基本介紹
- 中文名：鄭和根
- 國籍：中國
- 民族：漢
- 出生地：安徽太湖
- 出生日期：1965年2月
- 職業：教師
- 畢業院校：南京大學
教育經歷,工作簡歷,學術獎勵,主研方向,代表性論文,
教育經歷
2003 - 2004年，台灣中央研究院化學所訪問學者
1999 - 2000年，日本北海道大學博士後
1997 - 1998年，香港科技大學訪問學者
1995 - 1998年，南京大學博士學位
1990 - 1992年，鄭州大學碩士學位
1983 - 1987年，安徽師範大學學士學位
工作簡歷
2005 -Current，南京大學教授，博士生導師
2000 - 2005年，南京大學副教授
1992 - 1994年，安徽師範大學講師
學術獎勵
"教育部提名國家科學技術獎自然科學獎"一等獎(第三完成人)
主研方向
1.敏化染料太陽能電池（Dye Sensitized Solar Cell）
合理設計、簡便合成新型高效率染料，並對電池器件中電子的界面轉移過程進行詳細研究，最終得到具有自主智慧財產權的高效率、低成本、長壽命的染料敏化太陽能電池。
2.原子簇化學（Cluster Chemistry）
以原子簇為節點，設計合適的配體和原子簇，通過自組裝合成得到一些高核高維度的具有新奇結構的原子簇配位聚合物，並對其溶致變色效應、吸附性能、催化性能以及光學性能進行研究探討，從中篩選出一些具有重要套用前景的原子簇配位聚合物。
3.配位聚合物化學（Coordination Chemistry）
以單個金屬離子為節點，設計合適的配體和過渡金屬結合，形成結構新穎的配位聚合物，研究它們的催化活性、氣體吸附與分離、分子/離子識別等性能，探索其在合成、能源儲存、分子/離子探針、分子器件等方面的套用。
代表性論文
1. Xiangjing Gao, Guohao Sun, Fayuan Ge, Hegen Zheng*, Three Anionic Indium–Organic Frameworks for Highly Efficient and Selective Dye Adsorption, Lanthanide Adsorption, and Luminescence Regulation,Inorg. Chem. 2019, 58, 13, 8396-8407.
2. Mingdao Zhang, Quanbin Dai, Hegen Zheng*, Mindong Chen, and Liming Dai*, Novel MOF-Derived Co@N-C Bifunctional Catalysts for Highly Efficient Zn–Air Batteries and Water Splitting, Adv. Mater, 2018, 1705431.
3. Li-Juan Han, Dong Zheng, Shu-Guang Chen, He-Gen Zheng,* and Jing Ma*, A Highly Solvent-Stable Metal–Organic Framework Nanosheet: Morphology Control, Exfoliation, and Luminescent Property, Small 2018, 14, 1703873.
3. Zhong-Jie Wang, Li-Juan Han, Xiang-Jing Gao, and He-Gen Zheng*, Three Cd(II) MOFs with Different Functional Groups: Selective CO2 Capture and Metal Ions Detection, Inorg Chem., 2018, 57, 5232−5239.
4. Chuanlei Zhang, Yanle Li, Heng Xu, Jing Ma and Hegen Zheng*, The Mutation in the Single-Crystal Structural Transformation Process, Induced by the Combined Stimuli of Temperature and Solvent, Chem. Eur. J., 2018, 24, 327-331.
5. Ning-Ning Ji, Zhi-Qiang Shi,* Hai-Liang Hu* and He-Gen Zheng,* A triphenylamine-functionalized luminescent sensor for efficient p-nitroaniline detection, Dalton Trans., 2018, 47, 7222-7228.
6. Zhi-Zun Xiao, Li-Juan Han, Zhong-Jie Wang and He-Gen Zheng,* Three Zn(II)-based MOFs for luminescence sensing of Fe3+ and Cr2O72− ions, Dalton Trans., 2018, 47, 3298-3302.
7. Li-Juan Han, Wei Yan, Shu-Guang Chen, Zhen-Zhen Shi and Hegen Zheng*, Exploring the Detection of Metal Ions by Tailoring the Coordination Mode of V-Shaped Thienylpyridyl Ligand in Three MOFs, Inorg. Chem. 2017, 56, 2936−2940.
8. Wei Yan, Chuanlei Zhang, Shuguang Chen, Lijuan Han and Hegen Zheng*, Two Lanthanide Metal-Organic Frameworks as Remarkably Selective and Sensitive Bifunctional Luminescence Sensor for Metal Ions and Small Organic Molecules, ACS Appl. Mater. Interfaces 2017, 9, 1629-1634.
9. Zhenzhen Shi, Zhaorui Pan, Ling Qin, Jianliang Zhou, and Hegen Zheng*, Five New Transition Metal Coordination Polymers Based on V‑Shaped Bis-triazole Ligand with Aromatic Dicarboxylates: Syntheses, Structures, and Properties, Cryst. Growth Des. 2017, 17, 2757-2766.
10. Ling Qin, Hong-Zhe Chen, Jiang Lei, Yan-Qing Wang, Tong-Qi Ye, and Hegen Zheng*, Photodegradation of Some Organic Dyes over Two Metal−Organic Frameworks with Especially High Efficiency for Safranine T, Cryst. Growth Des. 2017, 17, 1293-1298.
11. Shuguang Chen, Zhenzhen Shi, Ling Qin, Hailang Jia, and Hegen Zheng*, Two New Luminescent Cd(II)-Metal−Organic Frameworks as Bifunctional Chemosensors for Detection of Cations Fe3+, Anions CrO42−, and Cr2O72− in Aqueous Solution, Cryst. Growth Des. 2017, 17, 67-72.
12. Kang Shen, Zemin Ju, Ling Qin, Ting Wang, He-Gen Zheng*, Two stable 3D porous metal-organic frameworks with high selectivity for detection of PA and metal ions, Dyes and Pigments, 2017, 136, 515-521.
13. Shuguang Chen, Hailang Jia, Mengxi Zheng, Kang Shen and Hegen Zheng*, Insight into the effects of modifying p-bridges on the performance of dye-sensitized solar cells containing triphenylamine dyes, Phys. Chem. Chem. Phys., 2016, 18, 29555-29560.
14. Hai-Lang Jia, Ming-Dao Zhang, Wei Yan, Xue-Hai Ju and He-Gen Zheng*, Effects of structural optimization on the performance of dye-sensitized solar cells: spirobifluorene as a promising building block to enhance Voc. J. Mater. Chem. A, 2016, 4, 11782-11788.
15. Wei Yan, Li-Juan Han, Hai-Lang Jia, Kang Shen, Ting Wang, and He-Gen Zheng*, Three Highly Stable Cobalt MOFs Based on "Y"-Shaped Carboxylic Acid: Synthesis and Absorption of Anionic Dyes, Inorg. Chem., 2016, 55, 8816-8821.
17. Zhong-Jie Wang, Ling Qin, Jin-Xi Chen, and He-Gen Zheng*, H-Bonding Interactions Induced Two Isostructural Cd(II) Metal−Organic Frameworks Showing Different Selective Detection of Nitroaromatic Explosives, Inorg. Chem., 2016, 55, 10999-11005.
18. Qingxiang Yang, Shuangshuang Ren, Ying Hao, Qianqian Zhao, Zhijun Chen* and Hegen Zheng*, Cyclopentaneteracarboxylic Metal−Organic Frameworks: Tuning the Distance between Layers and Pore Structures with N-Ligands, Inorg. Chem., 2016, 55, 4951-4957.
19. Chuan-Lei Zhang, Yan-Le Li, Ting Wang, Ze-Min Ju, He-Gen Zheng* and Jing Ma*, Three different metal–organic frameworks derived from a one-pot crystallization and their controllable synthesis, Chem. Commun., 2015, 51, 8338-8341.
20. Zhi-Qiang Shi, Zi-Jian Guo and He-Gen Zheng*, Two luminescent Zn(II) metal–organic frameworks for exceptionally selective detection of picric acid explosives, Chem. Commun., 2015, 51, 8300-8303.
21. Jin-Song Hu, Lei Zhang, Ling Qin, He-Gen Zheng* and Xiang-Biao Zhang,* A rare three-coordinated zinc cluster–organic framework with two types of secondary building units, Chem. Commun., 2015, 51, 2899-2902.
23. Ling Qin, Mengxi Zheng, Zijian Guo, Hegen Zheng* and Yan Xu,* One Non-interpenetrated Chiral Porous Multifunctional Metal–Organic Framework and Its Applications for Sensing Small Solvent Molecules and Adsorption, Chem. Commun., 2015, 51, 2447-2449.
24. Hai-Lang Jia, Ming-Dao Zhang, Ze-Min Ju, He-Gen Zheng* and Xue-Hai Ju,* Picolinic acid as an efficient tridentate anchoring group adsorbing at Lewis acid sites and Brønsted acid sites of the TiO2surface in dye-sensitized solar cells, J. Mater. Chem. A, 2015, 3, 14809-14816.
25. Qingxiang Yang, Zhijun Chen, Jinsong Hu, Ying Hao, Yizhi Li, Qingyi Lu and He-Gen Zheng*, A second-order nonlinear optical material with a hydrated homochiral helix obtained via spontaneous symmetric breaking crystallization from an achiral ligand, Chem. Commun., 2013, 49(34), 3585-3587.
26. Jiehu Cui, Yizhi Li, Zijian Guo and Hegen Zheng*, A porous metal–organic framework based on Zn6O2clusters: chemical stability, gas adsorption properties and solvatochromic behavior, Chem. Commun., 2013, 49, 555-557.
27. Ling Qin, Jin-Song Hu, Ming-Dao Zhang, Zi-Jian Guo and He-Gen Zheng,* Structure–property relationship of homochiral and achiral supramolecular isomers obtained by one-pot synthesis, Chem. Commun., 2012, 48, 10757-10759.
28. Qingxiang Yang, Xingqiu Chen, Zhijun Chen, Ying Hao, Yizhi Li, Qingyi Lu and Hegen Zheng,* Metal–organic frameworks constructed from flexible V-shaped ligands: adjustment of the topology, interpenetration and porosity via a solvent system, Chem. Commun., 2012, 48, 10016-10018.
29. Jiehu Cui, Zhenzhong Lu, Yizhi Li, Zijian Guo and Hegen Zheng*, A microporous metal–organic framework with FeS2topology based on [Zn6(µ6-O)] cluster for reversible sensing of small molecules, Chem. Commun., 2012, 48, 7967-7969.
30. Jin-Song Hu, Ling Qin, Ming-Dao Zhang, Xiao-Qiang Yao, Yi-Zhi Li, Zi-Jian Guo, He-Gen Zheng,* Zi-Ling Xue, Three self-penetrated, interlocked, and polycatanated supramolecular isomers via one-pot synthesis and crystallization, Chem. Commun., 2012, 48, 681-683.
31. Zhen-Zhong Lu, Rui Zhang, Zhao-Rui Pan, Yi-Zhi Li, Zi-Jian Guo, He-Gen Zheng,* Metal-Organic Frameworks Constructed by Versatile (WS4Cux)x-2Units: Micropores in the Highly interpenetrated System, Chem, Eur. J., 2012, 18, 2812-2824.
32. Zhen-Zhong Lu, Rui Zhang, Yi-Zhi Li, Zi-Jian Guo, and He-Gen Zheng,* Solvatochromic Behavior of a Nanotubular Metal-Organic Framework for Sensing Small Molecules, J. Am. Chem. Soc., 2011, 133, 4172-4174.
33. Xiao-Qiang Yao, Zhao-Rui Pan, Jin-Song Hu, Yi-Zhi Li, Zi-Jian Guo and He-Gen Zheng,* The rational synthesize of (10,3)-type MOFs based on tetraunclear [W(Mo)OS3Cu3]+ secondary building units, Chem. Commun., 2011, 47, 10049.
34. Zhen-Zhong Lu, Rui Zhang, Yi-Zhi Li, Zi-Jian Guo, He-Gen Zheng,* [WS4Cu3I2]–and [WS4Cu4]2+Secondary Building Units Formed Metal-Organic Framework: Large Tubes in Highly Interpenetrated System, Chem. Commun., 2011, 47, 2919-2921.
