《功能化離子液體在分散液相微萃取中的萃取性能研究》是何麗君為項目負責人，河南工業大學為依託單位的青年科學基金項目。
基本介紹
- 中文名：功能化離子液體在分散液相微萃取中的萃取性能研究
- 項目類別 ：青年科學基金項目
- 依託單位：河南工業大學
- 項目負責人 ：何麗君
科研成果,項目摘要,
科研成果
序號 | 標題 | 類型 | 作者 |
|---|---|---|---|
1 | A new 1,3-dibutylimidazolium hexafluorophosphate ionic liquid-based dispersive liquid-liquid microextraction to determine organophosphorus pesticides in water and fruit samples by high-performance liquid chromatography | 科研獎勵 | 何麗君|駱獻麗|江秀明|屈凌波| |
2 | 基於離子液體的分散液相微萃取及流動相添加劑研究 | 科研獎勵 | 駱獻麗|何麗君（導師）| |
3 | A multiple-function stationary phase based on perhydro-26-membered hexaazamacrocycle for high performance liquid chromatography | 科研獎勵 | 何麗君|張靜|孫銀娟|劉捷|江秀明| |
4 | Ionic liquid-based dispersive liquid-liquid microextraction followed high- performance liquid chromatography for the determination of organophosphorus pesticides in water sample | 科研獎勵 | 何麗君|駱獻麗|謝洪學|王春健|江秀明| |
5 | 脂肪基咪唑離子液體-LPME-HPLC分析水中痕量有機污染物的研究 豫科鑒委字[2011]第1009號 | 科研獎勵 | 何麗君|趙文杰|劉建平|買文鵬|駱獻麗| |
6 | 苄基離子液體液液微萃取-高效液相色譜測定水中苯系物 | 會議論文 | 梅玉雯|何麗君| |
7 | 羥基功能化離子液體對苯環化合物的萃取性能 | 會議論文 | 梅玉雯|何麗君| |
8 | 大環化合物固定相分離氨基甲酸酯農藥和有機磷農藥 | 會議論文 | 張靜|何麗君| |
9 | 離子液體-DLLME-HPLC測定小麥中有機氯農藥 | 會議論文 | 劉偉|何麗君| |
10 | 苄基功能化離子液體萃取有機磷農藥的研究 | 會議論文 | 廖元|何麗君| |
11 | 分散液液微萃取-HPLC法測定水中碘酸根離子 | 會議論文 | 景帥鵬|何麗君| |
12 | 離子液體-分散液相微萃取富集水樣中的碘酸根離子 | 會議論文 | 劉龍輝|張紅霞|何麗君| |
13 | Two new azamacrocycle-based stationary phases for high-performance liquid chromatography: Preparation and comparative evaluation | 期刊論文 | Lijun He|Mingliang Zhang|Longhui Liu|Xiuming Jiang|Pu Mao|Lingbo Qu| |
14 | SFODME-HPLC測定環境水樣中的4種氨基甲酸酯 | 會議論文 | 劉龍輝|何麗君| |
15 | 基於[HMIM][Tf2N]的分散液液微萃取氨基甲酸酯 | 會議論文 | 張凱歌|何麗君| |
16 | A New Macrocyclic Polyamine-Bonded Silica Stationary Phase for HPLC | 會議論文 | 張明亮|何麗君| |
17 | 原子類型電拓撲狀態指數及QSAR模型對離子液體萃取性能的預測 | 會議論文 | 劉偉|展海軍|何麗君| |
18 | Determination of trace copper in food samples by flame atomic absorption spectrometry after solid phase extraction on modified soybean hull | 期刊論文 | Xiang, Guoqiang|Zhang, Yingming|Jiang, Xiuming|He, Lijun|Fan, Lu|Zhao, Wenjie| |
19 | 基於[BBIM][Tf2N]離子液體的分散液液微萃取水中的有機污染物 | 會議論文 | 張凱歌|何麗君| |
20 | Determination of three organochlorine pesticides in wheat based on benzyl functional ionic liquid-dispersive liquid-liquid mircoextraction coupled with HPLC. | 會議論文 | 劉偉|何麗君| |
21 | Dispersive Liquid-Liquid Microextraction Combined with Electrothermal Atomic Absorption Spectrometry for Determination of Trace Lead in Drinking Water Samples | 期刊論文 | Liu, Y. L.|Wu, X. Y.|Xiang, G. Q.|He, L. J.|Jiang, X. M.|Zhang, H. X.|Chen, F. P.| |
22 | Effective indirect enrichment and determination of nitrite ion in water and biological samples using ionic liquid-dispersive liquid-liquid microextraction combined with high-performance liquid chromatography | 期刊論文 | He, Lijun|Zhang, Kaige|Wang, Caijuan|Luo, Xianli|Zhang, Shusheng| |
23 | A new 14-membered tetraazamacrocycle-bonded silica stationary phase for reversed-phase high-performance liquid chromatography | 期刊論文 | He, Lijun|Zhang, Mingliang|Zhao, Wenjie|Liu, Jie|Jiang, Xiuming|Zhang, Shusheng|Qu, Lingbo| |
24 | 離子液體作薄層色譜添加劑對胺基酸分離的研究 | 期刊論文 | 劉建平|何麗君| |
25 | Determination of Trace Cadmium in Food Samples by Electrothermal Atomic Absorption Spectrometry After Cloud Point Extraction | 期刊論文 | Xiang, G. Q.|Wen, S. P.|Wu, X. Y.|Liu, Y. L.|Jiang, X. M.|He, L. J.| |
26 | A multiple-function stationary phase based on perhydro-26-membered hexaazamacrocycle for high-performance liquid chromatography | 期刊論文 | He, Lijun|Zhang, Jing|Sun, Yinjuan|Liu, Jie|Jiang, Xiuming|Qu, Lingbo| |
27 | Selective cloud point extraction for the determination of cadmium in food samples by flame atomic absorption spectrometry | 期刊論文 | Xiang, Guoqiang|Wen, Shengping|Wu, Xiaoyun|Jiang, Xiuming|He, Lijun|Liu, Yulan| |
28 | A new 1,3-dibutylimidazolium hexafluorophosphate ionic liquid-based dispersive liquid-liquid microextraction to determine organophosphorus pesticides in water and fruit samples by high-performance liquid chromatography | 期刊論文 | He, Lijun|Luo, Xianli|Jiang, Xiuming|Qu, Lingbo| |
29 | Tetraazacalix[2]arene[2]triazine modified silica gel: A novel multi-interaction stationary phase for mixed-mode chromatography | 期刊論文 | Zhao, Wenjie|Qian, Jiang|Zhang, Shusheng|Wang, Wenjing|Chang, Hong|Cui, Shiwei|Hu, Kai|He, Lijun|Lu, Kui|Liu, Jinxia|Wu, Yangjie| |
30 | Ionic liquid-based dispersive liquid-liquid microextraction followed high-performance liquid chromatography for the determination of organophosphorus pesticides in water sample | 期刊論文 | Lijun He|Xianli Luo|Hongxue Xie|Chunjian Wang|Xiuming Jiang|Kui Lu| |
項目摘要
本項目擬選取一系列-OH、-NH2、-SiR3功能化離子液體，將其用於分散液相微萃取中的萃取劑，與高效液相色譜聯用，研究功能化離子液體對水基體樣品中痕量極性有機物（如酚）的萃取及富集作用。根據功能化離子液體的結構描述符（陽離子種類、陰離子種類、結構對稱性等）和萃取效能描述符（富集因子和萃取回收率），結合溶質的描述符（偶極矩和pK值等），運用化學計量學方法，探討離子液體各描述符與萃取效能的相關性，獲取離子液體對富集酚類化合物的構-效關係規律。在上述相關性模型的指導下，預測新型功能化離子液體的萃取性能，針對特定分析物，設計和定製最優的功能化離子液體，提高萃取富集效能。結合萃取體系的熱力學性質與微觀結構，探討離子液體-分散液相微萃取相關萃取機理。本課題對發展痕量物質的微萃取新體系具有重要的學術意義和實際套用價值。
