開殼層有機金屬配合物活化小分子的研究

科研成果

序號	標題	類型	作者
1	水溶性卟啉銠催化烯烴和醇氧化的機理研究	會議論文	禹蒙蒙\|貟琳\|凌鎮\|付雪峰\|
2	Visible-Light-Induced Living Radical Polymerization (LRP) Mediated by (salen)Co(II)/TPO at Ambient Temperature	期刊論文	Liu, Xu\|Zhao, Xianyuan\|Peng, Chi-How\|Fu, Xuefeng\|
3	卟啉銠催化氧化芳香醇、脂肪醇反應機理的研究	會議論文	劉良會\|禹蒙蒙\|凌鎮\|付雪峰\|
4	The Mechanism of E-H (E = N, O) Bond Activation by a Germanium Corrole Complex: A Combined Experimental and Computational Study	期刊論文	Ge, Haonan\|Brothers, Penelope J.\|Fu, Xuefeng\|Ye, Shengfa\|
5	水相中卟啉銠催化氧化烯烴功能化的研究	會議論文	貟琳\|鄧強\|任臻\|付雪峰\|
6	Transition metal free oxidative esterification of alcohols with toluene	期刊論文	Yun, Lin\|Wang, Zikuan\|Fu, Xuefeng\|Yan, Chun-hua\|
7	Synthesis and Reactivity Studies of a Tin(II) Corrole Complex	期刊論文	Dietl, Christian\|Ghosh, Abhik\|Brothers, Penelope J.\|Fu, Xuefeng\|
8	Highly Efficient Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by [RhCl(CO)(2)](2)	期刊論文	Yu, Mengmeng\|Jing, Huize\|Fu, Xuefeng\|
9	Reactivity studies of a corrole germanium hydride complex with aldehydes, olefins and alkyl halides	期刊論文	Fang, Huayi\|Ling, Zhen\|Brothers, Penelope J.\|Fu, Xuefeng\|
10	Azobisisobutyronitrile Initiated Aerobic Oxidative Transformation of Amines: Coupling of Primary Amines and Cyanation of Tertiary Amines	期刊論文	Liu, Lianghui\|Wang, Zikuan\|Fu, Xuefeng\|Yan, Chun-Hua\|
11	Metal-free aerobic oxidative coupling of amines to imines	期刊論文	Liu, Lianghui\|Zhang, Siyu\|Fu, Xuefeng\|Yan, Chun-Hua\|
12	DFT study of cobalt porphyrin complex for living radical polymerization of olefins	期刊論文	Hou, Tingjun\|Zhao, Yaguang\|Fu, Xuefeng\|Li, Youyong\|
13	Visible light Induced Living/Controlled Radical Polymerization of Acrylates Catalyzed by Cobalt Porphyrins	期刊論文	付雪峰\|
14	Living radical polymerization of acrylates and acrylamides mediated by a versatile cobalt porphyrin complex	期刊論文	Zhao, Yaguang\|Dong, Huilong\|Li, Youyong\|Fu, Xuefeng\|
15	Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins	期刊論文	Yun, Lin\|Liu, Lianghui\|Wu, Bing\|Fu, Xuefeng\|
16	Photo-cleavage of the cobalt-carbon bond: visible light-induced living radical polymerization mediated by organo-cobalt porphyrins	期刊論文	Zhao, Yaguang\|Yu, Mengmeng\|Fu, Xuefeng\|
17	有機金屬配合物控制的活性自由基聚合研究進展	期刊論文	趙亞光\|禹蒙蒙\|劉禹初\|付雪峰\|
18	Hierarchical Self-Assembly of Superlattice Hybrids Consisting of Periodic and Alternating Cores of Porphyrin Molecules Separated by Nanoscale Silica Walls	期刊論文	Ren, Zhen\|Zhao, Ya-Guang\|Feng, Wei\|Yan, Chun-Hua\|
19	Reversible deactivation radical polymerization mediated by cobalt complexes: recent progress and perspectives	期刊論文	付雪峰\|
20	Visible Light Promoted Hydroxylation of a Si-C(sp(3)) Bond Catalyzed by Rhodium Porphyrins in Water	期刊論文	Yu, Mengmeng\|Fu, Xuefeng\|
21	Aerobic oxidative N-dealkylation of secondary amines in aqueous solution catalyzed by rhodium porphyrins	期刊論文	Yun, Lin\|Zhen, Ling\|Wang, Zikuan\|Fu, Xuefeng\|
22	Intramolecular oxidative cyclization of alkenes by rhodium/cobalt porphyrins in water	期刊論文	Yun, Lin\|Wang, Zikuan\|Fu, Xuefeng\|
23	Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins	期刊論文	Lin Yun\|Lianghui Liu\|Bing Wu\|Xuefeng Fu\|
24	Mechanistic comparison of beta-H elimination, beta-OH elimination, and nucleophilic displacement reactions of beta-hydroxy alkyl rhodium porphyrin complexes	期刊論文	Wu, Bing\|Zhang, Jiadi\|Yun, Lin\|Fu, Xuefeng\|
25	Germanium(III) corrole complex: reactivity and mechanistic studies of visible-light promoted N-H bond activations	期刊論文	Lang, Ke\|Brothers, Penelope J.\|de Bruin, Bas\|Fu, Xuefeng\|
26	N-H Bond Activation of Ammonia by Transition Metal and Main Group Element Complexes	期刊論文	Fang Huayi\|Ling Zhen\|Fu Xuefeng\|
27	Highly Efficient Generation of Hydrogen from the Hydrolysis of Silanes Catalyzed by [RhCl(CO)2]2	期刊論文	Yu Mengmegn\|Jing Huize\|Fu Xuefeng\|
28	Transition metal free oxidative esterification of alcohols with toluene	期刊論文	Liu Lianghui\|Yun Lin\|Wang Zikuan\|Fu Xuefeng\|
29	Germanium(III) corrole complex: reactivity and mechanistic studies of visible-light promoted N–H bond activations	期刊論文	Lang Ke\|Penelope J. Brothers\|Bas de Bruin\|Fu Xuefeng\|
30	Reactivity and kinetic-mechanistic studies of regioselective reactions of rhodium porphyrins with unactivated olefins in water that form beta-hydroxyalkyl complexes and conversion to ketones and epoxides	期刊論文	Wayland, Bradford B.\|Yun, Lin\|Li, Shan\|Fu, Xuefeng\|
31	Visible Light Induced Living/Controlled Radical Polymerization of Acrylates Catalyzed by Cobalt Porphyrins	期刊論文	Yu, Mengmeng\|Zhang, Shuailin\|Liu, Yuchu\|Fu, Xuefeng\|

項目摘要

設計新的金屬自由基並研究其反應性對於發現新的反應機理和新的成鍵方式，探索新的可催化烯烴等單體聚合的催化劑具有重要意義。目前，國內外在此領域的研究主要涉及過渡金屬，且多集中於開殼層金屬配合物的製備，而對於此類配合物的反應性的探究很少。申請者擬研究Corrole主族金屬鍺、錫、鉛和前過渡金屬鈦、鋯等開殼層金屬配合物與烷烴、烯烴、炔烴、氫氣、一氧化碳、氧氣等小分子的反應性，探索活化和構建C-H、C-C等化學鍵的途徑和方法，把底物活化與催化轉化反應相結合，發展有效的催化反應策略，為把小分子轉化為更有經濟價值的有機物和高分子材料開闢道路。

開殼層有機金屬配合物活化小分子的研究

基本介紹

科研成果

項目摘要

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