西蒙·杜特懷勒，男，博士，浙江大學化學系教授。
基本介紹
- 中文名：西蒙·杜特懷勒
- 畢業院校：蘇黎世大學
- 學位/學歷：博士
- 職業：教師
- 專業方向：碳硼烷化學
- 任職院校：浙江大學化學系
- 外文名：Simon Lukas Duttwyler
研究方向,個人經歷,主講課程,榮譽獎項,學術成果,
研究方向
·碳硼烷化學
·硼氫活化
·合成方法學
個人經歷
教育經歷：
2019年至今：浙江大學化學系教授。
2013-2018年：浙江大學化學系特聘研究員。
2010-2013年：耶魯大學 博士後研究。Rh-介導的C-H活化用於氮雜環化合物的合成。導師: Prof. Jonathan A. Ellman。
2007-2008年：加州大學湖濱分校 科學研究。碳硼烷及其活性中間體的合成。導師: Prof. Christopher A. Reed。
2005-2010年：蘇黎世大學 博士研究生學習。新型矽正離子的發展和套用。導師：Prof. Jay S. Siegel。
2000-2005年：蘇黎世大學 本科學習。
學術兼職：
應邀擔任Angewandte Chemie, Chemical Science, Chemical Reviews, Accounts of Chemical Research, Coordination Chemistry Reviews, Chemical Communications, Chemistry - A European Journal, ChemCatChem, Journal of Organic Chemistry, Inorganic Chemistry等10多家期刊的審稿人。
主講課程
- Organic Chemistry for students of medicine
- Physical Organic Chemistry
榮譽獎項
2014-2018 Research grants from the NSFC
20131000YoungTalentsProgram Fellowship (Chinese government)
2011YoungresearcherawardfromSwissAcademyofSciences
2011PrizeforbestscientificPhDthesisatUniversityofZurich
2010CommendationforPhDthesis
2009SwissNationalScienceFoundationFellowship
2005Commendationforundergraduateachievements
2005Commendationfordiplomathesis
2002AlfredWernerAward
2001AlfredWernerAward
學術成果
Research on boron clusters.
Publications:
35. 'The 12-ethynylmonocarba-closo-dodecaborate anion as a versatile ligand for Cu(I) alkyne and heterobimetallic Cu(I)/M(II) (M = Pd, Pt) alkynide complexes'
T. Jiang,K. Zhang,M. Hamdaoui, R. Dontha, J. Liu, B. Spingler*, S. Duttwyler*,
Dalton Trans.2019,48, 17192–17199.
34. 'A 3D Analogue of Phenyllithium: Solution-Phase, Solid-State and Computational Study of the Lithiacarborane [Li–CB11H11]'
R. Dontha, T. Zhu, Y. Shen, M. Wörle*, X. Hong*, S. Duttwyler*
Angew. Chem. Int. Ed.2019,58, 19007–19013.
33. 'A Microporous Metal-Organic Framework Supramolecularly Assembled from a Cu(II) Dodecaborate Cluster Complex for Selective Gas Separation'
Y. Zhang,L. Yang,L. Wang, S. Duttwyler*, H. Xing*
Angew. Chem. Int. Ed.2019,58, 8145–8150.
32. 'Atomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics'
K. Zhang,Y. Shen,X. Yang, J. Liu, T. Jiang, N,. Finney*, B. Spingler*, S. Duttwyler*
Chem. Eur. J.2019,25, 8754–8759.
31. 'Highly selective palladium-catalyzed one-pot, five-fold B–H/C–H cross coupling of monocarboranes with alkenes'
Y. Shen, K. Zhang, X. Liang, R. Dontha, S. Duttwyler*
Chem. Sci.2019,10, 4177–4184.
30. 'Emissions from a triphenylamine–benzothiadiazole–monocarborane triad and its applications as a fluorescent chemosensor and a white OLED component'
Z. Peng, K. Zhang, Z. Huang, Z. Wang, S. Duttwyler, Y. Wang*, P. Lu*
J. Mater. Chem. C2019,7, 2430–2435.
29. 'Synthesis and Structural Characterization of Amidine, Amide, Urea and Isocyanate Derivatives of the Amino-closo-dodecaborate Anion [B12H11NH3]'
Y. Zhang,Y. Sun,T. Wang,J. Liu, B. Spingler, S. Duttwyler*
Molecules2018,23, 3137–3148.
28. 'Palladium-Catalyzed Selective Five-Fold Cascade Arylation of the 12-Vertex Monocarborane Anion by B–H Activation'
F. Lin,J.-L. Yu,Y. Shen,S.-Q. Zhang, B. Spingler, J. Liu, X. Hong*, S. Duttwyler*
J. Am. Chem. Soc.2018,140, 13798–13807.
27. 'Rhodium(III)-catalyzed dehydrogenative dialkenylation of the monocarba-closo-decaborate cluster by regioselective B–H activation'
X. Liang, Y. Shen, K. Zhang, J. Liu, S. Duttwyler*
Chem. Commun.2018,54, 12451–12454.
26. 'Rh(III)-Catalyzed Functionalization ofcloso-DodecaboratesviaSelective B–H Activation: Bypassing Competitive C–H Activation '
Y. Zhang, T. Wang, L. Wang, Y. Sun, F. Lin, J. Liu, S. Duttwyler*
Chem. Eur. J.2018,24, 15812–15817.
25. 'Efficient access to amides of the carborane carboxylic acid [1-(COOH)-CB11H11]'
Y. Shen,K. Zheng,R. Dontha, Y. Pan, J. Liu and S. Duttwyler*
RSC Adv.2018,8, 22447–22451.
24. 'Thecloso-Dodecaborate Dianion Fused with Oxazoles Provides 3D Diboraheterocycles with Selective Antimicrobial Activity'
Y. Sun, J. Zhang, Y. Zhang, J. Liu, S. van der Veen*, S. Duttwyler*
Chem. Eur. J.2018,24, 10364–10371.
23. 'Recent advances in B–H functionalization of icosahedral carboranes and boranes by transition metal catalysis'
S. Duttwyler*
Pure Appl. Chem.2018,90, 733–744.
22. 'Crystal structure of a carboraneendo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks'
K. Zhang, Y. Shen, Y. Sun, J. Liu, B. Spingler, S. Duttwyler*
Chem. Commun.2018,54, 1698–1701.
21. 'Fusing Carborane Carboxylic Acids with Alkynes: 3D Analogues of IsocoumarinsviaRegioselective B–H Activation'
F. Lin, Y. Shen, Y. Zhang, Y. Sun, J. Liu, S. Duttwyler*
Chem. Eur. J.2018,24, 551–555.
20. 'Transition Metal Complexes of a Monocarba-closo-dodecaborate LigandviaB–H Activation'
Y. Shen, J. Liu, T. Sattasathuchana, K. K. Baldridge*, S. Duttwyler*
Eur. J. Inorg. Chem.2017,2017, 4420–4424.
19. 'Efficient Bronsted Acid-Catalyzed Deuteration of Arenes and Their Transformation to Functionalized Deuterated Products'
X. Liang, S. Duttwyler*
Asian J. Org. Chem.2017,6, 1063–1071.
18. 'B–H functionalization of the monocarba-closo-dodecaborate anion by rhodium and iridium catalysis'
Y. Shen, Y. Pan, K. Zhang, X. Liang, J. Liu, B. Spingler, S. Duttwyler*
Dalton Trans.2017,46, 3135–3140.
17. 'Synthesis and Full Characterization of an Iridium B–H Activation Intermediate of the Monocarba-closo-dodecaborate Anion'
Y. Shen, Y. Pan, J. Liu, T. Sattasathuchana, K. K. Baldridge*, S. Duttwyler*
Chem. Commun.2017,53, 176–179.
16. 'Rh(III)-Catalyzed Room Temperature Alkenylation–Annulation ofcloso-Dodecaborate Anions via Double B-H Activation'
Y. Zhang, Y. Sun, F. Lin, J. Liu, S. Duttwyler*
Angew. Chem. Int. Ed.2016,55, 15609–15614.
15. 'Facile synthesis of enantioenriched phenol-sulfoxides and their aluminum complexes'
Y. Tang, Y. Sun, J. Liu, S. Duttwyler*
Org. Biomol. Chem.2016,14, 5580–5585.
14. 'Synthesis and Structural Characterization of Ammonio/Hydroxo Undecachloro-closo-dodecaborates [B12Cl11(NH3)]–/[B12Cl11(OH)]2– and Their Derivatives'
Y. Zhang, J. Liu, S. Duttwyler*
Eur. J. Inorg. Chem.2015,2015, 5158.
13. 'Synthesis ofent-Ketorfanol via a C–H Alkenylation/Torquoselective 6pi Electrocyclization Cascade'
E. M. Phillips, T. Mesganaw, A. Patel, S. Duttwyler, B. Q. Mercado, K. N. Houk*, J. A. Ellman*
Angew. Chem. Int. Ed.2015,54, 12044–12048.
12. 'Cu(I) and Ag(I) Complexes of 7,10-bis-N-heterocycle-diazafluoranthenes: Programmed Molecular Grids?'
N. Rahanyan, S. Duttwyler, A. Linden, K. Baldridge*, J. S. Siegel*
Dalton Trans.2014, 43, 11027.
11. 'Regio- and Stereoselective 1,2-Dihydropyridine Alkylation/Addition Sequence for the Synthesis of Piperidines with Quaternary Centers'
S. Duttwyler, S. Chen, C. Lu, R. G. Bergman*, J. A. Ellman*
Angew. Chem Int. Ed.2014, 53, 3877.
10. 'Through-Space Interactions in Enshroudedmeta-Terphenylsilanes'
S. Duttwyler, P. Romanato, A. Linden, K. K. Baldridge*, J. S. Siegel*
J. Phys. Org. Chem.2014, 27, 277.
9. 'Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis'
S. Duttwyler, S. Chen, M. K. Takase, K. B. Wiberg, R. G. Bergman*,J. A. Ellman*
Science2013, 339, 678.
8. 'Arenium Acid Catalyzed Deuteration of Aromatic Hydrocarbons'
S. Duttwyler, A. Butterfield, J. S. Siegel*
J. Org. Chem.2013, 78, 2134.
7. 'Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade'
S. Duttwyler, C. Lu, A. L. Rheingold, R. G. Bergman*, J. A. Ellman*
J. Am. Chem. Soc.2012, 134, 4064.
6. 'Competition Between π-Arene and Lone Pair-Halogen Coordination of Silylium Ions?'
P. Romanato, S. Duttwyler, A. Linden, K. K. Baldridge*, J. S. Siegel*
J. Am. Chem. Soc.2011, 133, 11844.
5. 'Proton-Catalyzed, Silane-Fueled Friedel-Crafts Coupling of Fluoroarenes'
O. Allemann, S. Duttwyler, P. Romanato, K. K. Baldridge*, J. S. Siegel*
Science2011, 332, 574.
4. 'C-F Activation of Fluorobenzene by Silylium Carboranes: Evidence for Incipient Phenyl Cation Reactivity'
S. Duttwyler, C. Douvris, N. L. P. Fackler, F. S. Tham, C. A. Reed*, K. K. Baldridge*, J. S. Siegel*
Angew. Chem. Int. Ed.2010, 49, 7519.
3. 'Intramolecular Halogen Stabilization of Silylium Ions Directs Gearing Dynamics'
P. Romanato, S. Duttwyler, A. Linden, K. K. Baldridge*, J. S. Siegel*
J. Am. Chem. Soc.2010, 132, 7828.
2. 'Synthesis and Crystal Structure of a Silyl-Stabilized Allyl Cation Formed by Disruption of an Arene by a Protonation-Hydrosilylation Sequence'
S. Duttwyler, Y. Zhang, A. Linden, C. A. Reed, K. K. Baldridge*, J. S. Siegel*
Angew. Chem. Int. Ed.2009, 48, 3787.
1. 'Synthesis of 2,6-Diarylphenyldimethylsilyl Cations: Polar-p Distribution of Cationic Character'
S. Duttwyler, Q. Do, A. Linden, K. K. Baldridge*, J. S. Siegel*
Angew. Chem. Int. Ed.2008, 47, 1719.
