龔昱,男,中國科學院大學專職教師。
基本介紹
- 中文名:龔昱
- 畢業院校:復旦大學
- 學位/學歷: 博士
- 職業:教師
人物經歷,教育背景,工作經歷,研究領域,教授課程,主要成就,獎勵信息,專利成果,出版信息,科研活動,科研項目,參與會議,
人物經歷
教育背景
2005-09--2010-07 復旦大學化學系 博士
2001-09--2005-07 復旦大學化學系 學士
工作經歷
2015-02~現在, 中國科學院上海套用物理研究所, 研究員
2014-09~2014-11,美國維吉尼亞大學(University of Virginia), 博士後
2012-02~2014-08,美國勞倫斯伯克利國家實驗室(Lawrence Berkeley National Laboratory), 博士後
2010-08~2012-01,美國維吉尼亞大學(University of Virginia), 博士後
研究領域
錒系和鑭系化合物在熔鹽和溶液中的配位結構及其與分離效果和熔鹽堆運行間的關係、熔鹽體系中錒系和鑭系元素的綜合利用,為闡明釷鈾循環過程中關鍵元素在堆運行、後處理和再利用過程中的化學行為和規律提供科學基礎,具體包括:
1. 釷鈾循環關鍵元素的新型分離方法與機制研究
2. 新型錒系和鑭系化合物的合成、結構與性質
3. 基於光譜和質譜方法的錒系和鑭系配位化學研究
4. 鑭系和錒系元素化合物的綜合利用研究
教授課程
核能科學與技術概論
錒系化學前沿
主要成就
獎勵信息
(1) 瞬態新奇分子的光譜、成鍵和反應研究, 二等獎, 國家級, 2018
(2) 上海市研究生優秀成果(學位論文), 市地級, 2012
(3) 吳征鎧獎學金, 研究所(學校), 2010
(4) 張存浩優秀研究生獎, 國家級, 2007
專利成果
[1] 季男, 黃衛, 龔昱, 蔣鋒, 彭浩, 佘長鋒, 朱鐵建. 一種氯化物熔鹽體系中將稀土氧化物還原為稀土金屬單質的方法. CN: CN112391653A, 2021-02-23.
[2] 周金豪, 陳梓, 孫波, 竇強, 黃衛, 龔昱, 李晴暖. 一種固態鹽加熱熔融裝置及方法. CN: CN108295776B, 2020-03-27.
出版信息
已在Chem. Rev, J. Am. Chem. Soc., Angew. Chem. Int. Ed., Inorg. Chem.和J. Phys. Chem. 等期刊上發表第一和通訊作者論文80餘篇。
(1) Influence of Fluoride Ions on the Speciation and Electrochemical Behavior of Th(IV) in Molten LiCl-KCl with a Copper Electrode, JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2021, 第 3 作者
(2) HMNTA Complexes of Tetravalent Metal Ions: On the Roles of Carbonyl Oxygen and Amine Nitrogen in the Stabilization of Gas-Phase M(HMNTA)(2)(4+) Complexes, JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2021, 第 3 作者
(3) Mass spectrometric and theoretical study on the formation of uranyl hydride from uranyl carboxylate, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2021, 第 3 作者
(4) Molten salt synthesis of samarium borides with controllable stoichiometry and morphology, Journal of Alloys and Compounds, 2021,
(5) Photoluminescence of LaI3 switched on and off by association and dissociation of non-luminescent tetrahydrofuran, DALTON TRANSACTIONS, 2021, 第 3 作者
(6) Oxo-sulfido molybdenum and tungsten fluorides with M-O and M-S multiple bonds, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2021, 第 4 作者
(7) Vanadium, niobium and tantalum complexes with terminal sulfur radical ligands, DALTON TRANSACTIONS, 2021, 第 4 作者
(8) On the Structures of Thorium Fluoride and Oxyfluoride Anions in Molten FLiBe and FLiNaK, JOURNAL OF PHYSICAL CHEMISTRY B, 2021, 第 3 作者
(9) End-On Cyanogen Complexes of Iridium, Palladium, and Platinum, INORGANIC CHEMISTRY, 2020, 第 4 作者
(10) Complexation of Ln(3+) with Pyridine-2,6-dicarboxamide: Formation of the 1:2 Complexes in Solution and Gas Phase, INORGANIC CHEMISTRY, 2020, 第 3 作者
(11) Sulfur Dioxide Complexes of Main-Group Elements: from SO20 to SO2- and SO22- upon Coordination to Aluminum and Silicon Difluorides, INORGANIC CHEMISTRY, 2020, 第 3 作者
(12) Electrochemical separation of uranium from lanthanide (La, Eu, Gd) fluorides in molten LiCl-KCl, SEPARATION AND PURIFICATION TECHNOLOGY, 2020, 第 3 作者
(13) Raman Spectroscopic and Theoretical Study of Scandium Fluoride and Oxyfluoride Anions in Molten FLiNaK, JOURNAL OF PHYSICAL CHEMISTRY B, 2020, 第 4 作者
(14) Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F(2)viaoxidation of U(0) by SOF2, CHEMICAL COMMUNICATIONS, 2020, 第 3 作者
(15) Infrared Spectroscopic and Theoretical Studies of the 3d Transition Metal Oxyfluoride Molecules, INORGANIC CHEMISTRY, 2019, 第 6 作者
(16) Efficient Removal of Azo-Dyes in Aqueous Solution by CeB6 Nanocrystals, ACS APPLIED NANO MATERIALS, 2019, 第 3 作者
(17) Synthesis of a dinuclear europium(III) complex through deprotonation and oxygen-atom transfer of trimethylamine N-oxide, DALTON TRANSACTIONS, 2019, 第 3 作者
(18) Side-On OMoF2(eta(2)-SO) and OWF2(eta(2)-SO) Complexes Featuring Peroxo-Like Sulfur Monoxide Ligand, INORGANIC CHEMISTRY, 2019, 第 3 作者
(19) Formation of Cerium and Neodymium Isocyanides in the Reactions of Cyanogen with Ce and Nd Atoms in Argon Matrices, JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 第 4 作者
(20) Side-On Sulfur Monoxide Complexes of Tantalum, Niobium, and Vanadium Oxyfluorides, INORGANIC CHEMISTRY, 2019, 第 3 作者
(21) End-On Oxygen-Bound Sulfur Monoxide Complex of Titanium Oxyfluoride, INORGANIC CHEMISTRY, 2019, 第 3 作者
(22) Tetrapositive Hafnium-Diamide Complexes in the Gas Phase: Formation, Structure and Reaction, JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2019, 第 2 作者
(23) Electrochemical and Raman Spectroscopic Investigations on the Speciation and Behavior of Chromium Ions in Fluoride Doped Molten LiCl-KCl, JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2019, 第 5 作者
(24) Coordination Structures of the Uranyl(VI)-Diamide Complexes: A Combined Mass Spectrometric, EXAFS Spectroscopic, and Theoretical Study, INORGANIC CHEMISTRY, 2019, 第 3 作者
(25) Bidentate SO2 Complexes of Zirconium and Hafnium Difluorides with Highly Activated S-O Bonds, JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 第 3 作者
(26) Bidentate Sulfur Dioxide Complexes of Scandium, Yttrium, and Lanthanum Difluorides, INORGANIC CHEMISTRY, 2019, 第 3 作者
(27) Formation and Characterization of Zr4+ Stabilized by Neutral Tridentate Ligands in the Gas Phase, JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2018, 第 3 作者
(28) Electrochemical deposition of neodymium in LiF-CaF2 from Nd2O3 assisted by AlF3, ELECTROCHIMICA ACTA, 2018, 第 7 作者
(29) Reactions of Laser-Ablated Aluminum Atoms with Cyanogen: Matrix Infrared Spectra and Electronic Structure Calculations for Aluminum Isocyanides Al(NC)(1,2,3) and Their Novel Dimers, JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 第 3 作者
(30) Infrared Spectroscopic and Theoretical Studies of Group 3 Metal Isocyanide Molecules, JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 第 4 作者
(31) Infrared Spectra of the SO2F2- Anion in Solid Argon and Neon, JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 第 3 作者
(32) Infrared Spectroscopic and Theoretical Studies of Group 3 Metal Isocyanide Molecules, JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 第 4 作者
(33) Formation and Fragmentation Chemistry of Tripositive Ln(TMGA)(3)(3+) Complexes in the Gas Phase, JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2017, 第 3 作者
(34) Gas phase chemistry of the Ln(III)-TMGA/TMTGA complexes, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 第 3 作者
(35) Coordination Structure and Fragmentation Chemistry of the Tripositive Lanthanide-Thio-Diglycolamide Complexes, JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 第 3 作者
(36) Electrochemical behavior and electrowinning of uranium(IV) from FLiNaK molten salt, JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2017, 第 8 作者
(37) Matrix Infrared Spectra of Manganese and Iron Isocyanide Complexes, JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 第 4 作者
(38) Infrared Spectroscopic and Theoretical Studies on the OMF2 and OMF (M = Cr, Mo, W) Molecules in Solid Argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 第 3 作者
(39) Recent progress on the development of pyroprocessing techniques for TMSR in SINAP, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 第 1 作者
(40) Formation and Characterization of Homoleptic Thorium Isocyanide Complexes, INORGANIC CHEMISTRY, 2017, 第 3 作者
(41) Gas Phase Uranyl Activation: Formation of a Uranium Nitrosyl Complex from Uranyl Azide, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 第 1 作者
(42) Reactions of laser-ablated U atoms with (CN)(2): infrared spectra and electronic structure calculations of UNC, U(NC)(2), and U(NC)(4) in solid argon, CHEMICAL COMMUNICATIONS, 2015, 第 1 作者
(43) Electrospray production and collisional dissociation of lanthanide/methylsulfonyl anion complexes: Sulfur dioxide anion as a ligand, INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2015, 第 1 作者
(44) Reactions of Laser-Ablated U Atoms with HCN: Infrared Spectra in Solid Argon and Quantum Chemical Calculations for HUNC, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, 第 1 作者
(45) Crown Ether Complexes of Uranyl, Neptunyl, and Plutonyl: Hydration Differentiates Inclusion versus Outer Coordination, INORGANIC CHEMISTRY, 2014, 第 1 作者
(46) Activation of Gas-Phase Uranyl: From an Oxo to a Nitrido Complex, JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 第 1 作者
(47) Tetrapositive Plutonium, Neptunium, Uranium, and Thorium Coordination Complexes: Chemistry Revealed by Electron Transfer and Collision Induced Dissociation, JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 第 1 作者
(48) Dissociation of Diglycolamide Complexes of Ln(3+) (Ln = La-Lu) and An(3+) (An = Pu, Am, Cm): Redox Chemistry of 4f and 5f Elements in the Gas Phase Parallels Solution Behavior, INORGANIC CHEMISTRY, 2014, 第 1 作者
(49) Experimental and Theoretical Studies on the Fragmentation of Gas-Phase Uranyl-, Neptunyl-, and Plutonyl-Diglycolamide Complexes, JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 第 1 作者
(50) A Tetrapositive Metal Ion in the Gas Phase: Thorium(IV) Coordinated by Neutral Tridentate Ligands, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 第 1 作者
(51) Formation and Characterization of the Uranyl-SO2 Complex, UO2(CH3SO2)(SO2)(-), JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 第 1 作者
(52) Matrix Infrared Spectroscopic and Theoretical of the Difluoroamino Metal Fluoride Molecules: F2NMF (M = Cu, Ag, Au), INORGANIC CHEMISTRY, 2012, 第 1 作者
(53) Methane to Methanol Conversion Induced by Thorium Oxide through the CH3Th(O)H Intermediate in Solid Argon, INORGANIC CHEMISTRY, 2012, 第 1 作者
(54) Spectroscopic Observation of a Group 12 Oxyfluoride: A Matrix-Isolation and Quantum-Chemical Investigation of Mercury Oxyfluorides, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012,
(55) Reactions of Group 3 Metals with OF2: Infrared Spectroscopic and Theoretical Investigations of the Group 3 Oxydifluoride OMF2 and Oxyfluoride OMF Molecules, JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 第 1 作者
(56) Infrared Spectra of Rh12C and Rh13C in Solid Neon and Solid Argon, Chemical Physics Letters, 2012,
(57) Infrared spectroscopic and theoretical studies of the OTiF2, OZrF2 and OHfF2 molecules with terminal oxo ligands, DALTON TRANSACTIONS, 2012, 第 1 作者
(58) Formation of Metal Oxyfluorides from Specific Metal Reactions with Oxygen Difluoride: Infrared Spectroscopic and Theoretical Investigations of the OScF2 Radical and OScF with Terminal Single and Triple Sc?O Bonds, CHEMISTRY-A EUROPEAN JOURNAL, 2012, 第 1 作者
(59) Infrared Spectroscopic and Theoretical Investigations of the OUF2 and OThF2 Molecules with Triple Oxo Bond Character, INORGANIC CHEMISTRY, 2012, 第 1 作者
(60) Reactions of Late Lanthanide Metal Atoms and Methanol in Solid Argon: A Matrix Isolation Infrared Spectroscopic and Theoretical Study, JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 第 1 作者
(61) Matrix infrared spectroscopic and density functional theoretical investigations on thorium and uranium atom reactions with dimethyl ether, DALTON TRANSACTIONS, 2011, 第 1 作者
(62) Is rhodium tetroxide in the formal oxidation state VIII stable? a quantum chemical and matrix isolation investigation of rhodium oxides, THEORETICAL CHEMISTRY ACCOUNTS, 2011, 第 1 作者
(63) Infrared Spectrum of the CH3OCH2 Radical in Solid Argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 第 1 作者
(64) Matrix Infrared Spectra and Theoretical Studies of Thorium Oxide Species: ThOx, and Th2Oy, JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 第 2 作者
(65) Matrix Infrared Spectroscopic and Theoretical Investigations of Uranium Atom and Methanol Reaction Products, INORGANIC CHEMISTRY, 2011, 第 1 作者
(66) Matrix Infrared Spectroscopic and Theoretical Studies on the Reactions of Scandium, Yttrium, and Lanthanide Metal Atoms with Dimethyl Ether, JOURNAL OF PHYSICAL CHEMISTRY A, 2011,
(67) Infrared Spectra and Quantum Chemical Calculations of the Bridge-Bonded HC(F)LnF(2) (Ln = La-Lu) Complexes, ORGANOMETALLICS, 2011, 第 1 作者
(68) Water Adsorption on Platinum Dioxide and Dioxygen Complex: Matrix Isolation Infrared Spectroscopic and Theoretical Study of Three PtO2-H2O Complexes, CHEMPHYSCHEM, 2010, 第 1 作者
(69) Infrared spectra of zinc and cadmium dioxide anions in solid neon, CHEMICAL PHYSICS LETTERS, 2010, 第 1 作者
(70) Infrared Spectra of Transition-Metal Dioxide Anions: MO2- (M = Rh, Ir, Pt, Au) in Solid Argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 第 1 作者
(71) Formation and characterization of the CuO5, CuO4 and CuO4- complexes in solid argon, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 第 1 作者
(72) Spectroscopic and Theoretical Studies of Transition Metal Oxides and Dioxygen Complexes, CHEMICAL REVIEWS, 2009, 第 1 作者
(73) Spectroscopic Characterization of a Copper(III) Trisuperoxide Complex Bearing Both Side-On and End-On Ligands, JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 第 1 作者
(74) Formation and Characterization of the Iridium Tetroxide Molecule with Iridium in the Oxidation State plus VIII, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 第 1 作者
(75) Infrared Spectra of Oxygen-Rich Yttrium and Lanthanum Dioxygen/Ozonide Complexes in Solid Argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 第 1 作者
(76) Formation and Characterization of ZrO3 and HfO3 Molecules in Solid Argon, Formation and Characterization of ZrO3 and HfO3 Molecules in Solid Argon, CHINESE JOURNAL OF CHEMICAL PHYSICS, 2009, 第 1 作者
(77) Is the FeO2- Anion Bent or Linear?, JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 第 2 作者
(78) Matrix infrared spectra and density functional calculations of TiO3 and TiO5 in solid argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 第 1 作者
(79) Matrix isolation infrared spectroscopic and theoretical study of the hydrolysis of boron dioxide in solid argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 第 1 作者
(80) Formation and Characterization of Two FeO3 Isomers in Solid Argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 第 1 作者
(81) Formation and characterization of mononuclear and dinuclear manganese oxide-dioxygen complexes in solid argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 第 1 作者
(82) Formation and characterization of the tetranuclear scandium nitride: Sc4N4, JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 第 1 作者
(83) Formation and characterization of the photochemically interconvertible side-on and end-on bonded dioxygen-iron dioxide complexes in solid argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2007,
(84) Formation and characterization of the oxygen-rich hafnium Dioxygen complexes: OHf(eta(2)-O-2)(eta(2)-O-3), Hf(eta(2)-O-2)(3), and Hf(eta(2)-O-2)(4), JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 第 1 作者
(85) Matrix isolation infrared spectroscopic and theoretical study of group IV metal oxide clusters: M2O2 and M2O4, JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 第 1 作者
(86) Interconvertible side-on- and end-on-bonded oxo-superoxo titanium ozonide complexes, JOURNAL OF PHYSICAL CHEMISTRY A, 2007,
(87) Formation and characterization of the oxygen-rich scandium oxide/dioxygen complexes ScOn (n=4, 6, 8) in solid argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 第 1 作者
(88) Remarkable dinitrogen activation and cleavage by the Gd dimer: From dinitrogen complexes to ring and cage nitrides, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007,
科研活動
科研項目
( 1 ) 青年人才項目, 主持, 國家級, 2016-10--2020-07
( 2 ) 燃料鹽中錒系元素化合物的結構,性質與反應, 主持, 市地級, 2015-03--2020-12
( 3 ) 錒系金屬氟化物紅外光譜研究, 主持, 國家級, 2016-09--2018-08
( 4 ) 釷鏷鈾-中性二醯胺配合物的氣相結構與反應研究, 主持, 國家級, 2018-01--2021-12
( 5 ) 錒系和裂變產物氟化物與含氧分子反應的紅外光譜和理論計算研究, 主持, 省級, 2020-07--2023-06
( 6 ) 釷基燃料鹽的物化性質和轉化規律研究, 主持, 省級, 2021-12--2026-11
參與會議
(1)Mass spectrometric studies on the diamide complexes of lanthanide and actinide ions 2021-12-20
(2)釷鈾循環化學研究進展 第五屆全國核化學與放射化學青年學術研討會 2019-07-18
(3)錒系配位化合物的質譜和紅外光譜研究 第三屆錒系物理與化學學術交流會 2018-07-20
(4)金屬氟氧化物的紅外光譜研究 第4次環境放射化學戰略研討會 2017-10-26
(5)Recent progress on the development of pyroprocessing techniques for TMSR in SINAP 2017-04-02
(6)Recent progress on the development of pyroprocessing techniques for TMSR in SINAP 2016-07-19
(7)質譜和紅外光譜方法在錒系化學 第三屆全國核化學與放射化學青年學術研討會 龔昱 2015-11-29
(8)質譜方法在錒系化學中的套用 第六屆全國環境放射化學學術研討會 龔昱 2015-09-02
(9)質譜方法在錒系化學中的套用 第十四屆全國套用化學年會 龔昱 2015-07-23