閆超鹹，1991年11月出生，畢業於蘭州大學，現任安康學院化學化工學院教師。
基本介紹
- 中文名：閆超鹹
- 出生日期：1991年11月
- 畢業院校：蘭州大學
- 學位/學歷：博士/研究生
- 教學職稱：講師
研究方向,主要成就,
研究方向
理論計算化學。
主要成就
- 研究工作簡介
通過理論計算方法研究以下問題：
(1)有機小分子或過渡金屬催化的不對稱反應的機理與立體選擇性。
(2)新型功能有機分子的光電性質、磁學性質、芳香性、吸收/發射光譜等理化性質。
- 代表性成果：
1. Chao-Xian Yan, Fang-Ling Yang, Ka Lu, Xing Yang, Pan-Pan Zhou and Xiangfeng Shao. A semipinacol rearrangement of vinylogous α-ketol cocatalyzed by a cinchona-based primary amine and N-Boc-phenylglycines: mechanisms, roles of catalysts and the origin of enantioselectivity. Organic Chemistry Frontiers, 2020, 7: 1845-1861.
2. Chao-Xian Yan, Rui-Zhi Wu, Ka Lu, Fang-Ling Yang, Xiao-Shan Yang, Rui Wang, Xing Yang, Pan-Pan Zhou and Xiangfeng Shao. Why electrostatically enhanced thiourea is better than Schreiner’s thiourea in both catalytic activity and regioselectivity? Organic Chemistry Frontiers, 2019, 6: 1821-1831.
3. Chao-Xian Yan, Fang-Ling Yang, Ka Lu, and Pan-Pan Zhou. Organocatalytic Diels-Alder Reactions: Theoretical Perspective. General Chemistry, 2019, 5: 190014.
4. Chao-Xian Yan, Pan-Pan Zhou, Fang-Ling Yang, Rui-Zhi Wu, Xing Yang, Fan Yang and Xiangfeng Shao. Chiral bisoxazoline catalyzed decarboxylative aldol reactions between β-carbonyl acids and trifluoroacetaldehyde hemiacetals as well as trifluoroacetaldehyde: the mechanism, the origin of enantioselectivity and the role of a catalyst. Organic Chemistry Frontiers, 2018, 5: 2692-2709.
5. 閆超鹹, 楊帆, 吳睿智, 周大剛, 楊興, 周盼盼. 自然軌道福井函式和成鍵活性描述符套用於解釋苯硫醌和1,3-二烯的[2+4]和[4+2]環加成反應中的成鍵機理. 物理化學學報, 2018, 34: 497-502.
6. Chao-Xian Yan, Fan Yang, Xing Yang, Da-Gang Zhou, and Pan-Pan Zhou. Insights into the Diels-Alder Reaction between 3‑Vinylindoles and Methyleneindolinone without and with the Assistance of HydrogenBonding Catalyst Bisthiourea: Mechanism, Origin of Stereoselectivity, and Role of Catalyst. Journal of Organic Chemistry, 2017, 82: 3046-3061.
7. Shitao Wang, Chaoxian Yan, Jihai Shang, Wenbo Wang, Chengshan Yuan, Hao-Li Zhang, and Xiangfeng Shao. Doping sumanene with both chalcogens and phosphorus(V): Onestep synthesis, coordination, and selective response toward AgI. Angewandte Chemie International Edition, 2019, 58: 3819-3823.
8. Dawei Cao, Chaoxian Yan, Panpan Zhou, Huiying Zeng and Chao-Jun Li. Hydrogen bonding promoted simple and clean photo-induced reduction of C-X bond with isopropanol. Chemical Communications, 2019, 55: 767-770.
9. Xinming Li, Baoxin Zhang, Chaoxian Yan, Jin Li, Song Wang, Xiangxu Wei, Xiaoyan Jiang, Panpan Zhou and Jianguo Fang. A fast and specific fluorescent probe for thioredoxin reductase that works via disulphide bond cleavage. Nature Communications, 2019, 10: 1-12.
10. Jibin Sun, Yantao Sun, Chaoxian Yan, Dongxu Lin, Zheng Xie, Shuyun Zhou, Chengshan Yuan, Hao-Li Zhang and Xiangfeng Shao. Remarkable nonlinear optical response of pyrazinefused trichalcogenasumanenes and their application for optical power limiting. Journal of Material Chemistry C, 2018, 6: 13114-13119.
