《金屬-甲酸磁性/介電功能MOF材料的研究》是王哲明為項目負責人，北京大學為依託單位的面上項目。
基本介紹
- 中文名：金屬-甲酸磁性/介電功能MOF材料的研究
- 項目類別 ：面上項目
- 項目負責人：王哲明
- 依託單位 ：北京大學
科研成果,項目摘要,
科研成果
序號 | 標題 | 類型 | 作者 |
|---|---|---|---|
1 | An A-Site Mixed-Ammonium Solid Solution Perovskite Series of [(NH2NH3)x(CH3NH3)1-x][Mn(HCOO)3](x=1.00–0.67) | 期刊論文 | Ran Shang|Bing-Wu Wang|Zhe-Ming Wang|Song Gao| |
2 | A New Series ofChiral Metal Formate Frameworks of [HONH3][MII(HCOO)3](M = Mn, Co, Ni, Zn, and Mg): Synthesis, Structures, and Properties | 期刊論文 | Ran Shang|Ke-Li Hu|Zhe-Ming Wang|Song Gao| |
3 | Zinc-Diluted MagneticMetal Formate Perovskites: Synthesis, Structures, and Magnetism of [CH3NH3][MnxZn1-x(HCOO)3](x=0-1) | 期刊論文 | Ran Shang|Xuan Sun|Zhe-Ming Wang|Song Gao| |
4 | Phase Transitions,Prominent Dielectric Anomalies, and Negative Thermal Expansion in Three HighThermally Stable Ammonium Magnesium-Formate Frameworks | 期刊論文 | Ran Shang|Guan-Cheng Xu|Zhe-Ming Wang|Song Gao| |
5 | Static field inducedmagnetic relaxations in dinuclear lanthanide compounds of [phen2Ln2(HCOO)4(HCOO)2-2x(NO3)2x](1, Ln = Gd and x=0.52; 2, Ln = Er and x=0.90; phen=1,10-phenanthroline) | 期刊論文 | Bin Liu|Bing-Wu Wang|Zhe-Ming Wang|Song Gao| |
6 | Static field induced magnetic relaxations in dinuclear lanthanide compounds of [phen(2)Ln(2)(HCOO)(4)(HCOO)(2-2x) (NO3)(2x) ] (1, Ln = Gd and x=0.52; 2, Ln = Er and x=0.90; phen=1,10-phenanthroline) | 期刊論文 | Liu Bin|Wang BingWu|Wang ZheMing|Gao Song| |
7 | [(C2H5)4N][U2O4(HCOO)5],an Ammonium Uranyl Formate Framework Showing Para- to Ferro-ElectricTransition: Synthesis, Structures, and Properties | 期刊論文 | Sa Chen|Chun-Li Liu|Zhe-Ming Wang|Song Gao| |
8 | [NH2NH3][M(HCOO)3](M = Mn2+, Zn2+, Co2+ and Mg2+):Structural Phase Transitions, Prominent Dielectric Anomalies and Negative ThermalExpansion, and Magnetic Ordering | 期刊論文 | Ran Shang|Ke-Li Hu|Zhe-Ming Wang|Song Gao| |
9 | A Copper-FormateFramework Showing Simple to Helical Antiferroelectric Transition with ProminentDielectric Anomalies and Anisotropic Thermal Expansion, and Antiferromagnetism | 期刊論文 | Ran Shang|Sa Chen|Zhe-Ming Wang|Song Gao| |
10 | A New Series of Chiral Metal Formate Frameworks of [HONH3][MII(HCOO)3] (M = Mn, Co, Ni, Zn, and Mg): Synthesis, Structures, and Properties | 期刊論文 | Shang Ran|Hu Ke-Li|Wang Zhe-Ming|Gao Song| |
11 | Zinc-Diluted Magnetic Metal Formate Perovskites: Synthesis, Structures, and Magnetism of [CH3NH3][MnxZn1-x(HCOO)3] (x=0-1) | 期刊論文 | Shang Ran|Sun Xuan|Wang Zhe-Ming|Gao Song| |
12 | Temperature-Induced Irreversible Phase Transition FromPerovskite to Diamond But Pressure-Driven Back-Transition in an Ammonium CopperFormate | 期刊論文 | Sa Chen|Bing-Wu Wang|Zhe-Ming Wang|Song Gao| |
13 | A 36-Fold MultipleUnit Cell and Switchable Anisotropic Dielectric Responses in an Ammonium MgFormate Framework | 期刊論文 | Ran Shang|Zhe-Ming Wang|Song Gao| |
14 | HierarchicalCobalt-Formate Framework Series with (412·63)(49·66)n (n = 1-3) Topologies Exhibiting Slow Dielectric Relaxation and WeakFerromagnetism | 期刊論文 | Bing-Wu Wang|Mohamedally Kurmoo|Zhe-Ming Wang|Song Gao| |
項目摘要
金屬-甲酸功能MOF材料（MOF = Metal-Organic Frameworks：金屬-有機骨架）的研究一直被忽視。甲酸根小的空間阻礙、獨特的配位特性和有效傳遞磁相互作用、形成氫鍵的特點，十分利於構築具有新穎有趣的結構、磁性、介電/鐵電性質和功能的MOF材料。本項目將系統深入地開展金屬-甲酸磁性、介電/鐵電功能MOF材料的研究。將採用金屬離子（過渡金屬和稀土）、甲酸根、合適的陽離子模板（質子化有機胺、鹼金屬離子等）、以及有目的和仔細選擇的共配體等構築塊，設計、組裝和製備具有磁性、介電/鐵電等功能的金屬-甲酸MOF材料，探索和研究它們的製備、結構、性質和功能。
