《含剛性側鏈聚合物的聚合物刷：可控合成與性能研究》是范星河為項目負責人，北京大學為依託單位的重點項目。
基本介紹
- 中文名：含剛性側鏈聚合物的聚合物刷：可控合成與性能研究
- 項目類別 ：重點項目
- 項目負責人：范星河
- 依託單位 ：北京大學
科研成果,項目摘要,
科研成果
序號 | 標題 | 類型 | 作者 |
|---|---|---|---|
1 | Construction of a new class of MJCP system | 會議論文 | 張振宇|郝德朝|沈志豪|周其鳳| |
2 | 基於PLED的甲殼液晶型聚合物分子設計 | 會議論文 | 范星河|沈志豪|周其鳳| |
3 | Synthesis and Properties of Comb Polymers with Semirigid Mesogen-Jacketed Polymers as Side Chains | 期刊論文 | Zheng C.|Shen Z.|Liang D.|Fan X.| |
4 | 高溫、寬溫域熱塑性液晶彈性體的結構與性能 | 會議論文 | 范星河|張振宇|張其凱|沈志豪| |
5 | POSS-Containing Jacketed Polymer: Hybrid Inclusion Complex with Hierarchically Ordered Structures at Sub-10 nm and Angstrom Length Scales | 期刊論文 | Pan Y.|Shen Z. H.|Fan X. H.|Zhou Q. F.| |
6 | 近10nm超分子有序結構聚合物的構築與自組裝 | 會議論文 | 朱宇峰|候平平|沈志豪|| |
7 | POSS基元的甲殼型液晶高分子的合成和相行為 | 會議論文 | 張振宇|沈志豪|周其鳳|| |
8 | 剛性側鏈液晶聚合物基梳狀聚合物的合成與功能化 | 會議論文 | 平靜|候平平|張振宇|沈志豪| |
9 | Synthesis of Comb Polyphenylenes by Suzuki Coupling from AB Macromonomers | 期刊論文 | Zhou F.|Zhang Q.-K.|Shen Z.|Fan X.-H.| |
10 | Microphase Separation and High Ionic Conductivity at High Temperatures of Lithium Salt-Doped Amphiphilic Alternating Copolymer Brush with Rigid Side Chains | 期刊論文 | Wu B.|Zhou H. H.|Shen Z.|Fan X. H.| |
11 | Mesogen-Jacketed Liquid Crystalline Polymers with a Polynorbornene Main-Chain: Green Synthesis and Phase Behaviors | 期刊論文 | Qiao Y.-Y.|Shen Z.|Fan X.-H.|Zhou Q.-F.| |
12 | Effects of Rigid Cores and Flexible Tails on the Phase Behaviors of Polynorbornene-Based Mesogen-Jacketed Liquid Crystalline Polymers | 期刊論文 | Wang Q.|Hou P.P.|Shen Z. H.|Fan X. H.| |
13 | Precise size control of sub-10nm structures of cholesteryl-containing mesogen-jacketed liquid crystalline polymers | 期刊論文 | Zhang Z.-Y.|Liao P.-L.|Shen Z.|Fan X.-H.| |
14 | Synthesis and Characterization of New Liquid Crystalline Thermoplastic Elastomers Containing Mesogen-Jacketed Liquid Crystalline Polymers | 期刊論文 | Shen Z.|Yu J. P.|Wu Y. X.|Fan X.-H.| |
15 | Synthesis and Sub-10 nm Supramolecular Self-Assembly of a Nanohybrid with a Polynorbornene Main Chain and Side-Chain POSS Moieties | 期刊論文 | Pan H.-B.|Yang S.|Shen Z. H.|Fan X. H.| |
16 | Synthesis and Properties of a Coil-g-Rod Polymer Brush by Combination of ATRP and Alternating Copolymerization | 期刊論文 | Qiao Y.|Tian H.|Shen Z.|Fan X.| |
17 | Jacketed Homopolymer with Bipolar Dendritic Side Groups and Its Applications in Electroluminescent Devices | 期刊論文 | Chu Z.|Shen Z.|Zou D.|Fan X.| |
18 | Synthesis and Phase Behavior of a Polynorbornene-Based Molecular Brush with Dual “Jacketing” Effects | 期刊論文 | Zhou S.|Shen Z. H|Zheng S. J.|Fan X. H.| |
19 | Synthesis and Properties of a Rod-g-Rod Bottlebrush with a Semirigid Mesogen-Jacketed Polymer as the Side Chain | 期刊論文 | Qu W.|Zhu Y.-F.|Shen Z.|Fan X.-H.| |
20 | Synthesis and Phase Behavior of a New 2-Vinylbiphenyl-Based Mesogen-Jacketed Liquid Crystalline Polymer with High Glass Transition Temperature and Low Threshold Molecular Weight | 期刊論文 | Zhu Y.-F.|Liang Y.-R.|Shen Z.|Fan X.-H.| |
21 | Hierarchically Self-Assembled Amphiphilic Alternating Copolymer Brush Containing Side-Chain Cholesteryl Units | 期刊論文 | Zhou S.|Pan H.|Shen Z.|Fan X.-H.| |
22 | New Morphologies and Phase Transitions of Rod-Coil Dendritic-Linear Block Copolymers Depending on Dendron Generation and Preparation Procedure | 期刊論文 | Chen C.|Li Z.|Shen Z.|Fan X.-H.| |
23 | Synthesis and properties of a new high-temperature liquid crystalline thermoplastic elastomer based on mesogen-jacketed liquid crystalline polymer | 期刊論文 | Yu J. P.|Wu Y. X.|Shen Z.|Fan X.-H.| |
24 | 高分子工程基礎 | 學術專著 | 謝曉峰|范星河| |
25 | Synthesis and Characterization of Mesogen-Jacketed Liquid Crystalline Polymers through Hydrogen-Bonding | 期刊論文 | Zheng J. K.|Shen Z.|Fan X.|Zhou Q.| |
26 | Competition and Promotion between Two Different Liquid Crystalline Building Blocks: Mesogen-Jacketed Liquid Crystalline Polymers and Triphenylene Discotic Liquid Crystals | 期刊論文 | Guan X.-L.|Shen Z.|Fan X.-H.|Zhou Q.-F.| |
27 | Hierarchical Structures in a Combined Main-Chain/Side-Chain Liquid Crystalline Polymer with a Polynorbornene Backbone and Multi-Benzene Side-Chain Mesogens | 期刊論文 | Wang Q.|Zhang M. Y.|Shen Z. H.|Fan X. H.| |
28 | Ordered Nanostructures at Two Different Length Scales Mediated by Temperature: a Triphenylene-Containing Mesogen-Jacketed Liquid Crystalline Polymer with a Long Spacer | 期刊論文 | Zou D.-C.|Sun P.-C.|Fan X.-H.|Zhou Q.-F.| |
29 | Mesogen-Jacketed Liquid Crystalline Polymers: from Molecular Design to Polymer Light-Emitting Diode Applications | 期刊論文 | Gao L.|Shen Z.|Fan X.|Zhou Q.| |
30 | Influence of Fluorinated Substituent and Terminal Length on Phase Behavior of Mesogen-Jacketed Liquid Crystalline Polymers with a Biphenyl Mesogen | 期刊論文 | Cai H.|Shen Z.|Fan X.|Zhou Q.| |
31 | Synthesis and Characterization of Electrophosphorescent Jacketed Conjugated Polymers | 期刊論文 | Zhou F.|Shen Z.|Zou D.|Fan X.| |
32 | Effects of Dendron Generation and Salt Concentration on Phase Structures of Dendritic-Linear Block Copolymers with a Semi-rigid Dendron Containing PEG Tails | 期刊論文 | Cai H.|Jiang G.|Shen Z.|Fan X.-H.| |
33 | Solvent-Induced Hierarchical Self-Assembly of Amphiphilic PEG(Gm)-b-PS Dendritic-Linear Block Copolymers | 期刊論文 | Cai H. H.|Jiang G. L.|Shen Z.|Fan X. H.| |
34 | 高分子化學 | 學術專著 | 范星河|謝曉峰| |
項目摘要
在本項目中我們選取通過可控聚合方法、設計合成一系列以剛性甲殼型液晶聚合物為側鏈、主鏈為柔性/半剛性/剛性的聚合物刷作為研究對象。主要研究內容：（1）研究剛性側鏈聚合物和主鏈聚合物的結構、組成、功能性與聚合物刷體系的凝聚態結構，探索製備用傳統技術難以獲得的可調有序、多層次、多尺度納米新型材料。（2）利用甲殼型聚合物結構特點，系統研究聚合物刷分子結構和剛性側基長度、直徑、表面化學性質隨外界化學物理環境變化的聚集態與在溶液中組裝、高級有序結構構築、功能和性能，考察外場（特別是電場）對鏈構象及凝聚態結構穩定性，探討在化學生物螢光感測器中的潛在套用。（3）根據聚合物刷結構特點，系統研究剛性側鏈聚合物液晶相行為與聚合物刷自組裝性質及流變性能之間的關係，發展製備器件功能化方面的理論方法和實驗技術，探索這類特殊拓撲結構在光電器件等功能材料方面的潛在套用。本項目關於含剛性側鏈聚合物的聚合物刷的研究國內外尚屬空白。
