《氨合成催化劑：創新與實踐》是2015年1月化學工業出版社出版的圖書，作者是劉化章。
基本介紹
- 書名：氨合成催化劑：創新與實踐
- 作者：劉化章
- ISBN：9787122215987
- 頁數：872頁
- 定價：398元
- 出版社：化學工業出版社
- 出版時間：2015年1月
- 裝幀：精裝
- 開本：16開
內容簡介,圖書目錄,
內容簡介
合成氨是極其重要的化工產品，氨合成催化劑的重要性不言而喻。催化合成氨基礎知識的進步對其它領域的催化劑研究有較大的影響。《氨合成催化劑：創新與實踐》從理論與實踐相結合的視角，全面系統地論述了氨合成催化劑研究、開發和工業套用的基本理論和方法，闡述了氨合成催化劑製備的理論、方法、實驗技術及相關的催化反應機理、催化反應器、反應工程與工藝及其套用。
作者劉化章教授從事氨合成及其催化劑的開發研究數十年。《氨合成催化劑：創新與實踐》以作者獲國家發明二等獎的Fe1-xO催化劑為主線，結合其多年研究成果，全面、系統地論述有關氨合成催化劑（包括釕催化劑）的理論和相關技術問題。《氨合成催化劑：創新與實踐》尤其注重理論與實踐密切結合，既具有一定的理論深度，又與催化劑研發、工業套用和工程技術相結合。既有作者的實踐基礎，又汲取國內外的研究成果，並涉及基本原理和科學基礎。《氨合成催化劑：創新與實踐》同時闡述了根據催化劑性能選擇工業套用條件及其對催化過程經濟效益的影響，並介紹了近年來氨合成催化劑研究的新探索、新技術，包括光催化、電催化、生物催化以及氨的新用途等方面的新成果、新進展。
《氨合成催化劑：創新與實踐》可供廣大從事催化劑研究、開發和有關工業的科研人員、高校師生和工程技術人員參考。
圖書目錄
Preface
Foreword
Chapter 1.Historical Evolution of Catalysts for Ammonia Synthesis
1.1 Introduction of Catalysts for Ammonia Synthesis
1.1.1 Co-Mo hydrogenation catalysts
1.1.2 Zinc oxide desulfurizer
1.1.3 Hydrocarbon steam reforming catalysts
1.1.4 CO high-temperature shift catalysts
1.1.5 CO low-temperature shift catalysts
1.1.6 Methanation catalysts
1.1.7 Refine catalysts
1.2 Historical Retrospect of Catalysts for Ammonia Synthesis
1.2.1 Basic studies on physical chemistry of ammonia synthesis reaction
1.2.2 Realization of ammonia synthesis under high pressure
1.2.3 Development of fused iron catalysts for ammonia synthesis
1.2.4 Development of ammonia synthesis catalysts in China
1.2.5 Development trend of ammonia synthesis catalysts
1.3 Development of Magnetite (Fe304) Based Fused Iron Catalysts
1.3.1 Magnetite (Fe304) based fused iron catalysts
1.3.2 Development of Fe304 based catalysts containing cobalt
1.4 Discovery of Wiistite Based Fused Iron Catalysts
1.4.1 Search for new breakthrough of the technique
1.4.2 Activity of wiistite (Fe1-xO) based catalysts
1.4.3 Reduction of Fe1-xO based catalysts
1.4.4 Technical characteristics of wiistite-based catalysts
1.4.5 Significance of the Fe1-xO-based catalysts in theory
1.4.6 Industrial application
1.5 Discovery of Ruthenium Based Catalysts
1.5.1 Properties of the elements in the activation of dinitrogen
1.5.2 Properties of the elements in ammonia synthesis
1.5.3 Alloying effect
1.5.4 Activated carbon supported ruthenium catalysts for ammonia synthesis
References
Chapter 2.Catalytic Reaction Mechanisms of Ammonia Synthesis
2.1 Introduction
2.1.1 The development of catalysis theory
2.1.2 The chemical essences of catalysis
2.1.3 The methodology of catalytic investigation
2.2 Adsorption and Heterogeneous Catalysis
2.2.1 Adsorption and heterogeneous catalysis
2.2.2 Non-uniformity of the surface of heterogeneous catalysts
2.2.3 Isotherms of chemisorptions
2.2.4 Rate of adsorption: Elovich equation
2.2.5 Chemisorption state
2.2.5.1 Chemisorption states of hydrogen
2.2.5.2 Adsorption states of nitrogen
2.2.5.3 Infrared spectroscopy study of nitrogen adsorption
2.2.5.4 The study of electronic energy spectroscopy for nitrogen adsorption
2.2.5.5 The study of adsorption of N2 on non-iron metals
2.3 Mechanism of Catalytic Ammonia Synthesis Reaction
2.3.1 Elementary reactions
2.3.2 Catalytic reaction mechanisms for ammonia synthesis
2.3.2.1 The mechanisms of ammonia synthesis reaction
2.3.2.2 The mechanisms of ammonia decomposition
2.3.2.3 Isotope exchanges of N2
2.3.2.4 Distinguishing reaction mechanisms
2.3.3 Analysis of microreaction (intrinsic) kinetics of ammonia synthesis
2.3.3.1 Analysis of reactor
2.3.3.2 The conclusion of microkinetic analysis
2.4 Kinetics of Overall Reactions for Ammonia Synthesis
2.4.1 General relation between overall reaction and elementary steps
2.4.2 Two-step sequences
2.4.3 Fundamental hypothesis of Temkin theory
2.4.4 The reaction rate equation of Temkin-Pyzhev for ammonia synthesis
……
Chapter 3.Chemical Composition and Structure of FusedIron Catalysts
Chapter 4.Preparation of Fused Iron Catalysts
Chapter 5.Reduction of Fused Iron Catalysts
Chapter 6.Ruthenium Based Ammonia Synthesis Catalysts
Chapter 7.Performance Evaluation and Characterization of Catalysts
Chapter 8.Performance and Application of Catalysts
Chapter 9.Effect of Catalyst Performance on the Economic Benefits of Catalytic Process
Chapter 10.Innovation and Speculation
Index
