基本介紹
- 中文名：趙孔雙
- 職業：現任北京師範大學化學學院教授，博士生導師
- 畢業院校：京都大學(博士,碩士)，吉林大學(學士)
- 籍貫：吉林省長春市人
- 性別：男
基本情況,研究方向,個人成就,代表性論著,
基本情況
1982年1月畢業於吉林大學化學系物理化學專業；
1990年3月和93年3月分別獲得日本國京都大學理學碩士和理學博士學位；
2000年12月至2001年4月以在京都大學化學研究所做訪問教授。
研究方向
(1) 液體介質的介電理論和譜的解析方法
(2) 軟物質體系(聚電解質溶液和凝膠網路，膠體粒子分散系，表面活性劑自組織體系，離子液體多元體系， 生物膜)中物理化學問題的介電解析
(3) 液體分離膜相關的物理化學問題
(4) 介電譜在食品，農業，醫藥領域的套用
個人成就
將介電譜理論和方法拓展到軟物質和分離膜體系，①實現了對包括納米粒子分散系、膠束囊泡，以及球型聚電解質刷(SPB)等軟粒子的內部參數和界面電動力學參數的定量解析；②介電譜解析與標度論、對離子凝聚理論以及雙電層理論相結合，回答了聚電解質鏈構象以及對離子空間分布和鏈聚集動力學等問題；③實現了對溫敏凝膠相轉移過程的介電監測，闡明了該過程的分子機制；給出了凝膠網路的結構和荷電狀態與體積相轉移的關聯性；④提出了濃差極化的介電模型和理論公式並成功地套用到荷電膜/溶液體系，確立了介電譜的弛豫模式和體系組成相之間的定量關係；⑤建立了求解單一細胞介電模型體系的構造和電參數的解析方法。他的解析方法和手段取得了突出的成果，顯示了特有的原創性。他建立的“介電弛豫譜解析方法”，作為膠體與界面化學中的新方法得到國內學術界的公認，並多次被記入《化學學科發展報告》等中。此外，⑥將介電解析用於液體食品的質量評估和監測。
在國內外重要學術刊物共發表論文160餘篇，其中80%以上被SCI收錄。主要論文發表在Macromolecules; Soft Matter; PCCP; Langmuir; J.Phys. Chem. B(C); J. Chem. Phys; Phys. Review B; J.Membrane Sci; Biophysical Chemistry; J. Colloid & Interface Sci.等各領域的代表性刊物上。
主持教育部優秀年輕教師基金、教育部科學技術重點項目、教育部高校骨幹教師基金、以及國家自然科學基金等課題十餘項。撰寫《介電譜方法及套用》（54萬字，2008，化工出版社）；應邀撰寫《Surface Electrical Phenomena in Membranes and Microchanneles》（ISBN : 978-81-7895-326-7，Research Signpost 2008, pp141-171）中的一章” Characteristics and Inner Information of Membrane/Solution System as Viewed from Dielectric Spectroscopy: with an Emphasis on Dielectric Analysis Based on Electrical Model”。長期從事物理化學教學方面的工作且成績突出。曾在東北師範大學和華南師範大學任職，在華南師大期間任化學研究所副所長，校教學委員會委員。參與編寫《物理化學》（2002年，高教出版社）教材一部。
代表性論著
[1] Xue Li,Kongshuang Zhao*, “Phase transition and electrical properties of aggregations of ethoxylated phytosterol surfactants by dielectric spectroscopy”,J. Phys.: Condens. Matter,30(2018) 505402
[2]Xinlu Zhou,Kongshuang Zhao*, “Effect of grafting density on conformation of poly(acrylic acid) in solution by dielectric spectroscopy”,Soft Matter,14(2018)7190-7203
[3] Xinlu Zhou, Kongshuang Zhao*, “Chain conformation of poly(acrylic acid)-graftpoly(ethylene oxide)-graft-dodecyl in solution: an anomalous counter-ions condensation”,Soft Matter,14(2018) 1130-1141
[4] Cancan Zhang, Haixia RaoandKongshuang Zhao*, “Dielectric Insights into the Microcosmic Behavior of Ionic Liquid-Based Self-Assembly- Microemulsions/Micelles”,J. Phy. Chem. B,122(2018) 7170-7177
[5] Wantong Li, Juan Wang, Man Yang, andKongshuang Zhao*, “Dielectric Behavior and Phase Behavior of Block Copolymer PEO13-PPO30-PEO13 Aqueous Solution”,Langmuir,34(2018) 5574−5580
[6] Cancan Zhang, Man Yang andKongshuang Zhao*, “Insight into the effect mechanism of urea-induced protein denaturation by dielectric spectroscopy”,Phys.Chem.Chem.Phys.,19(2017) 32007-32015
[7] Xinlu Zhou,Kongshuang Zhao*, “How side chains affect conformation and electrical properties of poly(acrylic acid) in solution?”Phys.Chem.Chem.Phys.,19(2017) 20559-20572
[8] Man Yang, Cunyan Liu,Kongshuang Zhao*,“Concentration dependent phase behavior and collapse dynamics of PNIPAM microgel by dielectric relaxation”, Phys.Chem.Chem.Phys.,19(2017)15433-15443
[9] Man Yang, Chunyan Liu, Yiwei Lian,Kongshuang Zhao*, Dan Zhu, Jianfeng Zhou,“Relaxations and phase transitions during the collapse of a dense PNIPAM microgel suspension—thorough insight using dielectric spectroscopy”,Soft Matter,13(2017) 2663–2676
[10] Xiaoxia Guo,Kongshuang Zhao*, “Insight into the electrical properties and chain conformation of spherical polyelectrolyte brushes by dielectric spectroscopy”,J. Phys.:Condens. Matter, 29(2017)055102
[11] Xiaoxia Guo,Kongshuang Zhao*, “Dielectric analysis based on spherical-shell modelfor cationic and anionic spherical polyelectrolyte brushes”,J. Phys.: Condens. Matter, 29 (2017) 295101
[12] Man Yang, Wenjuan Su,Kongshuang Zhao*, “Quantification of Solvent Water and Hydration Dynamic of ThermoSensitive Microgel by Dielectric Spectroscopy”,Journal of Polymer Science, Part B: Polymer Physics,55(2017)1859-1864
[13] Man Yang,Kongshuang Zhao*, “Cononsolvency of Poly(N-isopropylacrylamide) in Methanol Aqueous Solution—Insight by Dielectric Spectroscopy”,Journal of Polymer Science, Part B: Polymer Physics, 55(2017) 1227–1234
[14] Cancan Zhang, Zhen Zhen, Liyan Ma andKongshuang Zhao*, “Dielectric relaxation of nonaqueous ionic liquid microemulsion: polarization, microstructure, and phase transition”,RSC Advances, 7(2017) 13733–13741
[15] Wenjuan Su, Man.Yang,Kongshuang Zhao*, To Ngai, “Influence of Charged Groups on the Structure of Microgel and Volume Phase Transition by Dielectric Analysis”,Macromolecules, 49(2016)7997−8008
[16] Shanshan Wang,Kongshuang Zhao*, “Dielectric Analysis for the Spherical and Rodlike Micelle Aggregates Formed from Gemini Surfactant: Driving Forces of Micellization and Stability of Micelles”.Langmuir, 32(2016)7530−7540
[17] Man Yang,Kongshuang Zhao*, “Influence of the structure on the collapse of poly(N-isopropylacrylamide)-based microgels: an insight by quantitative dielectric analysis”,Soft Matter, 12(2016)4093-4102
[18] Weiliang Hao, Man Yang,Kongshuang Zhao*, JiaoningTang, “Dielectric measurements of fouling of nanofiltration membranes by sparingly soluble salts”.J. Membrane Sci.，497(2016)339–347
[19] Man Yang,Kongshuang Zhao*, “Anomalous Volume Phase Transition Temperature of Thermosensitive Semi-Interpenetrating Polymer Network Microgel Suspension by Dielectric Spectroscopy”.J. Phys. Chem. B,119(2015)13198-13207
[20] Haiyan Wu,Kongshuang Zhao*, “Dielectric Relaxation of Spherical Polyelectrolyte Brushes: Movement of Counterions and Electrical Properties of the Brush Layer.”Langmuir, 31(2015)8566–8576
[21] Jingliang Li,Kongshuang Zhao*, “The chain conformation and dielectric relaxation of poly(acrylic acid)-graft-poly(ethylene oxide)-graft-dodecyl in water: effect of side-chains and counterions distribution.”Phys.Chem.Chem.Phys., 17(2015) 4175-4183
[22] Xiaoqing Fan,Kongshuang Zhao*, ”Thermodynamics of Micellization of Ionic Liquids C6mimBr and Orientation Dynamics of Water for C6mimBr–Water Mixtures: A Dielectric Spectroscopy Study.”J. Phys. Chem. B, 118(2014)13729-13736
[23]Kongshuang Zhao*, Qing Lu, Wenjuan Su, “Estimation of electrical parameters inside nanofiltration membrane in varying electrolyte solutions by dielectric spectroscopy analysis.”RSC Advances, 4(2014)63085–63099
[24] Wenjuan Su,Kongshuang Zhao*, Jingjing Wei, To Ngai, “Dielectric relaxations of poly(N-isopropylacrylamide) microgels near volume phase transition temperature: impact of cross-linking density distribution on volume phase transition.”Soft Matter, 10(2014)8711–8723
[25] Juan Wang,Kongshuang Zhao*, Lixin Wu, “Electrical transport properties and interaction of heteropolyacid in N,N-dimethylformamide by dielectric spectroscopy.”J. Chem. Phys., 141(2014)054502
[26] Xiaoqing Fan,Kongshuang Zhao*, “Aggregation behavior and electrical properties of amphiphilic pyrrole-tailed ionic liquids in water，from the viewpoint of dielectric relaxation spectroscopy.”Soft Matter, 10(2014)3259-3270
[27] Jingliang.Li,Kongshuang Zhao*, “Effect of Side-Chain on Conformation of Poly(acrylic acid) and Its Dielectric Behaviors in Aqueous Solution: Hydrophobic and Hydrogen-Bonding Interactions and Mechanism of Relaxations.”J. Phys. Chem. B, 117(2013)11843-11852
[28] Juan Wang,Kongshuang Zhao*, “Interaction and Dynamics of Associated Formamide in TX100-formamide Binary Mixtures by Dielectric Spectroscopy.”J. Phys. Chem. B, 117(2013)7026-7033
[29] Jingliang Li,Kongshuang Zhao*, Chunyan Liu, “Dielectric relaxations of poly(acrylic acid)-graft-poly(ethylene oxide) aqueous solution: Analysis coupled with scaling approach and hydrogen-bonding complex.”PHYSICAL REVIEW E, 87(2013)042603
[30] Yuhong Li, Weidong Gao,Kongshuang Zhao*, Gang Yang, Zhonghe Zhu, and Rongjing Cui， “Real-time Monitoring on the Adsorption Process of Salicylic Acid onto Chitosan Membrane Using Dielectric Spectroscopy: Macroscale Concentration Polarization and Dynamics.”J. Phys. Chem. B, 117(2013)3337-3344
[31] Liyan Ma,Kongshuang Zhao*, “Dielectric relaxation spectroscopy for the binary system of 1-butyl-3-methylimidazolium hexafluorophosphate and ethanol: Interactions and Micro phase behavior.”RSC Advances, 2(2012)10007-10014
[32] Chunyan Liu,Kongshuang Zhao*, “Effects of Concentration and Temperature on the Dynamic Behavior of PAA-g-PEO Aqueous Solutions with Different Counterion Species: A Dielectric Spectroscopy Study.”J. Phys. Chem. B, 116(2012)763-774
[33] Yiwei Lian,Kongshuang Zhao*, “Dielectric Analysis of Micelles and Microemulsions Formed in Hydrophilic Ionic Liquid. I. Interaction and Percolation.”J. Phys. Chem. B, 115(2011)11368-11374
[34] Yiwei Lian,Kongshuang Zhao*, “Study of micelles and microemulsions formed in hydrophobic ionic liquid by dielectric spectroscopy method. 1 Interaction and percolation.”Soft Matter, 7(2011)8828–8837
[35] Zhen Chen, Xin-Wei Li,Kongshuang Zhao*，Jin-Xin Xiao，Li-Kun Yang, “Dielectric Spectroscopy Investigation on the Interaction of Poly(diallyldimethylammonium- chloride) with Sodium Decylsulfate in Aqueous Solution.”J. Phys. Chem. B, 115(2011)5766–5774
[36] Qing Lu,Kongshuang Zhao*, “Dielectric Spectroscopy of a Nanofiltration Membranes-Electrolyte Solution System: I. Low-Frequency Dielectric Relaxation from the Counterion Polarization in Pores and Model Development.”J. Phys. Chem. B, 114(2010)16783–16791
[37] Cun-Yan Liu,Kongshuang Zhao*, “Dielectric Relaxations in Chitosan Solution with Varying Concentration and Temperature: Analysis Coupled with Scaling Approach and Thermodynamical function”.Soft Matter, 6(2010)2742-2750.
[38] Yi-wei Lian,Kongshuang Zhao*, Li-kun Yang，“Dielectric Analysis of Poly(diallyldimethylammonium chloride) Aqueous Solution coupled with Scaling Approach.”Phys.Chem.Chem.Phys., 12(2010)6732-6741.
[39] Mingjuan Han,Kongshuang Zhao*, “Effect of Volume Fraction and Temperature on Dielectric Relaxation Spectroscopy of Suspensions of PS/PANI composite Microspheres.”J. Phys. Chem. C, 112,49(2008)19412-19422
[40] Wei Zhou,Kongshuang Zhao*, “Dielectric Response and Analysis to Structural Evolution of NaA Zeolites with High Pretreatment Temperature.”J. Phys. Chem. C, 112,38(2008)15015-15021
[41] Mingjuan Han,Kongshuang Zhao*, “Dielectric Behaviour of Suspensions of Polystyrene-Zinc Oxide Composite Microspheres.”J. Phys. Chem. C, 112,25(2008) 9192-9202
[42] Likun Yang,Kongshuang Zhao*, “Dielectric Model and Theoretical Analysis of Cationic Reverse Micellar Solutions in CTAB/Isooctane/n-Hexanol/Water Systems.”Langmuir, 23(2007) 8732-8739
[43] Zhen Chen,Kongshuang Zhao*, Lin Guo, Cai-Hong Feng. “Dielectric Relaxation Behavior of Colloidal Suspensions of Palladium Nanoparticle Chains Dispersed in PVP/EG Solution.”J. Chem. Phys., 126(2007)164505
[44]Kongshuang Zhao*, Kejuan He, “Dielectric relaxations of the suspensions of nanoscale particles surrounded by a thick electric double layer.”Phys. Review B, 74,20(2006)205319-205328
[45] Lin-Kun Yang,Kongshuang Zhao*, Jin-Xin Xiao, “Study of Tetrabutylammonium Perfluorooctanoate Aqueous Solutions with Two Cloud-Points by Dielectric Relaxation Spectroscopy.”Langmuir, 22(2006)8655-8662
[46]Kongshuang Zhao*, Yuhong Li, “Dielectric Characterization of a Nanofiltration Membrane in Electrolyte Solutions: Its Double-Layer Structure and Ion Permeation.”J. Phys. Chem., B, 110(2006)2755-2763
[47] Kejuan He,Kongshuang Zhao*, “Dielectric Analysis of a Aanoscale Particle in an Aqueous Solution of Low Electrolyte Concentration.”Langmuir, 21(2005)11878-11887
著作
1. 趙孔雙著， 化學前言套用叢書——《介電譜方法及套用》(54萬字)，2008年，化學工業出版社
2.Kong-Shuang Zhao*, Zhen Chen, Yu-Hong Li, “Characteristics and Inner Information of Membrane/Solution System as Viewed from Dielectric Spectroscopy: with an Emphasis on Dielectric Analysis Based on Electrical Model.”, In: A. Szymczyk (ed.), Surface Electrical Phenomena in Membranes and Microchanneles, Transworld Research Network: Trivandrum, India, Chapter 8. 2008, pp. 141-171.
