曹利平，西北大學化學與材料科學學院教授、博士生導師。本科（2006年）和博士（2011年）畢業於華中師範大學化學學院，獲華中師範大學優秀博士論文；2011年-2014年在美國馬里蘭大學從事博士後研究；2014年以人才引進加入西北大學化學與材料科學學院，任教授、博導。獨立工作期間，先後榮獲西北大學青年學術骨幹（2015年）、陝西省青年百人計畫（2016年）、Thieme Chemistry Journals Award（2020年）、教育部霍英東青年教師基金（2020年）、陝西省傑出青年科學基金（2021年）、國家自然科學基金委優秀青年科學基金（2021年）。主持包括國家自然科學基金面上項目（3項）、陝西省自然科學基金面上項目（1項）和陝西省教育廳重點科研計畫（1項）等科研項目。主要從事大環超分子化學領域的研究工作，先後開展了水相超高強度分子識別、水相主客體螢光材料、新型水溶性大環分子的合成與生物分子識別套用等方面的研究工作；迄今以第一或通訊作者發表論文四十餘篇。
基本介紹
- 中文名：曹利平
- 國籍：中國
- 民族：漢族
- 畢業院校：華中師範大學
- 學位/學歷：博士
- 職業：教師
- 專業方向：超分子化學
人物經歷,研究方向,主要成就,獲獎記錄,
人物經歷
2014年-今：教授，博導，西北大學，化學與材料科學學院。
2017年-2018年：國家公派訪問學者，美國猶他大學，化學系，合作導師：Peter Stang教授。
2011年-2014年：博士後，美國馬里蘭大學，化學與生物化學系，合作導師：Lyle Isaacs教授。
2006年-2011年：理學博士（有機化學），華中師範大學，農藥與化學生物學教育部重點實驗室。
2002年-2006年：理學學士（套用化學），華中師範大學，化學學院。
研究方向
1、新穎水溶性陽離子型螢光大環分子的合成及生物分子識別研究；
2、基於大環分子識別的刺激回響型超分子組裝體系的建立與套用；
3、基於大環的超分子框架材料：構築、性質研究以及功能的套用。
主要成就
主要從事大環分子的設計合成與功能化，實現了水相高強度分子識別、基於主客體螢光功能材料、新型水溶性大環分子的合成與功能化套用等方面的研究工作；迄今以第一或通訊作者發表論文40餘篇。
代表性科研成果：
獨立工作（2014-今）：
41. Nian, H.; Cheng, L.; Wang, L.; Zhang, H.; Wang, P.; Li, Y.; Cao, L.* Hierarchical Two-Level Supramolecular Chirality of an Achiral Anthracene-Based Tetracationic Nanotube in Water. Angew. Chem. Int. Ed. 2021, 60, 15354-15358. (SCI, IF = 12.1, 一區)
40. Qin, C.; Li, Y.; Li, Q.; Yan, C.; Cao, L.* Aggregation-Induced Emission and Self-Assembly of Functional Tetraphenylethene-Based Tetracationic Dicyclophanes for Selective Detection of ATP in Water. Chin. Chem. Lett. 2021, 10.1016/j.cclet.2021.05.006.
39. Xu, W.; Duan, H.; Chang, X.; Wang, G.; Hu, D.; Wang, Z.; Cao, L.*; Fang, Y.* Polyanion and Anionic Surface Monitoring in Aqueous Medium Enabled by an Ionic Host-Guest Complex. Sensors and Actuators B: Chemical, 2021, 340, 129916. (SCI, IF = 7.1, 一區)
38. Duan, H.; Cao, F.; Hao, H.; Bian, H.; Cao, L.* Efficient Photoinduced Energy and Electron Transfers in a Tetraphenylethene-Based Octacationic Cage through Host-Guest Complexation. ACS Appl. Mater. & Interfaces 2021, 13, 16837-16845. (SCI, IF = 8.7, 一區)
37. Zhang, H.; Cheng, L.; Nian, H.; Du, J.; Chen, T.; Cao, L.* Adaptive Chirality of Achiral Tetraphenylethene-Based Tetracationic Cyclophanes with Dual Responses of Fluorescence and Circular Dichroism in Water. Chem. Commun. 2021, 57, 3135-3138. (SCI, IF = 5.9, 一區)
36. Li, Y.; Li, Q.; Miao, X.; Qin, C.; Chu, D.; Cao, L.* Adaptive Chirality of an Achiral Cucurbit[8]uril-Based Supramolecular Organic Framework for Chirality Induction in Water. Angew. Chem. Int. Ed. 2021, 60, 6744-6751. (SCI, IF = 12.1, 一區)
35. Cheng, L.; Liu, K.; Duan, Y.; Duan, H.; Li, Y.; Gao, M.; Cao, L.* Adaptive Chirality of an Achiral Cage: Chirality Transfer, Induction, and Circularly Polarized Luminescence Through Aqueous Host-Guest Complexation. CCS Chem. 2020, 2, 2749-2751. (中國化學會旗艦雜誌)
34. Duan, H.; Li, Y.; Li, Q.; Wang, P.; Liu, X.; Cheng, L.; Yu, Y.; Cao, L.* Host-Guest Recognition and Fluorescence of a Tetraphenylethene-Based Octacationic Cage. Angew. Chem., Int. Ed. 2020, 10.1002/anie.201912730. (SCI, IF = 12.1, 一區)
33. Wang, P.; Miao, X.; Meng, Y.; Wang, Q.; Wang, J.*; Duan, H.; Li, Y.; Li, C.; Liu, J.; Cao, L.* Tetraphenylethene-Based Supramolecular Coordination Frameworks with Aggregation-Induced Emission for Artificial Light-Harvesting System. ACS Appl. Mater. & Interfaces 2020, 12, 22630-22639.. (SCI, IF = 8.5, 一區)
32. Li, Y.; Qin, C.; Li, Q.; Wang, P.; Miao, X.; Jin, H.; Ao, W.; Cao, L.* Supramolecular Organic Frameworks with Controllable Shape and Aggregation-Induced Emission for Tunable Luminescent Materials Through Aqueous Host-Guest Complexation. Adv. Opt. Mater. 2020, 1902154. (SCI, IF = 7.1, 一區)
31. Nian, H.; Li, A.; Li, Y.; Cheng, L.; Wang, L.; Xu, W.; Cao, L.* Tetraphenylethene-Based Tetracationic Dicyclophanes: Synthesis, Mechanochromic Luminescence, and Photochemical Reaction. Chem. Commun.2020, 56, 3195-3198. (SCI, IF = 6.1, 一區)
30. Li, C.; Nian, H.; Dong, Y.*; Li, Y,; Zhang, B.; Cao, L.* Tetraphenylethene-Based Platinum(II) Bis-Triangular Dicycles with Tunable Emissions. Inorg. Chem. 2020, 59, 5713-5720. (SCI, IF = 4.8, 一區)
29. Li, C.; Zhang, B.; Dong, Y.*; Li, Y.; Wang, P.; Yu, Y.; Cheng, L.; Cao, L.* A Tetraphenylethene-Based Pd2L4Metallacage with Aggregation-Induced Emission and Stimuli-Responsive Behavior. Dalton Trans. 2020, DOI: 10.1039/D0DT00469C. (SCI, IF = 4.1, 二區)
28. Li, Y.; Dong, Y.; Cheng, L.; Qin, C.; Nian, H.; Zhang, H.; Yu, Y.; Cao, L.* Aggregation-Induced Emission and Light-Harvesting Function of Tetraphenylethene-Based Tetracationic Dicyclophane. J. Am. Chem. Soc. 2019, 141, 8412-8415.(SCI, IF = 14.1, 一區)
27. Cao, L.*; Wang, P.; Miao, X.; Duan, H.; Wang, H.; Dong, Y.; Ma, R.; Zhang, B.; Wu, B.; Li, X.; Stang, P. J. Diamondoid Frameworks via Supramolecular Coordination: Structural Characterization, Metallogel Formation, and Adsorption Study. Inorg. Chem. 2019, 58, 6268-6275.(SCI, IF = 4.8, 一區)
26. Cheng, L.; Zhang, H.; Dong, Y.; Zhao, Y.; Yu, Y.; Cao, L.* Tetraphenylethene-Based Tetracationic Cyclophanes and Their Selective Recognition for Amino Acids and Adenosine Derivatives in Water. Chem. Commun. 2019, 55, 2372 - 2375.(SCI, IF = 6.6, 一區)
25. Zhang, B.; Dong, Y.; Li, J.; Yu, Y.; Li, C.; Cao, L.* Pseudo[n,m]rotaxanes of Cucurbit[7/8]uril and Viologen-Naphthalene Derivative: A Precise Definition of Rotaxane. Chin. J. Chem. 2019, 37, 262-275. (SCI, IF = 2.03, 三區)
24. 李亞雯; 敖宛彤; 金慧琳; 曹利平* 四苯乙烯衍生物與大環主體在主客體相互作用下的聚集誘導發光, 化學進展, 2019, 31,121-133.(國內權威綜述期刊，SCI)
23. Cao, L.*; Wang, P.; Miao, X.; Dong, Y.; Wang, H.; Duan, H.; Yu, Y.; Li, X.; Stang, P. J.* Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages. J. Am. Chem. Soc. 2018, 140, 7005-7011. (SCI, IF = 14.4, 一區top)
22. Li, Y.; Dong, Y.; Miao, X.; Ren, Y.; Zhang, B.; Wang, P.; Yu, Y.; Li, B.; Isaacs, L.; Cao, L.* Shape-Controllable and Fluorescent Supramolecular Organic Frameworks through Aqueous Host–Guest Complexation. Angew. Chem., Int. Ed., 2018, 57, 729-733. (SCI, IF = 11.4, 一區top)
21. Yu, Y.; Li, Y.; Wang, X.; Nian, H.; Wang, L.; Zhao, Y.; Li, J.; Yang, X.; Liu, S.*; Cao, L.* Cucurbit[10]uril-based [2]Rotaxane: Preparation and Supramolecular Assembly-Induced Fluorescence Enhancement. J. Org. Chem.2017, 82, 5590-5596. (SCI, IF = 4.7, 二區top)
20. Wang, P.; Wu, Y.; Zhao, Y.; Yu, Y.; Zhang, M.*; Cao, L.* Crystalline Nanotubular Framework Constructed by Cucurbit[8]uril for Selective CO2 Adsorption. Chem. Commun. 2017, 53, 5503-5506. (SCI, IF = 6.5, 一區)
19. Li, J.; Zhao, Y.; Dong, Y.; Yu, Y.; Cao, L.;* Wu, B. Supramolecular Organic Frameworks of Cucurbit[n]uril-Based [2]Pseudorotaxanes in the Crystalline State. CrystEngComm, 2016, 18, 7929-7933.（前封面文章，SCI = 3.8, 二區）
18. Dong, Y.; Cao, L.* Functionalization of Cucurbit[n]uril. Progress in Chemistry,（化學進展） 2016, 28, 1039-1053.(國內權威綜述期刊，SCI)
17. Li, J.; Yu, Y.; Luo, L.; Li, Y.; Wang, P.; Cao, L.*; Wu, B. Square [5]Molecular Necklace Formed from Cucurbit[8]uril and Carbazole Derivative. Tetrahedron Lett. 2016, 57, 2306-2310. (SCI, IF = 2.6, 三區)
16. Yu. Y.; Li, J.; Zhang, M.; Cao, L.;* Isaacs, L.* Hydrophobic Monofunctionalized Cucurbit[7]Uril Undergoes Self-Inclusion Complexation and Forms Vesicle-Type Assemblies. Chem. Commun. 2015, 51, 3762-3765. (SCI, IF = 6.7, 一區)
博士後期間工作（2011-2014）：
15. Sigwalt, D.; Sekutor, M.; Cao, L.; Zavalij, P. Y.; Hostas, J.; Ajani, H.; Hobza, P.; Mlimaric-Majerski, K.*; Glaser, R.*; Isaacs, L.* Unraveling the Structure-Affinity Relationship between Cucurbit[n]urils (n = 7, 8) and Cationic Diamondoids. J. Am. Chem. Soc. 2017, 139, 3249-3258. (SCI, IF = 13, 一區top)
14. Cao, L.; Skalamera, D.; Zavalij, P. Y.; Hobza, P.*; Mlinarić-Majerski, K.*; Glaser R.*; Isaacs, L.* Influence of Hydrophobic Residues on the Binding of CB[7] toward Diammonium Ions of Common Ammonium···ammonium Distance. Org. Biomol. Chem. 2015, 13, 6249-6254. (SCI, IF = 3.5)
13. Cao, L.; Šekutor, M.; Zavalij, P. Y.; Mlinarić-Majerski, K.*; Glaser R.*; Isaacs, L.* Cucurbit[7]uril.Guest Pair with an Attomolar Dissociation Constant. Angew. Chem., Int. Ed. 2014, 53, 988-993. (SCI, IF = 13.4, VIP paper and Poster of the frontispiece, 一區top)
12. Zhang, M.#; Cao, L.# (共同第一作者); Isaacs, L.* Cucurbit[6]Uril-Cucurbit[7]Uril Heterodimer Promotes Controlled Self-Assembly Of Supramolecular Networks And Supramolecular Micelles By Self-Sorting Of Amphiphilic Guests. Chem. Commun. 2014, 50, 14756-14759. (SCI, IF = 6.7, 一區)
11. Cao, L.; Isaacs,L.* Absolute and Relative Binding Affinity of Cucurbit[7]uril Towards A Series of Cationic Guests. Supramol. Chem. 2014, 26, 251-258. (SCI, IF = 2.1)
10. Cao, L.; Hettiarachchi, G.; Briken, V.*; Isaacs, L.* Cucurbit[7]uril Containers for Targeted Delivery of Oxaliplatin to Cancer Cells. Angew. Chem., Int. Ed. 2013, 52, 12033-12037. (SCI, IF = 13.4, 一區top)
9. Vinciguerra, B.#; Cao, L.# (共同第一作者); Cannon, J. R.; Zavalij, P. Y.; Fenselau, C.; Isaacs, L.* Synthesis and Self-Assembly Processes of Monofunctionalized Cucurbit[7]uril. J. Am. Chem. Soc. 2012, 134, 13133-12140. (SCI, IF = 11.4, 一區top) (Spotlights on Recent JACS Publications, J. Am. Chem. Soc. 2012, 134, 14265-14266.)
8. Cao, L.; Isaacs, L.* Daisy Chain Assembly Formed from a Cucurbit[6]uril Derivative. Org. Lett. 2012, 14, 3072-3075. (SCI, IF = 6.3, 一區)
7. Lucas, D.; Minami, T.; Iannuzzi, G.; Cao, L.; Wittenberg, J. B.; Anzenbacher, Jr. P.*; Isaacs, L.* Templated Synthesis of Glycoluril Hexamer and Monofunctionalized Cucurbit[6]uril Derivatives. J. Am. Chem. Soc. 2012, 134, 13133-12140. (SCI, IF = 11.4)
博士期間工作（2006-2011）：
6. Cao, L.; Wang, J. G.; Ding, J. Y.; Wu, A. X.*; Isaacs,L.* Reassembly Self-Sorting Triggered by Heterodimerization. Chem. Commun. 2011, 47, 8548-8550. (SCI, IF = 6.7, 一區)
5. Cao, L.; Meng, X. G.; Ding, J. Y.; Chen, Y. F.; Gao, M.; Wu, Y. D.; Li, Y. T.; Wu, A. X.*; Isaacs, L.* Nanotubular Non-Covalent Macrocycle Within Non-Covalent Macrocycle Assembly: (MeOH)(12) Encapsulated in Amolecular Clip Cyclododecamer. Chem. Commun. 2010, 46, 4508-4510. (SCI, IF = 6.7)
4. Cao, L.; Ding, J. Y.; Gao, M.; Wang, Z. H.; Li, J.; Wu, A. X.* Novel and Direct Transformation of Methyl Ketones or Carbinols to Primary Amides by Employing Aqueous Ammonia. Org. Lett. 2009, 11, 3810-3813. (SCI, IF = 6.3) (highlighted by Organic Chemistry Portal: http://www.organic-chemistry.org/abstracts/lit2/649.shtm; ChemInform, 2010, 41, DOI:10.1002/chin.201004082)
3. Cao, L.; Ding, J. Y.; Wang, J. G.; Chen, Y.; Gao, M.; Xue, W. J.; Wu, A. X.* Colorimetric Fluoride Sensor Based on a Bisthiourea Functionalized Molecular Clip. Synlett 2010, 2553-2556. (SCI, IF = 2.8)
2. Cao, L.; Ding, J. Y.; Yin, G. D.; Gao, M.; Li, Y. T.; Wu, A. X.* Thioglycoluril as a Novel Organocatalyst: Rapid and Efficient alpha-Monobromination of 1,3-Dicarbonyl Compounds. Synlett. 2009, 1445-1448. (SCI, IF = 2.8)
1. 曹利平; 高蒙; 李義濤; 丁嬌陽; 吳彥東; 祝艷平; 佘能芳; 吳安心* 二元組裝體集群時的高選擇性雜化重組行為. 中國科學B輯: 化學, 2009, 39, 343-349. (國家核心期刊)
參與編寫專著
1. Cao, L.; Zhao, J.; Yang, D.; Yang, X.-J.; Wu, B.* Hydrogen Bonding-Driven Anion Recognition in Hydrogen Bonded Supramolecular Structures. Springer-Verlag Berlin Herdelberg, 2015, DOI:10.1007/978-3-662-45756-6_5.
*通訊作者（Corresponding author）
獲獎記錄
2021年：國家自然科學基金委優秀青年科學基金
2021年：西北大學優秀博士學位論文指導教師
2021年：陝西省傑出青年科學基金
2020年：西北大學優秀碩士學位論文指導教師
2020年：西北大學2019-2020教學年度優秀教師
2020年：教育部霍英東高校青年教師基金
2020年：Thieme Chemistry Journals Award
2016年：陝西省青年百人計畫
2015年：西北大學優秀青年學術骨幹計畫
2011年：華中師範大學優秀博士論文
