胡久榮，博士，主要研究方向為金屬有機化學，現為嘉興南湖學院新材料工程學院教授。
基本介紹
研究方向,所授課程,主要成就,1. 論文,2. 項目,3.專利,
研究方向
金屬有機化學
所授課程
《無機化學》、《無機及分析化學》、《化學前沿講座》等課程
主要成就
1. 論文
(1) Jiurong Hu*, Shiqing Sun, Kaijun He, and Yonghua Wang. Synthesis and Characterization of Multinuclear Ruthenium Clusters Assembled by Terminal Alkyne Alcohols and ortho-Carborane Diselenolate Ligands. J. Mol. Struct., 2022, 1263, 133198.
(2) Jiurong Hu*, Wenjie Dong and Jihong Wang. Synthesis, Structure, and Mechanism of the Isomers of Ruthenium Complexes Based on HC≡CC(OH)(CH3)2 and ortho-Carborane Dithiolate Ligands. Inorg. Chem. Commun., 2022, 143, 109722.
(3) Jiurong Hu*, and Jihong Wang. Reactivity of 16-Electron (p-cymene)Ru Half-sandwich Complex Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand with 1-Ethynyl-1-cyclohexanol. J. Struct. Chem., 2022, 63(10): 1551–1557.
(4) Jiurong Hu*, and Jihong Wang. Synthesis and Structural Characterization of the Ruthenium Complexes Based on ortho-Carborane-1,2-diselenolate Ligand and Terminal Alkynone. Russ. J. Inorg. Chem., 2022, 67(11): 1739–1744.
(5) Jiurong Hu*, Jihong Wang, Kuiguang Jin, and Changpeng Zhu. Synthesis and Structural Characterization of the Ruthenium Complex Based on 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligand and FcCH(OH)C≡CH. Russ. J. Coord. Chem., 2020, 46(6): 437–442.
(6) 胡久榮*，祝長鵬，葉明星, 鐘修鵬，張洪傑，林瑩. 含鄰位-碳硼烷與二茂鐵基半夾心式釕化合物的合成及表征. 合成化學, 2019, 27(7): 543–546.
(7) Jiurong Hu*, Weihua Chen, Dekui Nie, Yonghua Wang, and Hongde Ye. Reactivity of Dinuclear Ruthenium Complex Containing Two 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands toward HC≡CC(OH)(CH3)2, Russ. J. Coord. Chem., 2016, 42(12): 783–788.
(8) Jiurong Hu*, Weihong Yan, Nianhua Luo, Roujie Dong, Rongli Huang, and Hongde Ye. Synthesis, Crystal structure and Catalytic Activity of a Bimetallic Rhodium Complex with 1,5-Cyclooctadiene and 2,2′-Bipyridine. Chinese J. Struct. Chem., 2015, 34(7): 1107–1112.
(9) Jiurong Hu*, Linhai Liu, Xin Hu, and Hongde Ye. Ag(I)-catalyzed C–H borylation of terminal alkynes. Tetrahedron, 2014, 70(35): 5815–5819.
(10) Jiurong Hu*, Hongde Ye, Yonghua Wang, and Fayun Chen. Construction of 18-Electron Arene-ruthenium Complexes Based on ortho-Carborane-1,2-diselenolate Ligand. Russ. J. Coord. Chem., 2014, 40(6): 413–418.
(11) Jiurong Hu*, Wanjia Zhang, Linhai Liu, and Huanan Peng. Synthesis, Structure and Mechanism of Half-sandwich Ruthenium Complexes Based on ortho-Carborane-1,2-dithiolate Ligand and Alkyne Alcohol. Russ. J. Coord. Chem., 2014, 40(12): 954–958.
(12) Jiurong Hu*, and Dagui Zheng. Efficient Synthesis and Crystal Structures of Intermediates of Benzanilide Derivatives Catalyzed by Ph3P/DDQ. Chinese J. Inorg. Chem., 2014, 30(2): 459–465.
(13) Jiurong Hu*, Haijin Huang, Shangxi Wei, Linhai Liu, and Hongde Ye. Synthesis and Characterization of Half-sandwich Multinuclear Cobalt Complex Containing 1,2-Diselenolate Carborane Ligands. Chinese J. Inorg. Chem., 2014, 30(9): 2205–2210.
(14) Jiurong Hu*, Wanjia Zhang, and Dagui Zheng. A One-pot Synthesis of Bisarylhydrazones by Cu(I)-catalyzed Aerobic Oxidation. Tetrahedron, 2013, 69(46): 9865–9869.
(15) Jiurong Hu*, Huanan Peng, Xin Hu, Hongde Ye, and Hong Yan. Reactivity of Dinuclear Ruthenium Complex Containing One μ-Se2 Unit and Two 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands toward (cyclo-C6H10)(OH)C≡CH. Acta Chim. Sinica, 2013, 71(6): 892–896.
(16) 胡久榮*, 張婉佳, 葉紅德, 胡嬌, 王勇華. Ｎ-(2-羥苄基)-ＤＬ-丙氨酸銪(Ⅲ)配合物的合成及螢光性質. 化學世界, 2013, 54(6): 359–362.
(17) Jiurong Hu*, Xiao Tang, Guifeng Liu, Qibai Jiang, Yizhi Li, and Hong Yan. Mixed-valent Diruthenium Half-sandwich Complex Containing Two Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dithiolate Ligands: Reactivity towards (cyclo-C6H10)(OH)C≡CH and PhC(O)C≡CH. J. Organomet. Chem., 2012, 712, 1–6.
(18) 胡久榮*, 閆衛紅, 鄭大貴, 葉紅德, 饒敏. 以N-(2-羥苄基)-DL-纈氨酸及4,4'-聯吡啶為配體的銅(Ⅱ)配合物的合成、晶體結構及抑菌活性. 無機化學學報,2012, 28 (3), 531–535.
(19) 胡久榮*, 張霞兵, 鄭大貴, 魏尚曦. N-二茂鐵甲醯基甘氨酸鄰菲咯啉稀土三元配合物的合成、表征及抑菌活性研究. 稀土, 2012, 33(4): 14–18.
(20) Jiurong Hu, Jialin Wen, Dehong Wu, Rui Zhang, Guifeng Liu, Qibai Jiang, Yizhi Li, and Hong Yan. Multinuclear Self-assembly via a (p-Cymene)ruthenium Unit and an o-Carborane Selenolate Ligand. Organometallics, 2011, 30(2): 298–304.
(21) Jiurong Hu, Guifeng Liu, Qibai Jiang, Rui Zhang, Wei Huang, and Hong Yan. Controlled Assembly of Ruthenium Complexes through ortho-Carborane Dithiolate and Polysulfide Ligands. Inorg. Chem., 2010, 49(23): 11199–11204.
(22) 胡久榮*, 梁福沛, 陳自盧. Cu(Ⅱ)與N-(2-羥苄基)-DL-丙氨酸、4,4′-聯吡啶三元配合物的合成與晶體結構. 無機化學學報, 2007, 23(7): 1291–1294.
(23) Jiurong Hu, and Fupei Liang. Synthesis and Crystal Structure of [Zn(FcCOO)2(2,2′-bipy)(H2O)]2·H2O. Chinese J. Struct. Chem., 2007, 26(7): 793–796.
(24) 胡久榮, 梁福沛, 陳自盧, 黃世穩, 黃衍強. 銅(Ⅱ)-N-(2-羥苄基)-DL-α-苯丙氨酸-2, 2'-聯吡啶(或1,10-鄰菲咯啉)三元配合物的合成、晶體結構及抑菌活性. 無機化學學報, 2006, 22(11): 1989–1995.
(25) Hongde Ye*, Jiurong Hu, and Huanan Peng. Reactivity of Two MeCp-Cobalt Complexes Containing 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate (S2C2B10H10)2- Units toward Alkynes. Russ. J. Coord. Chem., 2015, 41(9): 585–591.
(26) Hongde Ye*, Baohua Xu, Jiurong Hu, and Hong Yan. Cobalt(Ⅲ)-Mediated Intramolecular Coupling of B(3)/B(6) in CpCoS2C2B10H10 with Cp Ligand. Chinese J. Inorg. Chem., 2015, 31(7): 1447–1452.
(27) 葉紅德*, 幸澤升, 胡久榮, 彭化南, 謝嘉霖, 劉林海. 半夾芯16 電子碳硼烷化合物Me4CpCoS2C2B10H10與二茂鐵炔酮的反應性. 無機化學學報, 2015, 31(8): 1534–1538.
(28) Huanan Peng*, Dagui Zheng, Xianhua Zeng, Jiurong Hu, and Hongde Ye. Synthesis, Crystal Structure, and Spectroscopic Properties of 5-Ethoxycarbonyl- 4-[(4-methoxy-carbonyl)phenyl]-6-methyl-3,4-dihydropyrimidin2(1H)-ones. Mol. Cryst. Liq. Cryst., 2015, 609, 266–276.
(29) Hongde Ye*, Xiang Li, Jiurong Hu, Huanan Peng, Xin Hu, and Hong Yan. Synthesis of A Paramagnetic Carborane Derivative Containing A Furyl Ring and Its Formation Mechanism. Chinese J. Inorg. Chem., 2014, 30(6): 1469–1473.
(30) Hongde Ye*, Jiurong Hu, Dagui Zheng, Huanan Peng, Qing Ye, Ruyi Zou, and Hong Yan. Synthesis and Crystal Structure of a B−H Activated Compound Containing a Furan Ring and an ortho-Carborane Cage. Chinese J. Struct. Chem., 2013, 32 (10): 1517–1522.
(31) Dagui Zheng, and Jiurong Hu*. Synthesis and Crystal Structure of a Cu(II) Complex with Reduced Schiff-base N-(2-hydroxybenzyl)-D,L-alanine and 4,4′-Bipyridine. Chinese J. Struct. Chem., 2012, 31(6): 867–871.
(32) Guifeng Liu, Jiurong Hu, Jialin Wen, Huimin Dai, Yizhi Li, and Hong Yan. Cobalt-mediated Selective B–H Activation and Formation of a Co–B Bond in the Reaction of the 16-Electron CpCo Half-sandwich Complex Containing an o-Carborane-1,2-dithiolate Ligand with Ethyl Diazoacetate. Inorg. Chem., 2011, 50, 4187–4194.
(33) Suni Qin, Jiurong Hu, Zilu Chen, and Fupei Liang*. Complexes Based on Ferrocenecarboxylate Ligands: Steric Hindrance Induced by Ferrocenyl Groups. J. Coord. Chem., 2011, 64, 3718–3728.
2. 項目
(1) 國家自然科學基金：含多個碳硼烷基團有機金屬化合物的可控制備及其與末端炔醇的反應研究(2013.1-2017.3, No. 21261020, 資助經費48萬, 主持完成)
(2) 江西省高等學校科技落地計畫項目：含碳硼烷基有機金屬化合物的設計、合成及套用潛能(2013.1-2016.3, No. KJLD12094, 資助經費20萬, 主持完成)
(3) 江西省自然科學基金：含芳香基有機金屬化合物的可控制備及其生物活性研究(2015.1-2017.3, No. 20151BAB203005, 資助經費5萬，主持完成)
(4) 上饒市“信江英才866工程” 領軍人才培養計畫：含芳香基有機金屬化合物的設計、合成及其性能研究 (2014.1-2016.12, 資助經費30萬, 主持完成)
(5) 江西省教育廳科技項目：半夾芯式多核釕配合物的設計、合成及性能研究(2018.1-2020.12, No. GJJ170921, 資助經費3萬，主持完成)
(6) 江西省教育廳科技項目：基於過渡金屬催化的新型碳–碳成鍵反應研究(2013.1-2014.6, No. GJJ12704, 資助經費2.5萬, 主持完成)
(7) 江西省教育廳科技項目：二茂鐵醯化胺基酸及其金屬配合物的合成與套用研究(2010.1-2012.12, No. GJJ10608, 資助經費2.5萬, 主持完成)
(8) 江西省教育廳科技項目：新型N-取代胺基酸金屬配合物的設計、合成及套用研究(2011.1-2012.12, No. GJJ10732, 資助經費2萬，主持完成)
(9) 上饒市科技計畫項目：含硫族元素配體構築的半夾芯結構金屬釕化合物的設計、合成及套用潛能(2021.1-2022.12, No. 2020L010, 資助經費2 萬，主持在研)
3.專利
發明專利
(1) 胡久榮, 宋娟. 一種含硒元素碳硼烷橋連的雙核釕化合物及其製備方法, 中國, 專利號：ZL201310022129.8, 授權公告號：CN103739627B, 授權公告日：2016-01-20.
(2) 胡久榮, 彭觀音. 一種含多個碳硼烷基團三核釕簇合物晶體及其製備方法, 中國, 專利號：ZL201310415992.X, 授權公告號：CN103739628B, 授權公告日：2016-01-20.
(3) 胡久榮, 王勇華, 聶德魁. 一種以炔醇為配體的含碳硼烷基雙核釕配合物及其製備方法, 中國, 專利號： ZL201310193296.9, 授權公告號：CN103739633B, 授權公告日：2016-08-31.
(4) 胡久榮, 劉林海. 一種基於硼氫鍵活化的金屬釕配合物晶體及其製備方法. 中國, 專利號：ZL201410182924.8, 授權公告號：CN103951712B, 授權公告日：2016-10-05.
實用新型專利
(1) 胡久榮, 陳偉華, 董柔婕. 一種具有避光和水浴控溫性能的電動攪拌器. 中國, 專利號: ZL201520789625.0, 授權公告號：CN205042383U, 授權公告日：2016-02-24
(2) 胡久榮, 姚一文. 一種化學實驗廢液回收裝置. 中國, 專利號: ZL201820306047.4, 授權公告號： CN208071490U, 授權公告日：2018-11-09
(3) 胡久榮, 祝長鵬. 一種配合物晶體合成探查裝置. 中國, 專利號: ZL201821913113.0, 授權公告號： CN209052801U, 授權公告日：2019-07-02
