董開武，博士，華東師範大學化學與分子工程學院教授、博士生導師。
基本介紹
- 中文名：董開武
- 畢業院校：中國科學院上海有機化學研究所
- 學位/學歷：博士
- 職業：教師
- 專業方向：綠色均相催化，金屬有機化學
- 職務：華東師範大學化學與分子工程學院博士生導師
- 任職院校：華東師範大學化學與分子工程學院
- 職稱：教授
個人經歷,研究方向,學術成果,
個人經歷
教育和工作經歷：
2018.03-至今 教授，華東師範大學；
2017.08-2017.09 訪問研究人員，德國康斯坦茨大學材料化學系（合作導師：Stefan Mecking教授）；
2014.06-2018.03 博士後，德國萊布尼茲催化研究所 (合作導師: Matthias Beller教授)；
2013.07-2014.05 研究助理，中國科學院上海有機化學研究所；
2008.09-2013.07 博士，中國科學院上海有機化學研究所 (導師: 丁奎嶺院士)；
2004.09-2008.07 學士，華東師範大學。
研究方向
綠色均相催化，金屬有機化學。
學術成果
代表性論文：
1.K. Dong, Z. Wang, K. Ding,* Rh(I)-Catalyzed Enantioselective Hydrogenation of α-Substituted Ethenylphosphonic Acids.J. Am. Chem. Soc.2012,134, 12474-12477.
2.K. Dong, Y. Li, Z. Wang, K. Ding,* Catalytic Asymmetric Hydrogenation of α-CF3- or β-CF3-Substituted Acrylic Acids using Rhodium(I) Complexes with a Combination of Chiral and Achiral Ligands.Angew. Chem. Int. Ed.2013,52, 14191-14195.
3.K. Dong, Y. Li, Z. Wang, K. Ding,* Asymmetric Hydrogenation of α-Arylacrylic and β-Arylbut-3-enoic Acids Catalyzed by a Rh(I) Complex of a Monodentate Secondary Phosphine Oxide Ligand.Org. Chem. Front.2014,1, 155-160.
4.K. Dong, X. Fang, R. Jackstell, M. Beller,* A novel rhodium-catalyzed domino-hydroformylation-reaction for the synthesis of sulphonamides.Chem. Commun.2015,51, 5059-5062.
5.K. Dong, X. Fang, R. Jackstell, G. Laurenczy, Y. Li,* M. Beller,* Rh(I)-Catalyzed Hydroamidation of Olefins via Selective Activation of N–H Bonds in Aliphatic Amines.J. Am. Chem. Soc.2015,137, 6053-6058.
6.K. Dong,R. Sang,J.-F. Soule, C. Bruneau, R. Franke, R. Jackstell, M. Beller,* Efficient Domino Hydroformylation/Benzoin Condensation: Highly Selective Synthesis ofα-Hydroxy Ketones.Chem. Eur. J.2015,21, 18033-18037.
7.K. Dong, S. Elangovan, R. Sang, A. Spannenberg, R. Jackstell, K. Junge, Y. Li,* M. Beller,* Selective catalytic two-step process for ethylene glycol from carbon monoxide.Nat. Commun.2016,7, 12075-12081.
8.K. Dong,X. Fang,S. Gülak, R. Franke, A. Spannenberg, H. Neumann, R. Jackstell, M. Beller,* Highly active and efficient catalysts for alkoxycarbonylation of alkenes.Nat.Commun.2017,8, 14117-14123.
9. K. Dong, R. Sang, X. Fang, R. Franke, A. Spannenberg, H. Neumann, R. Jackstell, M. Beller,* Efficient Palladium-catalyzed Alkoxycarbonylation of Bulk Industrial Olefins using Ferrocenyl Phosphines.Angew. Chem. Int. Ed.2017, 56, 5267-5271.
10.K. Dong,R. Sang,J. Liu, R. Razzaq, R. Franke, R. Jackstell, M. Beller, Palladium-Catalyzed Carbonylation ofsec- andtert-Alcohols.Angew. Chem. Int. Ed.2017, 56,6203-6207.
11.K. Dong, X.-F. Wu,* Carbonylations with CO2as the CO Source and Reactivity Modifier.Angew. Chem. Int. Ed.2017, 56,5399-5401.
12.K. Dong, R. Razzaq, Y. Hu, K. Ding,* Homogeneous Reduction of Carbon Dioxide with Hydrogen.Top. Curr. Chem.2017, 375, 23-48.
13.K. Dong, R. Sang, Z. Wei, J. Liu, R. Dühren, A. Spannenberg, H. Jiao, H. Neumann, R. Jackstell, R. Franke, M. Beller*, Cooperative catalytic methoxycarbonylation of alkenes: uncovering the role of palladium complexes with hemilabile ligands.Chem. Sci.2018, 9, 2510-2516.
