《北京高等教育精品教材:定量化學分析(英文)》是化學與環境工程系的一門主幹基礎課，它包括定量化學分析理論課和實驗課，授課對象為工業分析專業、食品理化檢驗專業、岩礦分析專業、環境監測與評價專業的在校學生。定量化學分析有很強的實踐性和實用性，同時又有嚴密、系統的理論，是理論與實際密切結合的學科。學習定量化學有利於培養學生嚴謹的科學態度和實事求是的作風，使學生初步掌握科學研究的技能並初步具備科學研究的綜合素質。
基本介紹
- 書名：北京高等教育精品教材:定量化學分析
- 類型：科學與自然
- 出版日期：2009年10月1日
- 語種：簡體中文, 英語
- ISBN：9787301156599
- 作者：李娜
- 出版社：北京大學出版社
- 頁數：308頁
- 開本：16
- 品牌：北京大學出版社
內容簡介,圖書目錄,
內容簡介
《北京高等教育精品教材:定量化學分析(英文)》由北京大學出版社出版。
圖書目錄
CHAPTER 1 INTRODUCTION OF ANALYTICAL CHEMISTRY
1.1 What is Analytical Chemistry
1.2 Steps in the Development of an Analytical Method
1.3 Classification of Quantitative Analytical Methods
1.3.1 Chemical Analysis
1.3.2 Instrumental Analysis
1.4 Principles of Volumetric Titration
1.4.1 Basic Terms
1.4.2 Requirements of Titration Reactions
1.4.3 Classification of Titration Processes
1.4.4 Primary Standards and Standard Solutions
1.4.5 Basic Apparatus in Chcmical Analyses
1.5 Calculations in Volumctric Titration
1.5.1 Preparation of Siandard Solutions
1.5.2 Titration Results
CHAPTER 2 DATA ANALYSIS
2.1 Error and Classification
2.1.1 Accuracy and Prccision
2.1.2 Errors and Deviation
2.1.3 Systematic and Random Errors
2.2 Distribution of Random Errors
2.2.1 Frequency Distribution
2， 2.2 Normal Distribution
2.2.3 Predicting the Probability of Random Errors—Area under Gaussian Curve
2.3 Statistical Data Treatment
2.3.1 Estimation of Popuiation Mean （μ） and Population Standard Devration （σ）
2.3.2 Confidence Interval for Population Mean
2.3.3 Statistical Aids to Hypothesis Testing
2.3.4 Detection of Gross Errors
2.4 Propagation of Error
2.4.1 Systematic Errors
2.4.2 Random Errors （Standard Deviation）
2.4.3 Maximum Errors （ER）
2.4.4 Distribution of Errors
2.5 Significant Figure Convention
2.5.1 Significant Figures
2.5.2 Numerical Rounding in Calculations
CHAPTER 3 ACID—BASE EQUILIBRIUM
3.1 Equilibrium Constants and Effect of Electrolytes
3.2 Acid—base Reactions and Equilibria
3.2.1 Acid and Base—Brφnsted Concepi
3.2.2 Dissociation of Acid or Base and Acid—base Equilibria
3.2.3 Magnitude of Dissociating Species at a Given pH： x—values
3.3 Solving Equilibrium Calculations Using pH Calculations as an Example
3.3.1 General Approaches （Systematic Approaches）
3.3.2 pH Calculations
3.4 Buffer Solutions
3.4.1 pH Calculations of Buffer Solutions
3.4.2 Buffer Capacity
3.4.3 Preparation of Buffers
CHAPTER 4 ACID—BASE TITRATION
1.1 Acid/Base Indicators
4.1.1 Principle
4.1.2 Examples
4.1.3 Titration Errors
4.1.4 Factors Influcncing Performance
4.2 Titration Curves and Selection of Indicators
4.2.1 Strong Acids （Bases）
4.2.2 Monoprotic Acids （Bases）
4.2.3 Strong and Weak Acids （Bases）
4.2.4 Polyfunctional Weak Acids （Bases）
4.2.5 Mixture of Weak Acids （Bases）
4.3 Titration Error Calculations
4.3.1 Strong Acids （Bases）
4.3.2 Monoprotic Weak Acids （Bases）
4.3.3 Polyfunctional Acids （Bases）
4.4 Preparation of Standard Solutions
4.4.1 Standard Acid Solutions
4.4.2 Standard Base Solutions
4.4.3 The Carbonate Error
4.5 Examples of Acid—base Titrations
4.5.1 Determination of Total Alkalinity
4.5.2 Determination of Nitrogen
4.5.3 Determination of Boric Acid
4.6 Acid—base Titrations in Non—aqueous Solvents
4.6.1 Non—aqueous Solvents
4.6.2 Examples of Non—aqueous Titrations
CHAPTER 5 COMPLEXATION REACTION AND COMPLEXOMETRIC TITRATION
5.1 Complexes and Formation Constants
5.1.1 Formation Constants
5.1.2 Concentration of MLn in Complexation Equilibria
5.1.3 Ethylenediaminetetraacetic Acid （EDTA） and Metal—EDTA Complexes
5.1.4 Side Reaction Coefficients and Conditionai Formation Constants in Complexation Reactions
5.2 Metallochromic Indicators
5.2.1 How a Metallochromic Indicator Works
5.2.2 Color Transition Point pM （（pM）） for Metallochromic Indicators
5.2.3 Frequently Used Metallochromic Indicalors
5.3 Titration Curves and Titration Errors
5.3.1 Titration Curves
5.3.2 Titration Errors
5.3.3 pH Control in Complexometric Titrations
5.4 Selective Titrations of Metal Ions in the Presence of Multiple Metal Ions
5.4.1 Selective Titration by Regulatmg pH
5.4.2 Selective Titration Using Masking Reagents
5.5 Applications of Complexometric Titrations
5.5.1 Buffer Selection in Complexometric Titrations
5.5.2 Titration Methods and Applications
5.5.3 Preparation of Standard Soiutions
……
CHAPTER 6 REDOX EQUILIBRIUM AND TITRATION
CHAPTER 7 PRECIPITATION EQUILIBRIUM， TITRATION， AND GRAVIMETRY
CHAPTER 8 SPECTROPHOTOMETRY
CHAPTER 9 INTRODUCTION TO ANALYTICAL SEPARATION
CHAPTER 10 SOLVING A REAL ANALYTICAL PROBLEM
APPENDICES
ANSWERS
INDEX
PERIODIC TABLE OF THE ELEMENTS
1.1 What is Analytical Chemistry
1.2 Steps in the Development of an Analytical Method
1.3 Classification of Quantitative Analytical Methods
1.3.1 Chemical Analysis
1.3.2 Instrumental Analysis
1.4 Principles of Volumetric Titration
1.4.1 Basic Terms
1.4.2 Requirements of Titration Reactions
1.4.3 Classification of Titration Processes
1.4.4 Primary Standards and Standard Solutions
1.4.5 Basic Apparatus in Chcmical Analyses
1.5 Calculations in Volumctric Titration
1.5.1 Preparation of Siandard Solutions
1.5.2 Titration Results
CHAPTER 2 DATA ANALYSIS
2.1 Error and Classification
2.1.1 Accuracy and Prccision
2.1.2 Errors and Deviation
2.1.3 Systematic and Random Errors
2.2 Distribution of Random Errors
2.2.1 Frequency Distribution
2， 2.2 Normal Distribution
2.2.3 Predicting the Probability of Random Errors—Area under Gaussian Curve
2.3 Statistical Data Treatment
2.3.1 Estimation of Popuiation Mean （μ） and Population Standard Devration （σ）
2.3.2 Confidence Interval for Population Mean
2.3.3 Statistical Aids to Hypothesis Testing
2.3.4 Detection of Gross Errors
2.4 Propagation of Error
2.4.1 Systematic Errors
2.4.2 Random Errors （Standard Deviation）
2.4.3 Maximum Errors （ER）
2.4.4 Distribution of Errors
2.5 Significant Figure Convention
2.5.1 Significant Figures
2.5.2 Numerical Rounding in Calculations
CHAPTER 3 ACID—BASE EQUILIBRIUM
3.1 Equilibrium Constants and Effect of Electrolytes
3.2 Acid—base Reactions and Equilibria
3.2.1 Acid and Base—Brφnsted Concepi
3.2.2 Dissociation of Acid or Base and Acid—base Equilibria
3.2.3 Magnitude of Dissociating Species at a Given pH： x—values
3.3 Solving Equilibrium Calculations Using pH Calculations as an Example
3.3.1 General Approaches （Systematic Approaches）
3.3.2 pH Calculations
3.4 Buffer Solutions
3.4.1 pH Calculations of Buffer Solutions
3.4.2 Buffer Capacity
3.4.3 Preparation of Buffers
CHAPTER 4 ACID—BASE TITRATION
1.1 Acid/Base Indicators
4.1.1 Principle
4.1.2 Examples
4.1.3 Titration Errors
4.1.4 Factors Influcncing Performance
4.2 Titration Curves and Selection of Indicators
4.2.1 Strong Acids （Bases）
4.2.2 Monoprotic Acids （Bases）
4.2.3 Strong and Weak Acids （Bases）
4.2.4 Polyfunctional Weak Acids （Bases）
4.2.5 Mixture of Weak Acids （Bases）
4.3 Titration Error Calculations
4.3.1 Strong Acids （Bases）
4.3.2 Monoprotic Weak Acids （Bases）
4.3.3 Polyfunctional Acids （Bases）
4.4 Preparation of Standard Solutions
4.4.1 Standard Acid Solutions
4.4.2 Standard Base Solutions
4.4.3 The Carbonate Error
4.5 Examples of Acid—base Titrations
4.5.1 Determination of Total Alkalinity
4.5.2 Determination of Nitrogen
4.5.3 Determination of Boric Acid
4.6 Acid—base Titrations in Non—aqueous Solvents
4.6.1 Non—aqueous Solvents
4.6.2 Examples of Non—aqueous Titrations
CHAPTER 5 COMPLEXATION REACTION AND COMPLEXOMETRIC TITRATION
5.1 Complexes and Formation Constants
5.1.1 Formation Constants
5.1.2 Concentration of MLn in Complexation Equilibria
5.1.3 Ethylenediaminetetraacetic Acid （EDTA） and Metal—EDTA Complexes
5.1.4 Side Reaction Coefficients and Conditionai Formation Constants in Complexation Reactions
5.2 Metallochromic Indicators
5.2.1 How a Metallochromic Indicator Works
5.2.2 Color Transition Point pM （（pM）） for Metallochromic Indicators
5.2.3 Frequently Used Metallochromic Indicalors
5.3 Titration Curves and Titration Errors
5.3.1 Titration Curves
5.3.2 Titration Errors
5.3.3 pH Control in Complexometric Titrations
5.4 Selective Titrations of Metal Ions in the Presence of Multiple Metal Ions
5.4.1 Selective Titration by Regulatmg pH
5.4.2 Selective Titration Using Masking Reagents
5.5 Applications of Complexometric Titrations
5.5.1 Buffer Selection in Complexometric Titrations
5.5.2 Titration Methods and Applications
5.5.3 Preparation of Standard Soiutions
……
CHAPTER 6 REDOX EQUILIBRIUM AND TITRATION
CHAPTER 7 PRECIPITATION EQUILIBRIUM， TITRATION， AND GRAVIMETRY
CHAPTER 8 SPECTROPHOTOMETRY
CHAPTER 9 INTRODUCTION TO ANALYTICAL SEPARATION
CHAPTER 10 SOLVING A REAL ANALYTICAL PROBLEM
APPENDICES
ANSWERS
INDEX
PERIODIC TABLE OF THE ELEMENTS
