趙建章(大連理工大學教師):主要經歷,社會兼職,研究領域及課題,在研工作,碩博研究

趙建章，男，大連理工大學教師。吉林大學化學系理學博士，浦項理工大學博士後，德國馬普研究所博士後，英國巴斯大學化學系高級研究人員。

2005年7月就職於大連理工大學化工學院。

基本介紹

中文名：趙建章
國籍：中國
民族：漢
職業：大連理工大學教師
性別：男

主要經歷,社會兼職,研究領域及課題,在研工作,碩博研究方向,工作成果,出版著作和論文,工作成果（獎勵、專利等）,

主要經歷

1996-2000年, 吉林大學化學系工作；

2000年, 吉林大學化學系獲理學博士學位；

2000-2001年, 韓國國立智慧型超分子創新研究中心（浦項理工大學），博士後；

2001-2003年, 德國馬普研究所（蛋白質摺疊的酶學），博士後；

2003-2005年, 英國巴斯大學化學系，高級研究人員(Research Officer)；

2005年7月起在大連理工大學化工學院工作。

先後獲得國家自然科學基金委主任基金以及面上項目(20634040, 20972024, 21073028); 教育部新世紀優秀人才支持計畫(NCET-08-0077), 教育部博士點基金(200801410004), 英國皇家學會(RS)-NSFC聯合資助項目(21011130154), 英國皇家學會(RS)-國家留學基金管理委員會聯合資助項目; 瑞士-中國科技合作項目(EG21-092011), 愛爾蘭科學基金會E.T.S. Walton訪問學者(11/W.1/E2061)等項目的資助。

社會兼職

『遼寧師範大學學報』特約編委。曾為Angew. Chem. Int. Ed., Adv. Funct. Mater., Acc. Chem. Res., Chem. Eur. J., J. Org. Chem., J. Mater. Chem., Dalton Trans., Chem. Commun., New. J. Chem., J. Phys. Chem. 等期刊審稿80餘篇。此外審理國家自然科學基金申請、博士點基金申請等50餘項。

研究領域及課題

主要研究方向是分子光化學與光物理，主要從事螢光分子探針和磷光金屬配合物的研究。曾研究了基於2,4-二硝基磺醯基的巰基化合物螢光探針，以及用於檢測葡萄糖、酒石酸和扁桃酸等的硼酸探針。此外設計並製備具有強可見光吸收能力、長激發態壽命的Ru(II), Pt(II) 和Ir(III) 等過渡金屬配合物，這些金屬配合物可用於光伏、光催化、光動力治療等領域。研究結果被Dalton Trans. 選為內封面論文（兩篇），被Eur. J. Inorg. Chem. 選為封面論文，被Chem. Comm., PCCP以及J. Mater. Chem.等期刊選為封底論文（Back Cover，共6篇封面、封底論文），部分研究成果已被Nature China、Chem. Eur. J. 進行了專題介紹。國際知名科技網站對設計合成的具有強可見光吸收、長三重激發態壽命的配合物的合成和性質研究做了介紹。

研究工作涉及合成化學、光譜測試與套用研究。主要使用各種穩態與瞬態光譜對所製備的化合物的性質進行表征，如紫外-可見吸收光譜，分子螢光以及磷光光譜，低溫光譜(77 K), 以及納秒時間分辨瞬態吸收光譜（雷射閃光光解）。此外，系統將理論化學計算（DFT方法）用於化合物光物理性質的研究（如預測發光性質）。所製備的化合物可用於葡萄糖、酒石酸、扁桃酸、半胱氨酸等的檢測，以及發光法氧感測、三重態-三重態湮滅上轉換、光動力治療等。

在研工作

正在進行的研究工作包括：

1、提出了硼酸螢光探針的d-PET機理。與常見的a-PET機理的硼酸螢光探針不同，在d-PET機理的硼酸探針中，螢光基團做為光誘導電子轉移的電子給體。d-PET機理的螢光探針的螢光性質與傳統的a-PET探針的性質有很大不同，克服了傳統a-PET探針的某些局限、缺點；

2、系統地將理論化學計算套用於螢光探針的研究，預測、解釋螢光探針的螢光變化；提出用“態”的概念，而非分子軌道的概念，來解釋螢光探針的螢光性質，並已通過實例驗證了該概念；提出使用“暗態”的概念來解釋螢光探針的螢光開關效應(OFF-ON)。不發光的探針往往具有暗態（通常指S1激發態，S1->S0為禁阻躍遷，為非輻射躍遷），所以無螢光；探針與底物作用後，第一激發態的性質發生變化，S1態轉變為發射態（emissive state）, 所以會觀察到螢光增強。暗態和發射態的判斷依據是DFT計算的結果；

3、初步提出了使有機分子三重激發態得到布居的新方法，比如使用light-harvesting antenna 和分子內自旋轉換單元相結合的方法，可以靈活設計不含重原子、分子結構靈活可調、系間竄越(ISC)可預測的新型三重態光敏劑；

4、初步提出具有強可見光吸收能力、長壽命三重激發態的過渡金屬配合物的設計原則，即有機吸光配體的直接金屬化、或配體的能級必須與金屬配位中心的能級（MLCT激發態）匹配，並已通過實例驗證；

5、提出使用具有較長壽命的3IL激發態用於三重態-三重態湮滅上轉換，與傳統的MLCT激發態相比，提高了上轉換量子效率；此外，我們提出使用具有暗態的配合物進行上轉換，而現有的三重態敏化劑大多是發磷光的配合物。實際上敏化劑的磷光對上轉換不利。這些新的概念將提高TTA上轉換的效率、拓寬三重態敏化劑的選擇範圍；

6、我們提出使用有機三重態敏化劑取代傳統的、價格較貴的過渡金屬配合物三重態敏化劑，進行上轉換研究，並已通過製備BODIPY衍生得到敏化劑庫（library）予以了驗證。該敏化劑庫的合成，開啟了TTA 上轉換的三重態敏化劑由金屬配合物到有機化合物的轉變，與染料敏化太陽能電池（DSCs）中使用的敏化劑的發展所經歷的轉變類似，但更具挑戰性。

7、提出使用FRET(螢光共振能量轉移)作用，使用兩個以上的發色團，製備具有寬譜帶吸收的有機三重態光敏劑，克服了以往三重態光敏劑只含單一發色團、吸收譜帶較窄的局限；並使用飛秒、納秒時間分辨瞬態吸收光譜對該類多發色團化合物的光物理進行了詳細研究。

8、系統研究了分子三重激發態的調控途徑。

本課題組有合成化學實驗室（共十一個通風櫥），以及總價值120多萬元的光譜儀器設備，可進行穩態與瞬態光譜研究，如島津2550紫外-可見吸收光譜儀、安捷倫8453紫外-可見-近紅外吸收光譜儀，島津RF5301PC螢光光譜儀（紅敏檢測器）、FS5螢光光譜儀（光子計數檢測方式，信噪比>5000:1）、CRT 970 螢光光譜儀（經改裝，適於做氧感測、上轉換等研究工作）、牛津Optistat DN低溫光學杜瓦（77 K - 300 K，可控變溫）、不同輸出波長的二極體泵浦固體雷射器（DPSSL，5台）、OB 920 螢光/磷光壽命測定儀（Edinburgh Instruments. 可測發光壽命範圍ps - s）、用於理論化學計算的雙路八核伺服器（32執行緒。四台）、Gaussian 09W軟體、以及自行組裝的一些儀器設備（包括小型化的微秒時間分辨磷光壽命測定儀、發光法氧感測測試用流通池、光氧化反應線上光譜檢測裝置）；LP980 納秒時間分辨瞬態吸收光譜儀（雷射閃光光解，Edinburgh Instruments)。通過與國內外課題組的合作，還可利用飛秒時間分辨的瞬態吸收光譜對分子內能量轉移和電子轉移等光物理過程進行研究。

在精細化工、套用化學專業招生。畢業生就業去向：985/211等高校任教師（湘潭大學、四川大學、河北師範大學、中國石油大學等）、國家知識產權局（北京）、中石化勘查設計研究院（北京）、藥明康德新藥開發有限公司（天津、上海）、中石油新疆油田分公司（克拉瑪依）、青島海爾股份有限公司等；以及到國外讀博士、博士後（愛爾蘭、韓國、新加坡、澳大利亞、德國）、訪問博士生（瑞士、愛爾蘭、美國）等等。

碩博研究方向

分子光化學與光物理（涵蓋合成化學，穩態與瞬態光譜，理論化學計算，基礎套用研究等）。

工作成果

所培養的學生曾獲得教育部博士生學術新人獎（籍少敏，2010年）；遼寧省自然科學學術成果特等獎（學術論文類，2011年，籍少敏）；遼寧省自然科學學術成果一等獎（學術論文類，2011年，張欣）；大連市自然科學優秀學術論文特等獎（2011年，籍少敏）；遼寧省優秀畢業生（3人次）；大連理工大學優秀研究生（20人次）；大連理工大學中凱化學獎學金（2人次）、大連理工大學昭和電工獎學金（2人次）；大連理工大學贏創獎學金（3人次），等等。

出版著作和論文

155. Thiol-Activatable Triplet-Triplet Annihilation Upconversion with Maleimide-Perylene as the Caged Triplet Acceptor/Emitter.

Zafar Mahmood and Jianzhang Zhao.*

J. Org. Chem., 2015, Just Accepted.

154. Maximizing the Thiol-Activated Photodynamic and Fluorescence Imaging Functionalities of Theranostic Reagents by Modularization of the Bodipy-based Dyad Triplet Photosensitizers.

Jianzhang Zhao,* Ling Huang, Xiaoneng Cui, Shujing Li and Huijian Wu.*

J. Mater. Chem. B, 2015, 3, 9194–9211.

153. Triplet Excited State of Bodipy: Formation, Modulation and Application.

Jianzhang Zhao,* Kejing Xu, Wenbo Yang, Zhijia Wang and Fangfang Zhong.

Chem. Soc. Rev., 2015, 44, 8904–8939.

152. Controlling Triplet-Triplet Annihilation Upconversion by Tuning the PET in Aminomethyleneanthracene Derivatives.

Kejing Xu, Jianzhang Zhao,* Daniel Escudero, Zafar Mahmood and Denis Jacquemin.*

J. Phys. Chem. C, 2015, 119, 23801–23812.

151. Accessing the Long-lived Triplet Excited States in Transition Metal Complexes: Molecular Designing Rationales and Applications

Xiaoneng Cui, Jianzhang Zhao,* Zafar Mohmood and Caishun Zhang.

Chemical Record, 2015, in press. Invited Review (Personal Account).

150. Visible Light-harvesting Tricarbonyl Re(I) Complex: Synthesis and Application in Intracellular Photodynamic Effect and Luminescence Imaging.

Fangfang Zhong, Xiaolin Yuan, Jianzhang Zhao* and Quan Wang.

Science China: Chemistry. 2015, accepted. Invited article for special issue of 'Chemical/Biological Sensors and Imaging'. Edited by Prof. Shu Wang and Prof. Yu Fang.

149. Chiral Recognition Using Fluorescent Boronic Acids Chemosensors.

Poulomi Majumdar, Caishun Zhang and Jianzhang Zhao.*

Invited book chapter in 'Boron: Sensing, Synthesis and Supramolecular Self-Assembly'. RSC book, 2015, Edited by Prof. Tony James, John Fossey and Meng Li. In press.

148. Triplet–Triplet Energy Transfer Study in Hydrogen Bonding Systems.

Zhijia Wang, Jianzhang Zhao* and Song Guo.

Chimia, 2015, 69, 524–529. Supramolecular Chemistry Special Issue (Edited by Prof. Bruno Therrien), Invited Article.

147. Broadband Visible Light-Harvesting Triplet Photosensitizers.

Jianzhang Zhao.*

European Photochemistry Association (EPA) News Letter, June 2015, No. 88, Page 13–19. Invited Review Article.

146. H2O2-activated Triplet–triplet Annihilation Upconversion via Modulation of the Fluorescence Quantum yields of the Triplet Acceptor and the Triplet–triplet-energy-transfer Efficiency.

Renjie Tao, Jianzhang Zhao,* Fangfang Zhong, Caishun Zhang, Wenbo Yang and Kejing Xu.

Chem. Commun., 2015, 51, 12403–12406.

145. Broadband N^N Pt(II) Bisacetylide Visible Light-Harvesting Complex with Heteroleptic Bodipy Acetylide Ligands.

Fangfang Zhong, Ahmet Karatay, Liang Zhao, Jianzhang Zhao,* Cheng He, Caishun Zhang, Halime Gul Yaglioglu, Ayhan Elmali, Betül Kücükz and Mustafa Hayvalic.*

Inorg. Chem., 2015, 54, 7803–7817.

144. Application of Singlet Energy Transfer in Triplet State Formation: Broadband Visible light-Absorbing Triplet Photosensitizers, Molecular Structure Design, Related Photophysics and Applications.
Xiaoneng Cui, Caishun Zhang, Kejing Xu and Jianzhang Zhao.*
J. Mater. Chem. C, 2015, 3, 8735–8759. Invited Review Article.
143. Preparation of Bodipy-Ferrocene Dyads and Modulation of the Singlet/Triplet Excited State of Bodipy via Electron Transfer and Triplet Energy Transfer.
Xueyan Wu, Wenting Wu, Xiaoneng Cui, Jianzhang Zhao* and Mingbo Wu.*
J. Mater. Chem. C., 2015, in press. Shape-Responsive Fluorophores Special Issue. Edited by Prof. Benzong Tang and Prof. Kyril Solntsev. Invited Article.
142. Near–IR Broadband Absorbing Trans Bisphosphine Pt(II) Bisacetylide Complexes: Preparation and Study of the Photophysics.
Wenbo Yang, Ahmet Karatay, Jianzhang Zhao,* Jian Song, Liang Zhao, Yongheng Xing,* Caishun Zhang, Cheng He, Halime Gul Yaglioglu, Mustafa Hayvali,* Ayhan Elmali, and Betül Kücükoz.
Inorg. Chem., 2015, 54, 7492–7505.
141. Diiodobodipy-styrylbodipy Dyads: Preparation and Study of the Intersystem Crossing and Fluorescence Resonance Energy Transfer.
Zhijia Wang, Yun Xie, Kejing Xu, Jianzhang Zhao* and Ksenija D. Glusac.*
J. Phys. Chem. A 2015, 119, 6791–6806.
140.Thiol-Activated Triplet–Triplet Annihilation Upconversion: Study of the Different Quenching Effect of Electron Acceptor on the Singlet and Triplet Excited States of Bodipy.
Caishun Zhang, Jianzhang Zhao,* Xiaoneng Cui, and Xueyan Wu.
J. Org. Chem. 2015, 80, 5674–5686.
139. Book Chapter: Organometallics and Related Molecules for Energy Conversion. Springer, 2015 (Edited By Wai-Yeung Wong). Chapter 7, Page 171-206. Visible Light-Harvesting Transition Metal Complexes for Triplet–Triplet Annihilation Upconversion. By Poulomi Majumdar and Jianzhang Zhao*.
138. Molecular Structure-Intersystem Crossing Relationship of Heavy Atom-Free BODIPY Triplet Photosensitizers.
Shaomin Ji,* Jie Ge, Daniel Escudero, Zhijia Wang, Jianzhang Zhao,* and Denis Jacquemin.*
J. Org. Chem., 2015, 80, 5958–5963.
137. Broadband Visible Light-Harvesting Naphthalenediimide (NDI) Triad: Study of the Intra-/Intermolecular Energy/Electron Transfer and the Triplet Excited State.
Shuang Wu, Fangfang Zhong, Jianzhang Zhao,* Song Guo, Wenbo Yang and Tom Fyles.
J. Phys. Chem. A, 2015, 119, 4787–4799.
136. Bodipy-C60 Triple Hydrogen Bonding Assembly as Heavy Atom-Free Triplet Photosensitizers: Preparation and Study of the Singlet/Triplet Energy Transfer.
Song Guo, Liang Xu, Kejing Xu, Jianzhang Zhao,* Betül Kü?ük?z, Ahmet Karatay, Gul Yaglioglu, Mustafa Hayvali, Ayhan Elmali.
Chem. Sci., 2015, 6, 3724–3737.
135. DiiodoBodipy-Perylenebisimide Dyad/Triad: Preparation and Study of the Intramolecular and Intermolecular Electron/Energy Transfer.
Zafar Mahmood, Kejing Xu, Betül Kücükoz, Xiaoneng Cui, Jianzhang Zhao,* Zhijia Wang, Ahmet Karatay, Halime Gul Yaglioglu, Mustafa Hayvali,* and Ayhan Elmali.
J. Org. Chem., 2015, 80, 3036–3049.
134. DiiodoBodipy-Rhodamine Dyads: Preparation and Study of the Acid-Activatable Competing Intersystem Crossing and Energy Transfer Processes.
Kejing Xu, Yun Xie, Xiaoneng Cui, Jianzhang Zhao* and Ksenija D. Glusac.*
J. Phys. Chem. B, 2015, 119, 4175–4187.
133. Synergetic effect of C*N^N/C^N^N coordination and the arylacetylide ligands on the photophysical properties of cyclometalated platinum complexes.
Wenting Wu, Xueyan Wu, Jianzhang Zhao* and Mingbo Wu.*
J. Mater. Chem. C, 2015, 3, 2291–2301.
132. Switching of the photophysical properties of Bodipy-derived trans bis(tributylphosphine) Pt(II) bisacetylide complexes with rhodamine as the acid-activatable unit.
Poulomi Majumdar, Xiaoneng Cui, Kejing Xu and Jianzhang Zhao.*
Dalton Trans., 2015, 44, 4032–4045.
131. Switching of the Triplet-Triplet-Annihilation Upconversion with Photoresponsive Triplet Energy Acceptor: Photocontrollable Singlet/Triplet Energy Transfer and Electron Transfer.
Kejing Xu, Jianzhang Zhao,* Xiaoneng Cui, and Jie Ma.
J. Phys. Chem. A, 2015, 119, 468–481.
130. 2-(2-Hydroxyphenyl)-benzothiazole (HBT)-Rhodamine Dyad: Acid-switchable Absorption and Fluorescence of Excited-State Intramolecular Proton Transfer (ESIPT).
Poulomi Majumdar and Jianzhang Zhao.*
J. Phys. Chem. B, 2015, 119, 2384–2394. ESIPT special Issue.
129. Photoswitching of triplet–triplet annihilation upconversion showing large emission shifts using a photochromic fluorescent dithienylethene-Bodipy triad as a triplet acceptor/emitter.
Kejing Xu, Jianzhang Zhao,* Xiaoneng Cui and Jie Ma.
Chem. Commun., 2015, 51, 1803–1806.
128. Switching of the Triplet Excited State of Rhodamine/Naphthaleneimide Dyads: An Experimental and Theoretical Study.
Xiaoneng Cui, Jianzhang Zhao,* Zhangrong Lou, Shujing Li, Huijian Wu* and Ke-li Han.*
J. Org. Chem., 2015, 80, 568–581.
127. Switch the triplet excited state of the C60-dimethylaminostyryl bodipy dyads/triads.
Ling Huang and Jianzhang Zhao.*
J. Mater. Chem. C., 2015, 3, 538–550.
126. Switching of the Triplet Excited State of Rhodamine-C60 Dyads.
Fen Wang, Xiaoneng Cui, Zhangrong Lou, Jianzhang Zhao,* Ming Bao and Xingwei Li.*
Chem. Commun., 2014, 50, 15627–15630.
125. Photoswitching of the Triplet Excited State of DiiodoBodipy-Dithienylethene Triads and Application in Photo-Controllable Triplet-Triplet Annihilation Upconversion.
Jie Ma, Xiaoneng Cui, Fen Wang, Xueyan Wu, Jianzhang Zhao* and Xingwei Li.*
J. Org. Chem., 2014, 79, 10855–10866.
124. Switching of the Triplet Excited State of Styryl 2,6-Diiodo-Bodipy and Its Application in Acid-Activatable Singlet Oxygen Photosensitizing.
Ling Huang, Wenbo Yang, and Jianzhang Zhao.*
J. Org. Chem., 2014, 79, 10240–10255.
123. Trans bis(alkylphosphine) platinum(II)-alkynyl complexes showing broadband visible light absorption and long-lived triplet excited states.
Huiru Jia, Betül Kü?ük?z, Yongheng Xing, Poulomi Majumdar, Caishun Zhang, Ahmet Karatay, Gul Yaglioglu, Ayhan Elmali, Jianzhang Zhao,* and Mustafa Hayvali.*
J. Mater. Chem. C, 2014, 2, 9720–9736.
122. Broadband Visible-Light-Harvesting trans-Bis(alkylphosphine) Platinum(II)-Alkynyl Complexes with Singlet Energy Transfer between BODIPY and Naphthalene Diimide Ligands.
Lianlian Liu, Song Guo, Jie Ma, Kejing Xu, Jianzhang Zhao,* and Tierui Zhang.*
Chem. Eur. J. 2014, 20, 14282 – 14295. Inside Cover Paper. Hot Paper.
121. The effect of the regioisomeric naphthalimide acetylide ligands on the photophysical properties of N^N Pt(II) bisacetylide complexes.
Lianlian Liu, Caishun Zhang and Jianzhang Zhao*
Dalton Trans., 2014, 43, 13434-13444.
120. 具有強可見光吸收的富勒烯-Bodipy衍生物做為光催化劑在硫醚光催化氧化中的套用。
黃靈，趙建章.*
影像科學與光化學, 2014, 32, 471-483. 光化學反應專刊。所製備的有機光催化劑分子結構被選為封面圖片.
119. Photoredox catalytic organic reactions promoted with broadband visible light-absorbing Bodipyiodo-aza-Bodipy triad photocatalyst.
Song Guo, Renjie Tao and Jianzhang Zhao*
RSC Adv., 2014, 4, 36131-36139
118. Reversible Photoswitching of Triplet-Triplet Annihilation Upconversion Using Dithienylethene Photochromic Switches.
Xiaoneng Cui, Jianzhang Zhao,* Yuhan Zhou, Jie Ma and Yilong Zhao.
J. Am. Chem. Soc. 2014, 136, 9256-9259.
117. Resonance energy transfer-enhanced rhodamine–styryl Bodipy dyad triplet photosensitizers.
Jie Ma, Xiaolin Yuan, Betul Kucukoz, Shengfu Li, Caishun Zhang, Poulomi Majumdar, Ahmet Karatay, Xiaohuan Li, H. Gul Yaglioglu, Ayhan Elmali, Jianzhang Zhao* and Mustafa Hayvali.*
J. Mater. Chem. C, 2014, 2, 3900–3913. Cover Paper.
116. Activatable triplet photosensitizers: magic bullets for targeted photodynamic therapy.
Poulomi Majumdar, Raju Nomula and Jianzhang Zhao.*
J. Mater. Chem. C, 2014, 2, 5982–5997. Feature Article (Invited Review).
115. Cyclometalated Ir(III) complexes with styryl-BODIPY ligands showing near IR absorption/emission: preparation, study of photophysical properties and application as photodynamic/luminescence imaging materials.
Poulomi Majumdar, Xiaolin Yuan, Shengfu Li, Boris Le Guennic, Jie Ma, Caishun Zhang, Denis Jacquemin and Jianzhang Zhao.*
J. Mater. Chem. B, 2014, 2, 2838–2854.
114. Perylene-Derived Triplet Acceptors with Optimized Excited State Energy Levels for Triplet-Triplet Annihilation Assisted Upconversion.
Xiaoneng Cui, Azzam Charaf-Eddin, Junsi Wang, Boris Le Guennic, Jianzhang Zhao,* and Denis Jacquemin.*
J. Org. Chem. 2014, 79, 2038-2048
113. Strongly emissive long-lived 3IL excited state of coumarins in cyclometalated Ir(III) complexes used as triplet photosensitizers and application in triplet–triplet annihilation upconversion.
Xiuyu Yi, Caishun Zhang, Song Guo, Jie Ma and Jianzhang Zhao.*
Dalton Trans., 2014, 43, 1672–1683
112. BODIPY triads triplet photosensitizers enhanced with intramolecular resonance energy transfer (RET): broadband visible light absorption and application in photooxidation.
Song Guo, Lihua Ma, Jianzhang Zhao,* Betul Kucukoz, Ahmet Karatay, Mustafa Hayvali,* H. Gul Yaglioglu and Ayhan Elmali.
Chem. Sci., 2014, 5, 489–500. Back Cover Paper.
111. 含區位異構氨基萘醯亞胺配體的環Ir 配合物三重態光敏劑的合成、光物理性質以及在三重態湮滅上轉換中的套用.
馬麗花, 郭頌, 趙建章,* 郭慧敏.*
科學通報, 2014，59, 1655- 1666. 封面論文。光電功能配合物專輯。
110. Intramolecular RET Enhanced Visible Light-Absorbing Bodipy Organic Triplet Photosensitizers and Application in Photooxidation and Triplet-Triplet Annihilation Upconversion
Caishun Zhang, Jianzhang Zhao,* Shuo Wu, Zilong Wang, Wanhua Wu, Jie Ma, Song Guo and Ling Huang.
J. Am. Chem. Soc. 2013, 135, 10566-10578.
109. Hetero Bodipy-dimers as heavy atom-free triplet photosensitizers showing a long-lived triplet excited state for triplet–triplet annihilation upconversion.
Wanhua Wu, Xiaoneng Cui and Jianzhang Zhao.*
Chem. Commun., 2013, 49, 9009-9011.
108. Porous material-immobilized iodo-Bodipy as an efficient photocatalyst for photoredox catalytic organic reaction to prepare pyrrolo[2,1-a]isoquinoline.
Song Guo, Hongli Zhang, Ling Huang, Zhendong Guo, Guang Xiong* and Jianzhang Zhao*
Chem. Commun., 2013, 49, 8689-8691.
107. Zinc(II) tetraphenyltetrabenzoporphyrin complex as triplet photosensitizer for triplet–triplet annihilation upconversion.
Xiaoneng Cui, Jianzhang Zhao,* Pei Yang and Jifu Sun.
Chem. Commun., 2013, DOI: 10.1039/c3cc45843a
106. Energy-funneling Based Broadband Visible-Light Absorbing Bodipy-C60 Triads/Tetrads as Dual Functional Heavy Atom-free Organic Triplet Photosensitizers for Photocatalytic Organic Reactions.
Ling Huang, Xiaoneng Cui, Bruno Therrien and Jianzhang Zhao.*
Chem. Eur. J., 2013, 19, 17472-17482.
105. Iodo-Bodipys as visible-light-absorbing dual-functional photoredox catalysts for preparation of highly functionalized organic compounds by formation of C–C bonds via reductive and oxidative quenching catalytic mechanisms.
Ling Huang and Jianzhang Zhao.*
RSC Adv., 2013, 3, 23377–23388
104. Red-light-absorbing diimine Pt(II) bisacetylide complexes showing near-IR phosphorescence and long-lived 3IL excited state of Bodipy for application in triplet–triplet annihilation upconversion.
Wanhua Wu, Lianlian Liu, Xiaoneng Cui, Caishun Zhang and Jianzhang Zhao.*
Dalton Trans., 2013, 42, 14374–14379.
103. Observation of the room temperature phosphorescence of Bodipy in visible light-harvesting Ru(II) polyimine complexes and application as triplet photosensitizers for triplet–triplet-annihilation upconversion and
photocatalytic oxidation.
Wanhua Wu, Jifu Sun, Xiaoneng Cui and Jianzhang Zhao*
J. Mater. Chem. C, 2013, 1, 4577–4589.
102. Bodipy Derivatives as Organic Triplet Photosensitizers for Aerobic Photoorganocatalytic Oxidative Coupling of Amines and Photooxidation of Dihydroxylnaphthalenes.
Ling Huang, Jianzhang Zhao,* Song Guo, Caishun Zhang, and Jie Ma.
J. Org. Chem., 2013, 78, 5627–5637.
101. Observation of the long-lived triplet excited state of perylenebisimide (PBI) in C^N cyclometalated Ir(III) complexes and application in photocatalytic oxidation.
Jifu Sun, Fangfang Zhong and Jianzhang Zhao.*
Dalton Trans., 2013, 42, 9595–9605.
100. Triplet photosensitizers: from molecular design to applications.
Jianzhang Zhao,* Wanhua Wu, Jifu Sun and Song Guo.
Chem. Soc. Rev., 2013, 42 (12), 5323–5351. Review.
99. Visible light-harvesting trans bis(alkylphosphine) platinum(II)-alkynyl complexes showing long-lived triplet excited states as triplet photosensitizers for triplet–triplet annihilation upconversion.
Lianlian Liu, Dandan Huang, Sylvia M. Draper, Xiuyu Yi, Wanhua Wu and Jianzhang Zhao.*
Dalton Trans., 2013, 42, 10694–10706. Front Cover Paper.
98. C60-Bodipy dyad triplet photosensitizers as organic photocatalysts for photocatalytic tandem oxidation/[3+2] cycloaddition reactions to prepare pyrrolo[2,1-a]isoquinoline.
Ling Huang and Jianzhang Zhao.*
Chem. Commun., 2013, 49, 3751-3753.
97. Green light-excitable naphthalenediimide acetylide-containing cyclometalated Ir(III) complex with long-lived triplet excited states as triplet photosensitizers for triplet–triplet annihilation upconversion.
Lihua Ma, Song Guo, Jifu Sun, Caishun Zhang, Jianzhang Zhao* and Huimin Guo.*
Dalton Trans., 2013, 42, 6478-6488.
96. Preparation of ketocoumarins as heavy atom-free triplet photosensitizers for triplet–triplet annihilation upconversion.
Dandan Huang, Jifu Sun, Lihua Ma, Caishun Zhang and Jianzhang Zhao*
Photochem. Photobiol. Sci., 2013, 12, 872–882.
95. Efficient Enhancement of the Visible-Light Absorption of Cyclometalated Ir(III) Complexes Triplet Photosensitizers with Bodipy and Applications in Photooxidation and Triplet-Triplet Annihilation Upconversion.
Jifu Sun, Fangfang Zhong, Xiuyu Yi, and Jianzhang Zhao.*
Inorg. Chem., 2013, 52, 6299?6310. Front Cover Paper.
94. Visible light-absorbing rhenium(I) tricarbonyl complexes as triplet photosensitizers in photooxidation and triplet–triplet annihilation upconversion.
Xiuyu Yi, Jianzhang Zhao,* Jifu Sun, Song Guo and Hongli Zhang.
Dalton Trans., 2013, 42, 2062–2074.
93. Red-light excitable fluorescent platinum(II) bis(aryleneethynylene) bis(trialkylphosphine) complexes showing long-lived triplet excited states as triplet photosensitizers for triplet–triplet annihilation upconversion.
Wanhua Wu, Jianzhang Zhao,* Jifu Sun, Ling Huang and Xiuyu Yi.
J. Mater. Chem. C, 2013, 1, 705–716
92. Visible-Light Harvesting PtII Complexes as Singlet Oxygen Photosensitizers for Photooxidation of 1,5-Dihydroxynaphthalene.
Wenting Wu, Pei Yang, Lihua Ma, Jacques Lalevée and Jianzhang Zhao.*
Eur. J. Inorg. Chem. 2013, 228–231.
91. Visible light-harvesting cyclometalated Ir(III) complexes with pyreno[4,5-d] imidazole C^N ligands as triplet photosensitizers for tripletetriplet annihilation upconversion.
Xiuyu Yi, Pei Yang, Dandan Huang and Jianzhang Zhao.*
Dyes and Pigments 2013, 96, 104–115.
90. Tridentate cyclometalated platinum (II) complexes with strong absorption of visible light and long-lived triplet excited states as photosensitizers for triplet-triplet annihilation upconversion.
Wenting Wu, Dandan Huang, Xiuyu Yi and Jianzhang Zhao.*
Dyes and Pigments, 2013, 96, 220-231.
89. Visible light-harvesting naphthalenediimide (NDI)-C60 dyads as heavy-atom free organic triplet photosensitizers for tripletetriplet annihiation based upconversion.
Song Guo, Jifu Sun, Lihua Ma, Wenqin You, Pei Yang and Jianzhang Zhao.*
Dyes and Pigments, 2013, 96, 449-458.
88.Visible Light-Harvesting Triphenylamine EthynylC60-BODIPY Dyads as Heavy-Atom-Free Organic Triplet Photosensitizers for Triplet-Triplet Annihilation Upconversion.
Dandan Huang, Jianzhang Zhao,* Wanhua Wu, Xiuyu Yi, Pei Yang, and Jie Ma.
Asian J. Org. Chem. 2012, 1, 264-273. Front Cover Paper.
87. Fluorene as p-conjugation linker in N^N Pt (II) bisacetylide complexes and their applications for triplet triplet annihiation based upconversion.
Huimin Guo, Qiuting Li, Lihua Ma and Jianzhang Zhao.*
J. Mater. Chem., 2012, 22, 15757-15768. Back cover paper.
86. New excited state in tramolecular proton transfer (ESIPT) dyes based on naphtalimide and observation of long-lived triplet excited states.
Jie Ma, Jianzhang Zhao,* Pei Yang, Dandan Huang, Caishun Zhang and Qiuting Li.
Chem. Commun85. Using C60-Bodipy dyads that show strong absorption of visible light and longlived triplet excited states as organic triplet photosensitizers for triplet-triplet annihilation upconversion.
Pei Yang, Wanhua Wu, Jianzhang Zhao,* DandanHuang and Xiuyu Yi.
J. Mater. Chem., 2012, 22, 20273-20283.
84. Enhanced photooxidation sensitizers: the first examples of cyclometalated pyrene complexes of iridium (III).
Andrew J. Hallett, Nathan White, Wanhua Wu, Xiaoneng Cui, Peter N. Horton, Simon J. Coles, Jianzhang Zhao and Simon J. A. Pope.
Chem. Commun., 2012,48, 10838-10840.
83. Accessing the Long-Lived Triplet Excited States in Bodipy-Conjugated 2-(2-Hydroxyphenyl) Benzothiazole/Benzoxazoles and Applications as Organic Triplet Photosensitizers for Photooxidations.
Pei Yang, Jianzhang Zhao,* Wanhua Wu, Xuerong Yu and Yifan Liu.
J. Org. Chem., 2012, 77, 6166-6178.
82. Visible light-harvesting cyclometalated Ir (III) complexes as triplet photosensitizers
for triplet-triplet annihilation based upconversion.
Lihua Ma, Huimin Guo,* Qiuting Li, Song Guo and Jianzhang Zhao.*
Dalton Trans., 2012, 41, 10680-10689.
81. The development of triplet-triplet annihilation upconversion.
Wanhua Wu, Song Guo and Jianzhang Zhao.*
Scientia Sinica Chimica. 2012, 42, 1381–1398. (Invited review, Cover paper).
80. Light Harvesting Fullerene Dyads as Organic Triplet Photosensitizers for Triplet-triplet Annihilation Upconversions.
Wanhua Wu, Jianzhang Zhao,* Jifu Sun and Song Guo.
J. Org. Chem., 2012, in press.
79. Visible light-harvesting perylenebisimide–fullerene (C60) dyads with bidirectional ‘‘ping-pong’’ energy transfer as triplet photosensitizers for photooxidation of 1,5 dihydroxynaphthalene.
Yifan Liu and Jianzhang Zhao.*
Chem. Commun., 2012, 48, 3751–3753.
78. Styryl Bodipy-C60 Dyads as Efficient Heavy-Atom-Free Organic Triplet Photosensitizers.
Ling Huang, Xuerong Yu, Wanhua Wu, and Jianzhang Zhao*
Org. Lett., 2012, 14, 2594–2597.
77. Rhenium(I) tricarbonyl polypyridine complexes showing strong absorption of visible light and long-lived triplet excited states as triplet photosensitizer for triplet-triplet annihilation upconversion.
Xiuyu Yi, Jianzhang Zhao,* Wanhua Wu, Dandan Huang, Shaomin Ji and Jifu Sun.
Dalton Trans., 2012, in press.
76. Room Temperature Long-lived Triplet Excited State of Fluorescein in N^N Pt(II)Bisacetylide Complex and Its Applications for Triplet-triplet Annihilation Based Upconversions.
Wenting Wu, Jianzhang Zhao,* Wanhua Wu and Yinghui Chen.
J. Organomet. Chem., 2012, in press.
75. Access to a large stokes shift in functionalized fused coumarin derivatives by increasing the geometry relaxation upon photoexcitation: An experimental and theoretical study.
Dandan Huang, Yinghui Chen, Jianzhang Zhao.*
Dyes and Pigments, 2012, in press.
74. Iridium complexes incorporating coumarin moiety as catalyst photoinitiators:Towards household green LED bulb and halogen lamp irradiation.
Mohamad-Ali Tehfe, Jacques Lalevée,* Sofia Telitel, Jifu Sun, Jianzhang Zhao, Bernadette Graff, Fabrice Morlet-Savary, Jean-Pierre Fouassier.
Polymer, 2012, in press.
73. Efficient Triplet-triplet Annihilation Upconversion with Platinum (II) Bis(arylacetylide) Complexes That Show Long-lived Triplet Excited States.
Shaomin Ji, Wanhua Wu, Jianzhang Zhao,* Huimin Guo, and Wenting Wu.
Eur. J. Inorg. Chem., 2012, DOI: 10.1002/ejic.201200109.
72. Facilitative Functionalization of Cyanine Dye by On-Off-On Fluorescent Switch for Imaging of H2O2 Oxidative Stress and Thiols Reducing Repair in Cells and Tissues.
Fabiao Yu, Peng Li, Ping Song, Bingshuai Wang, Jianzhang Zhao and Keli Han.*
Chem. Commun., 2012, accepted.
71. Long-lived Room Temperature Deep-red Emissive Intraligand Triplet Excited State of Naphthalimide in Cyclometalated Ir(III) Complexes and Its Application in Triplet-triplet Annihilation Based Upconversion.
Jifu Sun, Wanhua Wu and Jianzhang Zhao.*
Chem. Eur. J., 2012, 18, 8100-8112.
., 2012, 48, 9720-9722.

70. Room Temperature Long-lived Triplet Excited States of Naphthalenediimides and Their Applications as Organic Triplet Photosensitizers for Photooxidation and Triplet-triplet Annihilation Upconversions.
Song Guo, Wanhua Wu, Huimin Guo, and Jianzhang Zhao.*
J. Org. Chem., 2012, 77, 3933–3943.
69. Thienyl-substituted BODIPYs with strong visible light-absorption and long-lived triplet excited states as organic triplet sensitizers for triplet-triplet annihilation upconversion.
Yinghui Chen, Jianzhang Zhao,* Lijuan Xie, Huimin Guo and Qiuting Li.
RSC Adv., 2012, 2, 3942–3953.
68. Geometry Relaxation-induced Large Stokes Shift in Red-emitting Borondipyrromethenes (BODIPY) and the Applications in Fluorescent Thiol Probes.
Yinghui Chen, Jianzhang Zhao,* Huimin Guo and Lijuan Xie.
J. Org. Chem., 2012, 77, 2192–2206.
Top 20 most downloaded JOC articles for the month of March, 2012. http://pubs.acs.org/action/showMostReadArticlesjournalCode=joceah&topArticlesType=month
67. An ICT-based strategy to a colorimetric and ratiometric fluorescence probe for hydrogen sulfide in living cells.
Fabiao Yu, Peng Li, Ping Song, Bingshuai Wang, Jianzhang Zhao and Keli Han.*
Chem. Commun., 2012, DOI: 10.1039/c2cc17658k.
66. Visible-light harvesting iridium complexes as singlet oxygen sensitizers for photooxidation of 1,5-dihydroxynaphthalene.
Jifu Sun, Jianzhang Zhao,* Huimin Guo and Wanhua Wu.
Chem. Commun., 2012, 48, 4169–4171. Back cover paper.
65. Encapsulation of hydrophobic pyrenylcycloplatinate complexes within a water-soluble arene ruthenium metallacage.
Nicolas P.E. Barry , Olivier Zava, Wenting Wu, Jianzhang Zhao, Bruno Therrien.*
Inorganic Chemistry Communications. 2012, accepted.
64. Selective Saccharide Recognition Using Modular Diboronic Acid Fluorescent Sensors.
Zhitao Xing, Hui-Chen Wang, Yixiang Cheng, Chengjian Zhu,* Tony D. James,* and Jianzhang Zhao.
Eur. J. Org. Chem. 2012, 10.1002/ejoc.201101633.
63. Ruthenium(II) Polyimine-Coumarin Light Harvesting Molecular Arrays: Design Rationales and Application for Triplet-triplet Annihilation Based Upconversion.
Wanhua Wu, Shaomin Ji, Wenting Wu, Jingyin Shao, Huimin Guo, Tony D. James, and Jianzhang Zhao.*
Chem.Eur. J., 2012, 18, 4953 – 4964
62. Tuning the Photophysical Properties of N^N Pt(II) Bisacetylide Complexes with Fluorene Moiety and Its Applications for Triplet-triplet-annihilation based Upconversion.
Qiuting Li, Huimin Guo,* Lihua Ma, Wanhua Wu, Yifan Liu and Jianzhang Zhao.*
J. Mater. Chem., 2012, 22, 5319–5329. Back cover paper.
61. Excited state intramolecular proton transfer (ESIPT): from principal photophysics to the development of new chromophores and applications in fluorescent molecular probes and luminescent materials.
Jianzhang Zhao,* Shaomin Ji, Yinghui Chen, Huimin Guo* and Pei Yang.
Phys. Chem. Chem. Phys., 2012. accepted. Invited Perspective Feature review. Back cover paper.
60. A Highly Selective Red-emitting FRET Fluorescent Molecular Probe Derived From BODIPY for the Detection of Cysteine and Homocysteine: An Experimental and Theoretical Study.
Jingyin Shao, Haiyang Sun, Huimin Guo, Shaomin Ji, Jianzhang Zhao,* Wenting Wu, Xiaolin Yuan, Chunlei Zhang and Tony D. James.*
Chem. Sci., 2012, 3, 1049–1061.
59. Transition Metal Complexes with Strong Absorption of Visible Light and Long-lived Triplet Excited States: From Molecular Design to Applications.
Jianzhang Zhao,* Shaomin Ji, Wanhua Wu, Wenting Wu, Huimin Guo,* Jifu Sun, Haiyang Sun, Yifan Liu, Qiuting Li and Ling Huang.
RSC Adv., 2012, 2, 1712–1728. Review.
58. Long-lived Room Temperature Near-IR Phosphorescence of BODIPY in a Visible light-harvesting N^C^N Pt(II) Acetylide Complex with Directly Metalated BODIPY Chromophore.
Wanhua Wu, Jianzhang Zhao,* Huimin Guo, Jifu Sun, Shaomin Ji and Zilong Wang.
Chem. Eur. J., 2012, 18, 1961 – 1968.
57. BF2-Bound Chromophore-containing N^N Pt(II) Bisacetylide Complex and Its Applications As Sensitizer for Triplet-triplet annihilation Based Upconversion.
Yifan Liu, Qiuting Li, Jianzhang Zhao* and Huimin Guo.*
RSC Adv., 2012, 2, 1061–1067.
56. Fluorescent coumarin derivatives with large stokes shift, dual emission and solid state luminescent properties: An experimental and theoretical study.
Lijuan Xie,* Yinghui Chen, Wenting Wu, Huimin Guo, Jianzhang Zhao,* Xuerong Yu.
Dyes and Pigments., 2012, 92, 1361－1369.
55. Colorimetric and Ratiometric Fluorescent Chemosensor Based on Diketopyrrolopyrrole (DPP) for Selective Detection of Thiols: An Experimental and Theoretical Study.
Ling Deng, Wenting Wu, Huimin Guo, Jianzhang Zhao,* Shaomin Ji, Xin Zhang, Xiaolin Yuan, and Chunlei Zhang.
J. Org. Chem., 2011, 76, 9294-9304.
54. Long-Lived Room Temperature Deep-Red/Near-IR Emissive Intraligand Triplet Excited State (3IL) of Naphthalimide in Cyclometalated Pt(II) Complexes and Its Application in Upconversion.
Wenting Wu, Huimin Guo, Wanhua Wu, Shaomin Ji, and Jianzhang Zhao.*
Inorg. Chem., 2011, 50, 11446-11460.
53. Ratiometric luminescent molecular oxygen sensors based on uni-luminophores of C^N Pt(II)(acac) complexes that show intense visible-light absorption and balanced fluorescence/phosphorescence dual emission.
Yifan Liu, Huimin Guo and Jianzhang Zhao.*
Chem. Commun. 2011, 47, 11471–11473.

52. Triplet–triplet annihilation based upconversion: from triplet sensitizers and triplet acceptors to upconversion quantum yields.

Jianzhang Zhao,* Shaomin Ji and Huimin Guo.

RSC Adv., 2011, 1, 937–950. Review.

51. Tuning the Emissive Triplet Excited States of Platinum(II) Schiff base Complexes with Pyrene, and Application for Luminescent Oxygen Sensing and Triplet–triplet-annihilation Based Upconversions.

Wanhua Wu, Jifu Sun, Shaomin Ji, Wenting Wu, Jianzhang Zhao* and Huimin Guo*

Dalton Trans. 2011, 40, 11550–11561.

50. Room Temperature Long-lived 3IL Excited State of Rhodamine in a N^N Pt(II) Bisacetylide Complex Which Shows Intense Visible Light Absorption.

Ling Huang, Le Zeng, Huimin Guo, Wanhua Wu, Wenting Wu, Shaomin Ji and Jianzhang Zhao*

Eur. J. Inorg. Chem., 2011, 4527–4533.

49. Organic Triplet Sensitizer Library Derived froma Single Chromophore (BODIPY) with Long-Lived Triplet Excited State for Triplet-Triplet Annihilation Based Upconversion.

Wanhua Wu, Huimin Guo, Wenting Wu, Shaomin Ji, and Jianzhang Zhao*

J. Org. Chem., 2011, 76 (17), 7056–7064.

48. Thiophene Inserted Aryl Dicyanovinyls: The Second Generation of Fluorescent Molecular Rotors with Substantially Red-shifted Emission and Large Stokes Shift.

Jingyin Shao, Shaomin Ji, Xiaolian Li, Jianzhang Zhao,* Fuke Zhou and Huimin Guo.*

Eur. J. Org. Chem., 2011, 39, 6100-6109.

47. Ruthenium(II) Polyimine-Coumarin Dyad with Non-emissive 3IL Excited State as Sensitizer for Triplet-Triplet-Annihilation Based Upconversion.

Shaomin Ji, Huimin Guo, Wenting Wu, Wanhua Wu, Jianzhang Zhao.*

Angew. Chem. Int. Ed., 2011, 11, 50, 8283-8286.

46. Visible-light Harvesting Cyclometalated Iridium (III) Complexes with Long-lived 3IL Excited States and Their Application for Triplet-triplet-annihilation Based Upconversions.

Jifu Sun, Wanhua Wu, Huimin Guo and Jianzhang Zhao.*

Eur. J. Inorg. Chem., 2011, 3165–3173. Front cover paper.

45. Enantioselective Recognition of Mandelic Acid by a 3,6-Dithiophen-2-yl-9H-carbazole Based Chiral Fluorescent Bisboronic Acid Sensor.

Yubo Wu, Huimin Guo, Tony D. James and Jianzhang Zhao.*

J. Org. Chem., 2011, 2011, 76, 5685–5695

44. Ruthenium(II) Polyimine Complexes with a Long-Lived 3IL Excited State or a 3MLCT/3IL Equilibrium: Efficient Triplet Sensitizers for Low-Power Upconversion.

Shaomin Ji, Wanhua Wu, Wenting Wu, Huimin Guo, Jianzhang Zhao.*

Angew. Chem. Int. Ed., 2011, 50, 1626－1629.

ighlighted by Nature China, 2011, doi:10.1038/nchina.2011.4Highlighted by Chem. Eur. J.

43. Chiral Donor Photoinduced-Electron-Transfer (d-PET) Boronic Acid Chemosensors for the Selective Recognition of Tartaric Acids, Disaccharides, and Ginsenosides.

Yubo Wu, Huimin Guo, Xin Zhang, Tony D. James, and Jianzhang Zhao.*

Chem. Eur. J., 2011, 17, 7632 – 7644.

42. Styryl-BODIPY based red-emitting fluorescent OFF–ON molecular probe for specific detection of cysteine.
Jingyin Shao, Huimin Guo, Shaomin Ji, Jianzhang Zhao.*
Biosensors and Bioelectronics, 2011, 26, 3012－3017.
41. Enhanced Enantioselective Recognition with Diastereoisomeric BINOL Based Chiral Fluorescent Boronic Acid Sensors.
Qiuting Li, Huimin Guo,* Yubo Wu, Xin Zhang, Yifan Liu, Jianzhang Zhao.*
J Fluoresc 2011, 21, 2077–2084
40. EnantioselectiveEnantioselective Recognition of Tartaric Acids with Ethynylated Carbazole-Based Chiral Bisboronic Acid Chemosensors with Improved Response at Acidic pH.
Yifan Liu, Xin Zhang, Huimin Guo, Yubo Wu, Qiuting Li, Liping Liu, Jianzhang Zhao.*
J Fluoresc., 2011, 21, 1979–1986.
39. Synthesis of Ethynylated Phenothiazine Based Fluorescent Boronic Acid Probes.
Yubo Wu, Huimin Guo,* Jingyin Shao, Xin Zhang, Shaomin Ji, Jianzhang Zhao.*
J Fluoresc., 2011, 21, 1143–1154.
38. Highly selective fluorescent OFF–ON thiol probes based on dyads of BODIPY and potent intramolecular electron sink 2,4-dinitrobenzenesulfonyl Subunits.
Huimin Guo,* Yingying Jing, Xiaolin Yuan, Shaomin Ji, Jianzhang Zhao,* Xiaohuan Li and Yanyan Kan.
Org. Biomol. Chem., 2011, 9, 3844–3853.
37. Molecular Rotors as Fluorescent Viscosity Sensors: Molecular Design, Polarity Sensitivity, Dipole Moments Changes, Screening Solvents and Deactivation Channel of the Excited States.
Fuke Zhou, Jingyin Shao, Yubin Yang, Jianzhang, Zhao,* Huimin Guo,* Xiaolian Li,* Shaomin Ji, and Zongying Zhang.
Eur. J. Org. Chem., 2011, 4773–4787.
36. Accessing the long-lived emissive 3IL triplet excited states of coumarin fluorophores by direct cyclometallation and its application for oxygen sensing and upconversion.
Wenting Wu, Wanhua Wu, Shaomin Ji, Huimin Guo and Jianzhang Zhao*
Dalton Trans., 2011, 40, 5953–5963.
35. Accessing the long-lived near-IR-emissive triplet excited state in naphthalenediimide with light-harvesting diimine platinum(II) bisacetylide complex and its application for upconversion.
Yifan Liu, Wanhua Wu, Jianzhang Zhao,* Xin Zhang and Huimin Guo*
Dalton Trans., 2011, 2011, 40, 9085–9089 (Inside Front Cover Paper).
34. Coumarin phosphorescence observed with N^N Pt(II) bisacetylide complex and its applications for luminescent oxygen sensing and triplettriplet- annihilation based upconversion.
Haiyang Sun, Huimin Guo,* Wenting Wu, Xin Liu, Jianzhang Zhao*
Dalton Trans., 2011, 40, 7834–7841 (Inside Front Cover Paper).
33. Tuning the emission property of carbazole-caped cyclometalated platinum(II) complexes and its application for enhanced luminescent oxygen sensing.
Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Jianzhang Zhao*
Journal of Organometallic Chemistry 2011, 696, 2388–2398.
32. Synthesis of 5,10,15,20-tetraarylporphyrins and Their Platinum(II) Complexes as Luminescent Oxygen Sensing Materials.
Wenting Wu, Wanhua Wu, Shaomin Ji, Huimin Guo, Xin Wang and Jianzhang Zhao.*
Dyes and Pigments, 2011, 89, 199-211
31. Long-lived Emissive Intra-ligand Triplet Excited States (3IL): Next Generation Luminescent Oxygen Sensing Scheme and a Case Study With Red Phosphorescent Diimine Pt(II) Bis(acetylide) Complexes Containing Ethynylated Naphthalimide or Pyrene Subunits.
Huimin Guo,* Shaomin Ji, Wanhua Wu, Wenting Wu, Jingyin Shao, and Jianzhang Zhao.*
Analyst, 2010, 135, 2832–2840.

30.Tuning the Emission Properties of Cyclometalated Platinum(II) Complexes by Intramolecular Electron-Sink/Arylethynylated Ligands and Its Application For Enhanced Luminescent Oxygen Sensing.
Wanhua Wu, Wenting Wu, Shaomin Ji, Huimin Guo, Peng Song, Keli Han, Lina Chi, Jingyin Shao, and Jianzhang Zhao.*
J. Mater. Chem., 2010, 20, 9775–9786.
29. Naphthalimide Phosphorescence Finally Exposed in a Platinum(II)Diimine Complex.
Huimin Guo, Maria L. Muro-Small, Shaomin Ji, Jianzhang Zhao* and Felix N. Castellano.*
Inorg. Chem., 2010, 49, 6802-6804.
28. Enhanced Luminescence Oxygen Sensing Property of Ru(II) Bispyridine Complexes by Ligand Modification.
Wanhua Wu, S. Ji, W. Wu, H. Guo, X. Wang, Jianzhang Zhao* and Zhonggang Wang.*
Sensors & Actuators: B. Chemical 2010, 149, 395–406.
27. Tuning the Emission Color of Triphenylamine Caped Cyclometalated Platinum(II) Complexes and Its Application for Luminescent Oxygen Sensing and Organic Light Emitting Diode.
Wenting Wu, Chuanhui Cheng, Wanhua Wu, Huimin Guo, Shaomin Ji, Peng Song, Keli Han, Jianzhang Zhao,* Xin Zhang, Yubo Wu and Guotong Du.
Eur. J. Inorg. Chem., 2010, 4683–4696.
26. Observation of Room-temperature Deep-red/Near IR Phosphorescence of Pyrene With Cycloplatinated Complexes: An Experimental and Theoretical Study.
Wenting Wu, Wanhua Wu, Shaomin Ji, Huimin Guo,* and Jianzhang Zhao.*
Eur. J. Inorg. Chem., 2010, 4470–4482.
25. A Highly Selective OFF-ON Red-Emitting Phosphorescent Thiol Probe with Large Stokes Shift and Long Luminescent Lifetime.
Shaomin Ji, Huimin Guo, Xiaolin Yuan, Xiaohuan Li, Haidong Ding, Peng Gao, Chunxia Zhao, Wenting Wu, Wanhua Wu, Jianzhang Zhao.*
Org. Lett. 2010, 12, 2876-2879.
24. Ethynylated Triphenylamine Monoboronic acid Chemosensors: Experimental and Theoretical Studies.
Lina Chi, Yubo Wu, Xin Zhang, Shaomin Ji, Jingyin Shao, Huimin Guo,* Xin Wang, and Jianzhang Zhao.*
J. Fluoresc. 2010, 20, 1255–1265
23. Effect of the Electron Donor/Acceptor Orientation on the Fluorescence Transduction Efficiency of the d-PET Effect of Carbazole-based Fluorescent Boronic Acid Sensors.
Xin Zhang, Yubo Wu, Shaomin Ji, Huimin Guo, Peng Song, Keli Han, Wenting Wu, Wanhua Wu,
Tony D. James, and Jianzhang Zhao.*
J. Org. Chem., 2010, 75, 2578-2588.
22. Synthesis of Polypyridyl Ruthenium Complexes with 2-(1-aryl)-1H-imidazo[4,5-f]-1,10-phenanthroline Ligand and Its Application for Luminescent Oxygen Sensing.
Shaomin Ji, Wanhua Wu, Wenting Wu, Huimin Guo, Xin Zhang, Yubo Wu and Jianzhang Zhao*
Frontiers of Chemistry in China, 2010, 5(2), 193-199. Special issue of Organic Photoswitchable
Multifunctional Molecules and Materials (Edited by Prof. He Tian).
21. Naked-Eye recognition of Cu(II), Zn(II) and Acetate ion by the First Guanine-Based Difunctional Chromoinophore.
K.K. Upadhyay,* Ajit Kumar, Jianzhang Zhao, Rakesh K. Mishra.
Talanta, 2010, in press.
20. Tuning the Luminescence Lifetimes of Ruthenium (II) Polypyridine Complexes and Its Application in Luminescent Oxygen Sensing.
Shaomin Ji, Wanhua Wu, Wenting Wu, Peng Song, Keli Han, Zhonggang Wang, Shasha Liu, Huimin Guo and Jianzhang Zhao.*
J. Mater. Chem., 2010, 20, 1953–1963.
19. Self Assembled Pseudo Double Helix Architecture and Anion Sensing Behavior of a Coumarin Based ICT Probe.
K. K. Upadhyay,* Rakesh K. Mishra, Ajit Kumar, Jianzhang Zhao and Rajendra Prasada.
J. Mol. Struc. 2010, 963(2-3), 228-233.
18. Rational Design of d-PeT Phenylethynylated-Carbazole Monoboronic Acid Fluorescent Sensors for the Selective Detection of alpha-Hydroxyl Carboxylic Acids and Monosaccharides.
Xin Zhang, Lina Chi, Shaomin Ji, Yubo Wu, Peng Song, Keli Han, Huimin Guo, Tony D. James and Jianzhang Zhao.*
J. Am. Chem. Soc. 2009, 131(47), 17452-17463.
17. Synthesis of Novel Bispyrene Diamines and Their Application as Ratiometric Fluorescent Probes for Detection of DNA.
Yubin Yang, Shaomin Ji, Fuke Zhou, Jianzhang Zhao.*
Biosensors and Bioelectronics. 2009, 24, 3442–3447
16. Tuning the Intramolecular charge Transfer of Alkynylpyrenes: Effect on Photophysical Properties and Its Application in Design of OFF-ON Fluorescent Thiol Probes.
Shaomin Ji, Jun Yang, Qing Yang, Shasha Liu, Maodu Chen and Jianzhang Zhao.*
J. Org. Chem. 2009, 74,4855-4865.

16. Tuning the Intramolecular charge Transfer of Alkynylpyrenes: Effect on Photophysical Properties and Its Application in Design of OFF-ON Fluorescent Thiol Probes.

Shaomin Ji, Jun Yang, Qing Yang, Shasha Liu, Maodu Chen and Jianzhang Zhao.*

J. Org. Chem. 2009, 74,4855-4865.

15. Real-time Monitoring of Luminescent Lifetime Changes of PtOEP Oxygen Sensing Film with LED/photodiode-based Time-domain Lifetime Device.

Shaomin Ji, Wanhua Wu, Yubo Wu, Taiyang Zhao, Fuke Zhou, Yubin Yang, Xin Zhang, Xiaofen Liang, Wenting Wu, Lina Chi, Zhonggang Wang and Jianzhang Zhao*.

Analyst, 2009, 134, 958-965.

14. 3,6-Disubstituted Carbazole-Based Bisboronic Acids with Unusual Fluorescence Transduction as Enantioselective Fluorescent Chemosensors for Tartaric Acid.

Feng Han, Lina Chi, Xiaofen Liang, Shaomin Ji, Shasha Liu, Fuke Zhou, Yubo Wu, Keli Han, Jianzhang Zhao,* and Tony D. James*.

J. Org. Chem. 2009, 74, 1333-1336.

13. Chiral Mono Boronic Acid As Fluorescent Enantioselective Sensor for Mono alpha-Hydroxyl Carboxylic Acids

Lina Chi, Jianzhang Zhao,* and Tony D. James*

J. Org. Chem. 2008, 73, 4684–4687

12. Colorimetric Fluoride-Anion Sensor Based on Intramolecular Hydrogen Bonding and Enol–Keto Tautomerization of a Phenothiazine Derivative.

Feng Han and Jianzhang Zhao*

Helv. Chim. Acta. 2008, 91, 635-645

11. Environment Sensitive Phenothiazine Dyes Strongly Fluorescence in Protic Solvents.

Feng Han, Lina Chi, Wenting Wu, Xiaofen Liang, Meiyan Fu, Jianzhang Zhao*

Journal of Photochemistry and Photobiology A: Chemistry 2008, 196, 10–23.

10. 6,6'-Bis-substituted BINOL Boronic Acids as Enantioselective and Chemoselective fluorescent chemosensors for D-sorbitol

Xiaofen Liang, Tony D. James, Jianzhang Zhao*

Tetrahedron 2008, 64, 1309-1315.

9. Cis/trans Configurations of the Peptide C-N bonds: Isomerization and Photoswitching.

Jean-Claude Micheau, Jianzhang Zhao*

J. Phys. Org. Chem. 2007, 20(11), 810-820. Review.

8. Simple Bisthiocarbonohydrazones as Sensitive, selective, Colorimetric, and Switch-On Fluorescent Chemosensors for Fluoride Anions.

Feng Han, Yuhui Bao, Zhigang Yang, Thomas M. Fyles, Jianzhang Zhao,* Xiaojun Peng,* Jiangli Fan, Shiguo Sun.

Chem. Eur. J. 2007, 13, 2880–2892.

7. Chemoselective and enantioselective fluorescent recognition of sugar alcohols by a bisboronic acid receptor.

Jianzhang Zhao, Tony D. James.*

J. Mater. Chem., 2005, 15(27-28), 2896-2901.

6. Fluorescence Quenching in a Dual Fluorophore Boronic Acid Receptor Enhances the Chiral Discrimination of the Receptor for Tartaric Acid.

Jianzhang Zhao, Tony D. James.*

Chem. Commun, 2005,1889-1891.

5. An Enantioselective Fluorescent Sensor for Sugar Acids.

Jianzhang Zhao, Matthew G. Davidson, Mary F. Mahon, Gabriele Kociok-Kohn, Tony D. James.*

J.Am.Chem.Soc. 2004,126(49),16179-16186.

4. cis/trans Photoisomerization of Secondary Thiopeptide Bonds.

Jianzhang Zhao,* Jean-Claude Micheau,* Carolyn Vargas, Cordelia Schiene-Fischer.*

Chem. Eur. J. 2004, 10, 6093-6101.

3. Chiral Binol Bisboronic Acid as Fluorescence Sensor for Sugar Acids.

Jianzhang Zhao, Thomas M. Fyles, Tony D. James.*

Angew. Chem. Int. Ed. Engl. 2004, 43(26), 3461-3464.

2. Direct Photomodulation of Peptide Backbone Conformations.

Jianzhang Zhao,* D. Wildemann, M. Jakob, C. Vargas, C. Schiene-Fischer.*

Chem. Commun. 2003,2810-2811.

1. Cucurbit[n]uril Derivatives Soluble in Water and Organic Solvents.

Jianzhang Zhao, Hee-Joon Kim, Jinho Oh, Soo-Young Kim, Jae Wook Lee, Shigeru Sakamoto, Kentaro Yamaguchi, Kimoon Kim.*

Angew. Chem. Int. Ed. Engl. 2001, 40(22), 4233-4235.

工作成果（獎勵、專利等）

所培養的學生多人次獲得各種獎勵，比如，教育部博士生學術新人獎（籍少敏，2010年）；遼寧省自然科學學術成果特等獎（學術論文類，2011年，籍少敏）；遼寧省自然科學學術成果一等獎（學術論文類， 2011年，張欣）；大連市自然科學優秀學術論文特等獎（2011年，籍少敏）；遼寧省優秀畢業生（3人次）；大連理工大學優秀研究生（20人次）；大連理工大學中凱化學獎學金（2人次）、大連理工大學昭和電工獎學金（2人次）；大連理工大學贏創獎學金（3人次），等等。

趙建章(大連理工大學教師)