侯召民，男，國家高層次“千人計畫”學者，大連理工大學教授。
基本介紹
- 中文名：侯召民
- 職業：大連理工大學教授
- 性別：男
個人簡介,主要學歷,工作經歷,社會兼職,研究領域（研究課題）,碩博研究方向,出版著作和論文,工作成果（獎勵、專利等）,
個人簡介
侯召民，男，國家高層次“千人計畫”學者，現任大連理工大學化工學院教授。
主要學歷
1978-1982年 中國石油大學 煉製系 本科
1984-1986年 日本九州大學 套用化學專業 碩士
1986-1989年 日本九州大學 套用化學專業 博士
工作經歷
1989-1990年 日本理化學研究所 有機金屬化學研究室 博士後
1991-1993年 加拿大溫莎大學 化學系 博士後
1993-1996年 日本理化學研究所 有機金屬化學研究室 研究員
1997-2002年 日本理化學研究所 有機金屬化學研究室 副主任研究員
2003-2007年 日本科學技術振興機構(JST)創新團隊 研究員
2004-2007年 日本千葉大學 客座教授
2005-2005年 法國路易·巴斯德大學 客座教授
2008-2011年 大連理工大學 長江學者講座教授
2002-present 日本理化學研究所 有機金屬化學研究室 主任研究員
2003-present 日本埼玉大學 客座教授
2004-present 北京大學 客座教授
2006-present 中國科學院長春套用化學研究所 客座教授
2008-present 日本東京工業大學 客座教授
2011-present 大連理工大學 國家高層次“千人計畫”學者 大連理工大學教授
社會兼職
日本化學會會員，日本有機合成化學協會會員，日本高分子化學會會員，日本催化學會會員，日本配位化學會會員，日本稀土學會會員，美國化學會會員，英國皇家化學會會員(Fellow, FRS)，日本稀土學會理事。
研究領域（研究課題）
1. "新穎稀土催化劑的開發" 日本學術振興會基盤研究（S）
2. "綠色化學研究" 日本理化學研究所基礎科學研究課題
3. "稀土氫簇的合成及其催化作用" 日本文部科學省科研費特定領域研究
4. "環境分子科學研究" 日本理化學研究所基礎科學研究課題
5. "d-f混合過渡金屬配位化合物的合成及其反應" 日本科學技術振興機構戦略創造研究推進事業先驅型研究
6. “利用新型稀土催化劑進行新型聚合反應的開發” 日本文部科學省特定領域研究
7. “稀土聚烯烴催化劑的開發和套用”日本學術振興會基盤研究（A）
8. 多項國際合作項目
碩博研究方向
催化劑是有機合成化學、烯烴聚合化學和材料化學等研究領域的關鍵和核心，改變催化劑可以得到特定結構和性能的產物。我們以“新催化劑，新反應，新材料”為宗旨，致力於開發新型的、高效高選擇性的、具有自主智慧財產權的稀土金屬有機配合物，並探索其在精細化工合成、小分子活化、烯烴聚合、材料開發等方面的催化作用，開發具有廣泛工業套用前景的新材料。目前的研究課題主要包括：
1. 開發新穎、高效和高選擇性的烯烴聚合催化劑，獲得結構新穎性能優異的高分子材料。
2. 開發新穎、高效和高選擇性的有機合成催化劑，提高有機合成反應的催化效率。
3. 稀土氫化物的合成及其在協同反應中的套用。
招收精細化工、套用化學和高分子等專業的博士研究生、碩士研究生以及博士後研究員。熱情歡迎崇尚科學、團結協作、志在創新的有機化學、金屬有機化學、催化化學、材料化學等專業優秀人才加盟本研究室學習深造、開展合作研究。
出版著作和論文
近五年內已發表論文74篇，其中12篇在Angew. Chem. Int. Ed., 6篇在J. Am. Chem. Soc., 2篇在Nature Chem.上發表，1篇在Science上發表，邀請撰寫綜述14篇，申請專利21項。
近年代表性論文
[43] T. Shima, S. Hu, G. Luo, X. Kang, Y. Luo, Z. Hou "Dinitrogen Cleavage and Hydrogenation by a Trinuclear Titanium Polyhydride Complex" Science, 2013, 340, 1549-1552.
[42] F. Guo, M. Nishiura, Y. Li, and Z. Hou "Copolymerization of Isoprene and Nonconjugated α,ω-Dienes by Half-Sandwich Scandium Catalysts with and without a Coordinative Side Arm" Chem. Asian J., 2013, 8, 2471-2482.
[41] Y. Luo, Y. Li, H. Yu, J. Zhao, Y. Chen, Z. Hou, and J. Qu "DFT Studies on the Reduction of Dinitrogen to Ammonia by a Thiolate-Bridged Diiron Complex as a Nitrogenase Mimic" Organometallics, 2012, 31, 335-344.
[40] X. Kang, Y. Song, Y. Luo, G. Li, Z. Hou, and J. Qu "Computional Studies on Isospecific Polymerization of 1-Hexene Catalyzed by cationic Rare Earth Metal Alkyl Complex Bearing a C3 iPr-trisox Ligand" Macromolecules, 2012, 45, 640-651.
[39] J. Cheng, Z. Hou "Cationic terminal hydrido rare earth complexes bearing an amidinate ancillary ligand" Chem. Comm., 2012, 48, 814-816.
[38] L. Pan, K. Zhang, M. Nishiura, and Z. Hou "Chain-Shuttling Polymerization at Two Different Scandium Sites: Regio- and Stereospecific "One-Pot" Block Copolymerization of Styrene, Isoprene, and Butadiene" Angew. Chem. Int. Ed., 2011, 50, 12012-12015.
[37] B. Guan, Z. Hou "Rare-Earth-Catalyzed C-H Bond Addition of pyridine to Olefins"
J. Am. Chem. Soc., 2011, 133, 18086-18089.
[36] J. Oyamada, M. Nishiura, Z. Hou "Scandium-Catalyzed Silylation of Aromatic C-H Bonds" Angew. Chem. Int. Ed., 2011, 50, 10720-10723.
[35] T.Shima, Y. Luo, T. Stewart, R. Bau, G.J.Mclntyre, S.A.Mason, Z. Hou "Molecular heterometallic hydride clusters composed of rare-earth and d-trantion metals" Nature Chem., 2011, 814-820.
[34] F. Guo, M. Nishiura, H. Koshino, and Z. Hou "Scandium-Catalyzed Cyclocopolymerization of 1,5-Hexadiene with Styrene and Ethylene: Efficient Synthesis of Cyclopolyolefins Containing Syndiotactic Styrene-Styrene Sequences and Methylene-1,3-cyclopentane Units" Macromolecules, 2011, 44, 6335-6344.
[33] T. Ohishi, L. Zhang, M. Nishiura, and Z. Hou "Carboxylation of Alkylboranes by N-Heterocyclic Carbene Copper Catalysts:Synthesis of Carboxylic Acids from Terminal Alkenes and Carbon Dioxide" Angew. Chem. Int. Ed., 2011, 50, 8114-8117.
[32] S. Li, J. Cheng, Y. Chen, M. Nishiura, and Z. Hou "Rare Earth Metal Boryl Complexes: Synthesis, Structure, and Insertion of a Carbodiimide and Carbon Monoxide" Angew. Chem. Int. Ed., 2011, 50, 6360-6363.
[31] Yi Luo, Yunjie Luo, J. Qu, Z. Hou "QQ/MM Studies on Scandium-Catalyzed Syndiospecific Copolymerization of Styrene and Ethylene" Organometallics, 2011, 30, 2908-2919.
[30] F. Guo, M. Nishiura, H. Koshino, Z. Hou "Cycloterpolymerization of 1,6-Heptadiene with Ethylene and Styrene Catalyzed by a THF-Free Half-Sandwich Scandium Complex" Macromolecules, 2011, 44, 2400-2403.
[29] M. Nishiura, J. Baldamus, T. Shima, K. mori, Z. Hou "Synthesis and Structures of the C5Me4SiMe3-Supported Polyhydride Complexes over the Full Size Range of the Rare Earth Series" Chem. Eur. J., 2011, 17, 5033-5044.
[28] W. Zhang, Z. Wang, M. Nishiura, Z. Xi, Z. Hou "Ln4(CH2)4 Cubane-Type Rare-Earth Methylidene Complexes Consisting of "(C5Me4SiMe3)LnCH2" Units (Ln=Tm,Lu)" J. Am. Chem. Soc., 2011, 133, 5712-5717.
[27] J. Cheng, T. Shima, Z. Hou "Rare-Earth Polyhydride Complexes Bearing Bis(phosphinophenyl) Amido Princer Ligands" Angew. Chem. Int. Ed., 2011, 50, 1857-1860.
[26] L. Pan, K. Zhang, M. Nishiura, Z. Hou "Syndiospecific Living Copolymerization of Styrene with ε-Caprolactone by Scandium Catalysts" Macromolecules, 2010, 43, 9591-9593.
[25] L. Zhang, J. Cheng , T. Ohishi , Z. Hou "Copper-Catalyzed Direct Carboxylation of C-H Bonds with Carbon Dioxide" Angew. Chem. Int. Ed., 2010, 49, 8670-8673.
[24] X. Li , Z. Hou "Scandium-catalyzed regio- and stereospecific cis-1,4-polymerization of 1,3-cyclohexadiene and copolymerization with ethylene" Macromolecules, 2010, 43, 8904-8909.
[23] M. Nishiura, Z. Hou "Novel polymerization catalysts and hydride clusters from rare-earth metal dialkyls" Nature Chem., 2010, 2, 257-268.
[22] M. Takimoto, S. Usami, Z. Hou "Scandium-Catalyzed Regio- and Stereospecific Methylalumination of Silyloxy/Alkoxy-Substituted Alkynes and Alkenes" J. Am. Chem. Soc., 2009, 131, 18266-18268.
[21] X. Li, M. Nishiura, L. Hu, K. Mori, Z. Hou "Alternating and Random Copolymerization of Isoprene and Ethylene Catalyzed by Cationic Half-Sandwich Scandium Alkyls" J. Am. Chem. Soc., 2009,131,13870-13882.
[20] W-X. Zhang, M. Nishiura, Z. Hou "Synthesis of (Z)-1-Aza-1,3-enynes by the Cross-Coupling of Terminal Alkynes with Isocyanides Catalyzed by Rare-Earth Metal Complexes" Angew. Chem. Int. Ed., 2008, 47, 9700-9703.
[19] L. Zhang, M. Nishiura, M. Yuki, Y. Luo, Z. Hou "Isoprene Polymerization with Yttrium Amidinate Catalysts: Switching the Regio- and Stereoselectivity by Addition of AlMe3" Angew. Chem. Int. Ed., 2008, 47, 2642-2645.
[18] H. Zhang, Y. Luo, Z. Hou "Scandium-Catalyzed Syndiospecific Copolymerization of Styrene with Isoprene" Macromolecules, 2008, 41, 1064-1066.
[17] X. Li , Z. Hou "Organometallic Catalysts for Copolymerization of Cyclic Olefins" Coord. Chem. Rev., 2008, 252, 1842-1869.
[16] X. Li, M. Nishiura, K. Mori, T. Mashiko, Z. Hou "Cationic Scandium Aminobenzyl Complexes. Synthesis, Structure and Unprecedented Catalysis of Copolymerization of 1-Hexene and Dicyclopentadiene" Chem. Commun., 2007, 4137-4139.
[15] Y. Luo, Z. Hou "Computational Study of Ethylene Insertion into the Metal-Hydrogen Bond of the Tetranuclear Yttrium Polyhydrido Complex [(η5-C5Me4SiMe3)YH2]4" Organometallics, 2007, 26, 2941-2944.
[14] L. Zhang, T. Suzuki, Y. Luo, M. Nishiura, Z. Hou "Cationic Alkyl Rare-Earth Metal Complexes Bearing an Ancillary Bis(phosphinophenyl)amido Ligand: A Catalytic System for Living cis-1,4-Polymerization and Copolymerization of Isoprene and Butadiene"
Angew. Chem. Int. Ed., 2007, 46, 1909-1913.
[13] W-X. Zhang, M. Nishiura, Z. Hou "Catalytic Addition of Amine N-H Bonds to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes: Efficient Synthesis of Substituted Guanidines through Amine Protonolysis of Rare-Earth Metal Guanidinates"
Chem. Eur. J. , 2007, 13, 4037-4051.
[12] X. Li, J. Baldamus, M. Nishiura, O. Tardif, Z. Hou "Cationic Rare-Earth Polyhydrido Complexes: Synthesis, Structure, and Catalytic Activity for the cis 1,4-Selective Polymerization of 1,3-Cyclohexadiene" Angew. Chem. Int. Ed., 2006, 45, 8184-8188.
[11] T. Shima, Z. Hou "Hydrogenation of Carbon Monoxide by Tetranuclear Rare Earth Metal Polyhydrido Complexes. Selective Formation of Ethylene and Isolation of Well-Defined Polyoxo Rare Earth Metal Clusters" J. Am. Chem. Soc., 2006, 128, 8124-8125.
[10] Y. Liu, M. Nishiura, Y. Wang, Z. Hou "π-Conjugated Aromatic Enynes as a Single-Emitting Component for White Electroluminescence" J. Am. Chem. Soc., 2006, 128, 5592-5593.
[9] Z. Hou, Y. Luo, X. Li "Cationic Rare Earth Metal Alkyls as Novel Catalysts for Olefin Polymerization and Copolymerization" J. Organomet. Chem., 2006, 691, 3114-3121.
[8] M. Takimoto, Z. Hou "Hydrogen at the Flick of a Switch" Nature, 2006, 443, 400-401.
[7] W.-X. Zhang, M. Nishiura, Z. Hou "Catalytic Addition of Terminal Alkynes to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes" J. Am. Chem. Soc., 2005, 127, 16788-16789.
[6] L. Zhang, Y. Luo, Z. Hou "Unprecedented Isospecific 3,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Resulting from a Binuclear Precursor" J. Am. Chem. Soc., 2005, 127, 14562-14563.
[5] X. Li, J. Baldamus, Z. Hou "Alternating Ethylene-Norbornene Copolymerization Catalyzed by Cationic Half-Sandwich Scandium Complexes" Angew. Chem. Int. Ed., 2005, 44, 962-964.
[4] D. Cui, M. Nishiura, Z. Hou "Rare Earth Metal Imido Complexes and their Reactions with Benzonitrile" Angew. Chem. Int. Ed., 2005, 44, 959-961.
[3] Y. Luo, J. Baldamus, Z. Hou "Scandium Half-Metallocene-Catalyzed Syndiospecific Styrene Polymerization and Styrene-Ethylene Copolymerization: Unprecedented Incorporation of Syndiotactic Styrene-Styrene Sequences in Styrene-Ethylene Copolymers" J. Am. Chem. Soc., 2004, 126, 13910-13911.
[2] O. Tardif, D. Hashizume, Z. Hou "Hydrogenation of Carbon Dioxide and Aryl Isocyanates by a Tetranuclear Tetrahydrido Yttrium Complex. Isolation, Structures, and CO2-Insertion Reactions of Methylene Diolate and 3-Oxo Yttrium Complexes"
J. Am. Chem. Soc., 2004, 126, 8080-8081.
[1] D. Cui, O. Tardif, Z. Hou "Tetranuclear Rare Earth Metal Polyhydrido Complexes Composed of "(C5Me4SiMe3)LnH2" Units. Unique Reactivities toward Unsaturated C-C, C-N, and C-O Bonds" J. Am. Chem. Soc., 2004, 126, 1312-1313.
[10] Y. Liu, M. Nishiura, Y. Wang, Z. Hou "π-Conjugated Aromatic Enynes as a Single-Emitting Component for White Electroluminescence" J. Am. Chem. Soc., 2006, 128, 5592-5593.
[9] Z. Hou, Y. Luo, X. Li "Cationic Rare Earth Metal Alkyls as Novel Catalysts for Olefin Polymerization and Copolymerization" J. Organomet. Chem., 2006, 691, 3114-3121.
[8] M. Takimoto, Z. Hou "Hydrogen at the Flick of a Switch" Nature, 2006, 443, 400-401.
[7] W.-X. Zhang, M. Nishiura, Z. Hou "Catalytic Addition of Terminal Alkynes to Carbodiimides by Half-Sandwich Rare Earth Metal Complexes" J. Am. Chem. Soc., 2005, 127, 16788-16789.
[6] L. Zhang, Y. Luo, Z. Hou "Unprecedented Isospecific 3,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Resulting from a Binuclear Precursor" J. Am. Chem. Soc., 2005, 127, 14562-14563.
[5] X. Li, J. Baldamus, Z. Hou "Alternating Ethylene-Norbornene Copolymerization Catalyzed by Cationic Half-Sandwich Scandium Complexes" Angew. Chem. Int. Ed., 2005, 44, 962-964.
[4] D. Cui, M. Nishiura, Z. Hou "Rare Earth Metal Imido Complexes and their Reactions with Benzonitrile" Angew. Chem. Int. Ed., 2005, 44, 959-961.
[3] Y. Luo, J. Baldamus, Z. Hou "Scandium Half-Metallocene-Catalyzed Syndiospecific Styrene Polymerization and Styrene-Ethylene Copolymerization: Unprecedented Incorporation of Syndiotactic Styrene-Styrene Sequences in Styrene-Ethylene Copolymers" J. Am. Chem. Soc., 2004, 126, 13910-13911.
[2] O. Tardif, D. Hashizume, Z. Hou "Hydrogenation of Carbon Dioxide and Aryl Isocyanates by a Tetranuclear Tetrahydrido Yttrium Complex. Isolation, Structures, and CO2-Insertion Reactions of Methylene Diolate and 3-Oxo Yttrium Complexes"
J. Am. Chem. Soc., 2004, 126, 8080-8081.
[1] D. Cui, O. Tardif, Z. Hou "Tetranuclear Rare Earth Metal Polyhydrido Complexes Composed of "(C5Me4SiMe3)LnH2" Units. Unique Reactivities toward Unsaturated C-C, C-N, and C-O Bonds" J. Am. Chem. Soc., 2004, 126, 1312-1313.
工作成果（獎勵、專利等）
1996年 日本配位化學會青年科學家獎
1997年 日本稀土學會青年科學家獎
2000年 日本有機合成化學進步獎
2007年 日本學術振興會獎
2007年 日本化學會學術獎
2007年 三井化學催化科學獎
2008年 教育部長江學者
2008年 日本文部科學大臣表彰：科學技術獎
2009年 日本稀土學會獎
2011年 國家高層次“千人計畫”學者
2012年 日本高分子學會獎
1997年 日本稀土學會青年科學家獎
2000年 日本有機合成化學進步獎
2007年 日本學術振興會獎
2007年 日本化學會學術獎
2007年 三井化學催化科學獎
2008年 教育部長江學者
2008年 日本文部科學大臣表彰：科學技術獎
2009年 日本稀土學會獎
2011年 國家高層次“千人計畫”學者
2012年 日本高分子學會獎
在讀學生人數10人
畢業學生人數12人
