張絜

張絜

張絜，博士，河南師範大學化學化工學院教授。

基本介紹

  • 中文名：張絜
  • 畢業院校：中國科學院蘭州化學物理研究所
  • 學位/學歷：博士
  • 職業：教師
  • 專業方向：金屬有機合成化學，硼化學，均相催化反應機理
  • 任職院校：河南師範大學化學化工學院
個人經歷,主講課程,研究方向,學術成果,

個人經歷

博士, 中國科學院蘭州化學物理研究所，1999
碩士,中國科學院青海鹽湖研究所，1996
2013/09—河南師範大學，化學化工學院，研究員，特聘教授
2010/11—2013/08，美國俄亥俄國家生化試劑公司，研究員，研發部主任
2004/04—2010/10，美國布魯克黑文國家實驗室，辛辛那提大學，研究員
2001/06—2004/03，英國諾丁漢大學，化學系，研究員
1999/08—2001/06，中國科學院化學研究所，博士後

主講課程

高等無機化學, 無機化學前沿。

研究方向

金屬有機合成化學，硼化學，均相催化反應機理。

學術成果

國家自然科學基金資助項目(2016.01-2019.12)：“新型硼氮空間受阻路易斯酸鹼對的合成及其在催化還原二氧化碳中的套用”, 批准號：21571052.
河南省重點科技攻關項目(2015.01-2016.12)：“新型硼氮空間受阻路易斯酸鹼對的合成與催化性能研究”, 批准號：152102210085.
代表性論文：
  1. Liu, T.; Meng,W.; Ma,Q.-Q.;Zhang,J.*; Li,H.; Li,S.;Zhao,Q.; Chen,X.*“Hydroboration of CO2Catalyzed by Bis(phosphinite) Pincer Ligated Nickel Thiolate Complexes”Dalton Trans.,2017,46, 4504-4509.
  2. Ma, Q.-Q.; Liu, T.; Adhikary, A.;Zhang, J.*; Krause, J. A.; Guan, H.* “Using CS2to Probe the Mechanistic Details of Decarboxylation of Bis(phosphinite)-Ligated Nickel Pincer Formate Complexes”Organometallics,2016,35, 4077-4082.
  3. Ma, Q.-Q.; Liu, T.; Li, S.;Zhang, J.*; Chen, X.;* Guan, H.* “Highly Efficient Reduction of Carbon Dioxide with a Borane Catalyzed by Bis(phosphinite) Pincer Ligated Palladium Thiolate Complexes”Chem. Commun.,2016,52, 14262-14265.
  4. Cao,H.-J.; Zhao,Q.; Zhang,Q.-F.;Li,J.; Hamilton,E. J. M.;Zhang, J.*; Wang, L.-S.*; Chen, X.* “Catalyst Design Based on Agostic Interactions: Synthesis, Characterization, and Catalytic Activity of Bis(pyrazolyl)borate Copper Complexes”Dalton Trans.,2016,45, 10194-10199.
  5. Li, H.;Meng, W.;Adhikary,A.;Li,S.;Ma,N.;Zhao,Q.;Yang,Q.;Eberhardt,N. A.;Leahy,K. M.;Krause,J. A.;Zhang,J.*;Chen,X.*;Guan,H.*“Metathesis Reactivity of Bis(phosphinite) Pincer Ligated Nickel Chloride, Isothiocyanate and Azide Complexes”J. Organomet. Chem.,2016,804, 132-141.
  6. Li, S.; Peng, Q.; Chen, X.*; Wang, R.; Zhai, J.; Hu, W.; Ma, J.*;Zhang, J.*; Liu, S. “A Ta/W Mixed Addenda Heteropolyacid with Excellent Acid Catalytic Activity and Proton-Conducting Property”J. Solid State Chem.,2016,243, 1–7.
  7. Zhang, J.; Li, D.;Yao, Y.*; Sun, B.; Zeng, D.; Song, P.-S. “Thermodynamic Properties of LiCl + MgSO4+ H2O at Temperatures from 273.15 K to 373.15 K and Representation with Pitzer Ion-Interaction Model”J. Chem. Eng. Data,2016,61, 2277−2291.
  8. Li, H.; Ma, N.; Meng, W.; Gallucci, J.; Qiu, Y.; Li, S.; Zhao, Q.;Zhang, J.*; Zhao, J.-C.*; Chen, X.* “Formation Mechanisms, Structure, Solution Behavior and Reactivity of Aminodiborane”J. Am. Chem. Soc.,2015,137, 12406-12414.
  9. Lewandowska-Andralojc, A.; Grills, D. C.*;Zhang, J.;Bullock, R. M.*; Miyazawa, A.; Kawanishi, Y.; Fujita, E.* "Kinetic and Mechanistic Studies of Carbon-to-Metal Hydrogen Atom Transfer Involving Os-Centered Radicals: Evidence for Tunneling"J. Am. Chem. Soc.,2014, 136,3572-3578.
  10. Chakraborty, S.;Zhang, J.; Patel, Y. J.; Krause, J. A.; Guan, H.* “Pincer-Ligated Nickel Hydridoborate Complexes: the Dormant Species in Catalytic Reduction of Carbon Dioxide with Boranes”Inorg. Chem.,2013,52, 37-47.
  11. Zhang, J.; Adhikary, A.; King, K. M.; Krause, J. A.; Guan, H.* “Substituent Effects on Ni-S Bond Dissociation Energies and Kinetic Stability of Nickel Arylthiolate Complexes Supported by a Bis(phosphinite)-Based Pincer Ligand”Dalton Trans.2012,41, 7959-7968.
  12. Zhang, J.; Medley, C.; Krause, J. A.; Guan, H.* “Mechanistic Insights into C-S Cross-Coupling Reactions Catalyzed by Nickel Bis(phosphinite) Pincer Complexes”Organometallics,2010, 29,6393-6410.
  13. Chakraborty, S.;Zhang, J.; Krause, J. A.; Guan, H.* “An Efficient Nickel Catalyst for the Reduction of Carbon Dioxide with a Borane”J. Am. Chem. Soc.,2010, 132,8872-8873.
  14. Yi, C. S.*;Zhang, J.“Formation of Bicyclic Pyrroles from the Catalytic Coupling Reaction of 2,5-Disubstituted Pyrroles with Terminal Alkynes, Involving the Activation of Multiple C–H Bonds”Chem. Commun.,2008,2349–2351.
  15. Zhang, J.; Du, P.; Schneider, J.; Jarosz, P.; Eisenberg, R.* “Photogeneration of Hydrogen from Water Using an Integrated System Based on TiO2and Platinum(II) Diimine Dithiolate Sensitizers”J. Am. Chem. Soc.,2007,129, 7726-7727.
  16. Zhang, J.;Grills, D. C.; Huang, K.-W.;Fujita, E.; Bullock, R. M.* “Carbon-to-Metal Hydrogen Atom Transfer: Direct Observation Using Time-Resolved Infrared Spectroscopy”J. Am. Chem. Soc.,2005,127, 15684-15685. (This work was featured inSciencemagazine as an "Editors' Choice" highlight:Science,2005,310, 749).

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