富勒烯包合物的選擇性化學合成及其性能研究

《富勒烯包合物的選擇性化學合成及其性能研究》是甘良兵為項目負責人，北京大學為依託單位的面上項目。

基本介紹

• 中文名：富勒烯包合物的選擇性化學合成及其性能研究
• 項目類別：面上項目
• 項目負責人 ：甘良兵
• 依託單位 ：北京大學

科研成果

序號	標題	類型	作者
1	Carving two adjacent holes on [60]fullerene through two consecutive epoxide to diol to dione transformations	期刊論文	Xiao, Zuo|Yao, Jiayao|Yu, Yuming|Jia, Zhenshan|Gan, Liangbing|
2	The Chemistry of Open-cage Fullerene, Hydroxylamine Mediated Hole-closing and -opening Reactions	期刊論文	Zhang, Jianxin|Yang, Dazhi|Xiao, Zuo|Gan, Liangbing|
3	Bromination-Mediated Regioselective Preparation of Cyclopentadienyl-Type [60]Fullerene Derivatives with Alkoxy, Peroxy, and Bromo or Hydro Addends	期刊論文	Zhang, Jianxin|Xin, Nana|Gan, Liangbing|
4	Synthesis of a green [60]fullerene derivative through cage-opening reactions	期刊論文	Shuming Liu|Changqi Zhang|Xiang Xie|Yuming Yu|Zhifei Dai|Yuanhua Shao|Liangbing Gan|Yuliang Li|
5	Fullerene Doping: Preparation of Azafullerene C59NH and Oxafulleroids C59O3 and C60O4	期刊論文	Nana Xin|Huan Huang|Jianxin Zhang|Zhifei Dai|Liangbing Gan|
6	Synthesis of Decahydropyrrolo[2,1,5-cd]indolizine through Consecutive [2+3] Cycloadditions and 6-Exo-Trig Cyclization	期刊論文	Cui, Peipei|Xu, Liang|Shi, Zhangjie|Gan, Liangbing|
7	Heating a bowl of single-molecule-soup: structure and desorption energetics of water-encapsulated open-cage [60] fullerenoid anions in the gas-phase	期刊論文	Oliver He|* Tatjana Karpuschkin|Matthias Vonderach|Patrick Weis|Yuming Yu|Liangbing Gan|Wim Klopper|Manfred M. Kappes|
8	Synthesis of 18-Membered Open-Cage Fullerenes through Controlled Stepwise Fullerene Skeleton Bond Cleavage Processes and Substituent-Mediated Tuning of the Redox Potential of Open-Cage Fullerenes	期刊論文	Yu, Yuming|Xie, Xiang|Zhang, Tong|Liu, Shuming|Shao, Yuanhua|Gan, Liangbing|Li, Yuliang|
9	Synthesis and Reactivity of 2H-Pyran Moiety in [60]Fullerene Cage Skeleton	期刊論文	Yang, Dazhi|Shi, Lijun|Huang, Huan|Zhang, Jianxin|Gan, Liangbing|
10	Head-to-Tail and Back-to-Back Dimerization of an Open-Cage Fullerene Derivative through π-π Interaction-Based Self-Assembly	期刊論文	Shuming Liu|Qianyan Zhang|Yuming Yu|Liangbing Gan|
11	Preparation of a 12-Membered Open-Cage Fullerendione through Silane/Borane-Promoted Formation of Ketal Moieties and Oxidation of a Vicinal Fullerendiol	期刊論文	Zhang, Gang|Zhang, Qianyan|Jia, Zhenshan|Liang, Sisi|Gan, Liangbing|Li, Yuliang|
12	Switchable Open-Cage Fullerene for Water Encapsulation	期刊論文	zhang, Qianyan|Pankewitz, Tobias|Liu, Shuming|Klopper, Wim|Gan, Liangbing|
13	Selective Synthesis of Fullerenol Derivatives with Terminal Alkyne and Crown Ether Addends	期刊論文	Huang, Huan|Zhang, Gang|Liang, Sisi|Xin, Nana|Gan, Liangbing|
14	Facile preparation of fullerenyl boronic esters	期刊論文	Dai, Zhifei|Jiang, Zhongping|Zhang, Gang|Xin, Nana|Gan, Liangbing|
15	Preparation of Open-Cage Fullerenes and Incorporation of Small Molecules Through Their Orifices	期刊論文	Gan, Liangbing|Yang, Dazhi|Zhang, Qianyan|Huang, Huan|
16	Fullerenyl azide: synthesis and reactivity	期刊論文	Jiang, Zhongping|Xiao, Zuo|Zhang, Gaihong|Gan, Liangbing|Wang, Dian|Zhang, Wenxiong|
17	Synthesis of fullerene multiadducts with mixed oxygen and nitrogen addends including five secondary amino groups	期刊論文	Gang Zhang|Xiangqing Hu|Liangbing Gan|Yuliang Li|
18	Preparation of Ketolactone and Bislactone [60]Fullerene Derivatives and Their Conversion into Open-Cage Fullerenes with a 12-or 15-Membered Orifice	期刊論文	Zhang, Jianxin|Wang, Fudong|Xin, Nana|Yang, Dazhi|Gan, Liangbing|
19	Synthesis of decahydropyrrolo[2,1,5-cd]indolizine derivatives through RuCl3/AgOTf induced alkene-alkene and alkene-arene double cycloisomerizations	期刊論文	Cui, Peipei|Xu, Liang|Cheng, Hao|Gan, Liangbing|
20	Facile Synthesis of Isomerically Pure Fullerenols and Formation of Spherical Aggregates from C-60(OH)(8)	期刊論文	Zhang, Gang|Liu, Yun|Liang, Dehai|Gan, Liangbing|Li, Yuliang|

項目摘要

富勒烯包合物是富勒烯空腔內含有其它原子或分子的一類富勒烯衍生物，這類化合物的化學合成具有選擇性好效率高的特點，而且可以合成傳統的物理方法所不能合成的富勒烯包合物，有關研究是富勒烯化學的前沿研究課題。本項目以前期工作為基礎，設計了多個具有不同孔徑大小和不同官能團的開孔富勒烯衍生物，計畫將一些常見的小分子如氫氣、氨氣、水、硫化氫等通過開孔富勒烯的缺口填入富勒烯空腔，最後再經過缺口處官能團的化學反應來減小缺口的大小或將缺口完全關閉從而得到穩定的富勒烯包合物。主要合成路線依據富勒烯過氧化物的化學反應，利用該反應本課題組已經合成了一些開孔富勒烯衍生物並得到了水分子的包合物，本項目的研究內容是這些初步結果的進一步拓展。由於富勒烯所特有的骨架結構，很多經典的有機化學反應不能套用於富勒烯體系，本項目的部分研究內容探索性很強。本項目還將測定所合成富勒烯包合物的功能特性，探討富勒烯的開發套用途徑。