王正寶(浙江大學化學工程與生物工程學系教授)

王正寶博士，浙江大學化學工程與生物工程學系教授，博導

研究方向無機膜（沸石分子篩膜）及催化新材料；滲透汽化膜分離

新型沸石分子篩膜的研究與開發，沸石分子篩膜製備的新方法及新套用的研究；沸石分子篩及介孔材料在催化上的新套用及新催化材料的研究，研究並解決分子篩催化劑在工業化套用時所遇到的問題。

基本介紹

• 中文名：王正寶
• 國籍：中國
• 職業：博士
• 性別：男

人物經歷

學習經歷

84年9月-88年7月 浙江大學化學系物理化學專業理學學士，連續三年獲浙江大學一等獎學金，88年獲“浙江大學竺可楨獎學金”。

88年9月-93年11月 中國科學院大連化學物理研究所物理化學、催化化學專業理學博士(直接攻博) 導師: 林勵吾院士。

工作經歷

93年12月-96年11月 日本東京工業大學理學部化學科，博士後 導師: Prof. Yashima。

96年12月-99年2月 日本北陸先端科學技術大學院大學材料科學研究科，文部省教官。

99年3月-01年11月 美國University of California, Riverside (UCR) 化學與環境工程系，訪問學者。

01年12月-06年12月 日本旭化成株式會社中央技術研究所，主任研究員。

06年12月—浙江大學化學工程與生物工程學系聯合化學反應工程研究所，教授，博導。

研究方向

無機膜（沸石分子篩膜）及催化新材料；滲透汽化膜分離 在化學工程與工業催化兩個二級學科招收碩士和博士研究生。

主要貢獻

在做博士論文期間，研究了ZSM-5沸石分子篩催化劑上的低碳烴芳構化反應及機理。在東京工業大學做博士後期間，從事了Pt擔載H-beta分子篩催化劑上正己烷和正庚烷的異構化研究。日本北陸先端科學技術大學院大學任助手時，進行了分子篩合成、修飾及表征方面的研究工作，還從事了分子篩膜的合成和評價研究，共發表論文20篇。

在UCR期間，主要進行了分子篩薄膜（絕緣膜和防腐膜等）的合成和套用研究，發表學術論文20多篇，獲美國專利3項。主要成就包括：成功地合成了有取向性MFI薄膜(國際領先)，發表在Chem. Mater.和Micropor. & Mesopor. Mater.，共被引99次，並探討了其在絕緣薄膜（Low-k film）方面的套用(國際首例)；用Spin-on法製備了分子篩薄膜, 並考察了其在絕緣膜方面的套用(國際首創)，成果兩次發表在Advanced Materials上，共被引186次；在鋁片上合成的MFI分子篩膜可用作鋁防腐膜(Electrochem. & Solid State Lett.，被他引11次)；探討了MFI分子篩微粒子的套用，成果發表在J. Am. Chem. Soc上，被引150次。

在旭化成期間，先研究了分子篩絕緣薄膜，然後又研究開發了分子篩脫水分離膜，共申請了日本專利15項，還從事了沸石分子篩催化劑的研究開發。

迄今共發表SCI收錄論文39篇、EI收錄論文2篇（其中第一、二作者23篇，通訊作者7篇），累計被引1400多次，SCI收錄論文影響因子總和超過120。2009年發表了兩篇J Am Chem Soc（影響因子>8.0）論文，在中空纖維分子篩脫水膜方面取得了重要進展，乙醇脫水的膜通量可達6-8kg/m2h，是日本三井造船公司的3-4倍；開發了氧化鋁中空纖維上新的塗晶方法，並設計了聚合物與分子篩形成的複合中空纖維支撐體。研究開發了具有高通量的氧化鋁管分子篩膜的製備，有望用於工業套用。通過簡單地控制模板劑TPAOH的用量，能很好地抑制b取向MFI晶種二次生長時a取向晶體的生長，從而獲得高度b取向的MFI分子篩連續膜。

在研項目

1. 沸石分子篩滲透汽化膜製備與套用研究, 浙江省錢江人才項目, J20080444, 2008-01-01, 2009-12-31

2. 變壓吸附法及膜法回收氯甲烷技術研究, 企事業單位委託科技項目, H20080093, 2008-01-07

3. 高水熱穩定性沸石分子篩催化劑的研究, 企事業單位委託科技項目, H20081790, 2008-08-01

4. 複合支撐體法製備沸石分子篩膜, 國家自然科學基金項目, J20080765, 2009-01-01

5. 王正寶研究團隊，浙江省自然科學基金項目，R4090099， 2010-01-01

6. 先進催化技術創新團隊，浙江省科技廳，2009R50020，2010-

專利情況

已授權專利

7.王正寶，葛琴琴，李顯明，一種分子篩複合膜，王正寶，葛琴琴，邵佳，浸塗-滾擦塗晶法合成分子篩膜的方法。5.王正寶，李顯明，一種微波加熱合成取向性MFI型分子篩膜的方法

4.王正寶，花畑　博之，層間絕緣用薄膜，授權日2009.8.28 (24363824)，公開號2004-0795923. Y. Yan, X. Cheng, Z. Wang 2003. Metal surfaces coated with molecular sieves for corrosion resistance.USPatent Application No. 09/745,852, May 17, 2000,U.S.Patent No. 6,521,198, February 18, 2003.

2. Y. Yan, Z. Wang, H. Wang 2003. Silica zeolite low-k dielectric thin films. Application No. 09/900,386. US Patent No. 6,573,131, June 3, 2003.

1. Y. Yan, Z. Wang, H. Wang 2003. Silica zeolite low-k dielectric thin films. Application No. 09/900,386. US Patent No. 6,630,696, October 7, 2003

專利(申請中)

16.王正寶，李顯明，彭勇，孿晶受控二次生長合成高度取向性MFI型分子篩膜的方法。

15.王正寶，佘慧玲，劉春傑，吳濤，曹陽，任不凡，鄭捷，由氯甲烷混合氣體分離回收氯甲烷的方法，中國專利。公開號CN10134320914.花畑　博之，王正寶，層間絕緣用薄膜，日本專利，申請號2008-128470，. Shirataki Hironobu，王正寶，複合膜的製造方法，日本專利，申請號。Shirataki Hironobu，青木謙介，王正寶，分子篩複合膜及其製造方法，日本專利，申請號2006-220807，公開號2008-4386411. Shirataki Hironobu，王正寶，青木謙介，清住嘉道，長谷川泰久，長瀨多加子，水上富士夫，Pillipsite型分子篩膜及其製造方法，日本專利，申請號2006-143047，Merlinoite型分子篩膜及其製造方法，日本專利，申請號2006-143046. Shirataki Hironobu，王正寶，青木謙介，複合膜及其製造方法，日本專利，申請號2006-117632，公開號2006-3208968. Shirataki Hironobu，王正寶，青木謙介，大屋博義，複合膜，日本專利，申請號2005-71432，公開號2006-2476167. Shirataki Hironobu，王正寶，大屋博義，複合膜，日本專利，申請號2005-45847，公開號2006-2311236.清住嘉道，長谷川泰久，長瀨多加子，水上富士夫，王正寶，Shirataki Hironobu，Pillipsite型分子篩膜及其製造方法，日本專利，申請號2005-344634，公開號2006-176399

5. Shirataki Hironobu，王正寶，大屋博義，複合膜，日本專利，申請號2004-357659，公開號2006-1591444，Merlinoite型分子篩膜及其製造方法，日本專利，申請號2004-345040，公開號2006-1502393.花畑　博之，王正寶，分子篩複合薄膜，日本專利，申請號2003-143922,公開號2004-3447552.王正寶、花畑博之，反射防止膜用的多孔性Silica，日本專利，申請號2002-194202，公開號2004-377951.王正寶、花畑博之，層間絕緣膜製造用塗布組成物，申請號2002-050160,公開號2003-249495

代表性論文

61) Jiangang Li, Jia Shao, Qinqin Ge, Guolong Wang, Zhengbao Wang*, Yushan Yan, Influences of the zeolite loading and particle size in composite hollow fiber supports on properties of zeolite NaA membranes, Microporous and Mesoporous Materials, 160, 10–17(2012)60) Lulu Lai, Jia Shao, Qinqin Ge, Zhengbao Wang∗, Yushan Yan, The preparation of zeolite NaA membranes on the inner surface of hollow fiber supports, J membr. Sci. 409– 410, 318– 328 (2012) 59) Yanjuan Dong, Yong Peng, Guolong Wang, Zhengbao Wang*, and Yushan Yan, Corrosion-Resistant Zeolite Silicalite-1 Coatings Synthesized by Seeded Growth, Ind. Eng. Chem. Res., 51, 3646−3652 (2012).（化工top期刊）58) Qinqin Ge, Jia Shao, Zhengbao Wang*, Yushan Yan, Effects of the synthesis hydrogel on the formation of zeolite LTA membranes, Microporous and Mesoporous Materials, 151, 303–310 (2012).（影響因子>3.0）57) 黃先亮，王正寶*，無模板劑兩步法合成小顆粒ZSM-5沸石團聚體，催化學報 (SCI 收錄），32（11），1702-1711 (2011)56) Zhengbao Wang*, Qinqin Ge, Jingsi Gao, Jia Shao, Chunjie Liu, and Yushan Yan, High-Performance Zeolite Membranes on Inexpensive Large-Pore Supports: Highly Reproducible Synthesis using a Seed Paste, ChemSusChem, 4(11), 1570-1573 (2011).55) Jia Shao, Qinqin Ge, Lijun Shan, Zhengbao Wang* and Yushan Yan, Influences of Seeds on the Properties of Zeolite NaA Membranes on Alumina Hollow Fibers, Ind. Eng. Chem. Res. 50(16), 9718-9726 (2011).54) Lijun Shan, Jia Shao, Zhengbao Wang*, Yushan Yan, Preparation of zeolite MFI membranes on alumina hollow fibers with high flux for pervaporation, J. Membr. Sci., 378 (1-2), 319-329 (2011).53) Xianming Li, Yong Peng, Zhengbao Wang*, Yushan Yan, "Synthesis of highly b-oriented zeolite MFI films by suppressing twin crystal growth during the secondary growth", CrystEngComm, 13 (11), 3657 - 3660 (2011). 52) Xiaojing He, Xianliang Huang, Zhengbao Wang*, Yushan Yan, "The role of silver species on the hydrothermal stability of zeolite catalysts", Microporous and Mesoporous Materials 142, 398–403 (2011).51) Xianming Li, Zhengbao Wang*, Jie Zheng, Shiqun Shao, Yinchao Wang, Yushan Yan, "Dynamic Hydrothermal Synthesis of a b-Oriented MFI Zeolite Film", 催化學報（SCI收錄）（Chin. J. Catal.）, 32: 217–223 (2011).50) 何曉京，黃先亮，王正寶，“AgNaZSM-5催化劑的酸性質表征”，化學反應工程與工藝，26（4），361-365（2010）49) 王正寶，邵 佳，葛琴琴, "LTA型分子篩膜製備和套用的研究進展", 石油化工, 39(6), 583-591 (2010).48) Xiangming Li, Yushan Yan, Zhengbao Wang*, "Continuity Control of b-Oriented MFI Zeolite Films by Microwave Synthesis", Ind. Eng. Chem. Res. 49, 5933–5938 (2010)47）李顯明，王正寶*，“微波合成b軸取向MFI型分子篩膜”，石油學報（石油加工）（EI收錄），（增刊），65-69 (2009)46) Qinqin Ge, Zhengbao Wang*, Yushan Yan, "High-performance zeolite NaA membranes on polymer-zeolite composite hollow fiber supports", J. Am. Chem. Soc. 131 (47), 17056-17057 (2009).45) Zhengbao Wang*, Qinqin Ge, Jia Shao, Yushan Yan, "High performance zeolite LTA pervaporation membranes on ceramic hollow fibers by dipcoating-wiping seed deposition", J. Am. Chem. Soc. 131(20), 6910-6911 (2009). 44) A. Mitra, T. Cao, H. Wang, Z. B. Wang, L. Huang, S. Li, Z. Li, Y. Yan. “Synthesis and evaluation of pure-silica-zeolite BEA as low dielectric constant material for microprocessors”, Ind. Eng.Chem. Res. 43, 2946-2949 (2004). 43) Mitra A.; Wang Z.B.;Cao T.; Wang H.; Huang L.; Yan Y. ”Synthesis and corrosion resistance of high-silica zeolite MTW, BEA and MFI coatings on steel and aluminum”. J. Electrochem. Soc. 149:B472-B478 (2002). 42) Mitra A.; Kirby C. W.; Wang Z.B.; Huang L.; Wang H.; Huang Y.; Yan Y. ”Synthesis of pure silica MTW powder and supported films”. Microporous and Mesoporous Materials. 54:175-186 (2002). 41) Wang H.; Holmberg B. A.; Huang L.; Wang Z.B.; Mitra A.; Norbeck J. M.; Yan Y. ”Nafion-bifunctional silica composite proton conductive membranes”. J. Mater. Chem. 12:834-837 (2002).40) Limin Huang, Zhengbao Wang, Huanting Wang, Anupam Mitra, Yushan Yan, “Polyaniline nanostructures by liquid-crystal template electropolymerization”, J. Mater. Chem. 12:388-391(2002).39) Limin Huang, Zhengbao Wang, Huanting Wang, Anupam Mitra, and Yushan Yan, “Cuprite nanowires by electrodepositon from surfactant mesophases”, Chem. Mater. 14, 876-880 (2002).38) Limin Huang, Huanting Wang, Zhengbao Wang, Anupam Mitra, Krassimir N. Bozhilov, and Yushan Yan, Nanowire arrays electrodeposited from liquid crystalline phases, Adv. Mater. 14,61-64 (2002).37) Z.B. Wang, H.T. Wang, L.M. Huang, A.Mitra and Y.Yan, “Pure-silica zeolite low-k dielectric thin films by spin-on process”, Studi. Surf. Sci. & Catal., 135, p. 292 (20-P-11) (2001).36) Z.B. Wang, A. Mitra, H.T. Wang, L.M. Huang, Y. Yan, “Pure silica zeolite films as low-k materials by spin-on of as-synthesized nanoparticle suspension”, Advanced Materials, 13 (19), 1463 (2001).35) Z.B. Wang, H.T. Wang, and Y. Yan, "Pure silica zeolite low k thin films", Advanced Materials, 13, 746-749 (2001).34) Z.B. Wang and Y. Yan, " Controlling crystal orientation in zeolite MFI thin films by direct in situ crystallization", Chem. Mater., 13, 1101-1107 (2001).33) Z.B. Wang and Y. Yan, "Oriented Zeolite MFI Monolayer Films on Metal Substrates by In-Situ Crystallization", Microporous and Mesoporous Mater., 48, 205-214 (2001).32) X. Cheng, Z.B. Wang and Y. Yan, "Corrosion Resistant Zeolite Coatings", Electrochem. &SolidStateLett., 4(5), B23-26 (2001).31) H.T. Wang, Z.B. Wang, X. Cheng, A. Mitra, L.M. Huang and Y. Yan, “Characterization of corrosion-resistant zeolite coatings on Al alloys”, Studi. Surf. Sci. & Catal., 135, p.169 (22-O-04) (2001).30) H.T. Wang, L.M. Huang, Z.B. Wang, A. Mitra, Y. Yan, “Hierarchical zeolite structures with designed shape by gel-casting of colloidal nanocrystal suspensions”, Chem. Commun., 15, 1364-1365 (2001).29) H.T. Wang, Z.B. Wang, L.M. Huang, A. Mitra, B. Holmberg, Y. Yan, “High-surface-area zeolitic silica with mesoporosity”, J. Mater. Chem., 11(9), 2307-2310 (2001).28) H.T. Wang, Z.B. Wang, L.M. Huang and Y. Yan, “Surface patterned porous films by convection-assisted dynamic self-assembly of zeolite nanoparticles”, Langmuir, 17, 2572-2574 (2001).27) L.M. Huang, Z.B. Wang, H.T. Wang, J. Sun, Q. Li, Y. Yan, and D. Zhao," Hierarchical Porous Structures by Using Zeolite Nanocrystals as Building Blocks ", Microporous and Mesoporous Mater., 48, 73-78 (2001).26) H.T. Wang, Z.B. Wang, and Yushan Yan, "Colloidal suspension of template-removed zeolite nanocrystals", Chem. Commun., 23, 2333-2334 (2000).25) L. Huang, Z.B. Wang, J. Sun, L. Miao, Q. Li, Y. Yan, and D. Zhao, "Fabrication of ordered porous structures by solvent-assisted self-assembly of zeolite nanocrystals", J. Am. Chem. Soc., 122, 3530-3531 (2000)24) T. Sano, K. Doi, H. Hagimoto, Z.B. Wang, T. Uozumi and K. Soga, "Adsorption separation of methylalumoxane by mesoporous molecular sieve MCM-41",Chem. Commun., 733-734 (1999)23) T. Sano, K. Doi, H. Hagimoto, Z.B. Wang, T. Uozumi and K. Soga, "Potential use of MCM-41 for adsorptive separation of methylalumoxane", Stud.Sur.Sci. & Catal., Vol. 125,777-784 (1999)22) T. Sano, Y. Uno, Z.B. Wang, C.H. Ahn and K. Soga, "Realumination of dealuminated HZSM-5 zeolites by acid treatment and their catalytic properties", Microporous and Mesoporous Materials, 31, 89-95 (1999)21) T. Sano and Z.B. 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