中國科學院化學研究所研究員、博士生導師
中國科學院大學教授、博士生導師
主要從事天然高分子化學與物理、高分子溶液和凝膠、高分子結構和性能調控、高分子加工過程中的物理化學問題、高性能纖維方面的研究工作。主持和參加國家自然科學基金面上項目(主持5項)和創新群體項目、科技部高技術研究發展計畫(863)項目(項目編號:2015AA03A204,主持)、國家重點基礎研究發展計畫(973)項目(骨幹,項目編號:2006CB605304和2011CB605600)、中國科學院創新項目、教育部留學回國人員科研啟動基金、國家分子科學中心、天津市科委、企業合作研究等項目多項。已經國際學術期刊上發表SCI收錄研究論文100多篇,授權中國發明專利20餘項。多次在國內外學術會議上做邀請和分會報告,出版專著1部、英文專著3章。
中國化學會會員、中國化學會纖維素專業委員會委員、美國化學會會員、中國造紙學會會員、中國造紙學會納米纖維素及材料專業委員會理事。
基本介紹
- 中文名:劉瑞剛
- 國籍:中國
- 民族:漢
- 出生地:山東省單縣
- 出生日期:1970年9月14日
- 職業:研究員
- 畢業院校:東華大學
- :
簡歷
研究方向
- 天然高分子化學與物理
- 高性能碳纖維結構與性能
- 高分子材料結構與性能
發表論文
- Kang, H. L.; Liu, R. G.*; Huang, Y.* Cellulose-based gels. Macromol. Chem. Phys. 2016, 217(12), 1322-1334.
- Zhang, C.; Li, P. P.; Zhang, Y. J.; Lu, F.; Li, W. W.; Kang, H. L.; Xiang, J. F.; Huang, Y.*; Liu, R. G.* Hierarchical porous structures in cellulose: NMR relaxometry approach. Polymer 2016, 98, 237-243.
- Lu, F.; Zhang, C.; Kang, H. L.; Huang, Y.*; Liu, R. G.* Extensional rheology of cellulose/NaOH/urea/H2O solutions. Cellulose 2016, 23(5), 2877-2885.
- Guo, X. S.; Cheng, Y. X.; Fan, Z.; Feng, Z. H.; He, L. L.*; Liu, R. G.; Xu, J. New insights into orientation distribution of high strength polyacrylonitrile-based carbon fibers with skin-core structure. Carbon 2016, 109, 444-452.
- Cao, C.; Kang, H. L.*; Li, P. P.; Zhang, C.; Li, W. W.; Huang, Y.; Liu, R. G.* Adsorption of fluorinion on polyacrylamidoxime decorated wool and the mechanism. Acta Polym. Sin. 2016, (4), 486-493.
- Zhang, C.; Kang, H. L.; Li, P. P.; Liu, Z. J.; Zhang, Y. J.; Liu, R. G.*; Xiang, J. F.*; Huang, Y.* Dual effects of dimethylsulfoxide on the solvating ability of 1-allyl-3-methylimidazolium chloride to cellulose. Cellulose, 2016, 23(2), 1165–1175.
- Liu, Z. J.; Zhang, C.; Liu, R. G.*; Zhang, W. S.*; Kang, H. L.; Che, N.; Li, P. P.; Huang, Y.* Dissolution of cellobiose in the aqueous solutions of chloride salts: Hofmeister series consideration. Cellulose, 2016, 23(1), 295-305.
- Li, P. P.; Kang, H. L.; Zhang, C.; Li, W. W.; Huang, Y.*; Liu, R. G.* Reversible redox activity of ferrocene functionalized hydroxypropyl cellulose and its application to detect H2O2. Carbohydr. Polym. 2016, 140, 35-42.
- Chen, M. Y.; Kang, H. L.*; Gong, Y. M.*; Guo, J.; Zhang, H.; Liu, R. G.* Bacterial cellulose supported gold nanoparticles with excellent catalytic properties. ACS Appl. Mater. Interfaces 2015, 7(39), 21717-21726.
- Lu, F.; Wang, L. J.; Zhang, C.; Chen, B. W.; Liu, R. G.*; Huang, Y.* Influence of temperature on the solution rheology of cellulose in 1-ethyl-3-methylimidazolium chloride/dimethyl sulfoxide. Cellulose 2015; 22(5):3077-3087.
- Li, P. P.; Kang, H. L.; Che, N.; Liu, Z. J.; Zhang, C.; Cao, C.; Li, W. W.; Liu, R. G.*; Huang, Y.* Synthesis, self-assembly and redox-responsive properties of well-defined hydroxypropyl cellulose-graft-poly(2-acryloyloxyethyl ferrocenecarboxylate) copolymers. Polym. Int. 2015, 64(8), 1015-1022.
- Li, P. P.; Liu, R. G.* Cellulose gels and microgels: Synthesis, service, and supramolecular interactions. Adv. Polym. Sci. 2015, 268, 209-251.
- Liu, Z. J.; Zhang, C.; Liu, R. G.*; Zhang, W. S.; Kang, H. L.; Che, N.; Li, P. P.; Huang, Y.*, Effects of additives on dissolution of cellobiose in aqueous solvents. Cellulose 2015, 22(3), 1641-1652.
- Kang, H. L.; Liu, R. G.*; Huang, Y.*, Graft modification of cellulose: Methods, properties and applications. Polymer 2015, 70, A1-A16.
- Liu, X. F.; Zhu, C. Z.; Dong, H. X.; Wang, B. M.; Liu, R. G.*; Zhao, N.*; Li, S. X.; Xu, J.*, Effect of microgel content on the shear and extensional rheology of polyacrylonitrile solution. Colloid Polym. Sci. 2015, 293(2), 587-596
- Li, Q. M.; Yang, S. N.; Zhu, L. J.; Kang, H. L.; Qu, X. Z.*; Liu, R. G.*; Huang, Y.*, Dual-stimuli sensitive keratin graft PHPMA as physiological trigger responsive drug carriers. Polym. Chem. 2015, 6(15), 2869-2878.
- Ci, J. L.; Kang, H. L.; Liu, C. G.; He, A. H.; Liu, R. G.* Progress in protein resistance adsorption mechanism and applications of zwitterionic polymers. Prog. Chem. 2015, 27(9), 1198-1212.
- Zhang, C.; Liu, R. G.*; Xiang, J. F.; Kang, H. L.; Liu, Z. J.; Huang, Y.* Dissolution mechanism of cellulose in N,N-dimethylacetamide/lithium chloride: Revisiting through molecular interactions. J. Phys. Chem. B 2014, 118, 9507-9514.
- Jiang, Z. W.; Fang, Y.; Xiang, J. F.; Ma, Y. P.; Lu, A.; Kang, H. L.; Huang, Y.; Guo, H. X.; Liu, R. G.*; Zhang, L. N.* Intermolecular interactions and 3D structure in cellulose-NaOH-urea aqueous system. J. Phys. Chem. B 2014, 118, 10250-10257.
- Li, Z.; Kang, H. L.; Li, Q. M.; Che, N.; Liu, Z. J.; Li, P. P.; Zhang, C.; Liu, R. G.*; Huang, Y.* Ultrathin core-sheath fibers for liposome stabilization. Colloid Surf. B-Biointerfaces 2014, 122, 630-637.
- Li, Z.; Kang, H. L.; Che, N.; Liu, Z. J.; Li, P. P.; Li, W. W.; Zhang, C.; Cao, C.; Liu, R. G.*; Huang, Y.* Controlled release of liposome-encapsulated naproxen from core-sheath electrospun nanofibers. Carbohydr. Polym. 2014, 111, 18-24.
- Cao, C.; Kang, H. L.; Che, N.; Liu, Z. J.; Li, P. P.; Zhang, C.; Li, W. W.; Liu, R. G.; Huang, Y. Wool graft polyacrylamidoxime as the adsorbent for both cationic and anionic toxic ions from aqueous solutions. RSC Adv. 2014, 4, 60609-60616.
- Kang, H. L.; Shu, Y.; Li, Z.; Guan, B.; Peng, S. J.; Huang, Y.*; Liu, R. G.* An effect of alginate on the stability of LDH nanosheets in aqueous solution and preparation of alginate/LDH nanocomposites. Carbohydr. Polym. 2014, 100, 158-165.
- Mao, Y. Z.; Wang, H.; Wang, D.; Shen, H.; Yang, S. G.; Ma, J. H.; Zhao, N.; Liu, R. G.; Xu, J. Studies on properties of regenerated cellulose hydrogel membranes prepared by solution pre-gelation. Acta Polym. Sin. 2014, 1023-1028.
- Liu, X. F.; Zhu, C. Z.; Guo, J.; Liu, Q. L.; Dong, H. X.; Gu, Y. Z.; Liu, R. G.*; Zhao, N.*; Zhang, Z. G.; Xu, J.* Nanoscale dynamic mechanical imaging of the skin-core difference: From PAN precursors to carbon fibers. Mater. Lett. 2014, 128, 417-420.
- Gao, X.; Liu, R. G.*; Huang, Y.*; Starykov, O.; Oppermann, W. Clathrate δ form crystal transitions of syndiotactic polystyrene in atactic polystyrene networks. Macromolecules 2008, 41, 2554-2560.
- Li, W. W.; Liu, R. G.*; Kang, H. L.; Sun, Y. M.; Dong, F. Y.; Huang, Y. Synthesis of amidoxime functionalized cellulose derivatives as a reducing agent and stabilizer for preparing gold nanoparticles. Polym. Chem. 2013, 4, 2556-2563.
- Kang, H. L.; Liu, R. G.*; Huang, Y.* Synthesis of ethyl cellulose grafted poly(N-isopropylacrylamide) copolymer and its micellization. Acta Chim. Sin. 2013, 71, 114-120.
- Kang, H. L.; Liu, R. G.*; Huang, Y.* Cellulose derivatives and graft copolymers as blocks for functional materials. Polym. Int. 2013, 62, 338-344.
- Jin, X.; Kang, H. L.; Liu, R. G.*; Huang, Y.* Regulation of the thermal sensitivity of hydroxypropyl cellulose by poly(N-isopropylacryamide) side chains. Carbohydr. Polym. 2013, 95, 155-160.
- Jin, X.; Kang, H. L.; Liu, R. G.*; Huang, Y.* Controlled radical emulsion polymerization of polystyrene. Colloid Polym. Sci. 2013, 291, 2481-2485.
- Huang, Y. Z.; Kang, H. L.; Li, G. H.; Wang, C. Y.; Huang, Y.; Liu, R. G.* Synthesis and photosensitivity of azobenzene functionalized hydroxypropylcellulose. RSC Adv. 2013, 3, 15909-15916.
- Liu, W. Y.; Liu, Y. J.; Hao, X. H.; Zeng, G. S.; Wang, W.; Liu, R. G.*; Huang, Y. Backbone-collapsed intra- and inter-molecular self-assembly of cellulose-based dense graft copolymer. Carbohydr. Polym. 2012, 88, 290-298.
- Li, Q. M.; Zhu, L. J.; Liu, R. G.*; Huang, D.; Jin, X.; Che, N.; Li, Z.; Qu, X. Z.; Kang, H. L.; Huang, Y.* Biological stimuli responsive drug carriers based on keratin for triggerable drug delivery. J. Mater. Chem. 2012, 22, 19964-19973.
- Li, Q. M.; Kang, H. L.; Liu, R. G.* Huang, Y.* Block and hetero ethyl cellulose graft copolymers synthesized via sequent and one-pot ATRP and "click" reactions. Chin. J. Chem. 2012, 30, 2169-2175.
- Liu, W. Y.; Liu, Y. J.; Zeng, G. S.; Liu, R. G.*; Huang, Y.* Coil-to-rod conformational transition and single chain structure of graft copolymer by tuning the graft density. Polymer, 2012, 53, 1005-1014.
- Kang, H. L.; Liu, R. G.*; Sun, H. F.; Zhen, J. M.; Li, Q. M.; Huang, Y.* Osmium bipyridine-containing redox polymers based on cellulose and their reversible redox activity. J. Phys. Chem. B 2012, 116, 55-62.
- Liu, W. Y.; Liu, Y. J.; Hao, X. H.; Zeng, G. S.; Wang, W.; Liu, R. G.*; Huang, Y.* Backbone-collapsed intra- and inter-molecular self-assembly of cellulose-based dense graft copolymer. Carbohydr. Polym. 2012, 88, 290-298.
- Muhammad, K.; Hameed, S.; Tan, J.; Liu, R. G. Facile synthesis and mesomorphic properties of 4-hydroxybutyl 4-(4-alkoxybenzoyloxy) benzoate mesogens. Liq. Cryst. 2011, 38, 333-348.
- Tian, Y.; Wu, M.; Liu, R. G.; Li, Y.; Wang, D.; Tan, J.; Wu, R.; Huang, Y. Electrospun membrane of cellulose acetate for heavy metal ion adsorption in water treatment. Carbohydr. Polym. 2011, 83, 743-748.
- Tian, Y.; Wu, M.; Liu, R. G.; Wang, D.; Lin, X.; Liu, W.; Ma, L.; Li, Y.; Huang, Y. Modified native cellulose fibers-A novel efficient adsorbent for both fluoride and arsenic. J. Hazard. Mater. 2011, 185, 93-100.
- Zheng, K.; Liu, R. G.*; Kang, H.; Gao, X.; Shen, D.; Huang, Y.* Chirality amplification of syndiotactic polystyrene induced circular dichroism chiral film in delta form upon annealing. Polymer 2011, 52, 3671-3676.
- Wang, D.; Liu, R. G.*; Che, N.; Li, Q.; Li, Z.; Tian, Y.; Kang, H.; Jia, B.; Huang, Y.* Improving the blood clearance time of I labeled Dex-g-PMAGGCONHTyr by copolymerization. Polym. Chem. 2011, 2, 1872-1878.
- Wang, D.; Shi, J.; Tan, J.; Jin, X.; Li, Q.; Kang, H.; Liu, R. G.*; Jia, B.; Huang, Y.* Synthesis, characterization, and in vivo biodistribution of I-labeled Dex-g-PMAGGCONHTyr. Biomacromolecules 2011, 12, 1851-1859.
- Wang, D.; Tan, J.; Kang, H.; Ma, L.; Jin, X.; Liu, R. G.*; Huang, Y.* Synthesis, self-assembly and drug release behaviors of pH-responsive copolymers ethyl cellulose-graft-PDEAEMA through ATRP. Carbohydr. Polym. 2011, 84, 195-202.
- Wang, W.; Liu, R. G.*; Kang, H.; Liu, W.; Liu, W.; Huang, Y.* UV irradiation gradient induced banded texture in photo-polymerized ethyl-cyanoethyl cellulose/poly(acrylic acid) cholesteric liquid crystalline films and patterns fabrication thereof. Colloid Polym. Sci. 2011, 289, 371-379.
- Tan, J.; Kang, H.; Liu, R. G.*; Wang, D.; Jin, X.; Li, Q.; Huang, Y.* Dual-stimuli sensitive nanogels fabricated by self-association of thiolated hydroxypropyl cellulose. Polym. Chem. 2011, 2, 672-678.
- Wang, W.; Liu, R. G.*; Liu, W.; Tan, J.; Liu, W.; Kang, H.; Huang, Y. Hierarchical mesoporous silica prepared from ethyl-cyanoethyl cellulose cholesteric liquid crystalline phase. J. Mater. Sci. 2010, 45, 5567-5573.
- Wei, X.; Qi, L.; Tan, J.; Liu, R. G.; Wang, F. A colorimetric sensor for determination of cysteine by carboxymethyl cellulose-functionalized gold nanoparticles. Analytica Chimica Acta 2010, 671, 80-84.
- Tan, J.; Li, Y.; Liu, R. G.*; Kang, H.; Wang, D.; Ma, L.; Liu, W.; Wu, M.; Huang, Y.* Micellization and sustained drug release behavior of EC-g-PPEGMA amphiphilic copolymers. Carbohydr. Polym. 2010, 81, 213-218.
- Ma, L.; Kang, H.; Liu, R. G.*; Huang, Y.* Smart assembly behaviors of hydroxypropylcellulose-graft-poly(4-vinyl pyridine) copolymers in aqueous solution by thermo and pH stimuli. Langmuir 2010, 26, 18519-18525.
- Zheng, K.; Liu, R. G.*; Huang, Y.* A two-dimensional IR correlation spectroscopic study of the conformational changes in syndiotactic polypropylene during crystallization. Polym. J. 2010, 42, 81-85.
- Ma, L.; Liu, R. G.*; Tan, J.; Wang, D.; Jin, X.; Kang, H.; Wu, M.; Huang, Y.* Self-assembly and dual-stimuli sensitivities of hydroxypropylcellulose-graft-poly(N,N-dimethyl aminoethyl methacrylate) copolymers in aqueous solution. Langmuir 2010, 26, 8697-8703.
- Zhang, S.; Guo, Y.; Zhang, Y.; Liu, R. G.; Li, Q.; Zhan, X.; Liu, Y.; Hu, W. Synthesis, self-assembly, and solution-processed nanoribbon field-effect transistor of a fused-nine-ring thienoacene. Chem. Commun. 2010, 46, 2841-2843.
- Liu, W.; Liu, R. G.*; Huang, Y. Tailoring the Morphology of the Poly(3-hexylthiophene)/C60 Films and Charge Carrier Mobility. In Functional Polymer Nanocomposties For Energy Storage and Conversion, 2010; Vol. 1034, pp 123-136.
- Liao, B.; He, B.; Liu, R. G.; Huang, Y. Induced circular dichroism of anionic porphyrin TPPS aggregates in DNA solutions. Polymer Journal 2009, 41, 739-743.
- Wang, X.; Liu, R. G.; Wu, M.; Wang, Z.; Huang, Y. Effect of chain disentanglement on melt crystallization behavior of isotactic polypropylene. Polymer 2009, 50, 5824-5827.
- Zhang, S.; Guo, Y.; Wang, L.; Li, Q.; Zheng, K.; Zhan, X.; Liu, Y.; Liu, R. G.; Wan, L. Synthesis, self-assembly and solution-processed field-effect transistors of a liquid crystalline bis(dithienothiophene) derivative. J. Phys. Chem. C 2009, 113, 16232-16237.
- Liu, W. Y.; Liu, R. G.*; Li, Y.; Kang, H.; Shen, D.; Wu, M.; Huang, Y.* Self-assembly of ethyl cellulose-graft-polystyrene copolymers in acetone. Polymer 2009, 50, 211-217.
- Liu, W. Y.; Liu, R. G.*; Li, Y.; Wang, W.; Ma, L.; Wu, M.; Huang, Y.* Self-organized ordered microporous thin films from grafting copolymers. Polymer 2009, 50, 2716-2726.
- Zheng, K.; Liu, R. G.*; Chang, H.; Shen, D.; Huang, Y.* In situ FTIR spectroscopic study of the conformational change of syndiotactic polypropylene during the isothermal crystallization. Polymer 2009, 50, 5782-5786.
- Li, Y.; Wu, M.; Liu, R. G.; Huang, Y. Cellulose-based solid-solid phase change materials synthesized in ionic liquid. Sol. Energy Mater. Sol. Cells 2009, 93, 1321-1328.
- Liu, W.; Liu, R. G.*; Wang, W.; Li, W.; Liu, W.; Zheng, K.; Ma, L.; Tian, Y.; Bo, Z.; Huang, Y.* Tailoring nanowire network morphology and charge carrier mobility of poly(3-hexylthiophene)/C60 films. J. Phys. Chem. C 2009, 113, 11385-11389.
- Zhang, S.; Guo, Y.; Xi, H.; Di, C.; Yu, J.; Zheng, K.; Liu, R. G.; Zhan, X.; Liu, Y. Effect of substituents on electronic properties, thin film structure and device performance of dithienothiophene-phenylene cooligomers. Thin Solid Films 2009, 517, 2968-2973.
- Gao, X.; Liu, R. G.*; Zhang, J.; Zhang, J. Crystallization behaviors of poly(ethylene 2,6-naphthalate) in the presence of liquid crystalline polymer. Ind. Eng. Chem. Res. 2008, 47, 2590-2596.
- Kang, H.; Liu, W.; Liu, R. G.*; Huang, Y.* A novel, amphiphilic ethyl cellulose grafting copolymer with poly(2-hydroxyethyl methacrylate) side chains and its micellization. Macromol. Chem. Phys. 2008, 209, 424-430.
- Li, Y. X.; Liu, R. G.*; Huang, Y. Synthesis and phase transition of cellulose-graft-poly(ethylene glycol) copolymers. J. Appl. Polym. Sci. 2008, 110, 1797-1803.
- Li, Y. X.; Liu, R. G.*; Liu, W.; Kang, H.; Wu, M.; Huang, Y.* Synthesis, self-assembly, and thermosensitive properties of ethyl cellulose-g-P(PEGMA) amphiphilic copolymers. J. Polym. Sci.: Polym. Chem. 2008, 46, 6907-6915.
- Yu, H.; Liu, R. G.*; Shen, D.; Wu, Z.; Huang, Y.* Arrangement of cellulose microfibrils in the wheat straw cell wall. Carbohydr. Polym. 2008, 72, 122-127.
- Liao, B.; Liu, R. G.; Huang, Y. A supramolecular chiroptical switch based on chitosan and anionic porphyrin complex film. Polym. J. 2007, 39, 1071-1077.
- Saalwachter, K.; Gottlieb, M.; Liu, R. G.; Oppermann, W. Gelation as studied by proton multiple-quantum NMR. Macromolecules 2007, 40, 1555-1561.
- Yu, H.; Liu, R. G.*; Qiu, L.; Huang, Y. Composition of the cell wall in the stem and leaf sheath of wheat straw. J. Appl. Polym. Sci. 2007, 104, 1236-1240.
- Liu, R. G.; Oppermann, W. Spatial inhomogeneities of polystyrene gels prepared from semidilute solutions. Macromolecules 2006, 39, 4159-4167.
- Liu, R. G.; Gao, X.; Oppermann, W. Dynamic light scattering studies on random cross-linking of polystyrene in semi-dilute solution. Polymer 2006, 47, 8488-8494.
- Liu, R. G.; Hu, X. Precipitation kinetics of cellulose in the Lyocell spinning process. Ind. Eng. Chem. Res. 2006, 45, 2840-2844.
- Liu, R. G.; Gao, X.; Adams, J.; Oppermann, W. A fluorescence correlation spectroscopy study on the self-diffusion of polystyrene chains in dilute and semidilute solution. Macromolecules 2005, 38, 8845-8849.
- Yu, H.; Liu, R. G.; Shen, D.; Jiang, Y.; Huang, Y. Study on morphology and orientation of cellulose in the vascular bundle of wheat straw. Polymer 2005, 46, 5689-5694.
- Liu, R. G.; Yu, H.; Huang, Y. Structure and morphology of cellulose in wheat straw. Cellulose 2005, 12, 25-34.
- Gao, X.; Liu, R. G.; Yu, Y.; Jin, M.; Bus, H. Influence of additives on the crystal structure and melting behavior of poly(ethylene-2,6-naphthalene dicarboxylate). J. Polym. Sci. Polym. Phys. 2004, 42, 296-301.
- Gao, X.; Liu, R. G.; Yu, Y.; Jin, M.; Bu, H. Crystallization and morphology of poly(ethylene 2,6-naphthalene dicarboxylate) containing additives. Macromol. Mater. Eng. 2003, 288, 372-379.
- Li, L.; Liu, R. G.; Zhang, S.; Li, Z. High strength disclinations in the nematic and smectic states of 2,5-bis(4-alkoxybenzoyloxy)-p-benzoquinones. Liq. Cryst. 2003, 30, 259-263.
- Gao, X.; Liu, R. G.; Jin, M.; Bu, H. Chemical nucleation of carboxylic salt nucleating agent in poly(ethylene 2,6-naphthalate). Acta Polym. Sin. 2002, 723-728.
- Liu, R. G.; Shao, H.; Hu, X. The online measurement of Lyocell fibers and investigation of elongational viscosity of cellulose N-methylmorpholine-N-oxide monohydrate solutions. Macromol. Mater. Eng. 2001, 286, 179-186.
- Liu, R. G.; Shen, Y.; Shao, H.; Wu, C.; Hu, X. An analysis of Lyocell fiber formation as a melt-spinning process. Cellulose 2001, 8, 13-21.