-Benzylation of Sulfones with Esters via C-O Activation.RSC Advances, 2016, 6, 42656 - 42659 (JCR一區,IF: 3.289).

[32] Li S,Chen T Q,*Saga Y, Han L-B.* Chloroform-Based Atherton-Todd-Type Reactions of Alcohols and Thiols with Secondary Phosphine Oxides Generating Phosphinothioates and Phosphinates.RSC Advances, 2015, 5, 71544-71546 (JCR一區,IF: 3.289).

[33]Chen T Q,Han L-B.*Optically Active H-Phosphinates and Their Stereospecific Transformations to Optically Active P-Stereogenic Organophosphoryl Compounds.Synlett, 2015, 26, 1153-1163 (Invited Review) (JCR二區,IF: 2.323,2016年11月23日web of science數據顯示該論文引用次數在該期刊自2015年以來發表論文中排名前17).

[34] Huang T-Z,Chen T Q,*Saga Y, Han L-B.*Me3P-catalyzed addition of hydrogen phosphoryl compounds P(O)H to electron-deficient alkenes: 1 to 1 vs 1 to 2 adducts.Tetrahedron, 2017, accepted (JCR二區,IF: 2.651).

[35] Yang J, Xiao J,Chen T Q,*Han L -B.*Nickel-Catalyzed Phosphorylation of Aryl Triflates with P(O)-H Compounds.Journal of Organometallic Chemistry, 2016, 820: 120-124 (JCR二區,IF: 2.336).

[36]Chen T Q,Xiao J, Zhou Y B, Yin S F, Han L -B.*Nickel-Catalyzed (E)-Selective Semihydrogenation of Internal Alkynes with Hypophosphorous Acid.Journal of Organometallic Chemistry, 2014, 749: 51-54(Most downloaded JOMC articles in the first half year of 2014) (JCR二區,IF: 2.336，2016年9月20日web of science數據顯示該論文引用次數在該期刊自2014年以來發表論文中排名前20).

[37] Xiao J, Li Q,Chen T Q,*Han L -B.*Copper-Mediated Selective Aerobic Oxidative C3-Cyanation of Indoles with DMF.Tetrahedron Letters, 2015, 56: 5937-5940 (JCR二區,IF: 2.347).

[38] Lei J,?Su L B,?Zeng K,?Chen T Q,?Qiu R H, Zhou Y B, Au C-T, Yin S F,*Recent advances of catalytic processes on the transformation of alkynes into functional compound.Chemical Engineering Science, 2017, 171, 404-425 (invited review,?:並列第一作者).

[39]Chen T Q,Zhou Y B, Guo C C,*Han L -B.*Selective Addition of P(O)-H Bonds to Alkynes Catalyzed by Transition Metals Immobilized on Polystyrene-Bound Triphenylphosphine.Chemistry Letters, 2013, 42: 1065-1067 (JCR三區,IF: 1.550).

[40]Chen T Q,Zhou Y B, Yin S-F, Zhao Y L, Goto M, Han L -B.*Identification of Alkenyl and Arylpalladium Hydrides by the Aid of Hydrosilanes.Chemistry Letters, 2013, 42: 1227-1229 (JCR三區,IF: 1.550).

[41] Yang J, Xiao J, Zhou Y B,*Chen T Q,*Yin S F, Han L-B.*Recent Advances in the Synthesis of Organophosphorus Compounds via Cross Coupling between Readily Available Materials and P-H Compounds.Chinese Journal of Organic Chemistry, 2017, 37, 1055-1068 (JCR三區,Invited review).

[42] Zhao Y L,Chen T Q,*Wang X B, Han L-B.*A Convenient Stereoselective Reduction of gem-Dibromides with a Combination of Dimethyl Phosphite and Potassium Carbonate.Phosphorus, Sulfur, and Silicon and the Related Elements, 2015, 190: 1820-1827 (JCR四區).

[1] Li Q,Chen T Q,Xu Q, Han L-B. Rhodium- and Iridium-Catalyzed Asymmetric Addition of Optically Pure P-Chiral H-Phosphinates to Aldehydes Leading to Optically Active α-Hydroxyphosphinates.Chemistry – A European Journal, 2016, 22,6213–6217 (Highlighted insynfacts:synfacts, 2016, 12(07), 0710).

[2] Yoshimura A, Saga Y, Sato Y, Ogawa A,Chen T Q, Han L-B. An efficient base-catalyzed double addition of H-phosphine oxides to alkynes.Tetrahedron Letters, 2016, 57, 3382-3384.

[3] Sheng W-B,Chen T Q, Zhang M-Z, Tian M, Jiang G F, Guo C-C. Copper porphyrin-catalyzed aerobic oxidative coupling of terminal alkynes with high TON.Tetrahedron Letters, 2016, 57, 1641-1643.

[4] Zhou Y B, Li Z W, Yang X, Chen X L, Li M,Chen T Q, Yin S-F. Phosphorous Acid Promoted Hydration-Condensation of Aromatic Alkynes with Aldehydes Affording Chalcones in an Oil/Water Two-Phase System.Synthesis-Stuttgart, 2016, 48, 231-237.

[5] Xiong B Q, Feng X F, Zhu L Z,Chen T Q, Zhou Y B, Au C-T, Yin S-F. Direct Aerobic Oxidative Esterification and Arylation of P(O)-OH Compounds with Alcohols and Diaryliodonium Triflates.ACS Catalysis, 2015, 5, 537?543.

[6] Chen X L, Ji F Y, Zhao Y L, Liu Y X, Zhou Y B,Chen T Q,Yin S-F. Copper-Catalyzed Aerobic Oxidative C(aryl)-OH Bond Functionalization of Catechols with Amines Affording Benzoxazoles.Advanced Synthesis & Catalysis, 2015, 357: 2924-2930.

[7] Zhao Y L, Chen X L,Chen T Q, Zhou Y B, Yin S-F, Han L-B. Catalyst-Free and Selective C–N Bond Functionalization: Stereospecific Three-Component Coupling of Amines, Dichloromethane, and >P(O)H Species Affording α-Aminophosphorus Compounds.The Journal of Organic Chemistry, 2015, 80, 62–69.

[8] Li Q, Huang Y,Chen T Q,Zhou Y B, Xu Q, Yin S-F, Han L-B. Copper-Catalyzed Aerobic Oxidative Amination of sp3C–H Bonds: Efficient Synthesis of 2-Hetarylquinazolin-4(3H)-ones.Organic Letters, 2014, 16: 3672-3675.

[9] Cao H Y,Chen T Q,Zhou Y B, Han D-Q, Yin S-F, Han L-B. Copper-Catalyzed Selective Semihydrogenation of Terminal Alkynes with Hypophosphorous Acid.Advanced Synthesis & Catalysis, 2014, 536: 765-769(Inside cover).

[10] Chen X L,Chen T Q, Zhou Y B, Au C-T, Han L-B, Yin S-F. Efficient Synthesis of Propargylamines from Terminal Alkynes, Dichloromethane and Tertiary Amines over Silver Catalysts.Organic & Biomolecular Chemistry, 2014, 12: 247-250.

[11] Chen X L,Chen T Q, Zhou Y B, Han D Q, Han L-B, Yin S-F. Metal-free Aerobic Oxidative C–N Bond Cleavage of Tertiary Amines for the Synthesis of N-Heterocycles with High Atom Efficiency.Organic & Biomolecular Chemistry, 2014, 12: 3802-3807.

[12] Xiong B Q, Zhu L Z, Feng X F, Lei J,Chen T Q, Zhou Y B, Han L B, Au C T, Yin S-F. Direct Amidation of Carboxylic Acids with Tertiary Amines: Amide Formation over Copper Catalysts through C-N Bond Cleavage.European Journal of Organic Chemistry, 2014, 20: 4244-4247.

[13] Xiong B Q, Ye Q Q, Feng X F, Zhu L Z,Chen T Q, Zhou Y B, Au C T, Yin S-F. Base-promoted O-deprotonation/alkylation reaction of P(O)-OH compounds with alkyl halides.Tetrahedron, 2014, 70, 9057-9063.

[14] Chen X L,Chen T Q, Xiang Y Q, Zhou Y B, Han D Q, Han L-B, Yin S-F. Metal-Free Regioselective Hydrobromination of Alkynes through C-H/C-Br Activation.Tetrahedron Letters, 2014, 55: 4572-4575.

[15] Zhao Y L, Zhou Y B,Chen T Q,Yin S-F, Han L-B. Synthesis and molecular structure of tetranuclear Cu4P4complexes with R2P–O–PR2ligands.Inorganica Chimica Acta, 2014, 422: 36-39.

[16] Zhou Y B, Yang J,Chen T Q,Yin S-F, Han D Q, Han L-B. Stereospecific Aerobic Oxidative Dehydrocoupling of P(O)–H Bonds with Amines Catalyzed by Copper.Bulletin of the Chemical Society of Japan, 2014, 87: 400-402.

會議報告

[1]Chen T Q,過渡金屬催化C-Z/P-H（Z = O,S,CN）交叉偶聯構建C-P鍵，第十一屆全國磷化學化工學術討論會.武漢, 2017.10.21-2017.10.23 (invited talk).

[2]Chen T Q,過渡金屬催化C-O鍵活化構建C-Z鍵，第十五屆全國均相催化學術討論會.杭州, 2017.9.26-2017.9.29 (Oral Talk).

[3]Chen T Q.過渡金屬催化脫氫偶聯反應合成有機磷化合物，一帶一路綠色化學高端論壇，蘭州，2017年7月14日-16日(Poster).

[4]Chen T Q, Yoshimura A, Han L-B. Ni-catalyzed C-O/Z-H cross coupling forming C-Z bonds. International Symposium on C-O activation (ISCO-2016). Himeji, Hyogo, Japan, 2016.10.25-2016.10.27 (Oral Talk).

[5]Chen T Q, Han L-B. Synthesis of organophosphorus compounds via metal-catalyzed dehydrogenative couplings. The 43rdSymposium on Main Group Element Chemistry. Sendai, Japan, 2016.12.08-2016.12.10 (Poster).

[6]Chen T Q.基於Z-H鍵轉化的綠色合成及其機理研究.海南師範大學,海口,中國, 2016.10.15 (Oral Talk).

會議論文

[1]陳鐵橋，付磊，袁擁軍，胡伯羽，郭燦城.活性有機胺促進的苯分子氧氧化羥基化的研究.第11屆全國絡合（均相）催化會議，湖南長沙：2009.10

[2]陳鐵橋，韓立彪.羰基酸，零價過渡金屬（鎳，鈀，鉑）配合物與炔烴化學選擇性的合成烯基金屬配合物：甲酸選擇性還原炔烴的機理研究.中國化學會第28屆學術年會，四川成都：2012.4

[3]陳鐵橋，韓立彪.鈀催化的高化學選擇性的高價H-膦螺烷與炔烴的加成及其機理研究.中國化學會第28屆學術年會，四川成都：2012.4

[4]黃慶，陳鐵橋，劉向丹，曾旭，盛文兵，郭燦城. CoTPP的合成經驗動力學研究.第11屆全國絡合（均相）催化會議.湖南長沙：2009.10

[5]劉向丹，黃慶，陳鐵橋，盛文兵，郭燦城. MnClTPP的合成經驗動力學研究.第11屆全國絡合（均相）催化會議.湖南長沙：2009.10

[6]尹雙鳳，陳鐵橋，韓立彪，黃堯，周永波.一種二級、三級芳香醯胺化合物的合成方法.發明專利，申請號：201410634539.2

[7]尹雙鳳，韓立彪，陳鐵橋，黃堯，周永波.一種一級芳香醯胺化合物的合成方法.發明專利，申請號：201410635839.2

[8]郭燦城，羅偉平，陳鐵橋，劉強.四芳基卟啉的合成方法與設備. PCT. ZL 200910043414.1; WO 2010130065.

基金支持

[1]過渡金屬催化惰性C-O鍵官能團化反應及其機理研究，21403062，國家自然科學基金，26萬，2015-2017，主持

[2]過渡金屬催化C-H/P-H鍵脫氫偶聯構建C-P鍵的研究，2015JJ3039，湖南省自然科學基金，4萬，2015-2017，主持

[3]過渡金屬催化脫氫偶聯構建P-Z鍵的研究，國家自然科學基金，67萬，2016-2019，第一參與

[4]末端炔烴交叉偶聯反應的精密控制及機理研究，國家自然科學基金，66萬，2016-2019，第一參與

[5]基於“金屬有機骨架體”的生物-化學催化體系的建立和催化串聯反應性能研究，國家自然科學基金，66萬，2016-2019，第一參與

學術獎勵

[1]張繼樹，陳鐵橋*，韓立彪*.鹼金屬促進的sp3碳-氰鍵和sp3碳-磷鍵的連續斷裂：肉桂腈與P(O)-H化合物的還原偶聯.第15屆全國均相催化學術討論會.杭州：2017，優秀牆報獎

[2]劉敏，陳鐵橋*，周永波，尹雙鳳*.銅催化氮雜芳基甲烷與醇的氧氣氧化直接酯化反應.第14屆全國絡合（均相）催化會議.大連：2015，優秀牆報獎

[3]黃慶，陳鐵橋，劉向丹，曾旭，盛文兵，郭燦城*. CoTPP的合成經驗動力學研究.第11屆全國絡合（均相）催化會議.長沙：2009，優秀牆報獎

[4]陳鐵橋，尹雙鳳，韓立彪.羧酸和第10族過渡金屬配合物與炔烴的高立體和區域選擇性氫金屬化反應極其甲酸和炔烴的高選擇性氫化反應. 2012年度湖南省化學化工學會優秀論文一等獎，2012-9.頒獎單位：湖南省化學化工學會

[5]沈如偉，陳鐵橋，尹雙鳳.羧酸和第10族過渡金屬配合物與炔烴的高立體和區域選擇性氫金屬化反應及其甲酸和炔烴的高選擇性氫化反應.湖南省第14屆自然科學優秀學術論文一等優秀論文，2012-9.頒獎單位：湖南省科學技術廳